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热动力学的研究——Ⅹ.一级反应的热谱峰高法 被引量:1
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作者 徐映宏 邓郁 《物理化学学报》 SCIE CAS CSCD 北大核心 1991年第5期601-604,共4页
本文根据一级反应的热谱曲线方程、建立了速度常数的一种新算法。这种新方法,只需要热谱曲线在各个特征时刻的峰高,而不需要任何峰面积,即可算得反应体系的无量纲参数和速度常数,称为一级反应的热谱峰高法。
关键词 热动力学 一级反应 热谱峰高法
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热动力学的研究(ⅩⅩⅢ)——一级反应的精选峰高法
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作者 王瑞林 段治华 +1 位作者 曾宪诚 邓郁 《高等学校化学学报》 SCIE EI CAS CSCD 北大核心 1992年第10期1295-1298,共4页
本文建立了一种只需要精选一级反应热谱曲线上2个任意时刻的峰高,而不需要任何其它数据即可算得其反应速度常数的新算法.研究了三乙胺和碘乙烷在二甲亚砜中的季铵化反应,其速度常数的计算值和文献值吻合很好,证明了本法的正确性.
关键词 热动力学 一级反应 精选峰高法
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峰高与峰面积统计量表示岩心黏土矿物相对含量的差异 被引量:7
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作者 张照鹏 褚忠信 李应坤 《海洋科学》 CAS CSCD 北大核心 2016年第12期107-113,共7页
目前黏土矿物分析主要依据XRD衍射峰的峰高或峰面积统计量,为了分析两种统计量计算黏土矿物相对含量的差异。对取自黄海的YSZD02岩心短柱开展了黏土矿物XRD测试,分别利用峰高和峰面积表示4种主要黏土矿物蒙皂石、伊利石、高岭石、绿泥... 目前黏土矿物分析主要依据XRD衍射峰的峰高或峰面积统计量,为了分析两种统计量计算黏土矿物相对含量的差异。对取自黄海的YSZD02岩心短柱开展了黏土矿物XRD测试,分别利用峰高和峰面积表示4种主要黏土矿物蒙皂石、伊利石、高岭石、绿泥石的相对百分含量,探究两种统计量表示黏土矿物相对含量随深度变化的差异,结果发现两算法都能显示黏土矿物的相对组成特征,对YSZD02岩心而言,其黏土矿物主要为伊利石,其次为高岭石,再次为绿泥石,最次为蒙皂石。两种算法得到的4种矿物的相关系数由高到低依次为:高岭石0.94,绿泥石0.93,蒙皂石0.82,伊利石0.73,呈正相关。峰面积法求4种矿物的相对含量随深度变化的离散程度比峰高法大。用峰高、峰面积法表示黏土矿物相对含量随深度的变化,两种方法相对差异由小到大依次为伊利石,高岭石,绿泥石和蒙皂石。以上结果表明两种算法既有共性又有明显的差异。随着分析技术的不断更新,相较于峰高法较难解决的误差问题,未来峰面积法会得到更广泛的应用。因此研发更精确的计算机分析软件、统一研究方法将是未来发展的必然趋势。本文的研究加深了对峰高与峰面积统计量的理解,为其他分析方法的比较与选择提供了参考。 展开更多
关键词 黏土矿物 相对含量 X射线衍射 峰高法 面积法
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付立叶变换红外光谱仪的定量分析方法 被引量:11
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作者 周长玉 《内蒙古石油化工》 CAS 2004年第5期81-82,共2页
本文对付立叶变换红外光谱常用的定量分析方法 ,如峰高法、峰面积法、谱带比值法、内标法、因子分析法、导数光谱法及化学计量方法进行了归纳总结。
关键词 付立叶变换红外光谱仪 定量分析 峰高法 面积法 谱带比值法 内标法 因子分析法 导数光谱法 化学计量方法
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用3600红外光谱数据站进行海泡石的定量分析
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作者 魏权凤 孔宪春 《陕西地质》 1989年第2期84-90,共7页
本文介绍用3600红外光谱数据站进行海泡石定量分析。该方法与以往用人工测量、计算的办法相比,可以提高效率和分析精度。与用 PE983G 红外分光光度计主机作定量分析相比,又可大批量测定含量。故为目前非金属矿物相定量较好的方法。用红... 本文介绍用3600红外光谱数据站进行海泡石定量分析。该方法与以往用人工测量、计算的办法相比,可以提高效率和分析精度。与用 PE983G 红外分光光度计主机作定量分析相比,又可大批量测定含量。故为目前非金属矿物相定量较好的方法。用红外光谱测定的值与化学分析结果相比,两者是正相关关系,误差在允许的范围内。 展开更多
关键词 海泡石 定量分析方法 红外光谱测定 数据站 分析结果 一阶导数 求值方法 峰高法 红外分光光度计 二阶导数
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OPTIMIZATION OF AIRPORT TAXIING PLANNING DURING CONGESTED HOURS BASED ON IMMUNE CLONAL SELECTION ALGORITHM 被引量:1
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作者 柳青 吴桐水 宋祥波 《Transactions of Nanjing University of Aeronautics and Astronautics》 EI 2012年第3期294-301,共8页
In order to ease congestion and ground delays in major hub airports, an aircraft taxiing scheduling optimization model is proposed with schedule time as the object function. In the new model, the idea of a classical j... In order to ease congestion and ground delays in major hub airports, an aircraft taxiing scheduling optimization model is proposed with schedule time as the object function. In the new model, the idea of a classical job shop-schedule problem is adopted and three types of special aircraft-taxi conflicts are considered in the constraints. To solve such nondeterministic polynomial time-complex problems, the immune clonal selection algorithm(ICSA) is introduced. The simulation results in a congested hour of Beijing Capital International Airport show that, compared with the first-come-first-served(FCFS) strategy, the optimization-planning strategy reduces the total scheduling time by 13.6 min and the taxiing time per aircraft by 45.3 s, which improves the capacity of the runway and the efficiency of airport operations. 展开更多
关键词 aircraft taxiing schedule airport operation control hub airport congested hours immune clonal selection algorithm(ICSA)
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Using Path Analysis to Identify the Influence of Climatic Factors on Spring Peak Flow Dominated by Snowmelt in an Alpine Watershed 被引量:16
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作者 ZHANG Fei-Yun LI Lan-Hai +1 位作者 AHMAD Sajjad LI Xue-Mei 《Journal of Mountain Science》 SCIE CSCD 2014年第4期990-1000,共11页
Spring snowmelt peak flow (SSPF) can cause serious damage. Precipitation as rainfall directly contributes to the SSPF and influences the characteristics of the SSPF, while temperature indirectly impacts the SSPF by ... Spring snowmelt peak flow (SSPF) can cause serious damage. Precipitation as rainfall directly contributes to the SSPF and influences the characteristics of the SSPF, while temperature indirectly impacts the SSPF by shaping snowmelt rate and determining the soil frozen state which partitions snowmelt water into surface runoff and soil infiltration water in spring. It is necessary to identify the important and significant paths of climatic factors influencing the SSPF and provide estimates of the magnitude and significance of hypothesized causal connections between climatic factors and the SSPF. This study used path analysis with a selection of five factors - the antecedent precipitation index (API), spring precipitation (SP), winter precipitation as snowfall (WS), 〈0℃ temperature accumulation in winter ([ATNI), and average 〉0℃temperature accumulation in spring (AT) - to analyze their influences on the SSPF in the Kaidu River in Xinjiang, China. The results show that {ATN}, AT and WS have a significant correlation with the SSPF, while API and SP do not show a significant correlation. AT and WS directly influence the SSPF, while as the influence of[ATN] on SSPF is indirect through WS and AT. The indirect influence of [ATN[ on SSPF through WS accounts for 69% of the total influence of [ATN] on SSPF. Compared to the multiple linear regression method, path analysis provides additional valuable information, including influencing paths from independent variables to the dependent variable as well as direct and indirect impacts of external variables on the internal variable. This information can help improve the description of snow melt and spring runoff in hydrologic models as well as the planning and management of water resources. 展开更多
关键词 SNOWMELT Peak flow Path analysis Alpine watershed
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A statistical approach to fit Gaussian part of full-energy peaks from Si(PIN) and SDD X-ray spectrometers 被引量:4
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作者 LI Zhe TUO XianGuo +1 位作者 SHI Rui YANG JianBo 《Science China(Technological Sciences)》 SCIE EI CAS 2014年第1期19-24,共6页
A new statistical fitting approach, named Statistical Distribution-Based Analytic (SDA) method, is proposed to fit single Gaussian-shaped Ka and KI3 X-ray peaks recorded by Si(PIN) and silicon drift detector (SDD... A new statistical fitting approach, named Statistical Distribution-Based Analytic (SDA) method, is proposed to fit single Gaussian-shaped Ka and KI3 X-ray peaks recorded by Si(PIN) and silicon drift detector (SDD). In this method, we use the dis- crete distribution theory to calculate standard deviation of energy resolution a. The calibration of cr and energy (E) for two de- tectors between the energy ranges of 4.5-26 keV are also completed by measuring characteristic X-ray spectra of nineteen types of pure elements. With the spectrum fraction (SF) parameter proposed in this paper, the SDA method can be used to re- solve overlapping peaks. In measured spectra, the Gaussian part of X-ray peaks can be fitted by a Gaussian function with two parameters, ~ and SF. This new fitting approach is simpler than traditional methods and it achieves relatively good results when fitting the complex X-ray spectra of national standard alloy samples detected by Si(PIN) and SDD detectors. The 3(2 values are obtained for each spectrum to assess fitting results, and the SDA fitting method gives a preferable fit for the SDD detector. 展开更多
关键词 Gaussian distribution Si(PIN) SDD EDXRF standard deviation of energy resolution
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