Binary solvent (CS2-NMP) has extreme high extraction ability to coals, and it can extract most bitumens out of coals and vitrinites. And large amount of messages on side chains and their distri- bution character in vi...Binary solvent (CS2-NMP) has extreme high extraction ability to coals, and it can extract most bitumens out of coals and vitrinites. And large amount of messages on side chains and their distri- bution character in vitrinites should be acquired through flash pyrolysis before and after binary solvent (CS2-NMP) extraction. A few low maturated coals have been selected and vitrinites are handpicked from coals. Then vitrinites have been extracted using different solvents in the order of polarity. Flash pyro- lysis-Gas Chromatography/Mass spectrum has been applied to samples. The result shows that CS2-NMP is efficient for the extraction of vitirnites, giving much higher extraction yield than common solvents. Pro- duction ratio of liquid hydrocarbons in pyrolysates of vitrinites extracted with CS2-NMP is lower than that of raw vitrinites. And relative ratio of each component in pyrolysates has changed apparently. Production ratio of aliphatic hydrocarbons, especially those long chain aliphatics have decreased much after mixed solvent extraction. It shows that bitumens extracted with CS2-NMP have largely contributed to pyrolysates, especially those aliphatics in pyrolysates.展开更多
This paper studies the characteristics of larch bark pyrolysis and analyzes factors that affect the pyrolysis and the liquid pyrolytic component. The results are as follows: TG curve shows that the pyrolysis can be di...This paper studies the characteristics of larch bark pyrolysis and analyzes factors that affect the pyrolysis and the liquid pyrolytic component. The results are as follows: TG curve shows that the pyrolysis can be divided into three parts: drying process, pyrolytic process, and carbonate and calcinated process. Both the size of grain and the temperature rising rate affect the shape of TG and DTG. Vinegar and sedimentary tar are main components of pyrolyzate products. GC-MS is applied to analyze vinegar. It is shown that the vinegar is a highly complex compound which is composed of phenol and its derivatives (45.620%), organic acid (13.851%), keto derivatives (9.754%), aldehydic derivatives (8.573%), alcoholic derivatives (1.794%), ester and its derivatives (0.205%).展开更多
文摘Binary solvent (CS2-NMP) has extreme high extraction ability to coals, and it can extract most bitumens out of coals and vitrinites. And large amount of messages on side chains and their distri- bution character in vitrinites should be acquired through flash pyrolysis before and after binary solvent (CS2-NMP) extraction. A few low maturated coals have been selected and vitrinites are handpicked from coals. Then vitrinites have been extracted using different solvents in the order of polarity. Flash pyro- lysis-Gas Chromatography/Mass spectrum has been applied to samples. The result shows that CS2-NMP is efficient for the extraction of vitirnites, giving much higher extraction yield than common solvents. Pro- duction ratio of liquid hydrocarbons in pyrolysates of vitrinites extracted with CS2-NMP is lower than that of raw vitrinites. And relative ratio of each component in pyrolysates has changed apparently. Production ratio of aliphatic hydrocarbons, especially those long chain aliphatics have decreased much after mixed solvent extraction. It shows that bitumens extracted with CS2-NMP have largely contributed to pyrolysates, especially those aliphatics in pyrolysates.
文摘This paper studies the characteristics of larch bark pyrolysis and analyzes factors that affect the pyrolysis and the liquid pyrolytic component. The results are as follows: TG curve shows that the pyrolysis can be divided into three parts: drying process, pyrolytic process, and carbonate and calcinated process. Both the size of grain and the temperature rising rate affect the shape of TG and DTG. Vinegar and sedimentary tar are main components of pyrolyzate products. GC-MS is applied to analyze vinegar. It is shown that the vinegar is a highly complex compound which is composed of phenol and its derivatives (45.620%), organic acid (13.851%), keto derivatives (9.754%), aldehydic derivatives (8.573%), alcoholic derivatives (1.794%), ester and its derivatives (0.205%).
