苏北东海花岗质岩石中主要造岩矿物和副矿物的地球化学特征

苏北东海地区主侵入花岗岩类岩石属Ⅰ型花岗岩类。其主要造岩矿物为阳起角闪石、富镁黑云母、更长石、钾长石和石英。主要副矿物为榍石、磷灰石、锆石、磁铁矿等。主侵入岩体的形成温度为910—690℃,logfo_2=-12,fH_2O=(1.3—1.8)×10~8Pa,log(fH_2O/f_(HF))=3—4。第一类过渡元素富集于角闪石、黑云母和榍石中,而在更长石、钾长石和石英中明显亏损。由于榍石、角闪石、黑云母和更长石对全岩REE含量的贡献最大,因此它们控制了本区花岗岩类岩石的稀土配分模式。前三者富重稀土,负Eu异常较强,斜长石相对富轻稀土,并表现为正Eu 异常。因此可以认为随着花岗质岩浆中铁镁矿物和斜长石的分离,将会导致残余岩浆中第一类过渡元素、重稀土元素和Eu的亏损。

Statistical evaluation of five failure criteria for intact salt rock

Five multiparameter empirical criteria were exclusively evaluated by comparing them with the strength data covering various stress conditions to find out which failure criterion best fits the test data and describes the mechanical behavior of the salt rock sequence (halite,bedded composite specimens and anhydrite interlayers).Full-scale comparison of all criteria for the three rock types was conducted based on five standard statistics calculated from least squares curve-fitting,which measures both the goodness of fitting and the quality of future prediction.The results indicate that all five nonlinear criteria with a basic power form are efficient in predicting the strength trend in the low tension area as well as in the high compression area of the soft rocks.The parameters obtained for the bedded rock salt are somewhat in the ones for the "pure" rocks and are even closer to those obtained for the halite.The generalized Hoek-Brown criterion is proven to perform best to two rock strength data followed by one for the Bieniawski empirical criterion,thus is the best candidate for the analysis of the salt rock.The Sheorey empirical criterion consistently achieves an intermediate performance for all the three rocks.It seems that the superiority of the poly-axial criteria (the Mogi 1967 criterion and the N-type criterion) over the former three triaxial criteria no longer exists when applied to the conventional triaxial strength data.Besides,the method of tension cut-off was proposed to solve the ambiguity problem of the two poly-axial criteria in the tension field in the plane of the major (σ1) andminor principal stress (σ3).

A damage constitutive model of rock-like materials containing a single crack under the action of chemical corrosion and uniaxial compression

To describe the deformation and strength characteristics of the corroded rock-like specimens containing a single crack under uniaxial compression,a damage constitutive model combining hydro-chemical damage with coupling damage of micro-flaws and macro-cracks is proposed.Firstly,based on phenomenological theory,the damage variable of the rock-like specimens subjected to water environment erosion and chemical corrosion is obtained.Secondly,a coupled damage variable for cracked rock-like specimens is derived based on the Lemaitre strain equivalence hypothesis,which combines the Weibull statistical damage model for micro-flaws and the fracture mechanics model for a macro single crack.Then,considering the residual strength characteristics of the rock-like materials,the damage variable is modified by introducing the correction coefficient,and the damage constitutive model of the corroded rock-like specimens with a single crack under uniaxial compression is established.The model is verified by comparing the experimental stress−strain curves,and the results are in good agreement with those provided in the literature.Finally,the correction coefficient of the damage variable proposed in this paper is discussed.The damage constitutive model developed in this paper provides an effective method to describe the stress−strain relationship and residual strength characteristics of the corroded rock-like specimens with a single crack under uniaxial compression.

Engineering geological classification of the structural planes for hydroelectric projects in Emeishan Basalts

The scale and characteristics of rock mass are important indexes of the rock mass structural plane classification. This paper firstly analyzes the spatial distribution characteristics, the structural plane types （original structural plane, tectonic structural plane and hypergenic structural plane） and the associated features of the Emeishan basalts and then studies the classification schemes of the built hydropower structure planes of different rock areas （the east district, the central district and the west district） in the Emeishan basalt distribution area, Southwest China. Based on the analysis and comparison of the scale and the engineering geological characteristics of the typical structure planes in the basalt hydroelectric Stations, the types of structural planes are used in the first order classification. The secondary order classification is made by considering the impact factors of rock mass quality, e.g., the state of the structural planes, infilling, joint opening, extending length, the grade of weathering and strength. The engineering geological classification for Emeishan basalt is proposed. Because there are no evidences of a large structure presenting in study area, the first-order （Ⅰ） controlling structural planes do not appear in the classification, there only appear Ⅱ, Ⅲ, Ⅳ and Ⅴ grade structural planes influencing the rock-mass quality. According to the different rock-block types in bedding fault zone, the second-grade （Ⅱ） structural planes consisted of bedding fault zone is further classified into Ⅱ1, Ⅱ2 and Ⅱ3. The third-grade （Ⅲ） structural planes constructed by intraformational faulted zones are not subdivided. According to the different characteristics of intrusion, alteration and weathering unloading structural planes, the Ⅳ grade structure plane is divided into Ⅳ1, Ⅳ2 and Ⅳ3. According to the development characteristics of joints and fractures, the V grade structure plane is divided into fracture Ⅴ1 and columnar joint Ⅴ2. In all, the structural planes are classified into four groups with nine subsets. The research proposes the engineering geological classification of the structural plane for the hydropower project in the Emishan basalts, and the result of the study has a potential application in similar regions.

Petrographic characterization and evolution of the Karharbari coals, Talcher Coalfield, Orissa, India

In the present study an attempt has been made to carry out the detailed petrographic characterization of the Karharbari coals of Talcher coalfield and to reconstruct the paleoenvironment conditions of coal formation using macerals and microlithtotypes as a tool. For these purposes a large number of samples were collected following the pillar sampling method and were subjected to detailed petrographic study. The petrographic observation shows that these coals are vitrinite rich followed by the liptinite and inertinite group of macerals. On microlithotype scale, these coals shows the dominance of the vitrite followed by clarite, vitrinertite and inertite. The concentration of liptite, clarodurite, duroclarite and vitriner- toliptite are insignificant. The vitrinite reflectance ranks the Karharbari coal as high volatile bituminous ＇C＇ to high volatile ＇B＇ bituminous. Coal petrography based depositional models suggest peat accumulation in forested telmatic swamp. Moreover, during the time of their evolution, there were alternate phases of oxic and anoxic moor conditions with good tissue preservation.

Rheology of Cement Mortars with Crushed Fine Aggregates of Different Lithological Types

Crushed fine aggregates are widely used for full or partial replacement of natural sands in concretes. The crushed sands present different characteristics from the natural sand, especially if taking into account the content of microfine particle, the distribution of particle sizes, the shape features, besides the different lithological origin. From the rheological point of view, the crushed sands frequently provide mixtures with high yield stress, high viscosity, high cohesion and internal friction, which hinders its use in concrete. This study is focused on the evaluation of the rheological behavior of concrete mortar phase when using different lithological types of crushed sand in total replacement of natural sand. The lithological types surveyed were granite, calcitic limestone, dolomite limestone and mica schist. Each of these sand types was studied in two ways： in natura and with adjusted grading curve. The results show the best performance of calcitic limestone providing lower viscosities and lower yield stress in mortars.

Relationship between the Classification of Rock Surrounding Underground Chambers and the Initial Damage Variations in Rock Masses

On the basis of the relationship between each classification index for underground chambers and the elastic wave velocity of rock mass, a corresponding relationship between the classification of rock surrounding underground chambers and the initial damage variable is established by using the wave velocity definition of the initial damage variable of rock masses. Calculation and analysis of relevant data from a hydropower dam located in Southwest China show that the initial damage variable obtained by means of surrounding rock classification has a close relationship with that calculated by wave velocity, which verifies the rationality of the relationship of the two classification indices. This study establishes a foundation for further damage mechanics and stability analysis on the basis of surrounding rock classification.

THE CLASSIFICATION OF THE SURROUNDINGS OF COAL MINING ROADWAYS

This paper introduces the calculation of the deformation of the surroundings of roadways and the division of surroundings into 5 levels by means of fuzzy integral assess matrix, which serves as the scientific basis for selecting supporting pattern of roadways and determining the parameters of support.

Effect of Characteristic Spectral Lines on Rock Identification of LIBS

The LIBS （Laser induced-breakdown spectroscopy） combined with BPNN （Back propagation neural network） was applied in rock sorting and distinguishing for 26 rock samples of 6 types. According to contents of major elements in samples, we selected lines of Si, Al, Fe, K, Ca, Mg, Na, Ti and Mn. These lines of 9 elements composed three characteristic spectral models which were the WSLM （Wide spectral line model）, the PM （Peak model） and the PRM （Peak ratio model）. The first and the second characteristic spectral model were divided into 9 kinds, as follows： the characteristic spectrum with 1 element, the characteristic spectrum with 2 elements, we can deduce the rest from this and the last one has 9 elements. The third model was divided into 8 kinds which were using AI as reference element. We analysed spectrums of the three models by BPNN. Experimental results shown that whether sorting or distinguishing these samples, identification accuracies of the PM were more than that of the PRM overall, the same as the WSLM did to the PM. While the selected number of elements was 5, 6 or 7, the identification accuracy of the WSLM could reach more than 90%. Continuing to add the number of elements to improve identification accuracy was not very obvious.