In this work, through the comparison analysis with the results of the thermogravimetry-differential scanning calorimetry-mass spectrometry (TG-DSC-MS) coupling techniques for the three organic additive and aqueous tap...In this work, through the comparison analysis with the results of the thermogravimetry-differential scanning calorimetry-mass spectrometry (TG-DSC-MS) coupling techniques for the three organic additive and aqueous tape casting aluminum nitride in air and nitrogen atmosphere, it can be found that the plasticity glycerol was almost burnout before 350℃ in two atmosphere; the binder PVA124 was almost burnout before 600℃ in air, there was little left in nitrogen; The mass losses of the dispersant DP270 in air and nitrogen atmosphere were about 73.32% and 65.51% before 600℃ ; The mass losses of the aqueous tape casting aluminum nitride in air (14.08%) were higher that in nitrogen (10.75%) before 600℃. It can be concluded that the organic additive burnout of the aqueous tape casting aluminum nitride in air atmosohere was better than in nitrogen atmosphere.展开更多
文摘In this work, through the comparison analysis with the results of the thermogravimetry-differential scanning calorimetry-mass spectrometry (TG-DSC-MS) coupling techniques for the three organic additive and aqueous tape casting aluminum nitride in air and nitrogen atmosphere, it can be found that the plasticity glycerol was almost burnout before 350℃ in two atmosphere; the binder PVA124 was almost burnout before 600℃ in air, there was little left in nitrogen; The mass losses of the dispersant DP270 in air and nitrogen atmosphere were about 73.32% and 65.51% before 600℃ ; The mass losses of the aqueous tape casting aluminum nitride in air (14.08%) were higher that in nitrogen (10.75%) before 600℃. It can be concluded that the organic additive burnout of the aqueous tape casting aluminum nitride in air atmosohere was better than in nitrogen atmosphere.
文摘为研究哈尔滨黏土在低温条件下冻土中未冻水含量特性,通过差式扫描量热法(differential scanning calorimetry,DSC)研究了不同初始含水量的哈尔滨本地黏土、高岭土和蒙脱土在冻结过程中的未冻水含量变化,并结合微观角度的扫描电子显微镜(scanning electron microscope,SEM)实验、中观角度的液塑限实验对不同黏土颗粒土质以及哈尔滨黏土粒度进行实验研究。结果表明,温度因素对于未冻水含量变化的影响最为显著,可将未冻水含量的变化过程依据节点温度分为3个典型阶段,分别为恒定不变段、剧烈下降段和缓慢降低段。初始含水量主要影响冻结过程第二阶段,初始含水量越高,第二阶段冻结的水量越多。土质不同,其未冻水变化曲线不同。粒度分布主要影响冻结过程的第三阶段,粒径越小,等效微小孔隙越多,第三阶段未冻水含量变化相对更剧烈。可见哈尔滨黏土的冻结过程中的未冻水含量特性除了与初始含水量和温度有着密切联系,同时也受到土体的土质、粒度的影响。
