The electronic structures and optical properties of rocksalt indium nitride (INN) under pressure were studied using the first-principles calculation by considering the exchange and correlation potentials with the ge...The electronic structures and optical properties of rocksalt indium nitride (INN) under pressure were studied using the first-principles calculation by considering the exchange and correlation potentials with the generalized gradient approximation. The calculated lattice constant shows good agreement with the experimental value. It is interestingly found that the band gap energy Eg at the F or X point remarkably increases with increasing pressure, but Eg at the L point does not increase obviously. The pressure coefficient of Eg is calculated to be 44 meV/GPa at the F point. Moreover, the optical properties of rocksalt InN were calculated and discussed based on the calculated band structures and electronic density of states.展开更多
Jianshanzi volcanic rocks at Qinghe valley in the northern Liaoning were considered belonging to Early Proterozoie Gaojiayu Formation of Liaohe Group, or to Early Cambrian Beidagou Formation of Qinghezhen Group, or Mi...Jianshanzi volcanic rocks at Qinghe valley in the northern Liaoning were considered belonging to Early Proterozoie Gaojiayu Formation of Liaohe Group, or to Early Cambrian Beidagou Formation of Qinghezhen Group, or Middle-Late Proterozoic Shenjiapu Formation-Complex of Kaiyuan Group-complex. Dating the zircons from the dacite with schistosity is 2 506 Ma in method of U-Pb (SHRIMP). This evidence indicates the rocks may be referred to Late Permian in age. Discovery of the rocks is significant to re-recognize stratigraphic property of "Liaohe Group", regional geoteetonie location and revolution of orogenic zone in Qinghe valley of the northern Liaoning.展开更多
In order to analyze the stability of the underground rock structures,knowing the sensitivity of geomechanical parameters is important.To investigate the priority of these geomechanical properties in the stability of c...In order to analyze the stability of the underground rock structures,knowing the sensitivity of geomechanical parameters is important.To investigate the priority of these geomechanical properties in the stability of cavern,a sensitivity analysis has been performed on a single cavern in various rock mass qualities according to RMR using Phase 2.The stability of cavern has been studied by investigating the side wall deformation.Results showed that most sensitive properties are coefficient of lateral stress and modulus of deformation.Also parameters of Hoek-Brown criterion and r c have no sensitivity when cavern is in a perfect elastic state.But in an elasto-plastic state,parameters of Hoek-Brown criterion and r c affect the deformability;such effect becomes more remarkable with increasing plastic area.Other parameters have different sensitivities concerning rock mass quality(RMR).Results have been used to propose the best set of parameters for study on prediction of sidewall displacement.展开更多
The methods combined by test, field monitoring and theoretical analysis were adopted to do the systemic research on the rock mass from micro-structure to macro-deformation, and rheological model of Jinchuan rock mass ...The methods combined by test, field monitoring and theoretical analysis were adopted to do the systemic research on the rock mass from micro-structure to macro-deformation, and rheological model of Jinchuan rock mass was established to discuss the reasonable supporting time. Resuhs show that supporting after suitable stress and displacement release can benefit for the long-term stability of surrounding rock.展开更多
The western Iratsu mass, the largest tectonic body in the Sambagawa metamorphic belt, central Shikoku, is mainly composed of epidote amphibolite with minor amounts of eclogite. Systematically, a majority of garnets sh...The western Iratsu mass, the largest tectonic body in the Sambagawa metamorphic belt, central Shikoku, is mainly composed of epidote amphibolite with minor amounts of eclogite. Systematically, a majority of garnets show bell-shaped chemical zoning of pyrope contents and Mg/(Mg+Fe2+) monotonously increasing outward. The grossular component in zonal garnet increases outwards, maximizes at an intermediate part, and then decreases towards the outermost rim, reflecting a process from increasing to decreasing pressure conditions during the prograde metamorphism. Jadeite contents of omphacite range from 25~20mole% within the cores to 15~10 mole% at the rims, implying a pressure-decreasing process (from 11 × 105 Pa to 8 × 105 Pa). The peak pressure-temperature (P-T) condition of 630~680 ℃ and ca. 15× 105 Pa in the western Iratsu mass is much higher than that of (610±25) ℃ and (10± 1)× 105 Pa of the Sambagawa oligoclase-biotite zone schists. The authors suggest a clockwise P-T-t path for the western Iratsu mass.展开更多
Apparent differences in sedimentation and diagenesis exist between carbonate reservoirs in different areas and affect their petrophysical and elastic properties.To elucidate the relevant mechanism,we study and analyze...Apparent differences in sedimentation and diagenesis exist between carbonate reservoirs in different areas and affect their petrophysical and elastic properties.To elucidate the relevant mechanism,we study and analyze the characteristics of rock microstructure and elastic properties of carbonates and their variation regularity using 89 carbonate samples from the different areas The results show that the overall variation regularities of the physical and elastic properties of the carbonate rocks are controlled by the microtextures of the microcrystalline calcite,whereas the traditional classification of rock-and pore-structures is no longer applicable.The micrite microtextures can be divided,with respect to their morphological features,into porous micrite,compact micrite,and tight micrite.As the micrites evolves from the first to the last type,crystal boundaries are observed with increasingly close coalescence,the micritic intercrystalline porosity and pore-throat radius gradually decrease;meanwhile,the rigidity of the calcite microcrystalline particle boundary and elastic homogeneity are enhanced.As a result,the seismic elastic characteristics,such as permeability and velocity of samples,show a general trend of decreasing with the increase of porosity.For low-porosity rock samples(φ<5%)dominated by tight micrite,the micritic pores have limited contributions to porosity and permeability and the micrite elastic properties are similar to those of the rock matrix.In such cases,the macroscopic physical and elastic properties are more susceptible to the formation of cracks and dissolution pores,but these features are controlled by the pore structure.The pore aspect ratio can be used as a good indication of pore types.The bulk modulus aspect ratio for dissolution pores is greater than 0.2,whereas that of the intergranular pores ranges from 0.1 to 0.2.The porous and compact micrites are observed to have a bulk modulus aspect ratio less than 0.1,whereas the ratio of the tight micrite approaches 0.2。展开更多
In this paper, firstly, the rock slope and rock mass structure are introduced. And then, two aspects of the study of the structural plane are discussed: The first aspect is method for determining mechanical parameter...In this paper, firstly, the rock slope and rock mass structure are introduced. And then, two aspects of the study of the structural plane are discussed: The first aspect is method for determining mechanical parameters of structural plane; The second aspect is analysis of shear strength of structural plane.展开更多
The influence of an upper,mined coal seam on the stability of rock surrounding a roadway in a lower coal seam is examined.The technical problems of roadway control are discussed based on the geological conditions exis...The influence of an upper,mined coal seam on the stability of rock surrounding a roadway in a lower coal seam is examined.The technical problems of roadway control are discussed based on the geological conditions existing in the Liyazhuang Mine No.2 coal seam.The stress distribution and floor failure in the lower works after mining the upper coal is studied through numerical simulations.The failure mechanism of the roof and walls of a roadway located in the lower coal seam is described.The predicted deformation and failure of the roadway for different distances between the two coal seams are used to design two ways of supporting the lower structure.One is a combined support consisting of anchors with a joist steel tent and a combined anchor truss.A field test of the design was performed to good effect.The results have significance for the design of supports for roadways located in similar conditions.展开更多
In recent years,the Yanchang shale-oil formations of the Ordos Basin are rich in reserves with complex lithology and structure characteristics,low porosity and low permeability,and weak anomalies for oil and water dis...In recent years,the Yanchang shale-oil formations of the Ordos Basin are rich in reserves with complex lithology and structure characteristics,low porosity and low permeability,and weak anomalies for oil and water discriminations,have been the key targets of unconventional oil/gas resource exploration and development in the relevant areas.The joint acoustic-electrical(AE)properties can be used to interpret reservoir lithology,mineralogy,pore structure,and fluid saturation.To conduct tests of thin section analysis,X-ray diff raction,and ultrasonic and electrical experiments at diff erent pressures and saturation degrees,cores from the shale-oil formations in the Q area of the basin are collected.The variations in AE properties with respect to clay content,porosity,pressure(microfracture),and saturation are analyzed.The experimental results indicate that the rock physics behaviors of sandstones with diff erent clay contents vary significantly.The AE properties of clean sandstones are basically dependent on the microfractures(pressure),while for muddy sandstones,the clay content is an important factor affecting the responses.The target reservoir consists of interbedded sandstone and shale layers.The AE equivalent medium equations and the Gurevich theory are applied to establish the joint models for the diff erent lithologies and simulate the variations in AE properties with respect to fluid type,pore structure,and mineral components.The three-dimensional joint templates of clean and muddy sandstones,as well as shale,are developed based on the elastic and electrical attributes and then calibrated using the experimental and well-log data.The reservoir properties are estimated with the templates and validated by the log data.The results indicate that the joint templates based on lithology characteristics can eff ectively characterize the properties of interbedded sandstone and shale layers.Furthermore,the combined application of AE data provides more beneficial information for the assessment of rock properties,leading to precise estimates that conform with the actual formation conditions.展开更多
The scale and characteristics of rock mass are important indexes of the rock mass structural plane classification. This paper firstly analyzes the spatial distribution characteristics, the structural plane types (ori...The scale and characteristics of rock mass are important indexes of the rock mass structural plane classification. This paper firstly analyzes the spatial distribution characteristics, the structural plane types (original structural plane, tectonic structural plane and hypergenic structural plane) and the associated features of the Emeishan basalts and then studies the classification schemes of the built hydropower structure planes of different rock areas (the east district, the central district and the west district) in the Emeishan basalt distribution area, Southwest China. Based on the analysis and comparison of the scale and the engineering geological characteristics of the typical structure planes in the basalt hydroelectric Stations, the types of structural planes are used in the first order classification. The secondary order classification is made by considering the impact factors of rock mass quality, e.g., the state of the structural planes, infilling, joint opening, extending length, the grade of weathering and strength. The engineering geological classification for Emeishan basalt is proposed. Because there are no evidences of a large structure presenting in study area, the first-order (Ⅰ) controlling structural planes do not appear in the classification, there only appear Ⅱ, Ⅲ, Ⅳ and Ⅴ grade structural planes influencing the rock-mass quality. According to the different rock-block types in bedding fault zone, the second-grade (Ⅱ) structural planes consisted of bedding fault zone is further classified into Ⅱ1, Ⅱ2 and Ⅱ3. The third-grade (Ⅲ) structural planes constructed by intraformational faulted zones are not subdivided. According to the different characteristics of intrusion, alteration and weathering unloading structural planes, the Ⅳ grade structure plane is divided into Ⅳ1, Ⅳ2 and Ⅳ3. According to the development characteristics of joints and fractures, the V grade structure plane is divided into fracture Ⅴ1 and columnar joint Ⅴ2. In all, the structural planes are classified into four groups with nine subsets. The research proposes the engineering geological classification of the structural plane for the hydropower project in the Emishan basalts, and the result of the study has a potential application in similar regions.展开更多
The development of long linear structures such as roads, rail roads, tunnels, canals and pipelines often has unique engineering geology challenges. These include geological modeling, the identification of material str...The development of long linear structures such as roads, rail roads, tunnels, canals and pipelines often has unique engineering geology challenges. These include geological modeling, the identification of material strength and support factors, stability and risk issues, material excavation characteristics and the proposal of techniques for overcoming geotechnical problems, which are normally assessed as part of the conventional engineering geological investigation. An additional factor that is becoming increasingly important but is seldom included in investigations is the sustainability of the geotechnical inputs, in contrast to the sustainability of the project which is generally included. Sustainability issues revolve around the non-renewable nature of most construction resources and there is no doubt that the injudicious use of these construction materials and construction water is not sustainable in the long term: it is thus essential that the engineering geo-logical investigation should take cognizance of such issues and be adapted to provide the design engineer with the information that will maximize the sustainability options. This will also require a closer on-going relation-ship between the engineering geologist and the design engineer. This paper highlights significant sustainability issues (note that these differ from conventional environmental issues) and suggests some mitigating solutions. The sustainability issues discussed include primarily material and water usage, with some reference to energy conservation (mostly through alternative material usage and processing techniques and transportation).展开更多
文摘The electronic structures and optical properties of rocksalt indium nitride (INN) under pressure were studied using the first-principles calculation by considering the exchange and correlation potentials with the generalized gradient approximation. The calculated lattice constant shows good agreement with the experimental value. It is interestingly found that the band gap energy Eg at the F or X point remarkably increases with increasing pressure, but Eg at the L point does not increase obviously. The pressure coefficient of Eg is calculated to be 44 meV/GPa at the F point. Moreover, the optical properties of rocksalt InN were calculated and discussed based on the calculated band structures and electronic density of states.
文摘Jianshanzi volcanic rocks at Qinghe valley in the northern Liaoning were considered belonging to Early Proterozoie Gaojiayu Formation of Liaohe Group, or to Early Cambrian Beidagou Formation of Qinghezhen Group, or Middle-Late Proterozoic Shenjiapu Formation-Complex of Kaiyuan Group-complex. Dating the zircons from the dacite with schistosity is 2 506 Ma in method of U-Pb (SHRIMP). This evidence indicates the rocks may be referred to Late Permian in age. Discovery of the rocks is significant to re-recognize stratigraphic property of "Liaohe Group", regional geoteetonie location and revolution of orogenic zone in Qinghe valley of the northern Liaoning.
文摘In order to analyze the stability of the underground rock structures,knowing the sensitivity of geomechanical parameters is important.To investigate the priority of these geomechanical properties in the stability of cavern,a sensitivity analysis has been performed on a single cavern in various rock mass qualities according to RMR using Phase 2.The stability of cavern has been studied by investigating the side wall deformation.Results showed that most sensitive properties are coefficient of lateral stress and modulus of deformation.Also parameters of Hoek-Brown criterion and r c have no sensitivity when cavern is in a perfect elastic state.But in an elasto-plastic state,parameters of Hoek-Brown criterion and r c affect the deformability;such effect becomes more remarkable with increasing plastic area.Other parameters have different sensitivities concerning rock mass quality(RMR).Results have been used to propose the best set of parameters for study on prediction of sidewall displacement.
文摘The methods combined by test, field monitoring and theoretical analysis were adopted to do the systemic research on the rock mass from micro-structure to macro-deformation, and rheological model of Jinchuan rock mass was established to discuss the reasonable supporting time. Resuhs show that supporting after suitable stress and displacement release can benefit for the long-term stability of surrounding rock.
基金Project supported by the National Natural Science Foundation of China (No. 40472040) and Starting Fund of Education Ministry, China
文摘The western Iratsu mass, the largest tectonic body in the Sambagawa metamorphic belt, central Shikoku, is mainly composed of epidote amphibolite with minor amounts of eclogite. Systematically, a majority of garnets show bell-shaped chemical zoning of pyrope contents and Mg/(Mg+Fe2+) monotonously increasing outward. The grossular component in zonal garnet increases outwards, maximizes at an intermediate part, and then decreases towards the outermost rim, reflecting a process from increasing to decreasing pressure conditions during the prograde metamorphism. Jadeite contents of omphacite range from 25~20mole% within the cores to 15~10 mole% at the rims, implying a pressure-decreasing process (from 11 × 105 Pa to 8 × 105 Pa). The peak pressure-temperature (P-T) condition of 630~680 ℃ and ca. 15× 105 Pa in the western Iratsu mass is much higher than that of (610±25) ℃ and (10± 1)× 105 Pa of the Sambagawa oligoclase-biotite zone schists. The authors suggest a clockwise P-T-t path for the western Iratsu mass.
基金supported by the National Natural Science Foundation of China(Nos.41774136 and 41374135)the Sichuan Science and Technology Program(No.2016ZX05004-003)
文摘Apparent differences in sedimentation and diagenesis exist between carbonate reservoirs in different areas and affect their petrophysical and elastic properties.To elucidate the relevant mechanism,we study and analyze the characteristics of rock microstructure and elastic properties of carbonates and their variation regularity using 89 carbonate samples from the different areas The results show that the overall variation regularities of the physical and elastic properties of the carbonate rocks are controlled by the microtextures of the microcrystalline calcite,whereas the traditional classification of rock-and pore-structures is no longer applicable.The micrite microtextures can be divided,with respect to their morphological features,into porous micrite,compact micrite,and tight micrite.As the micrites evolves from the first to the last type,crystal boundaries are observed with increasingly close coalescence,the micritic intercrystalline porosity and pore-throat radius gradually decrease;meanwhile,the rigidity of the calcite microcrystalline particle boundary and elastic homogeneity are enhanced.As a result,the seismic elastic characteristics,such as permeability and velocity of samples,show a general trend of decreasing with the increase of porosity.For low-porosity rock samples(φ<5%)dominated by tight micrite,the micritic pores have limited contributions to porosity and permeability and the micrite elastic properties are similar to those of the rock matrix.In such cases,the macroscopic physical and elastic properties are more susceptible to the formation of cracks and dissolution pores,but these features are controlled by the pore structure.The pore aspect ratio can be used as a good indication of pore types.The bulk modulus aspect ratio for dissolution pores is greater than 0.2,whereas that of the intergranular pores ranges from 0.1 to 0.2.The porous and compact micrites are observed to have a bulk modulus aspect ratio less than 0.1,whereas the ratio of the tight micrite approaches 0.2。
文摘In this paper, firstly, the rock slope and rock mass structure are introduced. And then, two aspects of the study of the structural plane are discussed: The first aspect is method for determining mechanical parameters of structural plane; The second aspect is analysis of shear strength of structural plane.
基金supported by the National Natural Science Foundation of China (No.50874103)the National Basic Research Program of China (No.2010CB226805)+1 种基金the Natural Science Foundation of Jiangsu Province (No.BK2008135)by the Open Foundation of State Key Laboratory of Geomechanics and Deep Underground Engineering (No.SKLGDUEK0905)
文摘The influence of an upper,mined coal seam on the stability of rock surrounding a roadway in a lower coal seam is examined.The technical problems of roadway control are discussed based on the geological conditions existing in the Liyazhuang Mine No.2 coal seam.The stress distribution and floor failure in the lower works after mining the upper coal is studied through numerical simulations.The failure mechanism of the roof and walls of a roadway located in the lower coal seam is described.The predicted deformation and failure of the roadway for different distances between the two coal seams are used to design two ways of supporting the lower structure.One is a combined support consisting of anchors with a joist steel tent and a combined anchor truss.A field test of the design was performed to good effect.The results have significance for the design of supports for roadways located in similar conditions.
基金supported by the National Natural Science Foundation of China (Nos.41974123,42174161)the Jiangsu Innovation and Entrepreneurship Plan and the Jiangsu Province Science Fund for Distinguished Young Scholars (grant no.BK20200021).
文摘In recent years,the Yanchang shale-oil formations of the Ordos Basin are rich in reserves with complex lithology and structure characteristics,low porosity and low permeability,and weak anomalies for oil and water discriminations,have been the key targets of unconventional oil/gas resource exploration and development in the relevant areas.The joint acoustic-electrical(AE)properties can be used to interpret reservoir lithology,mineralogy,pore structure,and fluid saturation.To conduct tests of thin section analysis,X-ray diff raction,and ultrasonic and electrical experiments at diff erent pressures and saturation degrees,cores from the shale-oil formations in the Q area of the basin are collected.The variations in AE properties with respect to clay content,porosity,pressure(microfracture),and saturation are analyzed.The experimental results indicate that the rock physics behaviors of sandstones with diff erent clay contents vary significantly.The AE properties of clean sandstones are basically dependent on the microfractures(pressure),while for muddy sandstones,the clay content is an important factor affecting the responses.The target reservoir consists of interbedded sandstone and shale layers.The AE equivalent medium equations and the Gurevich theory are applied to establish the joint models for the diff erent lithologies and simulate the variations in AE properties with respect to fluid type,pore structure,and mineral components.The three-dimensional joint templates of clean and muddy sandstones,as well as shale,are developed based on the elastic and electrical attributes and then calibrated using the experimental and well-log data.The reservoir properties are estimated with the templates and validated by the log data.The results indicate that the joint templates based on lithology characteristics can eff ectively characterize the properties of interbedded sandstone and shale layers.Furthermore,the combined application of AE data provides more beneficial information for the assessment of rock properties,leading to precise estimates that conform with the actual formation conditions.
基金funded by the National Natural Science Foundation of China (Grant No.41072228)
文摘The scale and characteristics of rock mass are important indexes of the rock mass structural plane classification. This paper firstly analyzes the spatial distribution characteristics, the structural plane types (original structural plane, tectonic structural plane and hypergenic structural plane) and the associated features of the Emeishan basalts and then studies the classification schemes of the built hydropower structure planes of different rock areas (the east district, the central district and the west district) in the Emeishan basalt distribution area, Southwest China. Based on the analysis and comparison of the scale and the engineering geological characteristics of the typical structure planes in the basalt hydroelectric Stations, the types of structural planes are used in the first order classification. The secondary order classification is made by considering the impact factors of rock mass quality, e.g., the state of the structural planes, infilling, joint opening, extending length, the grade of weathering and strength. The engineering geological classification for Emeishan basalt is proposed. Because there are no evidences of a large structure presenting in study area, the first-order (Ⅰ) controlling structural planes do not appear in the classification, there only appear Ⅱ, Ⅲ, Ⅳ and Ⅴ grade structural planes influencing the rock-mass quality. According to the different rock-block types in bedding fault zone, the second-grade (Ⅱ) structural planes consisted of bedding fault zone is further classified into Ⅱ1, Ⅱ2 and Ⅱ3. The third-grade (Ⅲ) structural planes constructed by intraformational faulted zones are not subdivided. According to the different characteristics of intrusion, alteration and weathering unloading structural planes, the Ⅳ grade structure plane is divided into Ⅳ1, Ⅳ2 and Ⅳ3. According to the development characteristics of joints and fractures, the V grade structure plane is divided into fracture Ⅴ1 and columnar joint Ⅴ2. In all, the structural planes are classified into four groups with nine subsets. The research proposes the engineering geological classification of the structural plane for the hydropower project in the Emishan basalts, and the result of the study has a potential application in similar regions.
文摘The development of long linear structures such as roads, rail roads, tunnels, canals and pipelines often has unique engineering geology challenges. These include geological modeling, the identification of material strength and support factors, stability and risk issues, material excavation characteristics and the proposal of techniques for overcoming geotechnical problems, which are normally assessed as part of the conventional engineering geological investigation. An additional factor that is becoming increasingly important but is seldom included in investigations is the sustainability of the geotechnical inputs, in contrast to the sustainability of the project which is generally included. Sustainability issues revolve around the non-renewable nature of most construction resources and there is no doubt that the injudicious use of these construction materials and construction water is not sustainable in the long term: it is thus essential that the engineering geo-logical investigation should take cognizance of such issues and be adapted to provide the design engineer with the information that will maximize the sustainability options. This will also require a closer on-going relation-ship between the engineering geologist and the design engineer. This paper highlights significant sustainability issues (note that these differ from conventional environmental issues) and suggests some mitigating solutions. The sustainability issues discussed include primarily material and water usage, with some reference to energy conservation (mostly through alternative material usage and processing techniques and transportation).