The commercial application results showed that the polymetallic reforming catalysts PRT exhibited high activity, good selectivity and stability. The performance of said catalysts could be restored completely through r...The commercial application results showed that the polymetallic reforming catalysts PRT exhibited high activity, good selectivity and stability. The performance of said catalysts could be restored completely through regeneration. After long period of operation, the activity of said catalysts still exhibited good sensitivity to temperature rise. Compared with the PR series catalysts, the PRT series catalysts had obviously better stability and lower coking rate.展开更多
With the increasing use of metal foams in various engineering applications, investigation of their dynamic behaviour under varying strain rate is necessary. Closed cell aluminium fly ash foam developed through liquid ...With the increasing use of metal foams in various engineering applications, investigation of their dynamic behaviour under varying strain rate is necessary. Closed cell aluminium fly ash foam developed through liquid metallurgy route was investigated for its stress--strain behaviour at different strain rates ranging from 700 s^-1 to 1950 s^-1. The numerical model of split Hopkinson pressure bar (SHPB) was simulated using commercially available finite element code Abaqus/Explicit. Validation of numerical simulation was carried out using available experimental and numerical results. Full scale stress--strain curves wez'e developed for various strain rates to study the effect of strain rate on compressive strength and energy absorption. The results showed that the closed cell aluminium fly ash foam is sensitive to strain rate.展开更多
There were many contradictory evaluation criteria to select next-hop in the delay-disruption tolerance networks(DTN).To solve this problem,an attribute hierarchical model was proposed,in which the predefined criteria ...There were many contradictory evaluation criteria to select next-hop in the delay-disruption tolerance networks(DTN).To solve this problem,an attribute hierarchical model was proposed,in which the predefined criteria were summarized as static identity attributes,forwarding desire attributes and delivery capability attributes(IDC).Based on this model,a novel multi-attributes congestion aware routing(MACAR) scheme with uncertain information for next-hop selection was presented,by adopting an decision theory to aggregate attributes with belief structure and computing partial ordering relations.The simulation results show that MACAR presents higher successful delivery rate,lower average delay and effectively alleviate congestion.展开更多
AIM: To investigate association of the 2Gor1Gsingle nudeotide polymorphism (SNP) in matrix metalloproteinase 1 (MMP1) promoter with susceptibility to esophageal squam-ous cell carcinoma (ESCC) and gastric cardiac aden...AIM: To investigate association of the 2Gor1Gsingle nudeotide polymorphism (SNP) in matrix metalloproteinase 1 (MMP1) promoter with susceptibility to esophageal squam-ous cell carcinoma (ESCC) and gastric cardiac adenocarcinoma (GCA) in a population of North China. METHODS: MMP1 promoter SNP was genotyped by polymerase-chain reaction (PCR)-restriction fragment length polymorphism (RFLP) analysis in 417 cancer patients (234 ESCC and 183 GCA) and 350 healthy controls. RESULTS: The genotype frequencies of the MMP1 promoter SNP in healthy controls were 55.4% (2G/2G), 30% (1G/2G) and 14.6% (1G/1G), respectively. The genotype and allelotype distribution in ESCC and GCA patients was not significantly different from that in healthy controls (all lvalues were above 0.05). Compared with the 1G/1Ggenotype, neither the 2G/2Gnor in combination with the 1G/2G genotype significantly modified the risk of developing ESCC and GCA, the adjusted odds ratio was 1.28 (95%CI = 0.78-2.09), 1.23 (95%CI = 0.38-2.05) in ESCC and 1.39 (95%CI = 0.80-2.41), 1.34 (95%CI = 0.74-2.40) in GCA, respectively. When stratified by smoking status and family history of upper gastrointestinal cancer, the 2G/2Ggenotype alone or in combination with the 1G/2G genotype also did not show any significant influence on the risk of ESCC and GCA development. In addition, influence of the MMP1 SNP on lymphatic metastasis in ESCC and GCA was also not obs-erved. CONCLUSION: The 2Gor 1GSNP in the MMP1 promoter might not modify the risk of ESCC and GCA development and might not be used as a stratification marker to predict the potential of lymphatic metastasis in these two tumor types.展开更多
Electric potentials were generated from carbon nanotubes immersed in flowing vapors. The nanomaterials used in this study were multiwall carbon nanotubes(MWCNTs) and silver nanopowders. These nanomaterials were disp...Electric potentials were generated from carbon nanotubes immersed in flowing vapors. The nanomaterials used in this study were multiwall carbon nanotubes(MWCNTs) and silver nanopowders. These nanomaterials were dispersed and densely packed on a substrate and immersed in flowing vapors generated from solution such as water, ethanol and KCI. The potentials generated from these samples were measured by a voltmeter. Experimental results showed that the electric potentials were produced at the surface of the MWCNT samlpes, and strongly dependent on the pretreatment of MWCNT and properties of the flowing vapors. The mechanism of vapor-flow induced potentials may be ascribed to ions in the flowing vapors. This property of MWCNTs can advantage their application to nanoscale sensors, detectors and power cells.展开更多
Ruthenium(Ru)serves as a promising catalyst for ammonia synthesis via the Haber-Bosch process,identification of the structure sensitivity to improve the activity of Ru is important but not fully explored yet.We presen...Ruthenium(Ru)serves as a promising catalyst for ammonia synthesis via the Haber-Bosch process,identification of the structure sensitivity to improve the activity of Ru is important but not fully explored yet.We present here density functional theory calculations combined with microkinetic simulations on nitrogen molecule activation,a crucial step in ammonia synthesis,over a variety of hexagonal close-packed(hcp)and face-center cubic(fcc)Ru facets.Hcp{2130}facet exhibits the highest activity toward N_(2) dissociation in hcp Ru,followed by the(0001)monatomic step sites.The other hcp Ru facets have N_(2) dissociation rates at least three orders lower.Fcc{211}facet shows the best performance for N_(2) activation in fcc Ru,followed by{311},which indicates stepped surfaces make great contributions to the overall reactivity.Although hcp Ru{2130}facet and(0001)monatomic step sites have lower or comparable activation barriers compared with fcc Ru{211}facet,fcc Ru is proposed to be more active than hcp Ru for N_(2) conversion due to the exposure of the more favorable active sites over step surfaces in fcc Ru.This work provides new insights into the crystal structure sensitivity of N_(2) activation for mechanistic understanding and rational design of ammonia synthesis over Ru catalysts.展开更多
In response to many multi-attribute decision-making(MADM)problems involved in chemical processes such as controller tuning,which suffer human's subjective preferential nature in human–computer interactions,a nove...In response to many multi-attribute decision-making(MADM)problems involved in chemical processes such as controller tuning,which suffer human's subjective preferential nature in human–computer interactions,a novel affective computing and preferential evolutionary solution is proposed to adapt human–computer interaction mechanism.Based on the stimulating response mechanism,an improved affective computing model is introduced to quantify decision maker's preference in selections of interactive evolutionary computing.In addition,the mathematical relationship between affective space and decision maker's preferences is constructed.Subsequently,a human–computer interactive preferential evolutionary algorithm for MADM problems is proposed,which deals with attribute weights and optimal solutions based on preferential evolution metrics.To exemplify applications of the proposed methods,some test functions and,emphatically,controller tuning issues associated with a chemical process are investigated,giving satisfactory results.展开更多
Metal-free indoline dyes for dye-sensitized solar cells were studied by employing quantum chemistry methods. Comparative study of the properties of both ground and excited states of metal-free indoline dyes for dye-se...Metal-free indoline dyes for dye-sensitized solar cells were studied by employing quantum chemistry methods. Comparative study of the properties of both ground and excited states of metal-free indoline dyes for dye-sensitized solar cells revealed: (i) as the number of rhodanine rings increases, the energy difference between HOMO and LUMO decreases and there is a red shift in the absorption spectrum with the binding energy increased, and the transition dipole moment decreased; (ii) Based on an analysis of charge differential density, we observed that the charge and energy are transfered from the phenylethenyl to the indoline and rhodanine rings; (iii) The electron-hole coherences are mainly on the indoline and rhodanine rings, and the exciton sizes are 30 and 40 atoms for indoline dyes with one and two rhodanline rings, respectively. These results serve as a good example of computer-aided design in metal-free indoline dyes for dye-sensitized solar cells.展开更多
The performance of the two newly developed bimetallic catalysts based on the precursor, Mo/Al_2O_3, was compared for reverse water gas shift(RWGS) reaction. The structures of the precursor and the catalysts were studi...The performance of the two newly developed bimetallic catalysts based on the precursor, Mo/Al_2O_3, was compared for reverse water gas shift(RWGS) reaction. The structures of the precursor and the catalysts were studied using X-ray diffraction(XRD), Brunauer–Emmett–Teller(BET) analysis, inductively coupled plasma-atomic emission spectrometry(ICP-AES), CO chemisorption, temperature programmed reduction of hydrogen(H_2-TPR) and scanning electron microscopy(SEM) techniques. The activity of Fe-Mo and Co-Mo catalysts was compared in a fixed bed reactor at different temperatures. It is shown that the Co-Mo catalyst has higher CO_2 conversion at all temperature level. The time-on-stream(TOS) analysis of the activity of catalysts for the RWGS reaction was carried out over a continuous period of 60h for both catalysts. The Fe-Mo/Al_2O_3 catalyst exhibits good stability within a period of 60h, however, the Co-Mo/Al_2O_3 is gradually deactivated after 50h of reaction time. Existence of(Fe_2(MoO4_))_3 phase in Fe-Mo/Al_2O_3 catalyst makes this catalyst more stable for RWGS reaction.展开更多
Liquid metals(LMs)are potential inorganic materials which could be applied in flexible and deformable electronics owing to their fluidity,low viscosity,high metallic conductivity,and low toxicity.However,recently repo...Liquid metals(LMs)are potential inorganic materials which could be applied in flexible and deformable electronics owing to their fluidity,low viscosity,high metallic conductivity,and low toxicity.However,recently reported sensing devices based on LMs required complex processes with high cost.Herein,a flexible three-dimensional(3 D)conductive network was prepared by coating LM droplets onto an electrospun thermoplastic polyurethane(TPU)fiber film.The LM is suspended between the TPU fibers and self-coalesces into a vertically buckled and laterally mesh-like structure,which provides good biocompatibility,conductivity,and stretchability simultaneously.The LM-TPU composite-filmbased flexible device demonstrates a multitude of desired features,such as a widely workable stretching range(0%-200%),sufficient sensitivity under stretching strain(gauge factor(GF)of 0.2 at 200%strain),and outstanding stability and durability(9000 cycles).In vitro biocompatibility experiments show that the LM-TPU composite film directly attached to the skin has excellent biocompatibility.Such strain sensorbased integrated monitoring systems could monitor human body motions in real time,such as muscle movement and joint motion,revealing application prospects in healthcare and human-machine interfacing.展开更多
The interval numbers are used to types and observation of sensors, a new fusion represent the characteristic values of object method for multi-sensor object recognition is proposed from the viewpoint of decision makin...The interval numbers are used to types and observation of sensors, a new fusion represent the characteristic values of object method for multi-sensor object recognition is proposed from the viewpoint of decision making theory. The method defines the distance matrix and grey association matrix between all object types and unknown object. After solving the optimization problem of maximizing the standard deviations for all attributes, the weights of the attributes are obtained. Thus, the result of recognition for the unknown object is given by the grey association degree. This method avoids the subjectivity of selecting attributes weights. It is straightforward and can be performed on computer easily. The simulated example demonstrates the feasibility and effectiveness of the proposed method.展开更多
文摘The commercial application results showed that the polymetallic reforming catalysts PRT exhibited high activity, good selectivity and stability. The performance of said catalysts could be restored completely through regeneration. After long period of operation, the activity of said catalysts still exhibited good sensitivity to temperature rise. Compared with the PR series catalysts, the PRT series catalysts had obviously better stability and lower coking rate.
文摘With the increasing use of metal foams in various engineering applications, investigation of their dynamic behaviour under varying strain rate is necessary. Closed cell aluminium fly ash foam developed through liquid metallurgy route was investigated for its stress--strain behaviour at different strain rates ranging from 700 s^-1 to 1950 s^-1. The numerical model of split Hopkinson pressure bar (SHPB) was simulated using commercially available finite element code Abaqus/Explicit. Validation of numerical simulation was carried out using available experimental and numerical results. Full scale stress--strain curves wez'e developed for various strain rates to study the effect of strain rate on compressive strength and energy absorption. The results showed that the closed cell aluminium fly ash foam is sensitive to strain rate.
基金Project(60973127) supported by the National Natural Science Foundation of ChinaProject(09JJ3123) supported by the Natural Science Foundation of Hunan Province,China
文摘There were many contradictory evaluation criteria to select next-hop in the delay-disruption tolerance networks(DTN).To solve this problem,an attribute hierarchical model was proposed,in which the predefined criteria were summarized as static identity attributes,forwarding desire attributes and delivery capability attributes(IDC).Based on this model,a novel multi-attributes congestion aware routing(MACAR) scheme with uncertain information for next-hop selection was presented,by adopting an decision theory to aggregate attributes with belief structure and computing partial ordering relations.The simulation results show that MACAR presents higher successful delivery rate,lower average delay and effectively alleviate congestion.
基金Supported by the Grant from the Natural Science Foundation of China, No. 30371591Grant from Natural Science Foundation of Hebei Province, China, No. C200400062
文摘AIM: To investigate association of the 2Gor1Gsingle nudeotide polymorphism (SNP) in matrix metalloproteinase 1 (MMP1) promoter with susceptibility to esophageal squam-ous cell carcinoma (ESCC) and gastric cardiac adenocarcinoma (GCA) in a population of North China. METHODS: MMP1 promoter SNP was genotyped by polymerase-chain reaction (PCR)-restriction fragment length polymorphism (RFLP) analysis in 417 cancer patients (234 ESCC and 183 GCA) and 350 healthy controls. RESULTS: The genotype frequencies of the MMP1 promoter SNP in healthy controls were 55.4% (2G/2G), 30% (1G/2G) and 14.6% (1G/1G), respectively. The genotype and allelotype distribution in ESCC and GCA patients was not significantly different from that in healthy controls (all lvalues were above 0.05). Compared with the 1G/1Ggenotype, neither the 2G/2Gnor in combination with the 1G/2G genotype significantly modified the risk of developing ESCC and GCA, the adjusted odds ratio was 1.28 (95%CI = 0.78-2.09), 1.23 (95%CI = 0.38-2.05) in ESCC and 1.39 (95%CI = 0.80-2.41), 1.34 (95%CI = 0.74-2.40) in GCA, respectively. When stratified by smoking status and family history of upper gastrointestinal cancer, the 2G/2Ggenotype alone or in combination with the 1G/2G genotype also did not show any significant influence on the risk of ESCC and GCA development. In addition, influence of the MMP1 SNP on lymphatic metastasis in ESCC and GCA was also not obs-erved. CONCLUSION: The 2Gor 1GSNP in the MMP1 promoter might not modify the risk of ESCC and GCA development and might not be used as a stratification marker to predict the potential of lymphatic metastasis in these two tumor types.
基金Funded by the Science Foundation from the Scientific Committee of Chongqing ( No.CSTC2005BB4200).
文摘Electric potentials were generated from carbon nanotubes immersed in flowing vapors. The nanomaterials used in this study were multiwall carbon nanotubes(MWCNTs) and silver nanopowders. These nanomaterials were dispersed and densely packed on a substrate and immersed in flowing vapors generated from solution such as water, ethanol and KCI. The potentials generated from these samples were measured by a voltmeter. Experimental results showed that the electric potentials were produced at the surface of the MWCNT samlpes, and strongly dependent on the pretreatment of MWCNT and properties of the flowing vapors. The mechanism of vapor-flow induced potentials may be ascribed to ions in the flowing vapors. This property of MWCNTs can advantage their application to nanoscale sensors, detectors and power cells.
基金supported by the National Natural Science Foundation of China(No.91645202 and No.91945302)the Key Technologies R&D Program of China(2017YFB0602205 and 2018YFA0208603)+1 种基金the Chinese Academy of Sciences Key Project(QYZDJSSW-SLH054)the Super Computing Center of USTC is gratefully acknowledged。
文摘Ruthenium(Ru)serves as a promising catalyst for ammonia synthesis via the Haber-Bosch process,identification of the structure sensitivity to improve the activity of Ru is important but not fully explored yet.We present here density functional theory calculations combined with microkinetic simulations on nitrogen molecule activation,a crucial step in ammonia synthesis,over a variety of hexagonal close-packed(hcp)and face-center cubic(fcc)Ru facets.Hcp{2130}facet exhibits the highest activity toward N_(2) dissociation in hcp Ru,followed by the(0001)monatomic step sites.The other hcp Ru facets have N_(2) dissociation rates at least three orders lower.Fcc{211}facet shows the best performance for N_(2) activation in fcc Ru,followed by{311},which indicates stepped surfaces make great contributions to the overall reactivity.Although hcp Ru{2130}facet and(0001)monatomic step sites have lower or comparable activation barriers compared with fcc Ru{211}facet,fcc Ru is proposed to be more active than hcp Ru for N_(2) conversion due to the exposure of the more favorable active sites over step surfaces in fcc Ru.This work provides new insights into the crystal structure sensitivity of N_(2) activation for mechanistic understanding and rational design of ammonia synthesis over Ru catalysts.
基金Supported by the Fundamental Research Funds for the Central Universities(ZY1347and YS1404)
文摘In response to many multi-attribute decision-making(MADM)problems involved in chemical processes such as controller tuning,which suffer human's subjective preferential nature in human–computer interactions,a novel affective computing and preferential evolutionary solution is proposed to adapt human–computer interaction mechanism.Based on the stimulating response mechanism,an improved affective computing model is introduced to quantify decision maker's preference in selections of interactive evolutionary computing.In addition,the mathematical relationship between affective space and decision maker's preferences is constructed.Subsequently,a human–computer interactive preferential evolutionary algorithm for MADM problems is proposed,which deals with attribute weights and optimal solutions based on preferential evolution metrics.To exemplify applications of the proposed methods,some test functions and,emphatically,controller tuning issues associated with a chemical process are investigated,giving satisfactory results.
基金ACKN0WLEDGMENT This work was supported by the National Nature Science Foundation of China (No.10374040).
文摘Metal-free indoline dyes for dye-sensitized solar cells were studied by employing quantum chemistry methods. Comparative study of the properties of both ground and excited states of metal-free indoline dyes for dye-sensitized solar cells revealed: (i) as the number of rhodanine rings increases, the energy difference between HOMO and LUMO decreases and there is a red shift in the absorption spectrum with the binding energy increased, and the transition dipole moment decreased; (ii) Based on an analysis of charge differential density, we observed that the charge and energy are transfered from the phenylethenyl to the indoline and rhodanine rings; (iii) The electron-hole coherences are mainly on the indoline and rhodanine rings, and the exciton sizes are 30 and 40 atoms for indoline dyes with one and two rhodanline rings, respectively. These results serve as a good example of computer-aided design in metal-free indoline dyes for dye-sensitized solar cells.
基金the Iranian Nano Technology Initiative Council and the Petroleum University of Technology for financial support
文摘The performance of the two newly developed bimetallic catalysts based on the precursor, Mo/Al_2O_3, was compared for reverse water gas shift(RWGS) reaction. The structures of the precursor and the catalysts were studied using X-ray diffraction(XRD), Brunauer–Emmett–Teller(BET) analysis, inductively coupled plasma-atomic emission spectrometry(ICP-AES), CO chemisorption, temperature programmed reduction of hydrogen(H_2-TPR) and scanning electron microscopy(SEM) techniques. The activity of Fe-Mo and Co-Mo catalysts was compared in a fixed bed reactor at different temperatures. It is shown that the Co-Mo catalyst has higher CO_2 conversion at all temperature level. The time-on-stream(TOS) analysis of the activity of catalysts for the RWGS reaction was carried out over a continuous period of 60h for both catalysts. The Fe-Mo/Al_2O_3 catalyst exhibits good stability within a period of 60h, however, the Co-Mo/Al_2O_3 is gradually deactivated after 50h of reaction time. Existence of(Fe_2(MoO4_))_3 phase in Fe-Mo/Al_2O_3 catalyst makes this catalyst more stable for RWGS reaction.
基金supported by the National Natural Science Foundation of China(61625404,61888102,and 62174152)Foshan Innovative and Entrepreneurial Research Team Program(2018IT100031)。
文摘Liquid metals(LMs)are potential inorganic materials which could be applied in flexible and deformable electronics owing to their fluidity,low viscosity,high metallic conductivity,and low toxicity.However,recently reported sensing devices based on LMs required complex processes with high cost.Herein,a flexible three-dimensional(3 D)conductive network was prepared by coating LM droplets onto an electrospun thermoplastic polyurethane(TPU)fiber film.The LM is suspended between the TPU fibers and self-coalesces into a vertically buckled and laterally mesh-like structure,which provides good biocompatibility,conductivity,and stretchability simultaneously.The LM-TPU composite-filmbased flexible device demonstrates a multitude of desired features,such as a widely workable stretching range(0%-200%),sufficient sensitivity under stretching strain(gauge factor(GF)of 0.2 at 200%strain),and outstanding stability and durability(9000 cycles).In vitro biocompatibility experiments show that the LM-TPU composite film directly attached to the skin has excellent biocompatibility.Such strain sensorbased integrated monitoring systems could monitor human body motions in real time,such as muscle movement and joint motion,revealing application prospects in healthcare and human-machine interfacing.
基金This project is supported by National Natural Science Foundation of China (10626029) Jiangxi Province Natural Science Foundation of China (0611082) Science and Technology Project of Jiangxi province educational department in China (GJJ08350)
文摘The interval numbers are used to types and observation of sensors, a new fusion represent the characteristic values of object method for multi-sensor object recognition is proposed from the viewpoint of decision making theory. The method defines the distance matrix and grey association matrix between all object types and unknown object. After solving the optimization problem of maximizing the standard deviations for all attributes, the weights of the attributes are obtained. Thus, the result of recognition for the unknown object is given by the grey association degree. This method avoids the subjectivity of selecting attributes weights. It is straightforward and can be performed on computer easily. The simulated example demonstrates the feasibility and effectiveness of the proposed method.