Formation of volatile nickel carbonyls with CO in catalytic reaction is one of the mechanisms of catalyst deactivation. CO is one of the most popular probe molecules to study the surface properties in model catalysis....Formation of volatile nickel carbonyls with CO in catalytic reaction is one of the mechanisms of catalyst deactivation. CO is one of the most popular probe molecules to study the surface properties in model catalysis. Under ultra-high vacuum (UHV) conditions, the problem of nickel carbonyl impurity almost does not exist in the case that a high purity of CO is used directly. While in the near ambient pressure (NAP) range, nickel carbonyl is easily found on the surface by passing through the Ni containing tubes. Here, the NAP techniques such as NAP-X-ray photoelectron spectroscopy and NAP-scanning tunneling microscopy are used to study the adsorption of nickel carbonyl contaminated CO gas on Cu(111) surface in UHV and NAP conditions. By controlling the pressure of contaminated CO, the Ni-Cu bimetallic catalyst can form on Cu(111) surface. Furthermore, we investigate the process of CO adsorption and dissociation on the formed Ni-Cu bi-metal surface, and several high-pressure phases of CO structures are reported. This work contributes to understanding the interaction of nickel carbonyl with Cu(111) at room temperature, and reminds the consideration of CO molecules contaminated by nickel carbonyl especially in the NAP range study.展开更多
This paper addresses estimation and its asymptotics of mean transformation θ = E[h（X）] of a random variable X based on n lid. observations from errors-in-variables model Y = X＋ v, where v is a measurement error wi...This paper addresses estimation and its asymptotics of mean transformation θ = E[h（X）] of a random variable X based on n lid. observations from errors-in-variables model Y = X＋ v, where v is a measurement error with a known distribution and h（.） is a known smooth function. The asymptotics of deconvolution kernel estimator for ordinary smooth error distribution and expectation extrapolation estimator are given for normal error distribution respectively. Under some mild regularity conditions, the consistency and asymptotically normality are obtained for both type of estimators. Simulations show they have good performance.展开更多
Multi-agent systems(MASs) are ubiquitous in natural and artificial systems. This paper aims to establish the finite-time adaptive consensus criterion for a class of MASs with nonlinear dynamics. Traditionally, the fin...Multi-agent systems(MASs) are ubiquitous in natural and artificial systems. This paper aims to establish the finite-time adaptive consensus criterion for a class of MASs with nonlinear dynamics. Traditionally, the finite-time consensus criterion is often established based on the prior information on Lipschitz constants and the eigenvalues of Laplacian matrix. However, it is difficult to acquire the above prior information for most real-world engineering systems. To overcome the above difficulty, this paper develops the finite-time consensus criteria for a class of MASs with nonlinear dynamics via adaptive technique. In detail, we design the finite-time distributed node-based and edge-based adaptive consensus protocols for a class of MASs with fixed and switching topologies. Numerical simulations are also given to validate the proposed finite-time adaptive consensus criterion.展开更多
基金supported by the National Natural Science Foundation of China(No.91845109)Key Laboratory of Surface Physics and Chemistry Discipline Development Fund(XKFZ201711)
文摘Formation of volatile nickel carbonyls with CO in catalytic reaction is one of the mechanisms of catalyst deactivation. CO is one of the most popular probe molecules to study the surface properties in model catalysis. Under ultra-high vacuum (UHV) conditions, the problem of nickel carbonyl impurity almost does not exist in the case that a high purity of CO is used directly. While in the near ambient pressure (NAP) range, nickel carbonyl is easily found on the surface by passing through the Ni containing tubes. Here, the NAP techniques such as NAP-X-ray photoelectron spectroscopy and NAP-scanning tunneling microscopy are used to study the adsorption of nickel carbonyl contaminated CO gas on Cu(111) surface in UHV and NAP conditions. By controlling the pressure of contaminated CO, the Ni-Cu bimetallic catalyst can form on Cu(111) surface. Furthermore, we investigate the process of CO adsorption and dissociation on the formed Ni-Cu bi-metal surface, and several high-pressure phases of CO structures are reported. This work contributes to understanding the interaction of nickel carbonyl with Cu(111) at room temperature, and reminds the consideration of CO molecules contaminated by nickel carbonyl especially in the NAP range study.
基金This research is supported by the National Natural Science Foundation of China(Grant No. 19771011 and 10071009) the RFDP (No. 20020027010) of MOE.
文摘This paper addresses estimation and its asymptotics of mean transformation θ = E[h（X）] of a random variable X based on n lid. observations from errors-in-variables model Y = X＋ v, where v is a measurement error with a known distribution and h（.） is a known smooth function. The asymptotics of deconvolution kernel estimator for ordinary smooth error distribution and expectation extrapolation estimator are given for normal error distribution respectively. Under some mild regularity conditions, the consistency and asymptotically normality are obtained for both type of estimators. Simulations show they have good performance.
基金supported by the National Basic Research Program of China("973"Project)(Grant No.2014CB845302)the National Science and Technology Major Project of China(Grant No.2014ZX10004001-014)the National Natural Science Foundation of China(Grant No.11472290)
文摘Multi-agent systems(MASs) are ubiquitous in natural and artificial systems. This paper aims to establish the finite-time adaptive consensus criterion for a class of MASs with nonlinear dynamics. Traditionally, the finite-time consensus criterion is often established based on the prior information on Lipschitz constants and the eigenvalues of Laplacian matrix. However, it is difficult to acquire the above prior information for most real-world engineering systems. To overcome the above difficulty, this paper develops the finite-time consensus criteria for a class of MASs with nonlinear dynamics via adaptive technique. In detail, we design the finite-time distributed node-based and edge-based adaptive consensus protocols for a class of MASs with fixed and switching topologies. Numerical simulations are also given to validate the proposed finite-time adaptive consensus criterion.
