A generalized rate model for free radical copolymerization was proposed. It can be applied not only to the system with the participation of charge-transfer complex (CTC), but also to the system without the participati...A generalized rate model for free radical copolymerization was proposed. It can be applied not only to the system with the participation of charge-transfer complex (CTC), but also to the system without the participation of CTC. The effects of equilibrium constant, total monomer concentration, homo-propagation parameters and reactivity ratios on free monomer, CTC, overall rates, and the contribution of CTC were considered in the simulation. North equation of copolymerization rate as a special case can be derived from the generalized model.展开更多
基金Supported by the Doctoral Foundation of the Education Commission of China.
文摘A generalized rate model for free radical copolymerization was proposed. It can be applied not only to the system with the participation of charge-transfer complex (CTC), but also to the system without the participation of CTC. The effects of equilibrium constant, total monomer concentration, homo-propagation parameters and reactivity ratios on free monomer, CTC, overall rates, and the contribution of CTC were considered in the simulation. North equation of copolymerization rate as a special case can be derived from the generalized model.
