针对飞行时间质谱仪(TOF-MS)定量分析过程中存在的同质峰干扰问题,提出了一种谱峰分离的处理方法。首先,根据"TOF-MS质量数相近的谱峰,其形态也相似"的特点,通过高斯曲线与质谱数据的相关运算寻找单峰位置,再按照幅度的"...针对飞行时间质谱仪(TOF-MS)定量分析过程中存在的同质峰干扰问题,提出了一种谱峰分离的处理方法。首先,根据"TOF-MS质量数相近的谱峰,其形态也相似"的特点,通过高斯曲线与质谱数据的相关运算寻找单峰位置,再按照幅度的"择高弃低"原则选择个体单峰,对其进行叠加和归一化处理得到特征峰。然后,由特征峰构建功率谱密度函数,按照最小原则确定重叠峰位置及幅度,从而达到谱峰分离的目的。最后,将本文方法分别与Gaussin匹配法和Lorentzian匹配法进行了仿真比较,当处理对称峰(对称系数δ=0.2)时,这3种方法的效果基本一致,但当处理非对称峰(δ=1.6)时,本文方法的效果明显优于后两者。应用实例结果表明,采用本文方法对实测29 Si和28 Si 1 H重叠谱峰进行分离,可使分离度由0.371提升至0.519,提高39.9%,且能保持谱峰原始形态信息。展开更多
针对二进制偏移载波(BOC)调制信号捕获模糊问题,提出了一种基于本地BOC信号分解-合成的算法。首先,将副载波按照本地BOC信号的阶数n进行分解;其次,把分解得到的函数分别与伪随机码相乘,得到2n个BOC信号子函数,再分别与接收BOC信号作互...针对二进制偏移载波(BOC)调制信号捕获模糊问题,提出了一种基于本地BOC信号分解-合成的算法。首先,将副载波按照本地BOC信号的阶数n进行分解;其次,把分解得到的函数分别与伪随机码相乘,得到2n个BOC信号子函数,再分别与接收BOC信号作互相关得到2n个互相关函数;最后,将上一步得到的2n个互相关函数按照分解-合成算法进一步处理。理论分析和仿真结果表明,与OQCC算法相比,在捕获BOC(1,1)和BOC(2,1)信号时,该分解-合成算法的主副峰分离度(ASDMSP)有21.51 d B和3.4 d B的提高。实验结果表明,该分解-合成算法能够有效解决BOC信号捕获模糊问题。展开更多
A resolution method based on Gaussian-like distribution for overlapped linear sweep polarographic peaks was proposed to simultaneously detect the polymetallic components, such as Zn（Ⅱ） and Co（Ⅱ）, coexisting in t...A resolution method based on Gaussian-like distribution for overlapped linear sweep polarographic peaks was proposed to simultaneously detect the polymetallic components, such as Zn（Ⅱ） and Co（Ⅱ）, coexisting in the leaching solution of zinc hydrometallurgy. A Gaussian-like distribution was constructed as the sub-model of overlapped peaks by analyzing the characteristics of linear sweep polarographic curve. Then, the abscissas of each peak and trough were pinpointed through multi-resolution wavelet decomposition, the curve and its derivative curves were fitted by using nonlinear weighted least squares （NWLS）. Finally, overlapped peaks were resolved into independent sub-peaks based on fitted reconstruction parameters. The experimental results show that the relative error of half-wave potential pinpointed by multi-resolution wavelet decomposition is less than 1% and the accuracy of Ip fitted by NWLS is higher than 96%. The proposed resolution method is effective for overlapped linear sweep polarographic peaks of Zn（Ⅱ） and Co（Ⅱ）.展开更多
文摘针对飞行时间质谱仪(TOF-MS)定量分析过程中存在的同质峰干扰问题,提出了一种谱峰分离的处理方法。首先,根据"TOF-MS质量数相近的谱峰,其形态也相似"的特点,通过高斯曲线与质谱数据的相关运算寻找单峰位置,再按照幅度的"择高弃低"原则选择个体单峰,对其进行叠加和归一化处理得到特征峰。然后,由特征峰构建功率谱密度函数,按照最小原则确定重叠峰位置及幅度,从而达到谱峰分离的目的。最后,将本文方法分别与Gaussin匹配法和Lorentzian匹配法进行了仿真比较,当处理对称峰(对称系数δ=0.2)时,这3种方法的效果基本一致,但当处理非对称峰(δ=1.6)时,本文方法的效果明显优于后两者。应用实例结果表明,采用本文方法对实测29 Si和28 Si 1 H重叠谱峰进行分离,可使分离度由0.371提升至0.519,提高39.9%,且能保持谱峰原始形态信息。
文摘针对二进制偏移载波(BOC)调制信号捕获模糊问题,提出了一种基于本地BOC信号分解-合成的算法。首先,将副载波按照本地BOC信号的阶数n进行分解;其次,把分解得到的函数分别与伪随机码相乘,得到2n个BOC信号子函数,再分别与接收BOC信号作互相关得到2n个互相关函数;最后,将上一步得到的2n个互相关函数按照分解-合成算法进一步处理。理论分析和仿真结果表明,与OQCC算法相比,在捕获BOC(1,1)和BOC(2,1)信号时,该分解-合成算法的主副峰分离度(ASDMSP)有21.51 d B和3.4 d B的提高。实验结果表明,该分解-合成算法能够有效解决BOC信号捕获模糊问题。
基金Project(2012BAF03B05)supported by the National Key Technology R&D Program of ChinaProject(61025015)supported by the National Natural Science Foundation for Distinguished Young Scholars of China+1 种基金Project(61273185)supported by the National Natural Science Foundation of ChinaProject(2012CK4018)supported by the Science and Technology Project of Hunan Province,China
文摘A resolution method based on Gaussian-like distribution for overlapped linear sweep polarographic peaks was proposed to simultaneously detect the polymetallic components, such as Zn（Ⅱ） and Co（Ⅱ）, coexisting in the leaching solution of zinc hydrometallurgy. A Gaussian-like distribution was constructed as the sub-model of overlapped peaks by analyzing the characteristics of linear sweep polarographic curve. Then, the abscissas of each peak and trough were pinpointed through multi-resolution wavelet decomposition, the curve and its derivative curves were fitted by using nonlinear weighted least squares （NWLS）. Finally, overlapped peaks were resolved into independent sub-peaks based on fitted reconstruction parameters. The experimental results show that the relative error of half-wave potential pinpointed by multi-resolution wavelet decomposition is less than 1% and the accuracy of Ip fitted by NWLS is higher than 96%. The proposed resolution method is effective for overlapped linear sweep polarographic peaks of Zn（Ⅱ） and Co（Ⅱ）.
