Using a gravity anomaly covariance function based on the second-order Ganssian Markov gravity anomaly potential model, the state equation of a gravity anomaly signal is obtained in marine gravimetry. Combined with the...Using a gravity anomaly covariance function based on the second-order Ganssian Markov gravity anomaly potential model, the state equation of a gravity anomaly signal is obtained in marine gravimetry. Combined with the system state equation and the measurement equation, a new method of the cascade Kalman filter is proposed and applied to the correction of gravity anomaly distortion. In the signal processing procedure, an inverse Kalman filter is used to restore the gravity anomaly signal and high frequency noises first. Then an adaptive Kalman filter, which uses the gravity anomaly state equation as the system equation, is set to estimate the actual gravity anomaly data. Emulations and experiments indicate that both the cascade Kalman filter method and the single inverse Kalman filter method are effective in alleviating the distortion of the gravity anomaly signal, but the performance of the cascade Kalman filter method is better than that of the single inverse Kalman filter method.展开更多
The positive and negative difference of deep and shallow resisitivity in formation without invasion is caused mainly by the fixed two tool constants from numerical simulations. A dynamic calibration method for tool co...The positive and negative difference of deep and shallow resisitivity in formation without invasion is caused mainly by the fixed two tool constants from numerical simulations. A dynamic calibration method for tool constants is proposed based on the effects of the mud and formation resisitivity ratio on the two constants calculated using the finite element method （FEM）. Finally, four specific examples are given to validate the dynamic calibration method. It is an automatic borehole correction method and can give more accurate formation resistivity. The method is useful for dual laterolog logging.展开更多
This paper studies the imminent anomalies observed by the Sacks volume strainmeter in Erzhangying station and Tiantanghe station before 80 earthquakes with Ms≥ 7. 0 which took place from January 2011 to April 2014 al...This paper studies the imminent anomalies observed by the Sacks volume strainmeter in Erzhangying station and Tiantanghe station before 80 earthquakes with Ms≥ 7. 0 which took place from January 2011 to April 2014 all over the world. Then, preconditions for anomaly identification are put forward for complex earthquake cases. Statistical results show that volume strain observation has a better earthquake reflecting ability for earthquakes with magnitudes larger than 7. 0 and epicentral distance within 8000kin. In addition, these results also reflect that the volume strain observation can better reflect precursory anomalies of such earthquakes. Based on categorization and description of those anomalies, we divide the anomalies into three types, that is, earth tide distortion type, abrupt change type and slow earthquake type. Furthermore, the paper makes a statistical analysis of these types and preliminarily discusses their mechanical properties as well. According to research, volume strain anomaly has an indicative significance to future strong earthquakes in the world.展开更多
The distributions of nicotinic acid (NA) between water and trialkylamine (N235) dissolved in n-octanol was studied. The complexes of N235 and NA were investigated by Fourier transformation infrared spectrometry to ded...The distributions of nicotinic acid (NA) between water and trialkylamine (N235) dissolved in n-octanol was studied. The complexes of N235 and NA were investigated by Fourier transformation infrared spectrometry to deduce the reaction mechanism. It was found that N235/n-octanol was an efficient extractant for extracting nicotinic acid. The favorable operation conditions were equilibrium aqueous pH 4.2 to 5.5 and initial N235 concentration<0.42 mol·L-1 . The reaction processes included the reaction between neutral N235 and neutral NA and the reaction between protonated N235 and anionic NA. Based on the mass action law and some assumptions, an expression for distribution coefficient D was proposed. The apparent extraction equilibrium constants were calculated by fitting the experimental data and the results were satisfactory.展开更多
Hydrolysis and oxidation of formamidine disulfide in acidic medium were investigated using high-performance liquid chro- matography （HPLC） and mass spectrometry （MS） at 25 ~C. By controlling the slow reaction rate...Hydrolysis and oxidation of formamidine disulfide in acidic medium were investigated using high-performance liquid chro- matography （HPLC） and mass spectrometry （MS） at 25 ~C. By controlling the slow reaction rate and choosing appropriate mobile phase, HPLC provides the unique advantages over other methods （UV-Vis, chemical separation） in species tracking and kinetic study. In addition to thiourea and formamidine sulfinic acid, two unreported products were also detected in the hy- drolysis reaction. Mass spectrometry measurement indicates these two products to be formamidine sulfenic acid and thiocyan- ogen with mass weights of 92.28 and 116,36, respectively. In the oxidation of formamidine disulfide by hydrogen peroxide, besides thiourea, formamidine sulfenic acid, formamidine sulfinic acid, thiocyanogen and urea, formamidine sulfonic acid and sulfate could be detected. The oxidation reaction was found to be first order in both forrnamidine disulfide and hydrogen per- oxide. The rate constants of hydrolysis and oxidation reactions were determined in the pH range of 1.5-3.0. It was found both rate constants are increased with the increasing of pH. Experimental curves of different species can be effectively simulated via a mechanism scheme for formamidine disulfide oxidation, including hydrolysis equilibrium of formamidine disulfide and irre- versible hydrolysis of formamidine sulfenic acid.展开更多
Recent studies have indicated that hypervelocity impacts by meteoroids and space debris can induce spacecraft anomalies. However, the basic physical process through which space debris impacts cause anomalies is not en...Recent studies have indicated that hypervelocity impacts by meteoroids and space debris can induce spacecraft anomalies. However, the basic physical process through which space debris impacts cause anomalies is not entirely clear. Currently, impact-generated plasma is thought to be the primary cause of electrical spacecraft anomalies, while the effects of impact-generated mechanical damage have rarely been researched. This paper presents new evidence showing that impact-generated mechanical damage strongly influences electrostatic discharge. Hypervelocity impact experiments were conducted in a plasma drag particle accelerator, using particles with diameters of 200–500 ?m and velocities of 2–7 km/s. The impact-generated mechanical damage on a specimen surface was measured by a stereoscopic microscope and 3D Profilometer and it indicated that microscopic irregularities around the impact crater could be responsible for local electric field enhancement. Furthermore, the influence of impact-generated mechanical damage on electrostatic discharge was simulated in an inverted potential gradient situation. The experimental results show that the electrostatic discharge voltage threshold was significantly reduced after the specimen was impacted by particles.展开更多
基金Pre-Research Program of General Armament Departmentduring the 11th Five-Year Plan Period(No.51309010201)the National Natural Science Foundation of China(No.60575010)
文摘Using a gravity anomaly covariance function based on the second-order Ganssian Markov gravity anomaly potential model, the state equation of a gravity anomaly signal is obtained in marine gravimetry. Combined with the system state equation and the measurement equation, a new method of the cascade Kalman filter is proposed and applied to the correction of gravity anomaly distortion. In the signal processing procedure, an inverse Kalman filter is used to restore the gravity anomaly signal and high frequency noises first. Then an adaptive Kalman filter, which uses the gravity anomaly state equation as the system equation, is set to estimate the actual gravity anomaly data. Emulations and experiments indicate that both the cascade Kalman filter method and the single inverse Kalman filter method are effective in alleviating the distortion of the gravity anomaly signal, but the performance of the cascade Kalman filter method is better than that of the single inverse Kalman filter method.
基金supported by the National Natural Science Foundation of China(Grant No.11134011)
文摘The positive and negative difference of deep and shallow resisitivity in formation without invasion is caused mainly by the fixed two tool constants from numerical simulations. A dynamic calibration method for tool constants is proposed based on the effects of the mud and formation resisitivity ratio on the two constants calculated using the finite element method （FEM）. Finally, four specific examples are given to validate the dynamic calibration method. It is an automatic borehole correction method and can give more accurate formation resistivity. The method is useful for dual laterolog logging.
基金Combined project of monitoring,prediction and research of China Earthquake Administration entitled "Statistical study on the earthquake cases of imminent anomaly in Sacks volume strain measurements(154201)""Special Fund for Basic Scientific Research of Institute of Earthquake Science,CEA(2012IES010202)""Research on Regional Tectonic Stability for the Dateng Gorge Water Conservancy Hub Project Site(880456)"
文摘This paper studies the imminent anomalies observed by the Sacks volume strainmeter in Erzhangying station and Tiantanghe station before 80 earthquakes with Ms≥ 7. 0 which took place from January 2011 to April 2014 all over the world. Then, preconditions for anomaly identification are put forward for complex earthquake cases. Statistical results show that volume strain observation has a better earthquake reflecting ability for earthquakes with magnitudes larger than 7. 0 and epicentral distance within 8000kin. In addition, these results also reflect that the volume strain observation can better reflect precursory anomalies of such earthquakes. Based on categorization and description of those anomalies, we divide the anomalies into three types, that is, earth tide distortion type, abrupt change type and slow earthquake type. Furthermore, the paper makes a statistical analysis of these types and preliminarily discusses their mechanical properties as well. According to research, volume strain anomaly has an indicative significance to future strong earthquakes in the world.
基金Supported by the Ministry of Education of Henan Province in China (2011A610004)
文摘The distributions of nicotinic acid (NA) between water and trialkylamine (N235) dissolved in n-octanol was studied. The complexes of N235 and NA were investigated by Fourier transformation infrared spectrometry to deduce the reaction mechanism. It was found that N235/n-octanol was an efficient extractant for extracting nicotinic acid. The favorable operation conditions were equilibrium aqueous pH 4.2 to 5.5 and initial N235 concentration<0.42 mol·L-1 . The reaction processes included the reaction between neutral N235 and neutral NA and the reaction between protonated N235 and anionic NA. Based on the mass action law and some assumptions, an expression for distribution coefficient D was proposed. The apparent extraction equilibrium constants were calculated by fitting the experimental data and the results were satisfactory.
基金supported by the National Natural Science Foundation of China (21073232 & 50921002)the Fundamental Research Fund from the Chinese Central University (2010LKHX02)
文摘Hydrolysis and oxidation of formamidine disulfide in acidic medium were investigated using high-performance liquid chro- matography （HPLC） and mass spectrometry （MS） at 25 ~C. By controlling the slow reaction rate and choosing appropriate mobile phase, HPLC provides the unique advantages over other methods （UV-Vis, chemical separation） in species tracking and kinetic study. In addition to thiourea and formamidine sulfinic acid, two unreported products were also detected in the hy- drolysis reaction. Mass spectrometry measurement indicates these two products to be formamidine sulfenic acid and thiocyan- ogen with mass weights of 92.28 and 116,36, respectively. In the oxidation of formamidine disulfide by hydrogen peroxide, besides thiourea, formamidine sulfenic acid, formamidine sulfinic acid, thiocyanogen and urea, formamidine sulfonic acid and sulfate could be detected. The oxidation reaction was found to be first order in both forrnamidine disulfide and hydrogen per- oxide. The rate constants of hydrolysis and oxidation reactions were determined in the pH range of 1.5-3.0. It was found both rate constants are increased with the increasing of pH. Experimental curves of different species can be effectively simulated via a mechanism scheme for formamidine disulfide oxidation, including hydrolysis equilibrium of formamidine disulfide and irre- versible hydrolysis of formamidine sulfenic acid.
文摘Recent studies have indicated that hypervelocity impacts by meteoroids and space debris can induce spacecraft anomalies. However, the basic physical process through which space debris impacts cause anomalies is not entirely clear. Currently, impact-generated plasma is thought to be the primary cause of electrical spacecraft anomalies, while the effects of impact-generated mechanical damage have rarely been researched. This paper presents new evidence showing that impact-generated mechanical damage strongly influences electrostatic discharge. Hypervelocity impact experiments were conducted in a plasma drag particle accelerator, using particles with diameters of 200–500 ?m and velocities of 2–7 km/s. The impact-generated mechanical damage on a specimen surface was measured by a stereoscopic microscope and 3D Profilometer and it indicated that microscopic irregularities around the impact crater could be responsible for local electric field enhancement. Furthermore, the influence of impact-generated mechanical damage on electrostatic discharge was simulated in an inverted potential gradient situation. The experimental results show that the electrostatic discharge voltage threshold was significantly reduced after the specimen was impacted by particles.
