This paper presents two approaches for system-level simulation of force-balance accelerometers. The derivation of the system-level model is elaborated and simulation results are obtained from the implementation of tho...This paper presents two approaches for system-level simulation of force-balance accelerometers. The derivation of the system-level model is elaborated and simulation results are obtained from the implementation of those strategies on the fabricated silicon force-balance MEMS accelerometer. The mathematical model presented is implemented in VHDL- AMS and SIMULINK TM,respectively. The simulation results from the two approaches are compared and show a slight difference. Using VHDL-AMS is flexible,reusable,and more accurate. But there is not a mature solver developed for the language and this approach takes more time, while the simulation model can be easily built and quickly evaluated using SIMULINK.展开更多
An experimental device was set up to study the hydrate formation conditions.Effects of pore size,salinity,and gas composition on the formation and dissociation of hydrates were investigated.The result indicates that t...An experimental device was set up to study the hydrate formation conditions.Effects of pore size,salinity,and gas composition on the formation and dissociation of hydrates were investigated.The result indicates that the induction time for the formation of hydrates in porous media is shorter than that in pure water.The decrease in pore size,by decreasing the size of glass beads,increases the equilibrium pressure when the salinity and temperature are kept constant.In addition,higher salinity causes higher equilibrium pressure when the pore size and temperature are kept constant.It is found that the effects of pore size and salinity on the hydrate equilibrium are quite different.At lower methane concentration,the hydrate equilibrium is achieved at lower pressure and higher temperature.展开更多
A vapor liquid equilibrium model and its related interactive energy parameters based on UNIQUAC model for the H2O-NH3-CO2 system without solid phase at the conditions of temperature from 30℃ to 90℃, pressure from 0....A vapor liquid equilibrium model and its related interactive energy parameters based on UNIQUAC model for the H2O-NH3-CO2 system without solid phase at the conditions of temperature from 30℃ to 90℃, pressure from 0.1 MPa to 0.4 MPa, and the maximum NH3 mass fraction up to 0.4 are provided. This model agrees with experimental data well (average relative error < 1%) and is useful for analysis of industrial urea production.展开更多
In this work we show that tending to thermal equilibrium in one system, at least in certain cases, is associated with the coherent dynamical evolution of this system in interaction with another identical system. The t...In this work we show that tending to thermal equilibrium in one system, at least in certain cases, is associated with the coherent dynamical evolution of this system in interaction with another identical system. The temperature varying effect with time is manifestly shown in our analyses.展开更多
Based on the non-linear air leakage seepage equation for an anisotropic porous medium, on the seepage diffusion equation of multicomponent gas and on the seepage synthetic heat transfer equation of a porous medium, th...Based on the non-linear air leakage seepage equation for an anisotropic porous medium, on the seepage diffusion equation of multicomponent gas and on the seepage synthetic heat transfer equation of a porous medium, the numerical model for field flow problems of irregular patterns of a goaf with multiple points of leaking air is established and simultaneously solved by the upwind mode finite element method (G3 computer program). According to the complexity of irregular patterns of a goaf with multiple points of leaking air, the flow pattern in a large area of such a goaf and the variation in gases of methane, oxygen and CO and in temperature are theoretically described. In the calculation, the goaf is regarded as a caving anisotropic medium and the coupling effect of methane effusion on spontaneous combustion is considered. The simulation results agree well with practical experience. In addition, the spontaneous combustion process is also simulated, indicating that 1) the spontaneous combustion often takes place near the area where fresh air leaks in and 2) the fire sources can be classified into static and dynamic zones. Therefore, in practical fire preventing and extinguishing, we should clearly distinguish the upstream air leaking points from the downstream ones in order to take proper measures for leakage stopping.展开更多
There are two states for the coal-mass on the goal-side which is in stress equilibrium: the state of limit equilibrium (the bearing stress in the coal-mass equals its ultimate bearing stress) and the state of non- ...There are two states for the coal-mass on the goal-side which is in stress equilibrium: the state of limit equilibrium (the bearing stress in the coal-mass equals its ultimate bearing stress) and the state of non- ultimate equilibrium (the bearing stress in the coal-mass is less than its ultimate bearing stress). To ana- lyze the bearing characteristics of a coal pillar in the state of limit equilibrium and guide the design of pillar width, we established a mechanical analytical model of the non-ultimate equilibrium zone in the coal-mass on the goal-side combined with the limit equilibrium theory as well as adopting the methods of theory analysis and mechanical analysis based on the assumption of a state of non-ultimate equilibrium. The width correction coeffident of the limit equilibrium zone has been given. The influence of mining depth, stress concentration coefficient of the surrounding rock, the non-limit strength of the coal-mass and stability of the coal rock interface has been studied. On this basis, we have confirmed that when the width ofa longwall mining face roadway protection coal pillar is between 11.6 m and 13.16 m in No. 4 coal seam of Xinrui coal mine in Lvliang in Shanxi province the elastic core region in the coal pillar can be assured and the roadway will be located in the area of lower stress which is outside the peak stress. So the revised width of the limit eauilibrium zone is more oractical.展开更多
The hydrogenation reaction characteristics and the properties of its hydrides for the magnetic regenerative material HoCu_2(CeCu_2-type) of a cryocooler were investigated. The XRD testing reveals that the hydrides of ...The hydrogenation reaction characteristics and the properties of its hydrides for the magnetic regenerative material HoCu_2(CeCu_2-type) of a cryocooler were investigated. The XRD testing reveals that the hydrides of HoCu_2 were a mixture of Cu, unknown hydride Ⅰ, and unknown hydride Ⅱ. Based on the PCT(pressure-concentration-temperature) curves under different reaction temperatures, the relationships among reaction temperature, equilibrium pressure, and maximum hydrogen absorption capacity were analyzed and discussed. The enthalpy change ΔH and entropy change ΔS as a result of the whole hydrogenation process were also calculated from the PCT curves. The magnetization and volumetric specific heat capacity of the hydride were also measured by SQUID magnetometer and PPMS, respectively.展开更多
Humidification is an important step in humid air turbine system. The calculation on humidification is carried out at 423.15—573.15K, 5—15MPa. The results suggest that to produce high-enthalpy moist air, high water t...Humidification is an important step in humid air turbine system. The calculation on humidification is carried out at 423.15—573.15K, 5—15MPa. The results suggest that to produce high-enthalpy moist air, high water temperature and large water flow are needed. The water temperature is the most sensitive parameter to the humidification tower. And it is better for the humidification tower to work at temperature higher than 523 K when the system pressure is higher than 5 MPa. The comparison between the model used in this paper and ideal model shows that the ideal model can be used in simulation to simply the calculation when the temperature is lower than 473 K and pressure is lower than 5 MPa.展开更多
The original van Laar's theory has been modified. The internal pressures of components and mixture are expressed by Frank's relation and the excess entropy for mixing of components is also considered. A new ac...The original van Laar's theory has been modified. The internal pressures of components and mixture are expressed by Frank's relation and the excess entropy for mixing of components is also considered. A new activity coefficient equation, which can be satisfactorily applied to polymer solutions, is obtained. The calculated results for the VLE of 179 polymer solutions show that the accuracy of fit is evidently superior to UNIQUAC equation.展开更多
The objective of the present study was to determine the proper sources and concentrations of soybean lecithin (phosphatidylcholine, PC) to be used as substitute for hen egg yolk in extender for preserving goat semen...The objective of the present study was to determine the proper sources and concentrations of soybean lecithin (phosphatidylcholine, PC) to be used as substitute for hen egg yolk in extender for preserving goat semen. Two sources of soybean lecithin (20% and 95% soybean phosphatidylcholine; PC20 and PC95) and three concentrations (1%, 2% and 3% v/v) of PC20 and PC95 supplemented in Tris-citric acid-fructose (TCF) extender were tested. The TCF extender supplemented with 20% hen egg yolk was used as a control. Fresh semen samples were collected from 3 goats by artificial vagina. Seminal plasma was removed by centrifugation and sperm pellets were pooled together and divided into 7 groups according to types of extender. The diluted semen samples were kept at 4 ℃ (equilibration). The semen qualities including progressive motility, sperm viability, sperm plasma membrane integrity and tail abnormalities were evaluated before dilution and after 4 hrs equilibration. It was found that the progressive motility of equilibrated semen in egg yolk and PC20 extenders were higher than those in PC95 extender (P 〈 0.05). Sperm viability was lower in 1% and 2% PC95 extender compared to other extenders (P 〈 0.05). PC20 extender maintained the sperm membrane integrity and normal tail morphology at low temperature better than egg yolk and PC95 (P 〈 0.05). It can be concluded that 20% soybean phosphatidylcholine supplemented in TCF extender at 1%-3% (v/v) is as effective as hen egg yolk to preserve goat semen during equilibration at 4 ℃ for 4 hrs .展开更多
Hoek–Brown(HB)strength criterion can reflect rock’s inherent failure nature,so it is more suitable for analyzing the stability of rock slopes.However,the traditional limit equilibrium methods are at present only sui...Hoek–Brown(HB)strength criterion can reflect rock’s inherent failure nature,so it is more suitable for analyzing the stability of rock slopes.However,the traditional limit equilibrium methods are at present only suitable for analyzing the rock slope stability using the linear equivalent Mohr–Coulomb(EMC)strength parameters instead of the nonlinear HB strength criterion.Therefore,a new method derived to analyze directly the rock slope stability using the nonlinear HB strength criterion for arbitrary curve slip surface was described in the limit equilibrium framework.The current method was established based on certain assumptions concerning the stresses on the slip surface through amending the initial normal stressσ0 obtained without considering the effect of inter-slice forces,and it can satisfy all static equilibrium conditions of the sliding body,so the current method can obtain the reasonable and strict factor of safety(FOS)solutions.Compared with the results of other methods in some examples,the feasibility of the current method was verified.Meanwhile,the parametric analysis shows that the slope angleβhas an important influence on the difference of the results obtained using the nonlinear HB strength criterion and its linear EMC strength parameters.Forβ≤45°,both of the results are similar,showing the traditional limit equilibrium methods using the linear EMC strength parameters and the current method are all suitable to analyze rock slope stability,but forβ>60°,the differences of both the results are obvious,showing the actual slope stability state can not be reflected in the traditional limit equilibrium methods,and then the current method should be used.展开更多
Estimation of protein-ligand binding affinity within chemical accuracy is one of the grand challenges in structure-based rational drug design. With the efforts over three decades, free energy methods based on equilibr...Estimation of protein-ligand binding affinity within chemical accuracy is one of the grand challenges in structure-based rational drug design. With the efforts over three decades, free energy methods based on equilibrium molecular dynamics (MD) simulations have become mature and are nowadays routinely applied in the community of computational chemistry. On the contrary, nonequilibrinm MD simulation methods have attracted less attention, despite their underlying rigor in mathematics and potential advantage in efficiency. In this work, the equilibrium and nonequilibrium simulation methods are compared in terms of accuracy and convergence rate in the calculations of relative binding free energies. The proteins studied are T4-lysozyme mutant L99A and COX-2. For each protein, two ligands are studied. The results show that the noneqnilibrium simulation method can be competitively as accurate as the equilibrium method, and the former is more efficient than the latter by considering the convergence rate with respect to the cost of wall clock time. In addition, Bennett acceptance ratio, which is a bidirectional post-processing method, converges faster than the unidirectional Jarzynski equality for the nonequilibrium simulations.展开更多
Inhalation of 222Rn progeny in the domestic environment contributes the greatest fraction of the natural radiation exposure to the public. The ultrafine activity of these progeny amounts up to about l 0 percent of the...Inhalation of 222Rn progeny in the domestic environment contributes the greatest fraction of the natural radiation exposure to the public. The ultrafine activity of these progeny amounts up to about l 0 percent of the total activity (attached and ultrafine), but is considered to yield about 50 percent of the total radiation dose. Therefore, measurements of ultrafine fraction are essential for the estimation of radiation dose. The current study presents measured data on the total equilibrium equivalent concentration (EEC) and ultrafine equilibrium equivalent concentration (EECUn), ultrafine fraction (fb), attached and unattached activity size distributions of radon progeny in the low ventilated rooms at Minia University, Minia city, Egypt. A screen diffusion battery was used for collection the ultrafine fraction and measuring the total activity concentration of radon progeny. The attached activity size distribution of 214pb is determined by using a low pressure cascade impactor. The EEC of radon progeny varied between 1.3 and 18.9 Bq/m3 with a mean value of 5.2 ± 0.48 Bq/m2. The mean activity thermodynamic diameter (AMTD) ofultrafine of radon progeny was determined to be 1.26 nm with relative mean geometric standard deviations (GSD) of 1.3. The ultrafine fraction of radon progeny, fb, has a range 0.01 to 0.21 with an average of 0.08 ± 0.03. A relative mean GSD of 2.7 was determined for attached 2Lapb at a mean active median aerodynamic diameter (AMD) of 350 nm. Based on the above experimental results, the deposition fractions have been evaluated in each air way generation through the human lung by applying a lung deposition model. The bronchial deposition efficiencies of particles in the size range of attached radon progeny were found to be lower than those of ultrafine progeny. The effect of radon progeny deposition by adult male has been also studied for various levels of physical exertion. The dose conversion factor has been discussed as a function of fb.展开更多
In this study, we selected 9 typical coal samples with different metamorphic grades as the study subjects,measured their initial 30-min gas desorption at 30℃ and different pressure using a self-developed gas adsorpti...In this study, we selected 9 typical coal samples with different metamorphic grades as the study subjects,measured their initial 30-min gas desorption at 30℃ and different pressure using a self-developed gas adsorption/desorption device. Based on the characteristics of gas desorption from coal samples, we proposed a direct fitting method for measurement of gas content in coalbed, analyzed the effects of sampling time on the measurement results and determined the reasonable sampling time of coal samples with different metamorphic grades at different gas adsorption pressure at equilibrium. The results show that (1)the error of gas contents obtained using the direct fitting method relative to that obtained using indirect method is less than 10%, which meets the actual on-site requirements and verifies the feasibility of the direct fitting method;(2) when the relative error is controlled within ±10%, the reasonable sampling time of coal samples is linearly related to the gas adsorption pressure at equilibrium;(3) the reasonable sampling time of coal samples with the same metamorphic grade exhibits a shortening trend with increasing gas adsorption pressure at equilibrium;(4) for coal samples with similar gas adsorption pressure at equilibrium, the reasonable sampling time of coal samples displays a shortening trend with increasing metamorphic grade. Overall, the study provides a basis for improving the measurement accuracy of gas content in coalbed.展开更多
Nanofluidics in hydrophilic nanopores is a common issue in many natural and industrial processes. Among all,the mass transport of nanofluidics is most concerned. Besides that, the heat transfer of a fluid flow in nano...Nanofluidics in hydrophilic nanopores is a common issue in many natural and industrial processes. Among all,the mass transport of nanofluidics is most concerned. Besides that, the heat transfer of a fluid flow in nano or micro channels is always considered with adding nanoparticles into the flow, so as to enhance the heat transfer by convection between the fluid and the surface. However, for some applications with around 1 nm channels such as nano filtration or erosion of rocks, there should be no nanoparticles included. Hence, it is necessary to figure out the heat transfer mechanism in the single phase nanofluidics. Via non-equilibrium molecular dynamics simulations, we revealed the heat transfer inside nanofluidics and the one between fluid and walls by setting simulation into extremely harsh condition. It was found that the heat was conducted by molecular motion without temperature gradient in the area of low viscous heat, while it was transferred to the walls by increasing the temperature of fluids. If the condition back to normal, it was found that the viscous heat of nanofluidics could be easily removed by the fluid-wall temperature drop of less than 1 K.展开更多
Traditional fracture analysis is based on fracture mechanics and damage mechanics. They focus on the propagation of the fracture. However, their propagation criterions are not easily applied in practice and the curren...Traditional fracture analysis is based on fracture mechanics and damage mechanics. They focus on the propagation of the fracture. However, their propagation criterions are not easily applied in practice and the current analysis is limited in planar problem. This paper presents a new theory that the occurrence of the unbalanced force (derived from the Deformation Reinforcement Theory) could be the criterion of the initiation of the fracture, and the distribution area and propagation of the unbalanced force could be the indication of the fracture propagation direction. By aggregate analysis with Stress Intensity Factor (SIF) criterion, the unbalanced force actually is the opposite external load that is the SIF difference incurred between the external loads and permitted by the structure. Numerical simulation and physical experiments on pre-fracture cuboid rock specimens proved that the occurrence of the unbalanced force could be the initiation of the fracture. Mesh size dependence was also considered by analysis of different mesh size finite element gravity dam models. Furthermore, the theory was applied to the feasibility analysis of the Baihetan arch dam together with physical experiments in order to evaluate the fracture propagation of dam heel. The results show that it is an effective way to use unbalanced force to analyze the fracture initiation and propagation when performing 3-dimensional nonlinear FEM calculation.展开更多
To determine the interdependence of intracranial pressure(ICP) and intraocular pressure(IOP) and how it affects optic nerve pressures, eight normal dogs were examined using pressure-sensing probes implanted into the l...To determine the interdependence of intracranial pressure(ICP) and intraocular pressure(IOP) and how it affects optic nerve pressures, eight normal dogs were examined using pressure-sensing probes implanted into the left ventricle, lumbar cistern, optic nerve subarachnoid space in the left eye, and anterior chamber in the left eye. This allowed ICP, lumbar cistern pressure(LCP), optic nerve subarachnoid space pressure(ONSP) and IOP to be simultaneously recorded. After establishing baseline pressure levels, pressure changes that resulted from lowering ICP(via shunting cerebrospinal fluid(CSF) from the ventricle) were recorded. At baseline, all examined pressures were different(ICP>LCP>ONSP), but correlated(P<0.001). As ICP was lowered during CSF shunting, IOP also dropped in a parallel time course so that the trans-lamina cribrosa gradient(TLPG) remained stable(ICP-IOP dependent zone). However, once ICP fell below a critical breakpoint, ICP and IOP became uncoupled and TLPG changed as ICP declined(ICP-IOP independent zone). The optic nerve pressure gradient(ONPG) and trans-optic nerve pressure gradient(TOPG) increased linearly as ICP decreased through both the ICP-IOP dependent and independent zones. We conclude that ICP and IOP are coupled in a specific pressure range, but when ICP drops below a critical point, IOP and ICP become uncoupled and TLPG increases. When ICP drops, a rise in the ONPG and TOPG creates more pressure and reduces CSF flow around the optic nerve. This change may play a role in the development and progression of various ophthalmic and neurological diseases, including glaucoma.展开更多
Based on non-equilibrium thermodynamic theory, a temperature field model of gun muzzle is setup We obtain not only a solitary solution, but also a bifurcation solution. The physical picture of the solutions is corresp...Based on non-equilibrium thermodynamic theory, a temperature field model of gun muzzle is setup We obtain not only a solitary solution, but also a bifurcation solution. The physical picture of the solutions is corresponding to the center flame and secondary flame of the gun muzzle.展开更多
文摘This paper presents two approaches for system-level simulation of force-balance accelerometers. The derivation of the system-level model is elaborated and simulation results are obtained from the implementation of those strategies on the fabricated silicon force-balance MEMS accelerometer. The mathematical model presented is implemented in VHDL- AMS and SIMULINK TM,respectively. The simulation results from the two approaches are compared and show a slight difference. Using VHDL-AMS is flexible,reusable,and more accurate. But there is not a mature solver developed for the language and this approach takes more time, while the simulation model can be easily built and quickly evaluated using SIMULINK.
基金Supported by the Key Program of National Natural Science Foundation of China(50736001) the National High Technology Research and Development Program of China(2006AA09A209-5) the Major State Basic Research Development Program of China(2009CB219507)
文摘An experimental device was set up to study the hydrate formation conditions.Effects of pore size,salinity,and gas composition on the formation and dissociation of hydrates were investigated.The result indicates that the induction time for the formation of hydrates in porous media is shorter than that in pure water.The decrease in pore size,by decreasing the size of glass beads,increases the equilibrium pressure when the salinity and temperature are kept constant.In addition,higher salinity causes higher equilibrium pressure when the pore size and temperature are kept constant.It is found that the effects of pore size and salinity on the hydrate equilibrium are quite different.At lower methane concentration,the hydrate equilibrium is achieved at lower pressure and higher temperature.
文摘A vapor liquid equilibrium model and its related interactive energy parameters based on UNIQUAC model for the H2O-NH3-CO2 system without solid phase at the conditions of temperature from 30℃ to 90℃, pressure from 0.1 MPa to 0.4 MPa, and the maximum NH3 mass fraction up to 0.4 are provided. This model agrees with experimental data well (average relative error < 1%) and is useful for analysis of industrial urea production.
基金National Natural Science Foundation of China under Grant No.10775097the Specialized Research Fund for the Doctorial Progress of Higher Education(SRFDP)
文摘In this work we show that tending to thermal equilibrium in one system, at least in certain cases, is associated with the coherent dynamical evolution of this system in interaction with another identical system. The temperature varying effect with time is manifestly shown in our analyses.
基金supported by the National Natural Science Foundation of China (No.50574038)the Scientific Research Foundation of Liaoning Technical University (No.2004-241).
文摘Based on the non-linear air leakage seepage equation for an anisotropic porous medium, on the seepage diffusion equation of multicomponent gas and on the seepage synthetic heat transfer equation of a porous medium, the numerical model for field flow problems of irregular patterns of a goaf with multiple points of leaking air is established and simultaneously solved by the upwind mode finite element method (G3 computer program). According to the complexity of irregular patterns of a goaf with multiple points of leaking air, the flow pattern in a large area of such a goaf and the variation in gases of methane, oxygen and CO and in temperature are theoretically described. In the calculation, the goaf is regarded as a caving anisotropic medium and the coupling effect of methane effusion on spontaneous combustion is considered. The simulation results agree well with practical experience. In addition, the spontaneous combustion process is also simulated, indicating that 1) the spontaneous combustion often takes place near the area where fresh air leaks in and 2) the fire sources can be classified into static and dynamic zones. Therefore, in practical fire preventing and extinguishing, we should clearly distinguish the upstream air leaking points from the downstream ones in order to take proper measures for leakage stopping.
基金supported by the National Programs for Fundamental Research and Development (No. 2013CB227900)the National Natural Science Foundation of China (Nos. 51204166, 51174195 and 51474209)the Project Funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
文摘There are two states for the coal-mass on the goal-side which is in stress equilibrium: the state of limit equilibrium (the bearing stress in the coal-mass equals its ultimate bearing stress) and the state of non- ultimate equilibrium (the bearing stress in the coal-mass is less than its ultimate bearing stress). To ana- lyze the bearing characteristics of a coal pillar in the state of limit equilibrium and guide the design of pillar width, we established a mechanical analytical model of the non-ultimate equilibrium zone in the coal-mass on the goal-side combined with the limit equilibrium theory as well as adopting the methods of theory analysis and mechanical analysis based on the assumption of a state of non-ultimate equilibrium. The width correction coeffident of the limit equilibrium zone has been given. The influence of mining depth, stress concentration coefficient of the surrounding rock, the non-limit strength of the coal-mass and stability of the coal rock interface has been studied. On this basis, we have confirmed that when the width ofa longwall mining face roadway protection coal pillar is between 11.6 m and 13.16 m in No. 4 coal seam of Xinrui coal mine in Lvliang in Shanxi province the elastic core region in the coal pillar can be assured and the roadway will be located in the area of lower stress which is outside the peak stress. So the revised width of the limit eauilibrium zone is more oractical.
基金Project(51276154)supported by the National Natural Science Foundation of ChinaProject(2012010111014)supported by the University Doctoral Subject Special Foundation of China
文摘The hydrogenation reaction characteristics and the properties of its hydrides for the magnetic regenerative material HoCu_2(CeCu_2-type) of a cryocooler were investigated. The XRD testing reveals that the hydrides of HoCu_2 were a mixture of Cu, unknown hydride Ⅰ, and unknown hydride Ⅱ. Based on the PCT(pressure-concentration-temperature) curves under different reaction temperatures, the relationships among reaction temperature, equilibrium pressure, and maximum hydrogen absorption capacity were analyzed and discussed. The enthalpy change ΔH and entropy change ΔS as a result of the whole hydrogenation process were also calculated from the PCT curves. The magnetization and volumetric specific heat capacity of the hydride were also measured by SQUID magnetometer and PPMS, respectively.
基金Supported by the Natural Science Foundation of Jiangsu Province (BK97124) the National Natural Science Foundation (No. 20376032)+1 种基金 the Outstanding Youth Fund of National Natural Science Foundation (No. 29925616)Key Fund of National Natural Science Fo
文摘Humidification is an important step in humid air turbine system. The calculation on humidification is carried out at 423.15—573.15K, 5—15MPa. The results suggest that to produce high-enthalpy moist air, high water temperature and large water flow are needed. The water temperature is the most sensitive parameter to the humidification tower. And it is better for the humidification tower to work at temperature higher than 523 K when the system pressure is higher than 5 MPa. The comparison between the model used in this paper and ideal model shows that the ideal model can be used in simulation to simply the calculation when the temperature is lower than 473 K and pressure is lower than 5 MPa.
基金Supported by the National Natural Science Foundation of China(No.29376236).
文摘The original van Laar's theory has been modified. The internal pressures of components and mixture are expressed by Frank's relation and the excess entropy for mixing of components is also considered. A new activity coefficient equation, which can be satisfactorily applied to polymer solutions, is obtained. The calculated results for the VLE of 179 polymer solutions show that the accuracy of fit is evidently superior to UNIQUAC equation.
文摘The objective of the present study was to determine the proper sources and concentrations of soybean lecithin (phosphatidylcholine, PC) to be used as substitute for hen egg yolk in extender for preserving goat semen. Two sources of soybean lecithin (20% and 95% soybean phosphatidylcholine; PC20 and PC95) and three concentrations (1%, 2% and 3% v/v) of PC20 and PC95 supplemented in Tris-citric acid-fructose (TCF) extender were tested. The TCF extender supplemented with 20% hen egg yolk was used as a control. Fresh semen samples were collected from 3 goats by artificial vagina. Seminal plasma was removed by centrifugation and sperm pellets were pooled together and divided into 7 groups according to types of extender. The diluted semen samples were kept at 4 ℃ (equilibration). The semen qualities including progressive motility, sperm viability, sperm plasma membrane integrity and tail abnormalities were evaluated before dilution and after 4 hrs equilibration. It was found that the progressive motility of equilibrated semen in egg yolk and PC20 extenders were higher than those in PC95 extender (P 〈 0.05). Sperm viability was lower in 1% and 2% PC95 extender compared to other extenders (P 〈 0.05). PC20 extender maintained the sperm membrane integrity and normal tail morphology at low temperature better than egg yolk and PC95 (P 〈 0.05). It can be concluded that 20% soybean phosphatidylcholine supplemented in TCF extender at 1%-3% (v/v) is as effective as hen egg yolk to preserve goat semen during equilibration at 4 ℃ for 4 hrs .
基金Project(2015M580702)supported by China Postdoctoral Science FoundationProject(51608541)supported by the National Natural Science Foundation of ChinaProject(2014122066)supported by the Guizhou Provincial Department of Transportation Foundation,China
文摘Hoek–Brown(HB)strength criterion can reflect rock’s inherent failure nature,so it is more suitable for analyzing the stability of rock slopes.However,the traditional limit equilibrium methods are at present only suitable for analyzing the rock slope stability using the linear equivalent Mohr–Coulomb(EMC)strength parameters instead of the nonlinear HB strength criterion.Therefore,a new method derived to analyze directly the rock slope stability using the nonlinear HB strength criterion for arbitrary curve slip surface was described in the limit equilibrium framework.The current method was established based on certain assumptions concerning the stresses on the slip surface through amending the initial normal stressσ0 obtained without considering the effect of inter-slice forces,and it can satisfy all static equilibrium conditions of the sliding body,so the current method can obtain the reasonable and strict factor of safety(FOS)solutions.Compared with the results of other methods in some examples,the feasibility of the current method was verified.Meanwhile,the parametric analysis shows that the slope angleβhas an important influence on the difference of the results obtained using the nonlinear HB strength criterion and its linear EMC strength parameters.Forβ≤45°,both of the results are similar,showing the traditional limit equilibrium methods using the linear EMC strength parameters and the current method are all suitable to analyze rock slope stability,but forβ>60°,the differences of both the results are obvious,showing the actual slope stability state can not be reflected in the traditional limit equilibrium methods,and then the current method should be used.
文摘Estimation of protein-ligand binding affinity within chemical accuracy is one of the grand challenges in structure-based rational drug design. With the efforts over three decades, free energy methods based on equilibrium molecular dynamics (MD) simulations have become mature and are nowadays routinely applied in the community of computational chemistry. On the contrary, nonequilibrinm MD simulation methods have attracted less attention, despite their underlying rigor in mathematics and potential advantage in efficiency. In this work, the equilibrium and nonequilibrium simulation methods are compared in terms of accuracy and convergence rate in the calculations of relative binding free energies. The proteins studied are T4-lysozyme mutant L99A and COX-2. For each protein, two ligands are studied. The results show that the noneqnilibrium simulation method can be competitively as accurate as the equilibrium method, and the former is more efficient than the latter by considering the convergence rate with respect to the cost of wall clock time. In addition, Bennett acceptance ratio, which is a bidirectional post-processing method, converges faster than the unidirectional Jarzynski equality for the nonequilibrium simulations.
文摘Inhalation of 222Rn progeny in the domestic environment contributes the greatest fraction of the natural radiation exposure to the public. The ultrafine activity of these progeny amounts up to about l 0 percent of the total activity (attached and ultrafine), but is considered to yield about 50 percent of the total radiation dose. Therefore, measurements of ultrafine fraction are essential for the estimation of radiation dose. The current study presents measured data on the total equilibrium equivalent concentration (EEC) and ultrafine equilibrium equivalent concentration (EECUn), ultrafine fraction (fb), attached and unattached activity size distributions of radon progeny in the low ventilated rooms at Minia University, Minia city, Egypt. A screen diffusion battery was used for collection the ultrafine fraction and measuring the total activity concentration of radon progeny. The attached activity size distribution of 214pb is determined by using a low pressure cascade impactor. The EEC of radon progeny varied between 1.3 and 18.9 Bq/m3 with a mean value of 5.2 ± 0.48 Bq/m2. The mean activity thermodynamic diameter (AMTD) ofultrafine of radon progeny was determined to be 1.26 nm with relative mean geometric standard deviations (GSD) of 1.3. The ultrafine fraction of radon progeny, fb, has a range 0.01 to 0.21 with an average of 0.08 ± 0.03. A relative mean GSD of 2.7 was determined for attached 2Lapb at a mean active median aerodynamic diameter (AMD) of 350 nm. Based on the above experimental results, the deposition fractions have been evaluated in each air way generation through the human lung by applying a lung deposition model. The bronchial deposition efficiencies of particles in the size range of attached radon progeny were found to be lower than those of ultrafine progeny. The effect of radon progeny deposition by adult male has been also studied for various levels of physical exertion. The dose conversion factor has been discussed as a function of fb.
基金the support of the National Natural Science Foundation of China(Nos.51674158,51604168 and 51504142)the Natural Science Foundation of Shandong Province(No.ZR2016EEQ18)+2 种基金the SDUST Research Fund(No.2015JQJH105)the Qingdao Postdoctoral Applied Research Project(No.2015204)the Taishan Scholar Talent Team Support Plan for Advantaged&Unique Discipline Areas
文摘In this study, we selected 9 typical coal samples with different metamorphic grades as the study subjects,measured their initial 30-min gas desorption at 30℃ and different pressure using a self-developed gas adsorption/desorption device. Based on the characteristics of gas desorption from coal samples, we proposed a direct fitting method for measurement of gas content in coalbed, analyzed the effects of sampling time on the measurement results and determined the reasonable sampling time of coal samples with different metamorphic grades at different gas adsorption pressure at equilibrium. The results show that (1)the error of gas contents obtained using the direct fitting method relative to that obtained using indirect method is less than 10%, which meets the actual on-site requirements and verifies the feasibility of the direct fitting method;(2) when the relative error is controlled within ±10%, the reasonable sampling time of coal samples is linearly related to the gas adsorption pressure at equilibrium;(3) the reasonable sampling time of coal samples with the same metamorphic grade exhibits a shortening trend with increasing gas adsorption pressure at equilibrium;(4) for coal samples with similar gas adsorption pressure at equilibrium, the reasonable sampling time of coal samples displays a shortening trend with increasing metamorphic grade. Overall, the study provides a basis for improving the measurement accuracy of gas content in coalbed.
基金Supported by the National Basic Research Program of China(2015CB655301)the National Natural Science Foundation of China(21506091)+2 种基金the Jiangsu Natural Science Foundations(BK20150944)the Special Program for Applied Research on Super Computation of the NSFC-Guangdong Joint Fund(the second phase)the Project of Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD)
文摘Nanofluidics in hydrophilic nanopores is a common issue in many natural and industrial processes. Among all,the mass transport of nanofluidics is most concerned. Besides that, the heat transfer of a fluid flow in nano or micro channels is always considered with adding nanoparticles into the flow, so as to enhance the heat transfer by convection between the fluid and the surface. However, for some applications with around 1 nm channels such as nano filtration or erosion of rocks, there should be no nanoparticles included. Hence, it is necessary to figure out the heat transfer mechanism in the single phase nanofluidics. Via non-equilibrium molecular dynamics simulations, we revealed the heat transfer inside nanofluidics and the one between fluid and walls by setting simulation into extremely harsh condition. It was found that the heat was conducted by molecular motion without temperature gradient in the area of low viscous heat, while it was transferred to the walls by increasing the temperature of fluids. If the condition back to normal, it was found that the viscous heat of nanofluidics could be easily removed by the fluid-wall temperature drop of less than 1 K.
基金supported by the National Natural Science Foundation of China (Grant No. 50709014)China National Funds for Distinguished Young Scientists (Grant No. 50925931)State Key Laboratory of Hydroscience and Engineering of China (Grant No. 2008-TC-2)
文摘Traditional fracture analysis is based on fracture mechanics and damage mechanics. They focus on the propagation of the fracture. However, their propagation criterions are not easily applied in practice and the current analysis is limited in planar problem. This paper presents a new theory that the occurrence of the unbalanced force (derived from the Deformation Reinforcement Theory) could be the criterion of the initiation of the fracture, and the distribution area and propagation of the unbalanced force could be the indication of the fracture propagation direction. By aggregate analysis with Stress Intensity Factor (SIF) criterion, the unbalanced force actually is the opposite external load that is the SIF difference incurred between the external loads and permitted by the structure. Numerical simulation and physical experiments on pre-fracture cuboid rock specimens proved that the occurrence of the unbalanced force could be the initiation of the fracture. Mesh size dependence was also considered by analysis of different mesh size finite element gravity dam models. Furthermore, the theory was applied to the feasibility analysis of the Baihetan arch dam together with physical experiments in order to evaluate the fracture propagation of dam heel. The results show that it is an effective way to use unbalanced force to analyze the fracture initiation and propagation when performing 3-dimensional nonlinear FEM calculation.
基金supported by the National Natural Science Foundation of China (81271005, 81300767)Beijing Natural Science Foundation (7122038)+3 种基金two separate donations by the China Health and Medical Development FoundationB.A.S. was supported by the BMBF network ERA-net Neuron “Restoration of Vision after Stroke (REVIS)” (BMBF 01EW1210)by the “Hai-ju” Beijing Overseas Talents ProgramRuowu Hou was supported by the Beijing Tongren Hospital Foundation (2015-YJJ-GGL-013)
文摘To determine the interdependence of intracranial pressure(ICP) and intraocular pressure(IOP) and how it affects optic nerve pressures, eight normal dogs were examined using pressure-sensing probes implanted into the left ventricle, lumbar cistern, optic nerve subarachnoid space in the left eye, and anterior chamber in the left eye. This allowed ICP, lumbar cistern pressure(LCP), optic nerve subarachnoid space pressure(ONSP) and IOP to be simultaneously recorded. After establishing baseline pressure levels, pressure changes that resulted from lowering ICP(via shunting cerebrospinal fluid(CSF) from the ventricle) were recorded. At baseline, all examined pressures were different(ICP>LCP>ONSP), but correlated(P<0.001). As ICP was lowered during CSF shunting, IOP also dropped in a parallel time course so that the trans-lamina cribrosa gradient(TLPG) remained stable(ICP-IOP dependent zone). However, once ICP fell below a critical breakpoint, ICP and IOP became uncoupled and TLPG changed as ICP declined(ICP-IOP independent zone). The optic nerve pressure gradient(ONPG) and trans-optic nerve pressure gradient(TOPG) increased linearly as ICP decreased through both the ICP-IOP dependent and independent zones. We conclude that ICP and IOP are coupled in a specific pressure range, but when ICP drops below a critical point, IOP and ICP become uncoupled and TLPG increases. When ICP drops, a rise in the ONPG and TOPG creates more pressure and reduces CSF flow around the optic nerve. This change may play a role in the development and progression of various ophthalmic and neurological diseases, including glaucoma.
文摘Based on non-equilibrium thermodynamic theory, a temperature field model of gun muzzle is setup We obtain not only a solitary solution, but also a bifurcation solution. The physical picture of the solutions is corresponding to the center flame and secondary flame of the gun muzzle.