A ternary composite of TiO2 and a SiO2-Al2O3 aerogel with good photocatalytic activity was prepared by a simple sol-gel method with TiO2 nanoparticles and SiO2-Al2O3 aerogels derived from industrial fly ash.The struct...A ternary composite of TiO2 and a SiO2-Al2O3 aerogel with good photocatalytic activity was prepared by a simple sol-gel method with TiO2 nanoparticles and SiO2-Al2O3 aerogels derived from industrial fly ash.The structural features of the TiO2/SiO2-Al2O3 aerogel composite were investigated by X-ray powder diffraction,Fourier transform infrared spectroscopy,transmission electron microscopy,gas adsorption measurements and diffuse reflectance UV-visible spectroscopy.The optimal conditions for photocatalytic degradation of 2-sec-butyl-4,6-dinitrophenol（DNBP],included an initial DNBP concentration of 0.167 mmol/L at pH = 4.86 with a catalyst concentration of 6 g/L,under visible light irradiation for 5 h.A plausible mechanism is proposed for the photocatalytic degradation of DNBP.Our composite showed higher photocatalytic activity for DNBP degradation than that of pure TiO2.This indicates that this material can serve as an efficient photocatalyst for degradation of hazardous organic pollutants in wastewater.展开更多
Northeast China is the largest old industrial base of China that endured persistent influence of the past planned economy system. This region has lost its leading place since the reform and opening up, and became a ba...Northeast China is the largest old industrial base of China that endured persistent influence of the past planned economy system. This region has lost its leading place since the reform and opening up, and became a backward region by contrast with the coastal areas. This paper elaborates the evolutionary process of the old industrial base of Northeast China, analyses the main reasons for the decline, gives a preliminary evaluation on the revitalizing polices in recent years, and points out major long-term challenges for future revitalization. It concludes that for Northeast China, a relative declining area: 1) it is indispensable to get the long-term policy support from the central government; 2) system reform and structure adjustment are the crucial strategies, particularly the reform of the large and medium state-owned enterprises; and devel-oping new industries is as important as upgrading traditional advantaged industries; 3) the local governments should play an indirect role, avoiding from any unnecessary intervention on economic activity; and 4) social security and investment climate must be improved simultaneously. In addition, the author stresses that the lack of knowledge on the nature of old industrial base had led to failures of the past initiatives, and revitalizing the old industrial base should be treated as a holis-tic regional project including economy growth, society progress and environment improvement.展开更多
With the purpose of enhancing effective collaboration between architects and structural engineers in the building design field, an integration tool was developed for supporting information exchange from architectural ...With the purpose of enhancing effective collaboration between architects and structural engineers in the building design field, an integration tool was developed for supporting information exchange from architectural model to structural model. The PKPM （Bopomofo acronym, a Chinese building design software） structural model and an industry foundation classes （IFC） data model were adopted and analyzed to design the framework of the integration tool. The technique of mixed program languages （C＋＋ and FORTRAN） was applied to developing the tool software, and the connectivity relationships and intersection nodes between the structural elements were optimized and simplified. A case study was implemented to illustrate the method to use the integration tool for information exchange from IFC-format architectural model to PKPM structural model. The results show that the tool can extract the information of architectural model and form a corresponding structural model. The presented method can help to enhance the modeline efficiency at the structural design phase.展开更多
基金supported by the National Natural Science Foundation of China(21377018)the Natural Science Foundation of Liaoning Province of China(2013020116)the Fundamental Research Funds for the Central Universities(DUT15ZD240)~~
文摘A ternary composite of TiO2 and a SiO2-Al2O3 aerogel with good photocatalytic activity was prepared by a simple sol-gel method with TiO2 nanoparticles and SiO2-Al2O3 aerogels derived from industrial fly ash.The structural features of the TiO2/SiO2-Al2O3 aerogel composite were investigated by X-ray powder diffraction,Fourier transform infrared spectroscopy,transmission electron microscopy,gas adsorption measurements and diffuse reflectance UV-visible spectroscopy.The optimal conditions for photocatalytic degradation of 2-sec-butyl-4,6-dinitrophenol（DNBP],included an initial DNBP concentration of 0.167 mmol/L at pH = 4.86 with a catalyst concentration of 6 g/L,under visible light irradiation for 5 h.A plausible mechanism is proposed for the photocatalytic degradation of DNBP.Our composite showed higher photocatalytic activity for DNBP degradation than that of pure TiO2.This indicates that this material can serve as an efficient photocatalyst for degradation of hazardous organic pollutants in wastewater.
基金Under the auspices of National Natural Science Foundation of China (No. 40635030, 40471038)Knowledge Innova-tion Program of Chinese Academy of Sciences (No. kzcxz-YW-321-04)
文摘Northeast China is the largest old industrial base of China that endured persistent influence of the past planned economy system. This region has lost its leading place since the reform and opening up, and became a backward region by contrast with the coastal areas. This paper elaborates the evolutionary process of the old industrial base of Northeast China, analyses the main reasons for the decline, gives a preliminary evaluation on the revitalizing polices in recent years, and points out major long-term challenges for future revitalization. It concludes that for Northeast China, a relative declining area: 1) it is indispensable to get the long-term policy support from the central government; 2) system reform and structure adjustment are the crucial strategies, particularly the reform of the large and medium state-owned enterprises; and devel-oping new industries is as important as upgrading traditional advantaged industries; 3) the local governments should play an indirect role, avoiding from any unnecessary intervention on economic activity; and 4) social security and investment climate must be improved simultaneously. In addition, the author stresses that the lack of knowledge on the nature of old industrial base had led to failures of the past initiatives, and revitalizing the old industrial base should be treated as a holis-tic regional project including economy growth, society progress and environment improvement.
基金Project(2006BAJ01B01-01) supported by the National Key Technologies R&D Program of China during the 11th Five-Year Plan Period
文摘With the purpose of enhancing effective collaboration between architects and structural engineers in the building design field, an integration tool was developed for supporting information exchange from architectural model to structural model. The PKPM （Bopomofo acronym, a Chinese building design software） structural model and an industry foundation classes （IFC） data model were adopted and analyzed to design the framework of the integration tool. The technique of mixed program languages （C＋＋ and FORTRAN） was applied to developing the tool software, and the connectivity relationships and intersection nodes between the structural elements were optimized and simplified. A case study was implemented to illustrate the method to use the integration tool for information exchange from IFC-format architectural model to PKPM structural model. The results show that the tool can extract the information of architectural model and form a corresponding structural model. The presented method can help to enhance the modeline efficiency at the structural design phase.
