云南巍山小纪罗异常区铜多金属矿找矿思路

小纪罗异常反映低温热液活动元素的主异常。已发现2个铜矿点。讨论异常区成矿围岩条件、矿化类型,分析矿化与构造、岩体之间的关系,为下一步铜多金属找矿工作提供思路。

金属矿产资源的深部找矿

随着我国社会经济的飞速发展,社会各个领域对于不同矿产资源的需求量越来越大,其中金属矿为典型代表,为满足社会对于金属矿的多层次需求,应更好、更安全的勘测隐藏矿床,根据成矿的方式与地质特征,利用先进的找矿技术,对我国金属矿产资源进行找矿,不仅仅标志着金属矿产资源进入了一个比较成熟的阶段,还预示着这是一个伟大的转折点。对其进行勘探不仅需要理论上具有新的方法,在技术方面也需要进行创造突破。

甘肃某复杂难选多金属氧化铅银金矿选矿工艺研究

该矿为多金属铅银矿,为典型的高氧化率多金属矿氧化矿。通过对矿石的工艺矿物研究查明矿物的结构、构造及矿物的相嵌关系和金、银赋存状态,针对该矿石主金属矿物铅氧化率较高、金银矿物嵌布粒度较细、矿物之间共生关系复杂等性质特点,进行选矿试验研究,确定适合该矿石特点工艺流程及药剂制度,取得较好的选矿指标。

矿属洗煤厂市场化运营的经济效益分析

山西方山金晖瑞隆煤业有限公司为了在低迷的煤炭形势下取得发展,以瑞隆矿洗煤厂的市场化托管运营模式为例进行分析,这种运营模式使得选煤厂取得客观经济效益,使瑞隆能够集中精力干煤炭主业,促进企业又好又快发展。

漳平市境内省地属厂矿污染调查及防治对策

通过对漳平市多年来环境质量变化趋势及境内省地属厂矿排污状况作比较分析,指出要控制该市大气及九龙江上游水质进一步恶化,首先应当解决好省地属厂矿的污染问题,并提出解决省地属厂矿污染问题的对策及建议。

矿业项目价值评估及敏感性分析

为了更好地实现我国的"走出去"战略目标,本文从矿业项目经济评价和敏感性分析方面着手,以折现现金流法(DCF)为基础,实例设计矿业项目经济评价模型,立体展现企业如何评估矿业项目当前价值,并且具体分析各参数的变化如何对项目产生影响及其敏感性,以解决矿企降低投资风险,提高国际竞争力的问题。作者在实际与国外矿企交流、谈判和合作过程中,发现他们会变换项目评价所涉及的参数,这些微小的变换却能造成结果的迥然不同,也是我国矿企与国际接轨的关键。因此,熟练掌握与运用价值评估模型是我们所欠缺的,培养和壮大结构合理的高水平人才队伍是实现我国"走出去"战略目标所应解决的重要环节。

Mechanism,prevention,and control of mining-induced dynamic disasters in underground metal mines in China:Challenges and solutions

Metal mineral resources play an indispensable role in the development of the national economy.Dynamic disasters in underground metal mines seriously threaten mining safety,which are major scientific and technological problems to be solved urgently.In this article,the occurrence status and grand challenges of some typical dynamic disasters involving roof falling,spalling,collapse,large deformation,rockburst,surface subsidence,and water inrush in metal mines in China are systematically presented,the characteristics of mining-induced dynamic disasters are analyzed,the examples of dynamic disasters occurring in some metal mines in China are summarized,the occurrence mechanism,monitoring and early warning methods,and prevention and control techniques of these disasters are highlighted,and some new opinions,suggestions,and solutions are proposed simultaneously.Moreover,some shortcomings in current disaster research are pointed out,and the direction of efforts to improve the prevention and control level of dynamic disasters in China’s metal mines in the future is prospected.The integration of forward-looking key innovative theories and technologies in the abovementioned aspects will greatly enhance the cognitive level of disaster prevention and mitigation in China’s metal mining industry and achieve a significant shift from passive disaster relief to active disaster prevention.

First-Principles Insights into Pt_(n)/ZnO(0001)Catalyst:Regulation of Metal-Support Interaction through Surface Polarity

Polar surfaces are prevalent in metal oxides,the interactions between surface species with polar surfaces are different from those with non-polar surfaces,a thorough understanding of the interactions is key to regulate the performance of heterogeneous catalysts.In this work,we delve into the interaction of Pt_(n)(n=1-4)with polar ZnO(0001)-Zn and ZnO(0001)-O,and the influence of the surface polarity on the electronic structures and reactivity of Pt_(n)by using density functional theory calculations.The results suggest distinct differences in electronic structures of two exposed terminations,leading to different interactions with Pt_(n).The interaction between Pt_(n)and two terminations not only stabilizes the surface and clusters through polar compensation,but also induces opposite charges on the cluster at two terminations.Remarkably,the Pearson correlation coefficient reveals the interdependency between the electronic states of Pt_(n)and its performance in terms of small molecule adsorption/activation.These observations demonstrate the crucial role of surface polarity in regulating the electronic states and catalytic performance of active sites,and offer a possible design principle for supported catalysts.

Bayes discriminant analysis method to identify risky of complicated goaf in mines and its application

A Bayes discriminant analysis method to identify the risky of complicated goaf in mines was presented. Nine factors influencing the stability of goaf risky, including uniaxial compressive strength of rock, elastic modulus of rock, rock quality designation （RQD）, area ratio of pillar, ratio of width to height of pillar, depth of ore body, volume of goaf, dip of ore body and area of goal, were selected as discriminant indexes in the stability analysis of goal. The actual data of 40 goals were used as training samples to establish a discriminant analysis model to identify the stability of goaf. The results show that this discriminant analysis model has high precision and misdiscriminant ratio is 0.025 in re-substitution process. The instability identification of a metal mine was distinguished by using this model and the identification result is identical with that of practical situation.

Ultimate pit optimization with ecological cost for open pit metal mines

The ecological costs of open pit metal mining are quantified, which include lost value of direct eco-services, lost value of indirect eco-services, prevention and restoration costs, and cost of carbon emission from energy consumption. These ecological costs are incorporated in an iterative ultimate pit optimization algorithm. A case study is presented to demonstrate the influence of ecological costs on pit design outcome. The results show that it is possible to internalize ecological costs in mine designs. The pit optimization outcome shifts considerably to the conservative side and the profitability decreases substantially when ecological costs are accounted for.

Mechanism of mechanical activation for spontaneous combustion of sulfide minerals

In order to uncover the intrinsic reasons for spontaneous combustion of sulfide minerals,representative samples were collected from typical metal mines to carry out the mechanical activation experiment.The structures and heat behaviors of activated samples were characterized by scanning electron microscopy（SEM）,X-ray diffraction（XRD） analysis,and simultaneous thermal analysis（STA）.It is found that the sulfide minerals after mechanical activation show many changes with increased specific surface areas,aggregation phenomenon,decreased diffraction peak intensity,broadened diffraction peak,declined initial temperatures of heat release and self-ignition points.A new theory for explaining the spontaneous combustion of sulfide minerals is put forward：the chemical reaction activity of sulfide minerals is heightened by all kinds of mechanical forces during the mining,and the spontaneous combustion takes place finally under proper environment.

Leaching of heavy metals from Dexing copper mine tailings pond

AThe wastewater source of 4# tailing pond in Dexing copper mine consists of alkaline flotation pulp and acid mine drainage （AMD） from the nearby opencast mine. Therefore, the heavy metals in tailing ore are very likely to be released due to acidification from AMD. The leaching behaviors ofZn, Cu, Fe and Mn in mine tailings from Dexing copper mine were investigated by a series of laboratory batch experiments. The effectcs ofpH, temperature, particle size and contact time on the leachability of such heavy metals were examined. It was evident that Zn, Cu, Fe and Mn were major heavy metals in the tailings while gangue minerals like quartz were major constituents in examined tailings. The tailing dissolution reaction was controlled by the acid, whose kinetics could be expressed according to the heterogeneous reaction models and explained by a shrinking core model with the surface chemical reaction as the rate-controlling step. The leachability of all metals examined depended on pH and contact time. The batch studies indicated that the maximum leaching ratios ofZn, Cu, Fe and Mn at pH 2.0 were 5.4%, 5.8%, l 1.1% and 34.1%, respectively. The dissolubility of all metals examined was positively correlated to the temperatures. The particle size would not change dissolution tendency of those heavy metals, but decrease the concentrations of leached heavy metals.

Ore-forming material of Dachang tin deposit in Guangxi, China:Lead isotope evidence

For revealing the ore sources of the Dachang tin?polymetallic ore deposit, the lead isotopes were analyzed systematically by using the single minerals of sulphides, including pyrite, pyrrhotite, sphalerite, and galena. Then, the mineral sources and their characteristics were discussed based on the classical lead isotope discriminating model. The results show that the lead isotope ratios of206Pb/204Pb,207Pb/204Pb, and208Pb/204Pb range from 17.478 to 18.638, 15.440 to 15.858, and 37.556 to 39.501, respectively. According to Zartman lead model, the ore lead contains the upper crust composition; however, the granite does not provide all ore leads, and other material sources exist. Obviously, the ore deposit belongs to the result of the combined effect of crust?mantle. The source rocks are characterized by a certain degree of similarity with the island arc material. Moreover, its distant origin in the upper and lower crusts may be related to the subduction island arc material or oceanic crust. The mantle-derived material may have a certain status in the source region. Meanwhile, based on the lead isotope three-dimensional topology projection vectors, the ore leads are concentrated in zoneA, which indicates the characteristics of Yangtze lead isotope province and a possible genetic relationship with Yangtze block.

Effect of pyrite, elemental sulfur and ferrous ions on EPS production by metal sulfide bioleaching microbes

Extracellular polymeric substances （EPS） produced by acidophilic bioleaching microorganisms play an important role in the production of acid mine drainage and metal sulfide bioleaching. EPS mediate the contact between microbial cells and growth substrates, having a pivotal role in organic film formation and bacterium-substratum interactions. The production and chemical composition of EPS produced by seven bioleaching strains grown with different substrates were studied. Analysis of the EPS extracted from these strains indicated that the EPS consisted of carbohydrates, proteins and galacturonic acid. The contents of EPS, carbohydrates, proteins and galacturonic acid of EPS were largely related to the kind of strain used and culture condition. The results show that EPS productions of microbes grown with pyrite were significantly higher than those of microbes grown with sulfur or FeSO4·7H2O. The highest EPS production of the seven acidiphilic strains was （159.43±3.93） mg/g, which was produced by Leptospirillum ferriphilum CBCBSUCSU208015 when cultivated with pyrite.

Optimization of copper extraction for bioleaching of complex Cu-polymetallic concentrate by moderate thermophiles

Effects of initial pH, temperature, liquid volume, rotation speed, galvanic interaction （pyrite ratio） and pulp density on bioleaching of complex Cu-polymetallic concentrate were investigated. The results indicated that the copper extraction at pH 1.5 was 1.5 and 1.4 times that at pH 1.0 and pH 2.0 respectively. The copper extraction obtained at 45 ℃ was 1236.8%higher than that at 50 ℃. With the increase of rotation speed or the decrease of liquid volume, copper extraction was improved obviously. Copper extraction was improved gradually with the increase of pyrite ratio. However, when the ratio was higher than 20.0%, no further increase in copper extraction was observed. And the statistically significant interactive effects on copper extraction were found between temperature and pH, and temperature and pyrite ratio.

Fluid inclusion and mineralization of Dafulou tin deposit in Dachang metal district, Guangxi, south China

Based on the study of the petrology, mineralogy, structural geology and fluid inclusion of the Dafulou ore deposit in the Dachang ore field, the ore deposit geology and ore-forming fluids were analyzed. It shows that there are five main hydrothermal alteration types in the Dafulou ore district, namely the silicification, carbonate, sericite, pyrite and pyrrhotite. The mineralization types are composed of the stratiform type, interlayer type and stockwork type. The ore textures present as metasomatic texture, euhedral-subhedral granular texture and solid solution texture. The ore structure consists of massive structure, dissemination structure, fine veined structure, stockwork structure and brecciated structure. Four ore types are recognized, namely the disseminated ore, dense massive ore, veinlet ore and brecciated ore. Six types of fluid inclusions are determined, i.e. the single-phase gaseous fluid inclusions, single-phase salt solution fluid inclusions, two-phase vapour-rich fluid inclusions, two-phase liquid-rich fluid inclusions, three-phase CO2-rich fluid inclusions and solid（s）-bearing fluid inclusions, all of which form in three dominant temperature scopes, 120-150, 230-270, 350-460 °C. But, the majority of them form in the high temperature environment （350-460 °C）. The tectonism plays an important role in the mineralization, which usually controls the scale, occurrence and shape of the Sn orebody. There are four types of hydrothermal fluid systems, H2O-NaCl-CaCl2, H2O-CaCl2, H2O-NaCl-MgCl2 and H2O-MgCl2. Similar to the other ore deposits in the Dachang ore field, there also exists the multiple source of ore-forming fluids. Overall, the Dafulou ore deposit should be the result of the crust-mantle interaction.

Petrogenesis of skarn in Shizhuyuan W-polymetallic deposit, southern Hunan,China:Constraints from petrology,mineralogy and geochemistry

Skarn is the main altered rock type and is of great importance to mineralization and ore-prospecting in the Shizhuyuan area of Hunan province, China. Its features of petrography, mineralogy and geochemistry were studied systematically. The results show that the skarn mainly consists of garnet skarn, secondary wollastonite-garnet skarn, tremolite-clinozoisite skarn, and few wolframine garnet skarn, idocrase-garnet skarn and wollastonite skarn with granoblastic texture, granular sheet crystalloblastic texture, and massive structure, disseminated structure, mesh-vein structure, comb structure, and banded structure. And, it is mainly composed of garnet, fluorite, chlorite, hornblende, epidote, tremolite, plagioclase, biotite, muscovite, plagioclase, quartz, idocrase, and calcite and so on. The chemical components mainly include SiO2, Al2O3, Fe2O3, MgO and CaO, and the trace elements and REEs consist of Li, Be, V, Co, Zn, Ga, Rb, Sr, Y, Ce, Nd, Pb and Bi, etc. And, the obvious fractionation exists between LREE and HREE, and it shows typical features of Nanling ore-forming granite for W？Sn polymetallic deposit. Skarn is derived from the sedimentary rock, such as limestone, mudstone, argillaceous rock, and few pelitic strips. It is affected by both Shetianqiao formation strata and Qianlishan granite during the diagenesis, indicating a strong reduction environment. The occurrence of skarn, whose mutation site is favorable to the mineralization enrichment, is closely related to the mineralization and prospecting.

Strategic equilibrium price analysis and numerical simulation of preponderant high-tech metal mineral resources

Based on exploitation compensation value system of preponderant high-tech metal mineral resources and distortion of pricing mechanism, social utility function was constructed to modify decision utility function of developers, and was extended to Stackelberg production decision model of preponderant high-tech metal mineral resources development. Analyzing the influences on market monopoly, output and price decision-making exerted by altruistic preferences, inequity aversion and sequential reciprocity fairness belief equilibrium, game fairness equilibrium which is significant in experimental economics can be obtained and verified by numerical simulation. In process of strategic pricing, method that uses the variation of producer surplus to measure strategic value from psychological preferences was proposed for the first time and technical support to improve exploitation compensation value system of preponderant metal mineral resources was available.

Catalytic removal of volatile organic compounds using ordered porous transition metal oxide and supported noble metal catalysts

Most of volatile organic compounds （VOCs） are harmful to the atmosphere and human health. Cata‐lytic combustion is an effective way to eliminate VOCs. The key issue is the availability of high per‐formance catalysts. Many catalysts including transition metal oxides, mixed metal oxides, and sup‐ported noble metals have been developed. Among these catalysts, the porous ones attract much attention. In this review, we focus on recent advances in the synthesis of ordered mesoporous and macroporous transition metal oxides, perovskites, and supported noble metal catalysts and their catalytic oxidation of VOCs. The porous catalysts outperformed their bulk counterparts. This excel‐lent catalytic performance was due to their high surface areas, high concentration of adsorbed oxy‐gen species, low temperature reducibility, strong interaction between noble metal and support and highly dispersed noble metal nanoparticles and unique porous structures. Catalytic oxidation of carbon monoxide over typical catalysts was also discussed. We made conclusive remarks and pro‐posed future work for the removal of VOCs.

Leaching of nickel-molybdenum sulfide ore in membrane biological reactor

The bioleaching of molybdenum from its sulfide ore using a Mo-resistant thermophilic bacterium sulfolobus metallics combined with a membrane biological reactor（MBR） was studied.The experimental results showed that the concentration of Mo can be controlled by filter of the membrane in MBR and the toxicity of Mo to microorganism is decreased in the process of bioleaching.It was also evidenced that there were different leaching rates of Ni and Mo when the concentration of Mo was different.After leaching for 20 d in the MBR at Mo concentration of 395 mg/L,the leaching rates of Ni and Mo reached the maximum of 79.57% and 56.23% respectively under the conditions of 100 g/L of mineral density,65 ℃,pH=2 and 1.0 L/min of the aeration rate.While 75.59% Ni and 54.33% Mo were leached out in column without membrane under the same conditions.