With the increase of mining depth of mineral resources,the rock mass stress state is being more and more complex.The rock mass show different features,namely,with the increase of hydrostatic pressure,rock mass failure...With the increase of mining depth of mineral resources,the rock mass stress state is being more and more complex.The rock mass show different features,namely,with the increase of hydrostatic pressure,rock mass failure mode turns from brittle tension failure to structure ductile failure and its limit strength also increases.The restriction of minimal principal stress on the initiation and development of microcrack and the change of micro-unit stress state by the intermediate principal stress play a decisive role in the increase of rock mass limit strength.Based on the rock mass failure behavior law under complex stress state and the σ2-dependence on the rock mass strength,we proposed a Modified Mohr-Coulomb(M-MC) strength criterion which is smooth and convex.Finally,the M-MC criterion is validated by multiaxial test data of eight kinds of rock mass.We also compared the fitting results with Mohr-Coulomb criterion(MC).It shows that the new criterion fits the test data better than the Mohr-Coulomb criterion.So the M-MC strength criterion well reveals the rock mass bearing behavior and can be widely used in the rock mass strength analysis.The results can provide theoretical foundations for stability analysis and reinforcement design of complex underground engineering.展开更多
Rapid pyrolysis of oil shale coupled with in-situ upgrading of pyrolysis volatiles over oil shale char was studied in a laboratory two-stage fluidized bed(TSFB) to clarify the shale oil yield and quality and their var...Rapid pyrolysis of oil shale coupled with in-situ upgrading of pyrolysis volatiles over oil shale char was studied in a laboratory two-stage fluidized bed(TSFB) to clarify the shale oil yield and quality and their variations with operating conditions. Rapid pyrolysis of oil shale in fluidized bed(FB) obtained shale oil yield higher than the Fischer Assay oil yield at temperatures of 500-600 ℃. The highest yield was 12.7 wt% at 500 ℃ and was about1.3 times of the Fischer Assay oil yield. The heavy fraction(boiling point > 350 ℃) in shale oil at all temperatures from rapid pyrolysis was above 50%. Adding an upper FB of secondary cracking over oil shale char caused the loss of shale oil but improved its quality. Heavy fraction yield decreased significantly and almost disappeared at temperatures above 550 ℃, while the corresponding light fraction(boiling point < 350 ℃) yield dramatically increased. In terms of achieving high light fraction yield, the optimal pyrolysis and also secondary cracking temperatures in TSFB were 600 ℃, at which the shale oil yield decreased by 17.74% but its light fraction yield of 7.07 wt% increased by 86.11% in comparison with FB pyrolysis. The light fraction yield was higher than that of Fischer Assay at all cases in TSFB. Thus, a rapid pyrolysis of oil shale combined with volatile upgrading was important for producing high-quality shale oil with high yield as well.展开更多
基金supported by the National Natural Science Foundation of China (Nos.50774082 and 50804046)
文摘With the increase of mining depth of mineral resources,the rock mass stress state is being more and more complex.The rock mass show different features,namely,with the increase of hydrostatic pressure,rock mass failure mode turns from brittle tension failure to structure ductile failure and its limit strength also increases.The restriction of minimal principal stress on the initiation and development of microcrack and the change of micro-unit stress state by the intermediate principal stress play a decisive role in the increase of rock mass limit strength.Based on the rock mass failure behavior law under complex stress state and the σ2-dependence on the rock mass strength,we proposed a Modified Mohr-Coulomb(M-MC) strength criterion which is smooth and convex.Finally,the M-MC criterion is validated by multiaxial test data of eight kinds of rock mass.We also compared the fitting results with Mohr-Coulomb criterion(MC).It shows that the new criterion fits the test data better than the Mohr-Coulomb criterion.So the M-MC strength criterion well reveals the rock mass bearing behavior and can be widely used in the rock mass strength analysis.The results can provide theoretical foundations for stability analysis and reinforcement design of complex underground engineering.
基金Supported by the National Basic Research Program of China(2014CB744303)
文摘Rapid pyrolysis of oil shale coupled with in-situ upgrading of pyrolysis volatiles over oil shale char was studied in a laboratory two-stage fluidized bed(TSFB) to clarify the shale oil yield and quality and their variations with operating conditions. Rapid pyrolysis of oil shale in fluidized bed(FB) obtained shale oil yield higher than the Fischer Assay oil yield at temperatures of 500-600 ℃. The highest yield was 12.7 wt% at 500 ℃ and was about1.3 times of the Fischer Assay oil yield. The heavy fraction(boiling point > 350 ℃) in shale oil at all temperatures from rapid pyrolysis was above 50%. Adding an upper FB of secondary cracking over oil shale char caused the loss of shale oil but improved its quality. Heavy fraction yield decreased significantly and almost disappeared at temperatures above 550 ℃, while the corresponding light fraction(boiling point < 350 ℃) yield dramatically increased. In terms of achieving high light fraction yield, the optimal pyrolysis and also secondary cracking temperatures in TSFB were 600 ℃, at which the shale oil yield decreased by 17.74% but its light fraction yield of 7.07 wt% increased by 86.11% in comparison with FB pyrolysis. The light fraction yield was higher than that of Fischer Assay at all cases in TSFB. Thus, a rapid pyrolysis of oil shale combined with volatile upgrading was important for producing high-quality shale oil with high yield as well.
