Ebulliometric method based on the error analysis equation is presented for systems with the large phase equilibrium constant. Application is given for the determination and calculation of binary vapor-liquid equilibri...Ebulliometric method based on the error analysis equation is presented for systems with the large phase equilibrium constant. Application is given for the determination and calculation of binary vapor-liquid equilibrium data for the ethanol+n-hexane system. It is also given the comparison results between the ebulliometric method based on the error analysis equation and the quasi-static method.展开更多
Isoplethic VLE data for the systems benzene-hexane at 9 different compositions in the temperature range from 298 K to 331K, chloroform-benzene at 11 different compositions in the temperature range from 308 K to 350 K ...Isoplethic VLE data for the systems benzene-hexane at 9 different compositions in the temperature range from 298 K to 331K, chloroform-benzene at 11 different compositions in the temperature range from 308 K to 350 K and chloroform-hexane at 9 different compositions in the temperature range from 311 K to 337 K were determined by using an inclined ebulliometer with a pump-like stirrer. Isothermal and isobaric VLE were calculated from the isoplethic results with a extended UNIQUAC equation and these data agree well with the literature data.展开更多
基金Supported by the National Natural Science Foundation of China(No. 29976035) and the Natural Science Foundation of Zhejiang Province.
文摘Ebulliometric method based on the error analysis equation is presented for systems with the large phase equilibrium constant. Application is given for the determination and calculation of binary vapor-liquid equilibrium data for the ethanol+n-hexane system. It is also given the comparison results between the ebulliometric method based on the error analysis equation and the quasi-static method.
基金Supported by Zhejiang Provincial Natural Science Foundation of China.
文摘Isoplethic VLE data for the systems benzene-hexane at 9 different compositions in the temperature range from 298 K to 331K, chloroform-benzene at 11 different compositions in the temperature range from 308 K to 350 K and chloroform-hexane at 9 different compositions in the temperature range from 311 K to 337 K were determined by using an inclined ebulliometer with a pump-like stirrer. Isothermal and isobaric VLE were calculated from the isoplethic results with a extended UNIQUAC equation and these data agree well with the literature data.