安徽石台大山地区岩石—土壤地球化学特征

通过对安徽石台大山地区内岩石、土壤地球化学特征的论述,阐述了岩石和土壤中元素地球化学背景值,对不同类型的岩石和不同时代的岩石中元素地球化学背景值、表层和深层土壤元素背景值特征进行了论述,并对岩石—土壤系统地球化学迁移性进行探讨,探讨了土壤元素背景值与基岩的关系、元素的富集与贫化特征和主要土壤元素类型特征。

沾化冬枣产地土壤元素分布特征及其对冬枣品质的影响

通过对沾化冬枣产地生态地球化学环境资料的系统整理,发现土壤中有益、有害元素的分布分配、迁移转化规律和赋存特征影响沾化冬枣的品质和食用安全性。对冬枣品质影响较大的元素有Mo、Cd、Co、Hg、S、N、Se等,其中Mo、Cd、Co、Hg、S含量过高时会降低冬枣果实的品质,尤以Hg、S、Cd影响最大,而N、Se可以提高冬枣的品质。结合基础研究成果,在土壤中增加Fe、K与水提取Se有效态含量或降低有效态B、Cu、P、N含量将有利于提高冬枣品质,该研究为冬枣统筹施肥和田间管理指明了方向。

岷江上游干旱河谷区汶川段风化壳剖面元素地球化学特征

选择岷江上游干旱河谷区汶川段不同基岩类型的岩石—土壤垂向剖面,开展地球化学测试分析工作,据此研究不同类型风化壳剖面元素垂向分布特征,探究基岩对土壤化学元素含量的影响,并从地质角度出发为该区域农业生产种植和生态环境修复提供建议。风化壳剖面自上而下可划分为腐殖层(A)、淀积层(B)、母质层(C)和基岩层(R),腐殖层中Al、Ca、K、Mg、Fe、Se、Zn、Cu、Cd、Pb均值高于其在全国土壤中的平均值,Si、Na、Mn、Cr、As、Cd、Hg均值低于全国土壤中的平均值。不同基岩风化壳剖面中,除去在基岩中含量较高的元素在所对应的土壤层中含量较高外,相同元素在其余土壤层中含量大致相同。风化剖面由基岩层至腐殖层,化学风化强度逐渐增强,土壤的风化程度普遍高于基岩风化程度。元素含量除继承母岩特征外,还发生了分异,Al、K、Se在腐殖层富集,Na、Fe、Si、Pb、Cu、Zn、Mn、As、Cd、Cr、Hg在淀积层富集,Mg、Ca在母质层富集。

Geographical Tendencies of Trace Element Contents in Soils Derived from Granite,Basalt and Limestone of Eastern China

92 soil samples were collected from granite, basalt and limestone areas of eastern China and determined for 13 trace element contents. The geographical tendencies of and factors affecting trace element contents in soils were studied.The sequences of soil trace element contents (especially the transitional elements in the 4th period) were: basalt soils > limestone soils > granite soils.The contents of trace elements in soils of granite areas and basalt areas showed great inheritance of trace element contents from the relevant parent rocks. The contents of trace elements in limestones were very low, but they became very high in limestone soils. Trace element contents of soils derived from limestone and basalt'increased significantly from north to south, these tendencies were similar to the tendency of ferric oxide contents in soils.There were differences of contents of trace elements bound to ferric oxide in different kinds of parent material and in different types of soil. The correlations between the contents of trace elements and the contents of ferric oxide were better in basalt soils than in granite soils.

Nutrient Release from Weathering of Purplish Rocks in the Sichuan Basin,China

Purplish soils having high fertility with mineral nutrients inherited from the parent rock are widely distributed in the hills along the Yangtze River,especially in the Sichuan Basin.Pot and field weathering experiments were conducted to mimic rock weathering and nutrient release processes in order to better understand soil fertility and nutrient compensation. Three types of purplish rock formations formed in the Jurassic period,Shaximiao(J_2s),Suining(J_3s),and Penglaizhen (J_3p),as well as one type formed in the Cretaceous period,the Chengqiangyan group(K_1c),were used in this study. Results showed that the soil formation rate was in the range from 11.2 to 19.6 mm every year,and rock weathering was in the order of J_3s>J_3p>J_2s>K_1c.Because more rock surface was exposed to sunlight and rainfall in field conditions,pot weathering was slower than field weathering.Nutrient release rates increased with rock weathering and was in the order similar to that of rock weathering:J_3p>J_3s>J_2s>K_1c.Potassium release was the most important in all rocks;after 2 years of weathering,19.4% to 46.9% of K was released from the initial parent rocks,which suggested that K release from weathering could meet most of the crop K requirement in purplish soils.Thus,rapid release of nutrients from weathering of purplish rocks was key to nutrient replenishment and fertility of purplish soils.

Solubilization of Rock Phosphate in Liquid Culture by Fungal Isolates from Rhizosphere Soil

Rock phosphate （RP） is a low efficiency P fertilizer that is directly applied to the soil and can be solubilized by phosphate-solubilizing microorganisms （PSMs） in fermentation or soil conditions. This study investigated dynamic solubilization of 2 concentrations of rock phosphate in a liquid culture with different dosages of glucose by two fungal isolates,Aspergillus niger P39 and Penicillium oxalicum P66, from soybean and wheat rhizosphere soil. Although during the 20 day culture period A. niger P39 had a stronger ability to acidify the culture media than P. ozalicum P66, soluble P concentrations at glucose dosages of 30 and 50 g L^-1 with RP of 15 g L^-1 in the culture solution were much higher by P. oxalicum P66. The greater effectiveness of P. oxalicum P66 compared to A. niger P39 in the solubilization of RP was strongly associated with the production of organic acids. This study suggested that for RP solubilization the type rather than the concentration of PSM-produced organic acids was more important.

Effects of Trichoderma harzianum YC_(459) and soil types on seed germination and seedling growth in rock slope restoration

We carried out experiments with various concentrations of Trichoderma harzianum YC459 in different soil types(forest soil, mixed soil,merchantable soil, and leaf mold soil) to evaluate its effect on seed germination and seedling establishment of four species(Festuca arundinacea Schreb., Dianthus barbatus var. asiaticus Nakai,Lespedeza cyrtobotrya Miq., and Parthenocissus tricuspidata Planch) for rock slope restoration. We also investigated the use of drilled slanted holes on the rock slopes for seedling establishment. The results showed that T. harzianum concentration had significant effects on seed germination, seedling growth, and seedling survival for all the species with different soil types. Seed germination and survival rates peaked at 5% T. harzianum concentration with leaf mold soil and decreased as T. harzianum concentration increased from 5% to 10%. Seedling survival rates of all four species were generally lowest at 0% T. harzianum concentration in all soil types.The height of F. arundinacea and L. cyrtobotrya peaked at 5% T. harzianum concentration whereas that of D. barbatus and P. tricuspidata peaked at 10%T. harzianum concentration. We concluded that 5% T. harzianum concentration with leaf mold soil is appropriate for seed germination and seedling survival rates of most species, thus enhancing seedling establishment. Practical application of the findings of this study will contribute in the vegetation restoration of steep rocks in mountain environments.

Characteristics of rock fragments in different forest stony soil and its relationship with macropore characteristics in mountain area, northern China

Rock fragments have major effect on soil macropores and water movement. However, the characteristics of rock fragments and their relationship with macropore characteristics remain elusive in forest stony soils in northern mountainous area of China. The objectives of this study are to(1) use Industrial Computed Tomography(CT) scanning to quantitatively analyze rock fragment characteristics in intact soil columns in different forest lands and(2) identify the relationship between characteristics of rock fragments and that of the macropores. Intact soil columns that were 100 mm in diameter and 300 mm long were randomly taken from six local forest stony soils in Wuzuolou Forest Station in Miyun, Beijing. Industrial CT was used to scan all soil column samples, and then the scanned images were utilized to obtain the three-dimensional(3 D) images of rock fragments and macropore structures. Next, theparameters of the rock fragments and macropore structure were measured, including the volume, diameter, surface area, and number of rock fragments, as well as the volume, diameter, surface area, length, angle, tortuosity and number of macropores. The results showed that no significant difference was found in soil rock fragments content in the 10-30 cm layer between mixed forest and pure forest, but in the 0-10 cm soil layer, the rock fragments in mixed forest were significantly less than in pure forest. The number density of macropores has significant negative correlation with the number of rock fragments in the 0-10 cm soil layer, whereas this correlation is not significant in 10-20 cm and 20-30 cm soil layers. The volume density of macropore was not correlated with the volume density of rock fragments, and there is no correlation between the density of macropore surface area and the density of rock fragment surface area. Industrial CT scanning combined with image processing technology canprovide a better way to explore 3 D distribution of rock fragments in soil. The content of rock fragments in soil is mainly determined by parent rocks. The surface soil(0-10 cm) of forest contains fewer rock fragments and more macropores, which may be caused by bioturbation, root systems, gravitational settling and faunal undermining.

Characteristics and distributions of humic acids in two soil profiles of the southwest China Karst area

Characteristics and distributions of humic acid(HA) and soil organic matter(SOM) in a yellow soil profile and a limestone soil profile of the southwest China Karst area were systematically investigated to reveal their evolutions in different soils of the study area. The results showed that characteristics and distribution of SOM along the two soil profiles were notably different. Total organic carbon(TOC) contents of soil samples decreased just slightly along the limestone soil profile but sharply along the yellow soil profile. TOCs of the limestone soils were significantly higher than those of the corresponding yellow soils, and C/N ratios of SOMs showed a similar variation trend to that of TOCs, indicating that SOM can be better conserved in the limestone soil than in the yellow soil. The soil humic acids were exhaustively extracted and further fractionated according to their apparent molecular weights using ultrafiltration techniques to explore underlying conservation mechanisms. The result showed that C/N ratios of HAs from different limestone soil layers were relatively stable and that large molecular HA fractions predominated the bulk HA of the top soil, indicating that HA in the limestone profile was protected while bio and chemical degradations were retarded. Combined with organic elements contents and mineral contents of two soils, weconcluded that high calcium contents in limestone soils may play a key role in SOM conservation by forming complexation compounds with HAs or/and enclosing SOMs with hypergene CaCO_3 precipitation.

Effect of Perched Water Tables on Aluminosilicate Stability and Soil Genesis

The mineral stability and solute activities of soil solution extracted from selected horizons of seven studied pedons of Alfisols in Kentucky, USA, and the relationship between distribution of iron-manganese concretions and the restrictive layers were investigated. The results showed that the genesis and development of these soils and mineral weathering trends were strongly influenced by the depth of bedrock and the presence of perched water tables at lithic (limestone) interfaces due to the dissolution and buffering effect of limestone bedrock. The extractable Mg/Ca ratio as depth function and soil depth above bedrock could be used as indices of weathering and degree of soil development. Maximum iron-manganese concretion accumulation was found to occur in the horizon overlying clay horizon (>40% clay) with a sharp increase in clay content (>10%), which suggested that zones of Fe-Mn concretion accumulation in soils of the Inner Bluegrass Region appeared to be a sensitive genetic indicator of argillic horizons with restrictive permeability.

Numerical Analysis on Soil and Rock Formation of Ancient Gravel Strata Around Nanjing

Research samples were taken from an ancient gravel stratum which is not only a representative soil layer along the middle-lower reaches of the Yangtze River in East China, but also one of the primary Neozoic strata in Naming district. Located mostly on the second and third terraces, the ancient gravel strata formed the geomorphic landscapes of terrace and step. They were complex in constitution, varied widely in stability, of multiple sources, locally derived, and associated with braided streams in the deposition environment. A CIPW (Cross, Iddings, Pirsson and Washington) method modified by the author was used to analyze the soil-rock-forming materials of finer grains (less than 2 mm in size) of the ancient gravel stratum. Results of the analysis showed that the sandy grains were composed of apatite, ilmenite, potassium feldspar, plagioclase, enstatite and free quartz, the clay mainly of kaolinite, and the cement of a combination of silicon, aluminum and iron at a ratio of 46:44:10. In the soil-rock-forming processes, including compactional solidification, water-stable illuviation-cementation t homogeneous overgrowth and so on, the loose soil-rock-forming components gradually changed into consolidated soil and further to the early stage of lithification. Meanwhile, from the analysis, we found that the ancient gravel stratum had been protected by the overlying Xiashu loess or basalt and the overloading resulted in overconsolidated strata. The modified CIPW method was applicable and effective for semi-quantitative analysis.

Features of soil redistribution and major element migration in a karst hillslope of Southwest China

In this study, we investigated the spatial characteristics of the rate of soil distribution and the mechanism of major element migration in a typical karst hillslope in Guangxi Province, Southwestern China. Soil redistribution was examined using (137~)Cs technique under different hillslope components. With the combination of geochemical methods, the migration characteristics of major elements in soils of three hillslope components in both the horizontal and vertical directions were determined. Thirty-seven soil samples were collected and analyzed for 137 Cs and the major elements were determined. By using the profile distribution model the mean soil redistribution rates were found to be-17.01, 0.40 and-23.30t ha-1 yr-1 in the summit(BYSD), shoulder(BYSY) and toeslope(BYSJ) components of the studied hillslope, respectively. In comparison to BYSD, the sesquioxides of Fe_2O_3 and TiO_2 tend to be enriched, whereas the alkalis(CaO, MgO, Na_2O and K_2O) tend to be depleted, both in the shoulder and toeslope components. Due to human and animal activities, the contents of CaO, MgO, K_2O and Na_2O have somewhat increased within the topsoil. The results indicated that (137~)Cs activities are significantly correlated with clay particles and organic matter, and are affected by the pedogenic process and vegatation. Overall, it maybe necessary to use techniques such as (137~)Cs to investigate soil erosion with the combination of geochemical methods.

Sources of dissolved inorganic carbon in rivers from the Changbaishan area, an active volcanic zone in North Eastern China

Major elements and carbon isotopes of dissolved inorganic carbon(DIC)have been measured in the waters of Changbaishan mountain,a volcanic area in northeastern China,between June and September 2016 to decipher the origin of the CO_2 involved in chemical weathering reactions.Spatial variations of major elements ratios measured in water samples can be explained by a change of the chemical composition of the volcanic rocks between the volcanic cone(trachytes)and the basaltic shield as evidenced by the variations in the composition of these rocks.Hence,DIC results from the neutralization of CO_2 by silicate rocks.DIC concentrations vary from 0.3 to 2.5 mmol/L and carbon isotopic compositions of DIC measured in rivers vary from-14.2‰to 3.5‰.At a first order,the DIC transported by rivers is derived from the chemical weathering’s consumption of CO_2 with a magmatic origin,enriched in^(13)C(-5%)and biogenic soil CO_2 with lower isotopic compositions.The highest δ^(13)C values likely result from C isotopes fractionation during CO_2 degassing in rivers.A mass balance based on carbon isotopes suggest that the contribution of magmatic CO_2 varied from less than 20%to more than 70%.Uncertainties in this calculation associated with CO_2 degassing in rivers are difficult to quantify,and the consequence of CO_2 degassing would be an overestimation of the contribution of DIC derived from the neutralization of magmatic CO_2 by silicate rocks.

Effect of soil-rock system on speleothems weathering in Bailong Cave,Yunnan Province,China

Bailong Cave with its well-developed Middle Triassic calcareous dolomite’s system was opened as a show cave for visitors in 1988. The speleothem scenery has been strongly weathered as white powder on the outer layers. Study of the cave winds, permeability of soil-rock system and the chemical compositions of the dripping water indicated: (1) The cave dimension structure distinctively affects the cave winds, which were stronger at narrow places. (2) Based on the different soil grain size distribution, clay was the highest in composition in the soil. The response sense of dripping water to the rainwater percolation was slow. The density of joints and other openings in dolomite make the dolomite as mesh seepage body forming piles of thin and high columns and stalactites. (3) Study of 9 dripping water samples by HYDROWIN computer program showed that the major mineral in the water was dolomite.

Origin of Red Color of the Lower Siwalik Palaeosols:A Micromorphological Approach

Palaeosols associated with fluvial of the Siwalik Group are and lacustrine deposits that occur as thick multiple pedocomplexes. The bright red color of the palaeosol beds has been earlier interpreted as a result of hot and arid palaeoclimate. However, as against this view, our investigations of the bright red palaeosol beds of the Lower Siwaliks suggest that the climate was cool and subhumid, instead of hot and arid during the deposition of these beds. Since cold climate is not very conducive to impart red coloration, further research is needed to explain the cause of these red beds. For this, the micromorphological study of soil thin sections was done which showed the presence of features such as dissolution and recrystallisation of quartz, feldspar and mica, compaction, slickensides, presence of calcite spars, subrounded and cracked nature of quartz grains, microfabric, complex patterns of birefringence fabrics, pigmentary ferric oxides, thick cutans and cementation by calcite. These features indicate that diagenesis took place on a large scale in these sediments. The positive Eh and neutral-alkaline pH of soils also suggest that the conditions were favorable for the formation of diagenetic red beds. During burial diagenesis of sediments, the hydroxides of ferromagnesian minerals got converted into ferric oxide minerals （hematite）. During deep burial diagenesis smectite was converted into illite and the preponderance of illite over smectite with increasing depth of burial also indicates the diagenesis of sediments. Thus, the red color of the Lower Siwalik palaeosols seems to be due mainly to the burial diagenesis of sediments and does not appear to be due to the then prevailing climatic condition.

Identification on rock and soil parameters for vibration drilling rock in metal mine based on fuzzy least square support vector machine

A single freedom degree model of drilling bit-rock was established according to the vibration mechanism and its dynamic characteristics. Moreover, a novel identification method of rock and soil parameters for vibration drilling based on the fuzzy least squares(FLS)-support vector machine(SVM) was developed, in which the fuzzy membership function was set by using linear distance, and its parameters, such as penalty factor and kernel parameter, were optimized by using adaptive genetic algorithm. And FLS-SVM identification on rock and soil parameters for vibration drilling was made by changing the input/output data from single freedom degree model of drilling bit-rock. The results of identification simulation and resonance column experiment show that relative error of natural frequency for some hard sand from identification simulation and resonance column experiment is 1.1% and the identification precision based on the fuzzy least squares-support vector machine is high.

Soil Organic Carbon Mineralization as Affected by Cyclical Temperature Fluctuations in a Karst Region of Southwestern China

The diurnal fluctuation in soil temperature may influence soil organic carbon （SOC） mineralization, but there is no consensus on SOC mineralization response to the cyclical fluctuation in soil temperature. A 56-d incubation experiment was conducted to investigate the effects of constant and variable temperatures on SOC mineralization. Three soils were collected from the karst region in western Guizhou Province, southwestern China, including a limestone soil under forest, a limestone soil under crops and a yellow soil under crops. According to the World Reference Base （WRB） classification, the two limestone soils were classified as Haplic Luvisols and the yellow soil as a Dystric Luvisol. These soils were incubated at three constant temperatures （15, 20 and 25 ℃） and cyclically fluctuating temperatures （diurnal cycle between 15 and 25 ℃）. The results showed that the 56-d cumulative SOC mineralized （C56） at the fluctuating temperatures was between those at constant 15 and 25 ℃, suggesting that the cumulative SOC mineralization was restricted by temperature range. The SOC mineralization responses to the fluctuating temperatures were different among the three soils, especially in contrast to those at constant 20 ~C. Compared with constant 20 ℃, significant （P 〈 0.05） decreases and increases in C56 value were found in the limestone soil under forest and yellow soil under crops at the fluctuating temperatures, respectively. At the fluctuating temperatures, the forest soil with lower temperature coefficient Q10 （the relative change in SOC mineralization rate as a result of increasing the temperature by 10 ℃） had a significantly （P 〈 0.05） lower SOC mineralization intensity than the two cropland soils. These indicated that differences in temperature pattern （constant or fluctuating） could significantly influence SOC mineralization, and SOC mineralization responses to the fluctuating temperatures might be affected by soil characteristics. Moreover, the warmer temperatures might improve the ability of soil microbes to decompose the recalcitrant SOC fraction, and cyclical fluctuations in temperature could influence SOC mineralization through changing the labile SOC pool size and the mineralization rate of the recalcitrant SOC in soils.

Influence of water content and shear rate on the mechanical behavior of soil-rock mixtures

Soil-rock mixtures(S-RMs) are widely distributed in the nature. The mesoscopic deformation and failure mechanisms as well as the macro-mechanical behaviors of the S-RMs depend largely upon the rate of deformation, water content and particle sizes. In this research, a series of large-scale direct shear tests with different water contents and different grain-size distributions were conducted to study the influence of the aforementioned factors on the mechanical properties of the S-RMs. Due to the effect of the rock blocks' breakage in the S-RMs, the relationship between the shear strength and the vertical stress of S-RM follows a power law instead of a linear one. It is found that there exists a threshold value for the vertical stress during the shearing process,below which the soil strength is mainly determined by the inter-locking of particles and the re-arrangement of meso-structure,and otherwise large-sized rock blocks are gradually broken into smaller fragments, resulting in a decrease in the soil strength.The shear rate can also significantly influence the degree of particle breakage and the meso-structural rearrangement of the SRMs, namely, under low shear rate, the particles of the samples are fully broken resulting in enhanced macro-strength. As a result, the lower the shear rate, the higher the macroscopic strength. So under unsaturated conditions, the water content will affect the strength of the S-RMs by reducing the strength of rock blocks. As the water content increases, the soil strength decreases gradually, and assumes a moderate value when the water content reaches 8%. At the same water content, the soil strength increases with the sizes of large rock blocks. For the occlusion, breakage and structure re-arrangement of the oversized rock blocks inside S-RM, which have a huge influence on the mechanical characteristics of the samples.

Assessment of Potential Nutrient Release from Phosphate Rock and Dolostone for Application in Acid Soils

Finding alternative local sources of plant nutrients is a practical, low-cost, and long-term strategy. In this study, laboratory column experiments were conducted in a completely randomized design to evaluate the feasibility of using phosphate rock and dolostone as fertilizers or acid-neutralizing agents for application in tropical acid soils. The dissolution rates of different particle-size fractions(0.063–0.25, 0.25–0.5, and 0.5–2 mm) of both rocks were studied by citric acid solution at p H 4 and 2 and water, with extraction times of 1, 3, 5, 7, 12, 24, 72, 144, 240, and 360 h. The results showed that the dissolution of both rocks depended on the particle size,leaching solution, and extraction time. The dissolution rate of rock-forming minerals increased as the specific surface area increased,corresponding to a decrease in particle size. In all cases, the release kinetics was characterized by two phases: 1) a first stage of rapid release that lasted 24 h and would ensure short-term nutrient release, and 2) a second stage of slow release after 24 h, representing the long-term nutrient release efficiency. Both rocks were suitable as slow-release fertilizers in strongly acid soils and would ensure the replenishment of P, Ca, and Mg. A combination of fine and medium particle-size fractions should be used to ensure high nutrient-release efficiency. Much work could remain to determine the overall impact of considerable amounts of fresh rocks in soils.

Numerical study of soil-rock mixture:Generation of random aggregate structure

The soil-rock mixture(SRM) is highly heterogeneous. Before carrying out numerical analysis,a structure model should be generated. A reliable way to obtain such structure is by generating random aggregate structure based on random sequential addition(RSA). The classical RSA is neither efficient nor robust since valid positions to place new inclusions are formulated by trial, which involves repetitive overlapping tests. In this paper, the algorithm of Entrance block between block A and B(EAB)is synergized with background mesh to redesign RSA so that permissible positions to place new inclusions can be predicted,resulting in dramatic improvement in efficiency and robustness.