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温度影响下短波近红外酒精度检测的传递校正 被引量:5
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作者 付庆波 索辉 +1 位作者 贺馨平 丛玉良 《光谱学与光谱分析》 SCIE EI CAS CSCD 北大核心 2012年第8期2080-2084,共5页
短波近红外光谱结合多元校正方法测量酒精度具有快速、无损的特点,可以现场应用和在线检测。但是温度对预测模型的性能影响很大。作者研究了温度变化对乙醇水溶液的短波近红外光谱的影响,采用四种方法建立了温度变化下的偏最小二乘(PLS... 短波近红外光谱结合多元校正方法测量酒精度具有快速、无损的特点,可以现场应用和在线检测。但是温度对预测模型的性能影响很大。作者研究了温度变化对乙醇水溶液的短波近红外光谱的影响,采用四种方法建立了温度变化下的偏最小二乘(PLS)传递校正模型:直接校正、全局校正、正交信号处理(OSC)和广义最小二乘加权法(GLSW)。结果表明,温度变化时直接传递校正存在很大的预测系统偏差,而采用全局校正、OSC和GLSW均能在一定程度上减小系统误差。全局校正需要较多的建模样品数量,得到的模型也更为复杂。而OSC和GLSW方法能得到更为简洁的模型和优良的预测结果。相比之下,GLSW算法得到的预测误差和使用的建模隐含变量数目均小于OSC方法,能够建立更为稳健的传递校正模型。 展开更多
关键词 短波近红外 温度校正 正交信号处理 广义最小二乘加权法
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Fitting Generalized Additive Logistic Regression Model with GAM Procedure
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作者 Suresh Kumar Sharma Rashmi Aggarwal Kanchan Jain 《Journal of Mathematics and System Science》 2013年第9期442-453,共12页
In dealing with nonparametric regression the GAM procedure is the most versatile of several new procedures. The terminology behind this procedure is more flexible than traditional parametric modeling tools. It relaxes... In dealing with nonparametric regression the GAM procedure is the most versatile of several new procedures. The terminology behind this procedure is more flexible than traditional parametric modeling tools. It relaxes the usual assumptions of parametric model and enables us to uncover structure to establish the relationship between independent variables and dependent variable in exponential family that may not be obvious otherwise. In this paper, we discussed two methods of fitting generalized additive logistic regression model, one based on Newton Raphson method and another based on iterative weighted least square method for first and second order Taylor series expansion. The use of the GAM procedure with the specified set of weights, using local scoring algorithm, was applied to real life data sets. The cubic spline smoother is applied to the independent variables. Based on nonparametric regression and smoothing techniques, this procedure provides powerful tools for data analysis. 展开更多
关键词 Logistic model iterative generalized additive model weighted least squares cubic splines.
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