θ条件下线性聚苯乙烯链的旋转半径及平动扩散系数的浓度依赖性(英文)

研究了线性聚苯乙烯链在稀和半稀的θ溶液中平动扩散系数（D）和均方旋转半径（Rg）的浓度依赖性．在θ条件下，Rg无浓度依赖性，而D的浓度依赖性可由Fixman软球模型理论描述．

一种新的标定体积排除色谱（SEC）的方法

基于体积排除色谱中测得的淋出体积和动态激光光散射中测得的平动扩散系数都直接依赖于高分子的流体力学体积这一事实，本文在理论上提出了一种把淋出体积分布和平动扩散系数分布二者结合起来标定体积排除色谱的新方法，并且在实验上通过对宽分布的聚苯乙烯标准样品的测试证实了该方法的可行性．

Adsorption Isotherm and Kinetics of Dibenzofuran on Granular Activated Carbons

The adsorption of dibenzofuran on three commercial granular activated carbons (ACs) was investigated by dynamic experiment to correlate the adsorption equilibrium and kinetics with the structure of activated carbons.Physical properties including surface area, average pore diameter, micropore area and micropore volume of the activated carbons were characterized by N2 adsorption experiment on ASAP2010. To calculate the adsorption parameters, adsorption isotherm data were fitted to the Langmuir equation, and adsorption kinetic data were fitted to the linear driving force (LDF) diffusion model. From the correlation results, it is concluded that the adsorption equilibrium and diffusion coefficient of dibenzofuran on activated carbon are controlled respectively by the total adsorbent surface area and the adsorbent pore diameter.