The Palaeo–Mesoproterozoic Tadapatri formation of the Cuddapah basin is comprised of clastic sedimentary rocks with minor carbonates and mafic–ultramafic sill bodies. Geochemistry of the shale is used to study the p...The Palaeo–Mesoproterozoic Tadapatri formation of the Cuddapah basin is comprised of clastic sedimentary rocks with minor carbonates and mafic–ultramafic sill bodies. Geochemistry of the shale is used to study the provenance, paleoweathering and paleoredox conditions of this Tadpatri formation in order to better understand the development of the Cuddapah basin during Palaeo–Mesoproterozoic time. The higher CIA(average 74.39), PIA(average 85.94) and CIW(average 87.59) values of the Tadpatri shales suggest intensely weathered sources.Higher Al2_ O_3/TiO_2(average 30.78) and LREE/HREE ratio(average 8.80) with negative europium anomaly indicate derivation of the clastic sediments from a felsic source rock. The geochemical parameters like U, U/Th, Cu/Zn,Ni/Co, V/Cr ratios reveal that the Tadpatri shales are mainly deposited in an oxic condition.展开更多
The damage constitutive relation of entire rock failure process was established using the theory of representative volume element obeying the Iognormal distribution law, and the integrated damages constitutive model o...The damage constitutive relation of entire rock failure process was established using the theory of representative volume element obeying the Iognormal distribution law, and the integrated damages constitutive model of rock under triaxial compression was established. Comparing with triaxial compression test result, it shows that this model correctly reflects the relationship of stress-strain. At the same time, according to the principle of the rock fatigue failure that conforms to completely the static entire process curve, a new method of establishing cyclic fatigue damage evolution equation was discussed, this method form is simple and the physics significance is clear, it may join preferably the damage relations of the rock static entire process curve.展开更多
This paper reports Precambrian rock magnetic fabrics in the Nyalam area of southern Tibet. The analytical results of magnetic fabrics show that the values of H are high (〉 10% in general), so the ductile deformatio...This paper reports Precambrian rock magnetic fabrics in the Nyalam area of southern Tibet. The analytical results of magnetic fabrics show that the values of H are high (〉 10% in general), so the ductile deformations of the Precambrian rock are strong. The orientation of the maximum principal stress inferred from the minimum magnetic susceptibility is nearly S-N, NE-SW and NW-SE. The Flinn diagram of the magnetic fabrics show that the strain pattern is oblate and constrictional type. Magnetic foliation of great majority of rock samples is well developed and the magnetic lineation is poor and the magnetic susceptibility ellipsoid is flattened. The magnetic lineation of the minority rock samples is well developed and the magnetic foliation is poor and the magnetic susceptibility ellipsoid is prolate. According to the geological field and the magnetic fabrics, there are 3 times tectonic stress field in SN directed extruding, NW-SE directed extruding, NW-SE directed extension. It shows that the Nyalam area has undergone process the orientation of SN, NW-SE nappe structure and NW-SE directed extension structure. The change of tectonic stress is reflected by the field characteristics of the Precambrian rock magnetic fabrics that is the direct responding result of the arc-continental, continent-continental collision between the India and Asian continents in the late part of the Late Cretaceous to Late Eocene and subsequently shifted to intra-continental convergent, the plateau uplifting and extension structure stage since the Late Eocene.展开更多
The shales of the Qiongzhusi Formation and Wufeng-Longmaxi Formations at Sichuan Basin and surrounding areas are presently the most important stratigraphic horizons for shale gas exploration and development in China. ...The shales of the Qiongzhusi Formation and Wufeng-Longmaxi Formations at Sichuan Basin and surrounding areas are presently the most important stratigraphic horizons for shale gas exploration and development in China. However, the regional characteristics of the seismic elastic properties need to be better determined. The ultrasonic velocities of shale samples were measured under dry conditions and the relations between elastic properties and petrology were systemically analyzed. The results suggest that 1) the effective porosity is positively correlated with clay content but negatively correlated with brittle minerals, 2) the dry shale matrix consists of clays, quartz, feldspars, and carbonates, and 3) organic matter and pyrite are in the pore spaces, weakly coupled with the shale matrix. Thus, by assuming that all connected pores are only present in the clay minerals and using the Gassmann substitution method to calculate the elastic effect of organic matter and pyrite in the pores, a relatively simple rock-physics model was constructed by combining the self-consistent approximation (SCA), the differential effective medium (DEM), and Gassmann's equation. In addition, the effective pore aspect ratio was adopted from the sample averages or estimated from the carbonate content. The proposed model was used to predict the P-wave velocities and generally matched the ultrasonic measurements very well.展开更多
When underground cavities are subjected to explosive stress waves,a uniquely damaged zone may appear due to the combined effect of dynamic loading and static pre-load stress.In this study,a rate-dependent two-dimensio...When underground cavities are subjected to explosive stress waves,a uniquely damaged zone may appear due to the combined effect of dynamic loading and static pre-load stress.In this study,a rate-dependent two-dimensional rock dynamic constitutive model was established to investigate the dynamic fractures of rocks under different static stress conditions.The effects of the loading rate and peak amplitude of the blasting wave under different confining pressures and the vertical compressive coefficient(K_(0))were considered.The numerical simulated results reproduced the initiation and further propagation of primary radial crack fractures,which were in agreement with the experimental results.The dynamic loading rate,peak amplitude,static vertical compressive coefficient(K_(0))and confining pressure affected the evolution of fractures around the borehole.The heterogeneity parameter(m)plays an important role in the evolution of fractures around the borehole.The crack propagation path became more discontinuous and rougher in a smallerheterogeneity parameter case.展开更多
For a safe extracting of the mine resource of the razor thin capping rock, a study of waterproof, sand prevention, roof fall prevention must be made. As a result, it’s necessary to master the engineering feature of w...For a safe extracting of the mine resource of the razor thin capping rock, a study of waterproof, sand prevention, roof fall prevention must be made. As a result, it’s necessary to master the engineering feature of weathering zone of bedrock. According to the lithology appraisal and X diffract analyses, the mineral feature of weathering zone of bedrock in 810 producing area has been studied in this article. By testing the physical mechanics index of weathering zone, we have found out some features of physical mechanic quality. Utilizing the determined result of viscosity index and slaking test, we reach a conclusion of the water stability of weathering zone, that is the weathering zone rock belongs to the type that is easily slaked when encountered water and the water stability is weak.展开更多
The mediate-low maturity continental shale oil reservoir in the 7th member of the Triassic Yanchang Formation is one of the main zones for shale oil exploration and development in Ordos Basin,China,but the seismic res...The mediate-low maturity continental shale oil reservoir in the 7th member of the Triassic Yanchang Formation is one of the main zones for shale oil exploration and development in Ordos Basin,China,but the seismic response mechanism of the reservoir remains unclear.Therefore,developing a new method for“sweet spot”seismic prediction combined with rock physics is necessary.To determine the petrophysical characteristics of continental shale in the 7th member of the Yanchang Formation in the study area,a series of tests,such as a systematic acoustic test on shale oil samples in the target segment,X-ray diffraction analyses,analysis of thin optical sections,and scanning electron microscopy,were conducted to summarize the patterns of seismic elastic property changes.Results show that the shale oil samples of the 7th member of the Yanchang Formation are primarily composed of lithic feldspar sandstone with feldspar dissolution and intergranular pores,widespread micron pores,and throats.Such composition indicates a positive correlation between porosity and permeability.The velocities of the samples are affected by their porosity and mineral composition.Velocity increases with the increase of the calcium content and decreases with the increase of the clay content,indicating a negative correlation with the porosity and total organic carbon(TOC)content on the condition of the same rock structure(quartz skeleton or clay skeleton).The elastic properties of the rock are horizontally isotropic(T1 medium),and the velocity is vertically anisotropic.In addition,the directional arrangement of clay controls the anisotropy of rock velocity.TOC is mainly distributed in the primary intergranular pores,and it has no contribution to the anisotropy of rock velocity.The results of this paper can provide a reference for the seismic prediction of continental shale oil reservoirs in the 7th member of the Yanchang Formation.展开更多
A test drilling exploration was implemented across the northern segment of the Nankou-Sunhe fault in the Beijing plain,and a combined borehole section was built by sequence stratigraphy,lithologic facies analysis,magn...A test drilling exploration was implemented across the northern segment of the Nankou-Sunhe fault in the Beijing plain,and a combined borehole section was built by sequence stratigraphy,lithologic facies analysis,magnetic susceptibilityand absolute chronology to investigate the episodic activities of the fault since 60 ka BP. The results show that the active stages of the fault are 60 ka to 47 ka BP,36 ka to 28 ka BP,and 16 ka BP to present. Other intervals are relatively stable. The average vertical slip rate is 0.35 mm/a from 60 ka to 37 ka BP,0 mm/a from 37 ka to 32 ka BP,0.78 mm/a from 32 ka to 12 ka BP,and 0.35 mm/a since 12 ka BP. Compared with the conventional analyses on lithology and sedimentary facies,the sequence stratigraphy method has certain advantages in the studies of borehole strata comparison and episodic activity of buried faults.展开更多
Petrographic analysis combined with various techniques, such as scanning electron microscopy and X-ray diffraction, was used to assess the timing of growth and original mineral cements, the controls on reservoir and r...Petrographic analysis combined with various techniques, such as scanning electron microscopy and X-ray diffraction, was used to assess the timing of growth and original mineral cements, the controls on reservoir and reservoir quality of the fourth member sandstones of Shahejie formation (Es4). The Es4 sandstones are mostly arkose and lithic arkose, rarely feldspathic litharenite, with an average mass fraction of quartz 51.6%, feldspar 33.8% and rock fragments 14.6% (Q51.6F33.8R14.6). They have an average framework composition (mass fraction) of quartz 57.10%, K-feldspar 5.76%, sodium-calcium feldspar 13.00%, calcite 5.77%, dolomite 5.63%, siderite 0.95%, pyrite 0.30%, anhydrite 0.04%, and clay mineral 11.46%. The diagenentic minerals typically include kaolinite, illite-smectite (I/S), illite, chlorite, authigenetic quartz and feldspar, and carbonate and pyrite. Es4 sandstone has undergone stages A and B of eodiagenesis, and now, it is experiencing stage A of mesodiagenesis. Reservoir quality is predominantly controlled by the mechanical compaction, for example, 45.65% of the original porosity loss is related to compaction. The original porosity loss related with cementation is only 26.00%. The reservoir quality is improved as a result of dissolution of feldspar, rock fragment and so forth. The porosity evolved from dissolution varies from 3% to 4%.展开更多
A study of the characteristics of the accumulative rock failure and its evolution byapplication of the group renormalization method were presented. In addition, the interactionand long-range correlated effects between...A study of the characteristics of the accumulative rock failure and its evolution byapplication of the group renormalization method were presented. In addition, the interactionand long-range correlated effects between the immediate neighboring units was studied.The concept of mechanical transference for model OFC, employed in the study ofself-organized criticality, and the coefficient a were introduced into the calculation model forgroup renormalization. With the introduction, mechanisms for the drastic increase and decrease of failure intensity of rocks were investigated under similar macro-conditions.展开更多
The main achievements in the development of hardly-recoverable resources are currently associated with shale oil and gas. The result of the "shale revolution" was billions of dollars in losses for oil exporters. The...The main achievements in the development of hardly-recoverable resources are currently associated with shale oil and gas. The result of the "shale revolution" was billions of dollars in losses for oil exporters. The question is how this situation w'ill be long-lasting or "shale bubble" will burst. The success of the shale revolution can be not only an economic win or economic defeat of the United States, the question is about reputation as a global political leader and the country's ability to solve the most difficult technological problems. Everything at stake to extend the "shale gas revolution" as it is possible longer, in time to prepare the conditions and technologies for a new energy revolution and to maintain the usual high level of energy consumption. The situation is further complicated by the introduction in the game of OPEC (organization of petroleum exporting countries) causing oil prices dropped below the cost of shale oil. The future of high technology in the production of oil depends on whether exporters and importers to negotiate the best price for oil, to ensure the sustainable development of the world economy.展开更多
The component additive modelling approach is based on summing the results from models already calibrated with pure mineral phases. The summation can occur as the sum of results for thermodynamic surface speciation mod...The component additive modelling approach is based on summing the results from models already calibrated with pure mineral phases. The summation can occur as the sum of results for thermodynamic surface speciation models or as the sum of pseudo-thermodynamic models for adsorption on individual mineral phases. Static batch sorption experiments of 63Ni are with different granitic rocks and component minerals. XRD analyses have been used to calculate the percentage mineralogical composition of the granitic rocks. Sorption data has been modelled using non electrostatic correction models to obtain Rdfor the granitic rocks and mineral. Ra values for the granitic rocks predicted from the component additive model have been compared to experimental values. Results showed that predicted Rd values for granite adamellite, biotite granite and rapakivi granite were identical to the experimentally determined values, whereas, for graphic granite and grey Granite, the predicted and experimentally determined Ra values were much different. The results also showed a greater contribution to the bulk Raby feldspar while quartz showed the least contribution to the Rd.展开更多
This paper discusses the vein rocks located in the central part of Khibina Mts.. These rocks are located on the border of two zones: ore and external. In the ore, zone is present titanite-nepheline bodies whilst in t...This paper discusses the vein rocks located in the central part of Khibina Mts.. These rocks are located on the border of two zones: ore and external. In the ore, zone is present titanite-nepheline bodies whilst in the outer zone are massive-syenites "khibinites". The veins can be divided into: mikrosyenites, melteigites and other rock types (e.g., tinguaites). The results of LA-ICP MS (laser ablation of inductively coupled plasma mass spectrometry) indicate that these rocks are associated with deep zones which formed as a result of injection of primary magma and contamination of fluids during migration, where there have hydrothermal processes. Rock-forming minerals, their corrosion and accessory minerals indicate these processes, too.展开更多
基金the Department of Science and Technology (DST), Government of India for financial support vide PURSE (Phase-Ⅱ) program (No. F4/SC/20/15)University Grants Commission (UGC), New Delhi for the scholarship of the first author
文摘The Palaeo–Mesoproterozoic Tadapatri formation of the Cuddapah basin is comprised of clastic sedimentary rocks with minor carbonates and mafic–ultramafic sill bodies. Geochemistry of the shale is used to study the provenance, paleoweathering and paleoredox conditions of this Tadpatri formation in order to better understand the development of the Cuddapah basin during Palaeo–Mesoproterozoic time. The higher CIA(average 74.39), PIA(average 85.94) and CIW(average 87.59) values of the Tadpatri shales suggest intensely weathered sources.Higher Al2_ O_3/TiO_2(average 30.78) and LREE/HREE ratio(average 8.80) with negative europium anomaly indicate derivation of the clastic sediments from a felsic source rock. The geochemical parameters like U, U/Th, Cu/Zn,Ni/Co, V/Cr ratios reveal that the Tadpatri shales are mainly deposited in an oxic condition.
基金Supported by the Key Project of the National Natural Science Foundation of China(50534080) National Natural Science Foundation of China(50574108)
文摘The damage constitutive relation of entire rock failure process was established using the theory of representative volume element obeying the Iognormal distribution law, and the integrated damages constitutive model of rock under triaxial compression was established. Comparing with triaxial compression test result, it shows that this model correctly reflects the relationship of stress-strain. At the same time, according to the principle of the rock fatigue failure that conforms to completely the static entire process curve, a new method of establishing cyclic fatigue damage evolution equation was discussed, this method form is simple and the physics significance is clear, it may join preferably the damage relations of the rock static entire process curve.
基金Acknowledgements This work was supported by China Geological Survey (Grant No. H45C004002, 1212010784007) and the Project of the National Natural Science Foundation of China (Grant No. 40272012).
文摘This paper reports Precambrian rock magnetic fabrics in the Nyalam area of southern Tibet. The analytical results of magnetic fabrics show that the values of H are high (〉 10% in general), so the ductile deformations of the Precambrian rock are strong. The orientation of the maximum principal stress inferred from the minimum magnetic susceptibility is nearly S-N, NE-SW and NW-SE. The Flinn diagram of the magnetic fabrics show that the strain pattern is oblate and constrictional type. Magnetic foliation of great majority of rock samples is well developed and the magnetic lineation is poor and the magnetic susceptibility ellipsoid is flattened. The magnetic lineation of the minority rock samples is well developed and the magnetic foliation is poor and the magnetic susceptibility ellipsoid is prolate. According to the geological field and the magnetic fabrics, there are 3 times tectonic stress field in SN directed extruding, NW-SE directed extruding, NW-SE directed extension. It shows that the Nyalam area has undergone process the orientation of SN, NW-SE nappe structure and NW-SE directed extension structure. The change of tectonic stress is reflected by the field characteristics of the Precambrian rock magnetic fabrics that is the direct responding result of the arc-continental, continent-continental collision between the India and Asian continents in the late part of the Late Cretaceous to Late Eocene and subsequently shifted to intra-continental convergent, the plateau uplifting and extension structure stage since the Late Eocene.
基金sponsored by the National Natural Science Foundation of China(No.41274185 and 41676032)
文摘The shales of the Qiongzhusi Formation and Wufeng-Longmaxi Formations at Sichuan Basin and surrounding areas are presently the most important stratigraphic horizons for shale gas exploration and development in China. However, the regional characteristics of the seismic elastic properties need to be better determined. The ultrasonic velocities of shale samples were measured under dry conditions and the relations between elastic properties and petrology were systemically analyzed. The results suggest that 1) the effective porosity is positively correlated with clay content but negatively correlated with brittle minerals, 2) the dry shale matrix consists of clays, quartz, feldspars, and carbonates, and 3) organic matter and pyrite are in the pore spaces, weakly coupled with the shale matrix. Thus, by assuming that all connected pores are only present in the clay minerals and using the Gassmann substitution method to calculate the elastic effect of organic matter and pyrite in the pores, a relatively simple rock-physics model was constructed by combining the self-consistent approximation (SCA), the differential effective medium (DEM), and Gassmann's equation. In addition, the effective pore aspect ratio was adopted from the sample averages or estimated from the carbonate content. The proposed model was used to predict the P-wave velocities and generally matched the ultrasonic measurements very well.
基金Projects(51878190,51779031,51678170)supported by the National Natural Science Foundation of China。
文摘When underground cavities are subjected to explosive stress waves,a uniquely damaged zone may appear due to the combined effect of dynamic loading and static pre-load stress.In this study,a rate-dependent two-dimensional rock dynamic constitutive model was established to investigate the dynamic fractures of rocks under different static stress conditions.The effects of the loading rate and peak amplitude of the blasting wave under different confining pressures and the vertical compressive coefficient(K_(0))were considered.The numerical simulated results reproduced the initiation and further propagation of primary radial crack fractures,which were in agreement with the experimental results.The dynamic loading rate,peak amplitude,static vertical compressive coefficient(K_(0))and confining pressure affected the evolution of fractures around the borehole.The heterogeneity parameter(m)plays an important role in the evolution of fractures around the borehole.The crack propagation path became more discontinuous and rougher in a smallerheterogeneity parameter case.
文摘For a safe extracting of the mine resource of the razor thin capping rock, a study of waterproof, sand prevention, roof fall prevention must be made. As a result, it’s necessary to master the engineering feature of weathering zone of bedrock. According to the lithology appraisal and X diffract analyses, the mineral feature of weathering zone of bedrock in 810 producing area has been studied in this article. By testing the physical mechanics index of weathering zone, we have found out some features of physical mechanic quality. Utilizing the determined result of viscosity index and slaking test, we reach a conclusion of the water stability of weathering zone, that is the weathering zone rock belongs to the type that is easily slaked when encountered water and the water stability is weak.
基金financially supported by the National Natural Science Foundation of China (No.41574067)Henan Provincial Science and Technology Research (No.222102210310)。
文摘The mediate-low maturity continental shale oil reservoir in the 7th member of the Triassic Yanchang Formation is one of the main zones for shale oil exploration and development in Ordos Basin,China,but the seismic response mechanism of the reservoir remains unclear.Therefore,developing a new method for“sweet spot”seismic prediction combined with rock physics is necessary.To determine the petrophysical characteristics of continental shale in the 7th member of the Yanchang Formation in the study area,a series of tests,such as a systematic acoustic test on shale oil samples in the target segment,X-ray diffraction analyses,analysis of thin optical sections,and scanning electron microscopy,were conducted to summarize the patterns of seismic elastic property changes.Results show that the shale oil samples of the 7th member of the Yanchang Formation are primarily composed of lithic feldspar sandstone with feldspar dissolution and intergranular pores,widespread micron pores,and throats.Such composition indicates a positive correlation between porosity and permeability.The velocities of the samples are affected by their porosity and mineral composition.Velocity increases with the increase of the calcium content and decreases with the increase of the clay content,indicating a negative correlation with the porosity and total organic carbon(TOC)content on the condition of the same rock structure(quartz skeleton or clay skeleton).The elastic properties of the rock are horizontally isotropic(T1 medium),and the velocity is vertically anisotropic.In addition,the directional arrangement of clay controls the anisotropy of rock velocity.TOC is mainly distributed in the primary intergranular pores,and it has no contribution to the anisotropy of rock velocity.The results of this paper can provide a reference for the seismic prediction of continental shale oil reservoirs in the 7th member of the Yanchang Formation.
基金the project of "Experimental Exploration of Active Fault in Urban Area" of National Development and Reform Commission of China(Grant No.20041138)
文摘A test drilling exploration was implemented across the northern segment of the Nankou-Sunhe fault in the Beijing plain,and a combined borehole section was built by sequence stratigraphy,lithologic facies analysis,magnetic susceptibilityand absolute chronology to investigate the episodic activities of the fault since 60 ka BP. The results show that the active stages of the fault are 60 ka to 47 ka BP,36 ka to 28 ka BP,and 16 ka BP to present. Other intervals are relatively stable. The average vertical slip rate is 0.35 mm/a from 60 ka to 37 ka BP,0 mm/a from 37 ka to 32 ka BP,0.78 mm/a from 32 ka to 12 ka BP,and 0.35 mm/a since 12 ka BP. Compared with the conventional analyses on lithology and sedimentary facies,the sequence stratigraphy method has certain advantages in the studies of borehole strata comparison and episodic activity of buried faults.
基金Project(2006AA09Z336) supported by the National High-Tech Research and Development Program of China
文摘Petrographic analysis combined with various techniques, such as scanning electron microscopy and X-ray diffraction, was used to assess the timing of growth and original mineral cements, the controls on reservoir and reservoir quality of the fourth member sandstones of Shahejie formation (Es4). The Es4 sandstones are mostly arkose and lithic arkose, rarely feldspathic litharenite, with an average mass fraction of quartz 51.6%, feldspar 33.8% and rock fragments 14.6% (Q51.6F33.8R14.6). They have an average framework composition (mass fraction) of quartz 57.10%, K-feldspar 5.76%, sodium-calcium feldspar 13.00%, calcite 5.77%, dolomite 5.63%, siderite 0.95%, pyrite 0.30%, anhydrite 0.04%, and clay mineral 11.46%. The diagenentic minerals typically include kaolinite, illite-smectite (I/S), illite, chlorite, authigenetic quartz and feldspar, and carbonate and pyrite. Es4 sandstone has undergone stages A and B of eodiagenesis, and now, it is experiencing stage A of mesodiagenesis. Reservoir quality is predominantly controlled by the mechanical compaction, for example, 45.65% of the original porosity loss is related to compaction. The original porosity loss related with cementation is only 26.00%. The reservoir quality is improved as a result of dissolution of feldspar, rock fragment and so forth. The porosity evolved from dissolution varies from 3% to 4%.
基金Supported by the National Science Foundation of China (50674002)
文摘A study of the characteristics of the accumulative rock failure and its evolution byapplication of the group renormalization method were presented. In addition, the interactionand long-range correlated effects between the immediate neighboring units was studied.The concept of mechanical transference for model OFC, employed in the study ofself-organized criticality, and the coefficient a were introduced into the calculation model forgroup renormalization. With the introduction, mechanisms for the drastic increase and decrease of failure intensity of rocks were investigated under similar macro-conditions.
文摘The main achievements in the development of hardly-recoverable resources are currently associated with shale oil and gas. The result of the "shale revolution" was billions of dollars in losses for oil exporters. The question is how this situation w'ill be long-lasting or "shale bubble" will burst. The success of the shale revolution can be not only an economic win or economic defeat of the United States, the question is about reputation as a global political leader and the country's ability to solve the most difficult technological problems. Everything at stake to extend the "shale gas revolution" as it is possible longer, in time to prepare the conditions and technologies for a new energy revolution and to maintain the usual high level of energy consumption. The situation is further complicated by the introduction in the game of OPEC (organization of petroleum exporting countries) causing oil prices dropped below the cost of shale oil. The future of high technology in the production of oil depends on whether exporters and importers to negotiate the best price for oil, to ensure the sustainable development of the world economy.
文摘The component additive modelling approach is based on summing the results from models already calibrated with pure mineral phases. The summation can occur as the sum of results for thermodynamic surface speciation models or as the sum of pseudo-thermodynamic models for adsorption on individual mineral phases. Static batch sorption experiments of 63Ni are with different granitic rocks and component minerals. XRD analyses have been used to calculate the percentage mineralogical composition of the granitic rocks. Sorption data has been modelled using non electrostatic correction models to obtain Rdfor the granitic rocks and mineral. Ra values for the granitic rocks predicted from the component additive model have been compared to experimental values. Results showed that predicted Rd values for granite adamellite, biotite granite and rapakivi granite were identical to the experimentally determined values, whereas, for graphic granite and grey Granite, the predicted and experimentally determined Ra values were much different. The results also showed a greater contribution to the bulk Raby feldspar while quartz showed the least contribution to the Rd.
文摘This paper discusses the vein rocks located in the central part of Khibina Mts.. These rocks are located on the border of two zones: ore and external. In the ore, zone is present titanite-nepheline bodies whilst in the outer zone are massive-syenites "khibinites". The veins can be divided into: mikrosyenites, melteigites and other rock types (e.g., tinguaites). The results of LA-ICP MS (laser ablation of inductively coupled plasma mass spectrometry) indicate that these rocks are associated with deep zones which formed as a result of injection of primary magma and contamination of fluids during migration, where there have hydrothermal processes. Rock-forming minerals, their corrosion and accessory minerals indicate these processes, too.