The microstructure,texture,and yield strength of an advanced heat-resistant alloy weldment made with composition-matched weld filler were investigated.Scanning electron microscopy,energy dispersive spectroscopy,and el...The microstructure,texture,and yield strength of an advanced heat-resistant alloy weldment made with composition-matched weld filler were investigated.Scanning electron microscopy,energy dispersive spectroscopy,and electron backscatter diffraction were used to characterize the microstructural and textural changes.Various grain boundary engineering(GBE)processes were performed on the weldment.The yield strengths of the weldment at 973 K were obtained before and after GBE processing,and were mostly consistent with the theoretically predicted values.The coincident-site lattices,misorientation,and recrystallization of the weld metal after GBE were analyzed,and the results indicate that the increase in dislocation density and the improvement in special grain boundaries in the weld metal are the main reasons for the yield strength elevation of the weldment after GBE.The variation in elongation after high-temperature tests has the same tendency as that in the impact toughness with different GBE parameters,which is related to the coarsening behavior of carbides.展开更多
A numerical approach was developed to analyze the transient behavior of towed cable during ac- tively controlled deployment/retrieval (DR).The cable motion is described by the lumped parameter method, its correspondin...A numerical approach was developed to analyze the transient behavior of towed cable during ac- tively controlled deployment/retrieval (DR).The cable motion is described by the lumped parameter method, its corresponding boundary conditions are presented.In view of its varying length during DR,two auxiliary arguments are introduced to describe its continuous varying length and discrete number of nodes(equations), the length is determined by the pay out(or reel-in) rate,which is then used to determine the node number by a logic relation.For the discrete mathematical model of towed cable,an algorithm was developed to deal with the discrete governing equations.The simulation results indicate that the cable experiences more com- plex motions due to its varying length,and tension fluctuates seriously in the startup and ending stage of deployment/retrieval.The effect of towing ship's motion in waves on cable during deployment/retrieval is also considered via numerical simulation.展开更多
A comprehensive understanding of the role of the electrocatalyst in photoelectrochemical(PEC)water splitting is central to improving its performance.Herein,taking the Si-based photoanodes(n^(+)p-Si/SiO_(x)/Fe/FeOx/MOO...A comprehensive understanding of the role of the electrocatalyst in photoelectrochemical(PEC)water splitting is central to improving its performance.Herein,taking the Si-based photoanodes(n^(+)p-Si/SiO_(x)/Fe/FeOx/MOOH,M=Fe,Co,Ni)as a model system,we investigate the effect of the transition-metal electrocatalysts on the oxygen evolution reaction(OER).Among the photoanodes with the three different electrocatalysts,the best OER activity,with a low-onset potential of∼1.01 VRHE,a high photocurrent density of 24.10 mA cm^(-2)at 1.23 VRHE,and a remarkable saturation photocurrent density of 38.82 mA cm^(-2),was obtained with the NiOOH overlayer under AM 1.5G simulated sunlight(100 mW cm^(-2))in 1 M KOH electrolyte.The optimal interfacial engineering for electrocatalysts plays a key role for achieving high performance because it promotes interfacial charge transport,provides a larger number of surface active sites,and results in higher OER activity,compared to other electrocatalysts.This study provides insights into how electrocatalysts function in water-splitting devices to guide future studies of solar energy conversion.展开更多
Many problems in rock engineering are limited by our imperfect knowledge of the material properties and failure mechanics of rock masses. Mining problems are somewhat unique, however, in that plenty of real world expe...Many problems in rock engineering are limited by our imperfect knowledge of the material properties and failure mechanics of rock masses. Mining problems are somewhat unique, however, in that plenty of real world experience is generally available and can be turned into valuable experimental data.Every pillar that is developed, or stope that is mined, represents a full-scale test of a rock mechanics design. By harvesting these data, and then using the appropriate statistical techniques to interpret them,mining engineers have developed powerful design techniques that are widely used around the world.Successful empirical methods are readily accepted because they are simple, transparent, practical, and firmly tethered to reality. The author has been intimately associated with empirical design for his entire career, but his previous publications have described the application of individual techniques to specific problems. The focus of this paper is the process used to develop a successful empirical method. A sixstage process is described: identification of the problem, and of the end users of the final product; development of a conceptual rock mechanics model, and identification of the key parameters in that model;identification of measures for each of the key parameters, and the development of new measures(such as rating scales) where necessary; data sources and data collection; statistical analysis; and packaging of the final product. Each of these stages has its own potential rewards and pitfalls, which will be illustrated by incidents from the author's own experience. The ultimate goal of this paper is to provide a new and deeper appreciation for empirical techniques, as well as some guidelines and opportunities for future developers.展开更多
Interface engineering has been widely investigated to regulate the structure and performance of electrodes and photoelectrodes,but the investigation of multiple carbon interface modifications on the electrocatalytic o...Interface engineering has been widely investigated to regulate the structure and performance of electrodes and photoelectrodes,but the investigation of multiple carbon interface modifications on the electrocatalytic oxygen evolution reaction(OER)is still shortage.Herein,we report remarkable promotion of OER performance on the NiFe‐based nanocomposite electrocatalyst via the synergy of multiple carbon‐based interface engineering.Specifically,carbon nanotubes were in situ grown on carbon fiber paper to improve the interface between CFP and NiFeO_(x)H_(y),and graphite carbon nanoparticles were in situ loaded and partly doped into the NiFeO_(x)H_(y) to modify the intergranular interface charge transfer and electronic structure of NiFeO_(x)H_(y).Consequently,the as‐obtained NiFeO_(x)H_(y)‐C/CNTs/CFP catalyst exhibited significantly enhanced electrocatalytic OER activity with an overpotential of 202 mV at 10 mA cm^(-2) in 1 mol L^(-1) KOH.Our work not only extends application of carbon materials but also provides an alternative strategy to develop highly efficient electrocatalysts.展开更多
Prediction of the state of roof collapse is a big challenge in tunnel engineering, while the limit analysis theory makes it possible to derive the analytical solutions of the collapse mechanisms. In this work, an exac...Prediction of the state of roof collapse is a big challenge in tunnel engineering, while the limit analysis theory makes it possible to derive the analytical solutions of the collapse mechanisms. In this work, an exact solution of collapsing shape in shallow underwater tunnel is obtained by using the variation principle and the upper bound theorem based on nonlinear failure criterion. Numerical results under the effect of river water and supporting pressure are derived and discussed. The maximum water depth above the river bottom surface is determined under a given buried depth of shallow cavities and the critical depth of roof collapse is obtained under a constant river depth. In comparison with the previous results, the present solution shows a good agreement with the practical results.展开更多
基金Project(51475326)supported by the National Natural Science Foundation of ChinaProject(BHSF2017-22)supported by the Demonstration Program of National Marine Economic Innovation of Tianjin City,China。
文摘The microstructure,texture,and yield strength of an advanced heat-resistant alloy weldment made with composition-matched weld filler were investigated.Scanning electron microscopy,energy dispersive spectroscopy,and electron backscatter diffraction were used to characterize the microstructural and textural changes.Various grain boundary engineering(GBE)processes were performed on the weldment.The yield strengths of the weldment at 973 K were obtained before and after GBE processing,and were mostly consistent with the theoretically predicted values.The coincident-site lattices,misorientation,and recrystallization of the weld metal after GBE were analyzed,and the results indicate that the increase in dislocation density and the improvement in special grain boundaries in the weld metal are the main reasons for the yield strength elevation of the weldment after GBE.The variation in elongation after high-temperature tests has the same tendency as that in the impact toughness with different GBE parameters,which is related to the coarsening behavior of carbides.
文摘A numerical approach was developed to analyze the transient behavior of towed cable during ac- tively controlled deployment/retrieval (DR).The cable motion is described by the lumped parameter method, its corresponding boundary conditions are presented.In view of its varying length during DR,two auxiliary arguments are introduced to describe its continuous varying length and discrete number of nodes(equations), the length is determined by the pay out(or reel-in) rate,which is then used to determine the node number by a logic relation.For the discrete mathematical model of towed cable,an algorithm was developed to deal with the discrete governing equations.The simulation results indicate that the cable experiences more com- plex motions due to its varying length,and tension fluctuates seriously in the startup and ending stage of deployment/retrieval.The effect of towing ship's motion in waves on cable during deployment/retrieval is also considered via numerical simulation.
文摘A comprehensive understanding of the role of the electrocatalyst in photoelectrochemical(PEC)water splitting is central to improving its performance.Herein,taking the Si-based photoanodes(n^(+)p-Si/SiO_(x)/Fe/FeOx/MOOH,M=Fe,Co,Ni)as a model system,we investigate the effect of the transition-metal electrocatalysts on the oxygen evolution reaction(OER).Among the photoanodes with the three different electrocatalysts,the best OER activity,with a low-onset potential of∼1.01 VRHE,a high photocurrent density of 24.10 mA cm^(-2)at 1.23 VRHE,and a remarkable saturation photocurrent density of 38.82 mA cm^(-2),was obtained with the NiOOH overlayer under AM 1.5G simulated sunlight(100 mW cm^(-2))in 1 M KOH electrolyte.The optimal interfacial engineering for electrocatalysts plays a key role for achieving high performance because it promotes interfacial charge transport,provides a larger number of surface active sites,and results in higher OER activity,compared to other electrocatalysts.This study provides insights into how electrocatalysts function in water-splitting devices to guide future studies of solar energy conversion.
文摘Many problems in rock engineering are limited by our imperfect knowledge of the material properties and failure mechanics of rock masses. Mining problems are somewhat unique, however, in that plenty of real world experience is generally available and can be turned into valuable experimental data.Every pillar that is developed, or stope that is mined, represents a full-scale test of a rock mechanics design. By harvesting these data, and then using the appropriate statistical techniques to interpret them,mining engineers have developed powerful design techniques that are widely used around the world.Successful empirical methods are readily accepted because they are simple, transparent, practical, and firmly tethered to reality. The author has been intimately associated with empirical design for his entire career, but his previous publications have described the application of individual techniques to specific problems. The focus of this paper is the process used to develop a successful empirical method. A sixstage process is described: identification of the problem, and of the end users of the final product; development of a conceptual rock mechanics model, and identification of the key parameters in that model;identification of measures for each of the key parameters, and the development of new measures(such as rating scales) where necessary; data sources and data collection; statistical analysis; and packaging of the final product. Each of these stages has its own potential rewards and pitfalls, which will be illustrated by incidents from the author's own experience. The ultimate goal of this paper is to provide a new and deeper appreciation for empirical techniques, as well as some guidelines and opportunities for future developers.
文摘Interface engineering has been widely investigated to regulate the structure and performance of electrodes and photoelectrodes,but the investigation of multiple carbon interface modifications on the electrocatalytic oxygen evolution reaction(OER)is still shortage.Herein,we report remarkable promotion of OER performance on the NiFe‐based nanocomposite electrocatalyst via the synergy of multiple carbon‐based interface engineering.Specifically,carbon nanotubes were in situ grown on carbon fiber paper to improve the interface between CFP and NiFeO_(x)H_(y),and graphite carbon nanoparticles were in situ loaded and partly doped into the NiFeO_(x)H_(y) to modify the intergranular interface charge transfer and electronic structure of NiFeO_(x)H_(y).Consequently,the as‐obtained NiFeO_(x)H_(y)‐C/CNTs/CFP catalyst exhibited significantly enhanced electrocatalytic OER activity with an overpotential of 202 mV at 10 mA cm^(-2) in 1 mol L^(-1) KOH.Our work not only extends application of carbon materials but also provides an alternative strategy to develop highly efficient electrocatalysts.
基金Foundation item： Project（2013CB036004） supported by the National Basic Research Program of China Project（51178468） supported by the National Natural Science Foundation of China Project（2013zzts235） supported by Research Foundation of Central South University, China
文摘Prediction of the state of roof collapse is a big challenge in tunnel engineering, while the limit analysis theory makes it possible to derive the analytical solutions of the collapse mechanisms. In this work, an exact solution of collapsing shape in shallow underwater tunnel is obtained by using the variation principle and the upper bound theorem based on nonlinear failure criterion. Numerical results under the effect of river water and supporting pressure are derived and discussed. The maximum water depth above the river bottom surface is determined under a given buried depth of shallow cavities and the critical depth of roof collapse is obtained under a constant river depth. In comparison with the previous results, the present solution shows a good agreement with the practical results.
