In the framework of systematic science of alloys,the average molar property(volume and potential energy) functions of disordered alloys were established.From these functions,the average molar property functions,part...In the framework of systematic science of alloys,the average molar property(volume and potential energy) functions of disordered alloys were established.From these functions,the average molar property functions,partial molar property functions,derivative functions with respect to composition,general equation of relationship between partial and average molar properties of components,difference equation and constraining equation of different values between partial and average molar properties,as well as general Gibbs-Duhem formula were derived.It was proved that the partial molar properties calculated from various combinative functions of average molar properties of alloys are equal,but in general,the partial molar properties are not equal to the average molar properties of a given component.This means that the partial molar properties cannot represent the corresponding properties of the component.All the equations and functions established in this work were proved to be correct by calculating the results of partial and average atomic volumes of components as well as average atomic volumes of alloys in the Au-Ni system.展开更多
Social stock for metal determines secondary or recoverable resources to a certain extent.Top-down analysis method for the studying of metal in social stock was given.Influences of metal consumption under three circums...Social stock for metal determines secondary or recoverable resources to a certain extent.Top-down analysis method for the studying of metal in social stock was given.Influences of metal consumption under three circumstances,that is keeping constant,varying in a linear trend and in an exponential trend,on one kind of metal’s social stock,recyclable ratio and average age were analyzed.Al-contents and Cu-contents in social stock for China during the period 2006-2009 were calculated.The results reveal that Al-contents and Cu-contents in social stock kept increasing and reached 88.9 million tons and 51.4 millions tons in 2009,respectively,their average recyclable ratios are 1.45% and 0.30%,and the average ages are 4.65 years and 6.89 years,respectively.The recyclable ratios and average ages of Al-contents and Cu-contents in social stock will rise in future along with the decline of the increasing rate of aluminum consumption and copper consumption.展开更多
Soil erosion and associated off-site sedimentation are threatening the sustainable use of the Three Gorges Dam. To initiate management intervention to reduce sediment yields, there is an increasing need for reliable i...Soil erosion and associated off-site sedimentation are threatening the sustainable use of the Three Gorges Dam. To initiate management intervention to reduce sediment yields, there is an increasing need for reliable information on soil erosion in the Three Gorges Reservoir Region (TGRR). The purpose of this study is to use 137Cs tracing methods to construct a sediment budget for a small agricultural catchment in the TGRR. Cores were taken from a pond and from paddy fields, for laTCs measurements. The results show that the average sedimentation rate in the pond since 1963 is 1.50 g cm-2 yr-1 and the corresponding amount of sediment deposited is 1,553 t. The surface erosion rate for the sloping cultivated lands and the sedimentation rate in the paddy fields were estimated to be 3,770 t km-2 yr-1 and 2,600 t km-2 yr^1 respectively. Based on the estimated erosion and deposition rates, and the area of each unit, the post 197o sediment budget for the catchment has been constructed. A sediment delivery ratio of 0.5 has been estimated for the past 42 years. The data indicate that the sloping cultivated lands are the primary sediment source areas, and that the paddy fields are deposition zones. The typical land use pattern (with the upper parts characterized by sloping cultivated land and the lower parts by paddy fields) plays an important role in reducing sediment yield from agricultural catchments in the TGRR. A 137Cs profile for the sediment deposited in a pond is shownto provide an effective means of estimating the land surface erosion rate in the upstream catchment.展开更多
The biogenic silica (BSi) ,total organic carbon (TOC) ,total nitrogen (TN) and grain size were analyzed with a gravity core (3250-6) collected from the mud area in the north East China Sea.The average deposition rate ...The biogenic silica (BSi) ,total organic carbon (TOC) ,total nitrogen (TN) and grain size were analyzed with a gravity core (3250-6) collected from the mud area in the north East China Sea.The average deposition rate of the upper core was about 0.078cm yr1based on the results of 210Pbex.The mean grain size increased with depth in general.The frequency distribution of grain size showed that two marked changes of deposition environment occurred at 30 cm and 50 cm depths (about 1550 AD and 1300 AD,respectively) .The variations of BSi and TOC indicated two distinct major periods of primary productivity over the past 800 years:a stage of low primary productivity corresponding to weak upwelling and low nutrient input below 30 cm depth (about 1200-1550 AD) ,and a stage of high primary productivity with strong currents and upwelling above 30 cm depth (about 1550-1950 AD) .The stage with high primary productive appeared to be due to the northward-expanded muddy area caused by strong Asian Winter Monsoon and enhanced Yellow Sea Warm Current in winter.In conclusion,the BSi and TOC in the muddy sediments,the symbols of marine primary productivity,can be then used to investigate the evolution history of currents and relative climate change in the offshore areas.展开更多
The southern Laizhou Bay is mainly composed of silt-sandy coasts with diverse landforms, and its marine hydrodynamic environment is sensitive to human activities. Marine hydrodynamic and sedimentary environments of th...The southern Laizhou Bay is mainly composed of silt-sandy coasts with diverse landforms, and its marine hydrodynamic environment is sensitive to human activities. Marine hydrodynamic and sedimentary environments of the study area have changed under the influence of large-scale port projects in recent years. In this paper, the evolution of hydrodynamic environment, deposition rate, and geochemical characteristics were studied based on sediment grain size, element analysis and ^(210)Pb dating of two cores, in order to analyze the influence of Weifang Port on marine environmental evolution, and provide theoretical and practical basis for protecting marine environment in developing marine resources reasonably. Results showed that sediments of the two cores were relatively coarser and mainly composed of silty sand. Sediments above 230 cm in core WF1 and 218 cm in core WF2 were deposited since 1855 when the Yellow River appeared to deposit its sediments within the modern active delta, and the average deposition rate was between 0.3 and 0.5 cm a^(-1). Implement of Weifang Port projects in 1997 and 2007 created great influence on the sedimentary environment evolution in the surrounding waters, and the deposition rate was significantly increased. The average annual deposition rates were 5.1 cm and 3.5 cm in WF1 and WF2 respectively between 1997 and 2007. Content of heavy metals in sediments showed no obvious change in the vertical, indicating that the heavy metals were less affected by human activity and there was no significant accumulation of such metals in the study area.展开更多
The well-known Three Gorges Dam(TGD) within the Yangtze catchment launched its operation in 2003. The effect of the TGD operation on the sediment size on the East China Sea shelf is rarely known. High resolution(0.5 c...The well-known Three Gorges Dam(TGD) within the Yangtze catchment launched its operation in 2003. The effect of the TGD operation on the sediment size on the East China Sea shelf is rarely known. High resolution(0.5 cm sampling) grain size analysis and 137 Cs and 210 Pb dating of the DH8-1 core were conducted with core collected from the distal part of a main sink for the modern Yangtze sediment entering the sea, the Min-Zhe Coastal Mud Deposits(MZCMD) on the inner East China Sea shelf. The 137 Cs dating results show that the core DH8-1 formed during 1946–2012 with a mean deposition rate of 0.65 cm yr^(-1), indicating that the 0.5 cm sampling for grain size analysis in this local area could reflect environmental changes generally on a one-year time scale. The mean grain size of DH8-1 core sediment that deposited after 2003 is significantly larger than that deposited during 1988–2002. After ruling out other possible factors, we infer that the sediment coarsening of DH8-1 core after 2003 is attributed to the TGD operation which causes the erosion of the Yangtze subaqueous delta. Specifically, the TGD operation significantly intensifies the declining trend of the Yangtze sediment loads to the sea despite no decreased water discharge, which results in extensive erosion of the Yangtze subaqueous delta. The relatively coarse sediment of the subaqueous delta is eroded and resuspended by ocean dynamics and then transported by coastal current, finally depositing on the MZCMD area. In addition, the general sediment fining of core DH8-1 that deposited during 1988–2002, comparing with 1946–1987, is mainly caused by dam construction and soil and water conservation within the Yangtze catchment. Our findings are helpful for better understanding the effects of such a huge dam as the TGD on a sediment sink like the MZCMD of such a large river as the Yangtze River.展开更多
Based on the 1990, 2000 and 2011 Landsat TM/ETM+ remote sensing data, glacier information of three periods in the Chinese Tianshan Mountains were extracted by using ratio threshold method(TM3/TM5) and visual interpret...Based on the 1990, 2000 and 2011 Landsat TM/ETM+ remote sensing data, glacier information of three periods in the Chinese Tianshan Mountains were extracted by using ratio threshold method(TM3/TM5) and visual interpretation, combined with digital processing of satellite images and analysis in GIS. The climate data in the surrounding area were analyzed by using linear regression, Mann-Kendall abrupt test, and Morlet wavelet analysis. Study results showed that: over the 23 years investigation, the glacier areas have markedly decreased. In the last 12 years(2000 to 2011), the rate of retreat has begun to accelerate. The most dramatic glacier shrinkage occurred in the central region, the lowest in the eastern region. The mean summer temperature and warm precipitation in Chinese Tianshan Mountains had an increasing trend, with rates of 0.22°C /10 a and 5.1mm/10 a from 1960 to 2011, respectively. Mean summer temperature have experienced a strong increase in 1998. The analysis of the results showed that the rise of mean summer temperature was the main factor that contributed to glacier shrinkage. Regional differences of glacier area changes were investigated by analyzing glacier behavior in five study sub-regions; regional differences are related to local climate, to the relative proportion of glaciers in different size classes, altitudinal and aspect distribution of glaciated areas. In addition, the lag theory indicated that glaciers may accelerate the retreat in the next decade, considering climate trends recognized for the period 2000-2011.展开更多
基金Project (51071181) supported by the National Natural Science Foundation of ChinaProject (2010FJ4034) supported by Natural Science Foundation of Hunan Province,China
文摘In the framework of systematic science of alloys,the average molar property(volume and potential energy) functions of disordered alloys were established.From these functions,the average molar property functions,partial molar property functions,derivative functions with respect to composition,general equation of relationship between partial and average molar properties of components,difference equation and constraining equation of different values between partial and average molar properties,as well as general Gibbs-Duhem formula were derived.It was proved that the partial molar properties calculated from various combinative functions of average molar properties of alloys are equal,but in general,the partial molar properties are not equal to the average molar properties of a given component.This means that the partial molar properties cannot represent the corresponding properties of the component.All the equations and functions established in this work were proved to be correct by calculating the results of partial and average atomic volumes of components as well as average atomic volumes of alloys in the Au-Ni system.
基金Project (71003018) supported by the National Natural Science Foundation of ChinaProject (N110402003) supported by the Fundamental Research Funds for the Central Universities,China
文摘Social stock for metal determines secondary or recoverable resources to a certain extent.Top-down analysis method for the studying of metal in social stock was given.Influences of metal consumption under three circumstances,that is keeping constant,varying in a linear trend and in an exponential trend,on one kind of metal’s social stock,recyclable ratio and average age were analyzed.Al-contents and Cu-contents in social stock for China during the period 2006-2009 were calculated.The results reveal that Al-contents and Cu-contents in social stock kept increasing and reached 88.9 million tons and 51.4 millions tons in 2009,respectively,their average recyclable ratios are 1.45% and 0.30%,and the average ages are 4.65 years and 6.89 years,respectively.The recyclable ratios and average ages of Al-contents and Cu-contents in social stock will rise in future along with the decline of the increasing rate of aluminum consumption and copper consumption.
基金funded by National Key Technology R&D Program (Grant No.2011BAD31B03)the Action Plan for West Development of Chinese Academy of Sciences(Grant No. KZCX2-XB3-09)+1 种基金the National Natural Science Foundation of China (Grant Nos.41201275,41101259,41001163)Western Light-Western Doctor of CAS
文摘Soil erosion and associated off-site sedimentation are threatening the sustainable use of the Three Gorges Dam. To initiate management intervention to reduce sediment yields, there is an increasing need for reliable information on soil erosion in the Three Gorges Reservoir Region (TGRR). The purpose of this study is to use 137Cs tracing methods to construct a sediment budget for a small agricultural catchment in the TGRR. Cores were taken from a pond and from paddy fields, for laTCs measurements. The results show that the average sedimentation rate in the pond since 1963 is 1.50 g cm-2 yr-1 and the corresponding amount of sediment deposited is 1,553 t. The surface erosion rate for the sloping cultivated lands and the sedimentation rate in the paddy fields were estimated to be 3,770 t km-2 yr-1 and 2,600 t km-2 yr^1 respectively. Based on the estimated erosion and deposition rates, and the area of each unit, the post 197o sediment budget for the catchment has been constructed. A sediment delivery ratio of 0.5 has been estimated for the past 42 years. The data indicate that the sloping cultivated lands are the primary sediment source areas, and that the paddy fields are deposition zones. The typical land use pattern (with the upper parts characterized by sloping cultivated land and the lower parts by paddy fields) plays an important role in reducing sediment yield from agricultural catchments in the TGRR. A 137Cs profile for the sediment deposited in a pond is shownto provide an effective means of estimating the land surface erosion rate in the upstream catchment.
基金funded by the National Basic Research Program of China (973 Program,No.2010CB428902)
文摘The biogenic silica (BSi) ,total organic carbon (TOC) ,total nitrogen (TN) and grain size were analyzed with a gravity core (3250-6) collected from the mud area in the north East China Sea.The average deposition rate of the upper core was about 0.078cm yr1based on the results of 210Pbex.The mean grain size increased with depth in general.The frequency distribution of grain size showed that two marked changes of deposition environment occurred at 30 cm and 50 cm depths (about 1550 AD and 1300 AD,respectively) .The variations of BSi and TOC indicated two distinct major periods of primary productivity over the past 800 years:a stage of low primary productivity corresponding to weak upwelling and low nutrient input below 30 cm depth (about 1200-1550 AD) ,and a stage of high primary productivity with strong currents and upwelling above 30 cm depth (about 1550-1950 AD) .The stage with high primary productive appeared to be due to the northward-expanded muddy area caused by strong Asian Winter Monsoon and enhanced Yellow Sea Warm Current in winter.In conclusion,the BSi and TOC in the muddy sediments,the symbols of marine primary productivity,can be then used to investigate the evolution history of currents and relative climate change in the offshore areas.
基金financially supported by the Marine Commonweal Scientific Research Foundation (Grant No. 201005009)the Basic Scientific Fund for National Public Research Institutes of China (Grant No. 2015G08)
文摘The southern Laizhou Bay is mainly composed of silt-sandy coasts with diverse landforms, and its marine hydrodynamic environment is sensitive to human activities. Marine hydrodynamic and sedimentary environments of the study area have changed under the influence of large-scale port projects in recent years. In this paper, the evolution of hydrodynamic environment, deposition rate, and geochemical characteristics were studied based on sediment grain size, element analysis and ^(210)Pb dating of two cores, in order to analyze the influence of Weifang Port on marine environmental evolution, and provide theoretical and practical basis for protecting marine environment in developing marine resources reasonably. Results showed that sediments of the two cores were relatively coarser and mainly composed of silty sand. Sediments above 230 cm in core WF1 and 218 cm in core WF2 were deposited since 1855 when the Yellow River appeared to deposit its sediments within the modern active delta, and the average deposition rate was between 0.3 and 0.5 cm a^(-1). Implement of Weifang Port projects in 1997 and 2007 created great influence on the sedimentary environment evolution in the surrounding waters, and the deposition rate was significantly increased. The average annual deposition rates were 5.1 cm and 3.5 cm in WF1 and WF2 respectively between 1997 and 2007. Content of heavy metals in sediments showed no obvious change in the vertical, indicating that the heavy metals were less affected by human activity and there was no significant accumulation of such metals in the study area.
基金the National Natural Science Foundation of China for its financial support (Nos. 41376052, 41030856, 40906024)
文摘The well-known Three Gorges Dam(TGD) within the Yangtze catchment launched its operation in 2003. The effect of the TGD operation on the sediment size on the East China Sea shelf is rarely known. High resolution(0.5 cm sampling) grain size analysis and 137 Cs and 210 Pb dating of the DH8-1 core were conducted with core collected from the distal part of a main sink for the modern Yangtze sediment entering the sea, the Min-Zhe Coastal Mud Deposits(MZCMD) on the inner East China Sea shelf. The 137 Cs dating results show that the core DH8-1 formed during 1946–2012 with a mean deposition rate of 0.65 cm yr^(-1), indicating that the 0.5 cm sampling for grain size analysis in this local area could reflect environmental changes generally on a one-year time scale. The mean grain size of DH8-1 core sediment that deposited after 2003 is significantly larger than that deposited during 1988–2002. After ruling out other possible factors, we infer that the sediment coarsening of DH8-1 core after 2003 is attributed to the TGD operation which causes the erosion of the Yangtze subaqueous delta. Specifically, the TGD operation significantly intensifies the declining trend of the Yangtze sediment loads to the sea despite no decreased water discharge, which results in extensive erosion of the Yangtze subaqueous delta. The relatively coarse sediment of the subaqueous delta is eroded and resuspended by ocean dynamics and then transported by coastal current, finally depositing on the MZCMD area. In addition, the general sediment fining of core DH8-1 that deposited during 1988–2002, comparing with 1946–1987, is mainly caused by dam construction and soil and water conservation within the Yangtze catchment. Our findings are helpful for better understanding the effects of such a huge dam as the TGD on a sediment sink like the MZCMD of such a large river as the Yangtze River.
基金supported by the National Science Foundation of China (Grant No. 41271024)the Fund Project for National Basic Science Talents Cultivation (Grant No. J1210065)the Fundamental Research Funds for the Central Universities- Excellent Graduate Innovation Project (Grant No. Lzujbky-2014-274)
文摘Based on the 1990, 2000 and 2011 Landsat TM/ETM+ remote sensing data, glacier information of three periods in the Chinese Tianshan Mountains were extracted by using ratio threshold method(TM3/TM5) and visual interpretation, combined with digital processing of satellite images and analysis in GIS. The climate data in the surrounding area were analyzed by using linear regression, Mann-Kendall abrupt test, and Morlet wavelet analysis. Study results showed that: over the 23 years investigation, the glacier areas have markedly decreased. In the last 12 years(2000 to 2011), the rate of retreat has begun to accelerate. The most dramatic glacier shrinkage occurred in the central region, the lowest in the eastern region. The mean summer temperature and warm precipitation in Chinese Tianshan Mountains had an increasing trend, with rates of 0.22°C /10 a and 5.1mm/10 a from 1960 to 2011, respectively. Mean summer temperature have experienced a strong increase in 1998. The analysis of the results showed that the rise of mean summer temperature was the main factor that contributed to glacier shrinkage. Regional differences of glacier area changes were investigated by analyzing glacier behavior in five study sub-regions; regional differences are related to local climate, to the relative proportion of glaciers in different size classes, altitudinal and aspect distribution of glaciated areas. In addition, the lag theory indicated that glaciers may accelerate the retreat in the next decade, considering climate trends recognized for the period 2000-2011.