To investigate the interactions of oppositely charged sites on the surfaces of variable-charge soil particles with cations and anions, and to evaluate the mean Gibbs free binding and adsorption energies of various cat...To investigate the interactions of oppositely charged sites on the surfaces of variable-charge soil particles with cations and anions, and to evaluate the mean Gibbs free binding and adsorption energies of various cations on particles of red soil and latosol, clay fractions smaller than 2 μm were separated from samples of the two variable-charge soils. Ferric oxides were removed from part of the clay fractions, which were then saturated with various chlorides （NaC1, KCl, CaCl2, CdCl2 or LaCl3）. Electrical conductivities （EC） of dilute suspensions of the original and of the iron oxides-free clay fractions in deionized water were measured with the SHP-2 short high-voltage pulse apparatus, which enables measurement of the Wien effect at field strengths （E） from 14 to 250 kV cm^-1. The Wien effect （EC-E） curves revealed EC increases of red soil suspensions between 14 and 200 kV cm^-1, of 8.3, 8.4, 12.1, 5.9, and 1.2 μS cm^-1 for NaCl, KCl, CaCl2, CdCl2, and LaCl3, respectively, reflecting the differing interactions with the various cations and chloride. The EC increments with the iron-free red soil suspensions were higher, being 29.7, 17.2, and 15.3 μS cm^-1 for NaCl, CaCl2, and CdCl2, respectively. In the natural latosol suspensions the EC increments were practically zero, whereas in the iron-free fractions there were significant EC increments of 10.3, 5.7, 5.0, and 1.6μS cm^-1 for NaCl, CaCl2, CdCl2, and LaCl3, respectively.展开更多
The galvanic corrosion behaviour of alumiuium 3004 - ∝ brass with different area ratios was studied in the tropical marine atmosphere at Tuticorin harbour over a period of 426 days. The area ratios, viz. AAluminiurn...The galvanic corrosion behaviour of alumiuium 3004 - ∝ brass with different area ratios was studied in the tropical marine atmosphere at Tuticorin harbour over a period of 426 days. The area ratios, viz. AAluminiurn：A∝ brass, studied were 0.125, 0.25, 0.5, 1, 2, 4 and 8. The galvanic corrosion behaviour of the metals was studied in terms of the relative increase in the corrosion rate of aluminium due to galvanic coupling with oc brass, the relative decrease in the corrosion rate of ∝ brass due to galvanic coupling with aluminium, and the susceptibility of aluminium to pitting owing to galvanic coupling with ∝ brass. The galvanic potential and galvanic current of the system were monitored. Pits of different dimensions ranging from mild etchings to perforations were experienced on the borders arid the surfaces of the interface of aluminium in contact with ∝ brass. The corrosion products resulting from galvanic corrosion were analysed using XRD and the pitting on aluminium as a result of galvanic corrosion was highlighted in terms of pit depth, size and density of pit, using a high resolution microscope. The most favourable area ratio of aluminium - ∝ brass in marine atmosphere in terms of gravimetric corrosion rate is 8：1 and the most unfavourable area ratio of aluminium - ∝ brass is 1：4.展开更多
Our analysis of published results of experiments in the Polar Regions substantiates and further develops our new approach to the photochemical processes in the polar stratosphere involving the charged particles. The d...Our analysis of published results of experiments in the Polar Regions substantiates and further develops our new approach to the photochemical processes in the polar stratosphere involving the charged particles. The dipole interaction of molecules with charged particles, primarily with ions, leads to the adhesion and disintegration of a number of molecules including ozone. Molecules acquire additional energy on the surface of the charged particles, enabling reactions that are not possible in space. Galactic cosmic rays are the main source of ions in the polar stratosphere, their equilibrium concentration at altitudes of 15 to 25 km can reach up ~ （1-5） ~ 103 ions/cm3. Estimations show that if the ozone destruction in the regime of＂collision＂ with ions then the lifetime of ozone will vary from 10 days to 2 months. We suppose that alongside with the chlorine mechanism of ozone destruction there is a mechanism of ozone decay on a charged particle which can act also at those latitudes and altitudes where chlorine oxide CIO is absent, as well as in the night conditions. Here, we demonstrated the close connection of photochemical processes with the dynamic, electrical and condensational phenomena in the stratosphere, in particular, with the accumulation of unipolar charged particles on the upper and lower boundaries of the polar stratospheric clouds and aerosol layers as a result of the activity of the global electric circuit.展开更多
Beam-beam interactions cause dynamic behaviour of the charged particle beams in circular coUiders, which is directly related to their luminosity. The linear beam-beam force introduces an additional quadrupole that per...Beam-beam interactions cause dynamic behaviour of the charged particle beams in circular coUiders, which is directly related to their luminosity. The linear beam-beam force introduces an additional quadrupole that perturbs betatron motion of particles, including dynamic β, dynamic emittance and beam-beam tune-shifts; while the nonlinear force may excite resonances and cause tune-spread. With the weak-strong beam-beam mode, the linear and nonlinear effects are studied, dynamic βand dy- namic emittance as functions of tunes are analyzed, and formulas of beam-beam octupole caused tune-spread are derived, starting from beam-beam potential and equations of particle motions, and the measures to increase luminosity of BEPCII are discussed.展开更多
The lunar soils evolution over time is mainly caused by space weathering that includes the impacts of varying-sized meteoroids and charged particles implantation of solar/cosmic winds as well.It has long been establis...The lunar soils evolution over time is mainly caused by space weathering that includes the impacts of varying-sized meteoroids and charged particles implantation of solar/cosmic winds as well.It has long been established that space weathering leads to the formation of outmost amorphous layers(50–200 nm in thickness)embedded nanophase iron(npFe^(0))around the mineral fragments,albeit the origin of the npFe^(0) remains controversial.The Chang’e-5(CE-5)mission returned samples feature the youngest mare basalt and the highest latitude sampling site,providing an opportunity to seek the critical clues for understanding the evolution of soils under space weathering.Here,we report the surface microstructures of the major minerals including olivine,pyroxene,anorthite,and glassy beads in the lunar soil of CE-5.Unlike the previous observations,only olivine in all crystals is surrounded by a thinner outmost amorphous SiO_(2) layer(∼10 nm thick)and embedded wüstite nanoparticles FeO(np-FeO,3–12 nm in size)instead of npFe^(0).No foreign volatile elements deposition layer and solar flare tracks can be found on the surface or inside the olivine and other minerals.This unique rim structure has not been reported for any other lunar,terrestrial,Martian,or meteorite samples so far.The observation of wüstite FeO and the microstructures support the existence of an intermediate stage in space weathering for lunar minerals by thermal decomposition.展开更多
基金supported by the Knowledge Innovation Program of the Chinese Academy of Sciences (No.ISSASIP 0718)the National Natural Science Foundation of China (Nos.40401030 and 40871114)
文摘To investigate the interactions of oppositely charged sites on the surfaces of variable-charge soil particles with cations and anions, and to evaluate the mean Gibbs free binding and adsorption energies of various cations on particles of red soil and latosol, clay fractions smaller than 2 μm were separated from samples of the two variable-charge soils. Ferric oxides were removed from part of the clay fractions, which were then saturated with various chlorides （NaC1, KCl, CaCl2, CdCl2 or LaCl3）. Electrical conductivities （EC） of dilute suspensions of the original and of the iron oxides-free clay fractions in deionized water were measured with the SHP-2 short high-voltage pulse apparatus, which enables measurement of the Wien effect at field strengths （E） from 14 to 250 kV cm^-1. The Wien effect （EC-E） curves revealed EC increases of red soil suspensions between 14 and 200 kV cm^-1, of 8.3, 8.4, 12.1, 5.9, and 1.2 μS cm^-1 for NaCl, KCl, CaCl2, CdCl2, and LaCl3, respectively, reflecting the differing interactions with the various cations and chloride. The EC increments with the iron-free red soil suspensions were higher, being 29.7, 17.2, and 15.3 μS cm^-1 for NaCl, CaCl2, and CdCl2, respectively. In the natural latosol suspensions the EC increments were practically zero, whereas in the iron-free fractions there were significant EC increments of 10.3, 5.7, 5.0, and 1.6μS cm^-1 for NaCl, CaCl2, CdCl2, and LaCl3, respectively.
基金Supported by the CSIR-CECRI under project No.MLP 0008
文摘The galvanic corrosion behaviour of alumiuium 3004 - ∝ brass with different area ratios was studied in the tropical marine atmosphere at Tuticorin harbour over a period of 426 days. The area ratios, viz. AAluminiurn：A∝ brass, studied were 0.125, 0.25, 0.5, 1, 2, 4 and 8. The galvanic corrosion behaviour of the metals was studied in terms of the relative increase in the corrosion rate of aluminium due to galvanic coupling with oc brass, the relative decrease in the corrosion rate of ∝ brass due to galvanic coupling with aluminium, and the susceptibility of aluminium to pitting owing to galvanic coupling with ∝ brass. The galvanic potential and galvanic current of the system were monitored. Pits of different dimensions ranging from mild etchings to perforations were experienced on the borders arid the surfaces of the interface of aluminium in contact with ∝ brass. The corrosion products resulting from galvanic corrosion were analysed using XRD and the pitting on aluminium as a result of galvanic corrosion was highlighted in terms of pit depth, size and density of pit, using a high resolution microscope. The most favourable area ratio of aluminium - ∝ brass in marine atmosphere in terms of gravimetric corrosion rate is 8：1 and the most unfavourable area ratio of aluminium - ∝ brass is 1：4.
文摘Our analysis of published results of experiments in the Polar Regions substantiates and further develops our new approach to the photochemical processes in the polar stratosphere involving the charged particles. The dipole interaction of molecules with charged particles, primarily with ions, leads to the adhesion and disintegration of a number of molecules including ozone. Molecules acquire additional energy on the surface of the charged particles, enabling reactions that are not possible in space. Galactic cosmic rays are the main source of ions in the polar stratosphere, their equilibrium concentration at altitudes of 15 to 25 km can reach up ~ （1-5） ~ 103 ions/cm3. Estimations show that if the ozone destruction in the regime of＂collision＂ with ions then the lifetime of ozone will vary from 10 days to 2 months. We suppose that alongside with the chlorine mechanism of ozone destruction there is a mechanism of ozone decay on a charged particle which can act also at those latitudes and altitudes where chlorine oxide CIO is absent, as well as in the night conditions. Here, we demonstrated the close connection of photochemical processes with the dynamic, electrical and condensational phenomena in the stratosphere, in particular, with the accumulation of unipolar charged particles on the upper and lower boundaries of the polar stratospheric clouds and aerosol layers as a result of the activity of the global electric circuit.
文摘Beam-beam interactions cause dynamic behaviour of the charged particle beams in circular coUiders, which is directly related to their luminosity. The linear beam-beam force introduces an additional quadrupole that perturbs betatron motion of particles, including dynamic β, dynamic emittance and beam-beam tune-shifts; while the nonlinear force may excite resonances and cause tune-spread. With the weak-strong beam-beam mode, the linear and nonlinear effects are studied, dynamic βand dy- namic emittance as functions of tunes are analyzed, and formulas of beam-beam octupole caused tune-spread are derived, starting from beam-beam potential and equations of particle motions, and the measures to increase luminosity of BEPCII are discussed.
基金supported by the Key Research Program of Chinese Academy of Sciences(ZDBS-SSW-JSC007-2)the Project from China National Space Administration(CE5C0400YJFM00507)。
文摘The lunar soils evolution over time is mainly caused by space weathering that includes the impacts of varying-sized meteoroids and charged particles implantation of solar/cosmic winds as well.It has long been established that space weathering leads to the formation of outmost amorphous layers(50–200 nm in thickness)embedded nanophase iron(npFe^(0))around the mineral fragments,albeit the origin of the npFe^(0) remains controversial.The Chang’e-5(CE-5)mission returned samples feature the youngest mare basalt and the highest latitude sampling site,providing an opportunity to seek the critical clues for understanding the evolution of soils under space weathering.Here,we report the surface microstructures of the major minerals including olivine,pyroxene,anorthite,and glassy beads in the lunar soil of CE-5.Unlike the previous observations,only olivine in all crystals is surrounded by a thinner outmost amorphous SiO_(2) layer(∼10 nm thick)and embedded wüstite nanoparticles FeO(np-FeO,3–12 nm in size)instead of npFe^(0).No foreign volatile elements deposition layer and solar flare tracks can be found on the surface or inside the olivine and other minerals.This unique rim structure has not been reported for any other lunar,terrestrial,Martian,or meteorite samples so far.The observation of wüstite FeO and the microstructures support the existence of an intermediate stage in space weathering for lunar minerals by thermal decomposition.
