Aim To determine the structure of the by-product produced in Grignard reaction for preparing mifepristone derivatives, and elucidate the reaction mechanism.Methods The structure of the by-product was determined with e...Aim To determine the structure of the by-product produced in Grignard reaction for preparing mifepristone derivatives, and elucidate the reaction mechanism.Methods The structure of the by-product was determined with elemental analysis, one- and two-dimension spectra NMR (DEPT, 1H-1Hcosy, HMQC, HMBC) and compared with those of mifepristone.Results The main by-product was 11,17-di-addition product of Grignard reagent of N, N-dimethylamino phenyl bromide.Conclusion This is the first complete assignment of 1H NMR and 13C NMR of compound (3).展开更多
Yam hairiness is a complex concept, which generally cannot be completely defined by a single figure. Hairiness can be considered as the fiber ends and loops standing out from the main compact yarn body. Uster hairines...Yam hairiness is a complex concept, which generally cannot be completely defined by a single figure. Hairiness can be considered as the fiber ends and loops standing out from the main compact yarn body. Uster hairiness system characterizes the hairiness by H value, i.e. the mean value of the total length of all hairs within one centimeter of yarn. The raw data HI are in fact realization of spatial process （hairiness spatial process -- HSP） and can be used for more complex evaluation of hairiness characteristics in the space and frequency domain. The main aim of this contribution is description of some tools for spatial characterization of yarn hairiness. The simple methods for complex characterization of lISP statistical behavior （stationarity, independence, linearity etc. ） are presented. The techniques based on the embedding dimension and correlation integral or long-range dependences evaluation are discussed. The selected methods are core of HYARN program in MATLAB. Application of this program for deeper characterization of artificial data and cotton type yam are shown.展开更多
文摘Aim To determine the structure of the by-product produced in Grignard reaction for preparing mifepristone derivatives, and elucidate the reaction mechanism.Methods The structure of the by-product was determined with elemental analysis, one- and two-dimension spectra NMR (DEPT, 1H-1Hcosy, HMQC, HMBC) and compared with those of mifepristone.Results The main by-product was 11,17-di-addition product of Grignard reagent of N, N-dimethylamino phenyl bromide.Conclusion This is the first complete assignment of 1H NMR and 13C NMR of compound (3).
基金Supported by the research project"Textile center"of Czech Ministry of Education1M4674788501
文摘Yam hairiness is a complex concept, which generally cannot be completely defined by a single figure. Hairiness can be considered as the fiber ends and loops standing out from the main compact yarn body. Uster hairiness system characterizes the hairiness by H value, i.e. the mean value of the total length of all hairs within one centimeter of yarn. The raw data HI are in fact realization of spatial process （hairiness spatial process -- HSP） and can be used for more complex evaluation of hairiness characteristics in the space and frequency domain. The main aim of this contribution is description of some tools for spatial characterization of yarn hairiness. The simple methods for complex characterization of lISP statistical behavior （stationarity, independence, linearity etc. ） are presented. The techniques based on the embedding dimension and correlation integral or long-range dependences evaluation are discussed. The selected methods are core of HYARN program in MATLAB. Application of this program for deeper characterization of artificial data and cotton type yam are shown.
