For the purpose of effective and economic desulfurization of flue-gas, the predominance area diagram of the Mn-S-O system at different temperatures was constructed based on the thermodynamic data obtained from the lit...For the purpose of effective and economic desulfurization of flue-gas, the predominance area diagram of the Mn-S-O system at different temperatures was constructed based on the thermodynamic data obtained from the literatures. It is seen from this figure that flue-gas desulfurization by manganese oxides is feasible from the thermodynamic point of view. Additionally, the most appropriate temperature range for flue-gas desulfurization is between 600 and 800 K, and the reaction is strongly exothermic to maintain the heat balance. The natural manganese ores encompass large tunnels that exhibit large surface areas and highly chemical activity, which can provide a high enough SO2 removing efficiency. From the superposition of the diagrams of Mn-S-O and Fe-S-O systems, it is found that there is a coexistent stability region of MnSO4 and Fe2O3, which provides the possibility of desulfurization by selective sulfation without ferric sulfate forming. A multi-stage desulfurization system has been discussed briefly.展开更多
Commercial grade weakly basic resin D301 was impregnated with iron through a simple method using ferric chloride. Experiments for single, bisolute and trinary competitive adsorption were carried out to investigate the...Commercial grade weakly basic resin D301 was impregnated with iron through a simple method using ferric chloride. Experiments for single, bisolute and trinary competitive adsorption were carried out to investigate the adsorption behavior of 2-naphthalenesulfonic acid(NSA), sulfuric acid and sulfurous acid from their solution at 298 K onto the novel hybrid iron impregnated D301(Fe-D301). Adsorption affinity of NSA on Fe-D301 was found to be much higher than that of sulfuric acid, while adsorption affinity of sulfuric acid was slightly higher than that of sulfurous acid. The data of single-solute adsorption were fitted to the Langmuir model and the Freundlich adsorption model. The non-ideal competitive adsorbed model coupled with the single-solute adsorption models were used to predict the bisolute and trinary-solute competitive adsorption equilibria. The NICM coupled with the Langmuir model yields the favorable representation of the bisolute and trinary-solute competitive adsorption behavior.展开更多
基金Project(51344006)supported by the National Natural Science Foundation of China
文摘For the purpose of effective and economic desulfurization of flue-gas, the predominance area diagram of the Mn-S-O system at different temperatures was constructed based on the thermodynamic data obtained from the literatures. It is seen from this figure that flue-gas desulfurization by manganese oxides is feasible from the thermodynamic point of view. Additionally, the most appropriate temperature range for flue-gas desulfurization is between 600 and 800 K, and the reaction is strongly exothermic to maintain the heat balance. The natural manganese ores encompass large tunnels that exhibit large surface areas and highly chemical activity, which can provide a high enough SO2 removing efficiency. From the superposition of the diagrams of Mn-S-O and Fe-S-O systems, it is found that there is a coexistent stability region of MnSO4 and Fe2O3, which provides the possibility of desulfurization by selective sulfation without ferric sulfate forming. A multi-stage desulfurization system has been discussed briefly.
基金Supported by the National Natural Science Foundation of China(No.21276027)the Higher Educational Science and Technology Program of Shandong Province,China(No.J14LC05)
文摘Commercial grade weakly basic resin D301 was impregnated with iron through a simple method using ferric chloride. Experiments for single, bisolute and trinary competitive adsorption were carried out to investigate the adsorption behavior of 2-naphthalenesulfonic acid(NSA), sulfuric acid and sulfurous acid from their solution at 298 K onto the novel hybrid iron impregnated D301(Fe-D301). Adsorption affinity of NSA on Fe-D301 was found to be much higher than that of sulfuric acid, while adsorption affinity of sulfuric acid was slightly higher than that of sulfurous acid. The data of single-solute adsorption were fitted to the Langmuir model and the Freundlich adsorption model. The non-ideal competitive adsorbed model coupled with the single-solute adsorption models were used to predict the bisolute and trinary-solute competitive adsorption equilibria. The NICM coupled with the Langmuir model yields the favorable representation of the bisolute and trinary-solute competitive adsorption behavior.