Using catalytic oxidative absorption for H_2S removal is of great interest due to its distinct advantages. However,traditional scrubbing process faces a great limitation in the confined space. Therefore, there is an u...Using catalytic oxidative absorption for H_2S removal is of great interest due to its distinct advantages. However,traditional scrubbing process faces a great limitation in the confined space. Therefore, there is an urgent demand to develop high-efficiency process intensification technology for such a system. In this article, H_2S absorption experimental research was conducted in a rotating packed bed(RPB) reactor with ferric chelate absorbent and a mixture of N_2 and H_2S, which was used to simulate natural gas. The effects of absorbent p H value, gas–liquid ratio, gravity level of RPB, absorption temperature and character of the packing on the desulfurization efficiency were investigated. The results showed that H_2S removal efficiency could reach above 99.6% under the most of the experimental condition and above 99.9% under the optimal condition. A long-time continuous experiment was conducted to investigate the stability of the whole process combining absorption and regeneration. The result showed that the process could well realize simultaneous desulfurization and absorbent regeneration, and the H_2S removal efficiency kept relatively stable in the whole duration of 72 h. It can be clearly seen that high gravity technology desulfurization process, which is simple, high-efficiency, and space intensive, has a good prospect for industrial application of H_2S removal in confined space.展开更多
The gas-liquid mass transfer of H2 and CO in a high temperature and high-pressure three-phase slurry bubble column reactor is studied. The gas-liquid volumetric mass transfer coefficients kLa are obtained by measuring...The gas-liquid mass transfer of H2 and CO in a high temperature and high-pressure three-phase slurry bubble column reactor is studied. The gas-liquid volumetric mass transfer coefficients kLa are obtained by measuring the dissolution rate of H2 and CO. The influences of the main operation conditions, such as temperature, pressure, superficial gas velocity and solid concentration, are studied systematically. Two empirical correlations are proposed to predict kLa values for H2 and CO in liquid paraffin/solid particles slurry bubble column reactors.展开更多
9th NPY Meeting was held for the f irst time in Japan in March 2008, which was organized by Akio Inui, Profes-sor and Chairman, Department of Psychosomatic In-ternal Medicine, Kagoshima University Graduate School of M...9th NPY Meeting was held for the f irst time in Japan in March 2008, which was organized by Akio Inui, Profes-sor and Chairman, Department of Psychosomatic In-ternal Medicine, Kagoshima University Graduate School of Medical and Dental Sciences, Kagoshima, Japan. We have invited him to write TOPIC HIGHLIGHT for WJG focused on ghrelin along the gut-brain axis.This TOPIC HIGHLIGHT is the 'ghrelin version' of the proceedings of 9th NPY Meeting and presents ex-amples of the critical interplay in ghrelin-NPY pathway in response to environmental,展开更多
This study aimed to obtain, by selection two lines of New Zealand white rabbits differing in total motor activity and to compare them for fertility, prolificacy, mortality and weight gains of young rabbits from birth ...This study aimed to obtain, by selection two lines of New Zealand white rabbits differing in total motor activity and to compare them for fertility, prolificacy, mortality and weight gains of young rabbits from birth until weaning. The emotional states of animals such as fear were analysed with the behavioural tests （open field, tonic immobility） and stress-induced hyperthermia （SIH）. These tests were the criterion for assigning animals to two experimental groups： group I, 10 males and 20 females with the highest total motor activity （A）; group II, 10 males and 20 females showing little or no motor activity （N）. Important differences were found in male and female fertility. During the first week, 80% of males mated in group I compared to only 20% in group II. Despite their normal breeding condition, passive males were timid and ponderous during mating, unlike active males which mated willingly and rapidly. Fertility was high in both groups （87.5% and 94.7% in group I and II）. Unlike females from group II, females from group I showed no tendency towards nest building. 40% of females from group I gave birth in different cage areas, while 90% of females from group II gave birth in nest boxes with down and straw bedding. No differences were found between the active and passive lines for body weight at birth or at 35 days of age.展开更多
The incipient condition of hang-up for three Geldart-D powders has been experimentally studied in a 21 m long standpipe hopper system. Experimental results show that the pressure gradient for hang-up to occur is indep...The incipient condition of hang-up for three Geldart-D powders has been experimentally studied in a 21 m long standpipe hopper system. Experimental results show that the pressure gradient for hang-up to occur is independent of the materials height in the hopper and the diameter of orifice and equals to (dpw/dl)s, which can be predicted by Eq. (7). While the corresponding gas velocity in the standpipe equals to the incipient fluidized velocity of particles at the high pressure and can be predicted by Kwauk's equation.展开更多
Risk quantification in grade is critical for mine design and planning.Grade uncertainty is assessed using multiple grade realizations,from geostatistical conditional simulations,which are effective to evaluate local o...Risk quantification in grade is critical for mine design and planning.Grade uncertainty is assessed using multiple grade realizations,from geostatistical conditional simulations,which are effective to evaluate local or global uncertainty by honouring spatial correlation structures.The sequential Gaussian conditional simulation was used to assess uncertainty of grade estimates and illustrate simulated models in Sivas gold deposit,Turkey.In situ variability and risk quantification of the gold grade were assessed by probabilistic approach based on the sequential Gaussian simulations to yield a series of conditional maps characterized by equally probable spatial distribution of the gold grade for the study area.The simulation results were validated by a number of tests such as descriptive statistics,histogram,variogram and contour map reproductions.The case study demonstrates the efficiency of the method in assessing risk associated with geological and engineering variable such as the gold grade variability and distribution.The simulated models can be incorporated into exploration,exploitation and scheduling of the gold deposit.展开更多
A new process is developed by using compound Mn as intermediate to produce Cl2from HCl,with the following steps.(1)HCl steam is decomposed by intermediate Mn2O3to produce Cl2and Mn Cl2at 500°C.(2)Produced Mn Cl2i...A new process is developed by using compound Mn as intermediate to produce Cl2from HCl,with the following steps.(1)HCl steam is decomposed by intermediate Mn2O3to produce Cl2and Mn Cl2at 500°C.(2)Produced Mn Cl2is oxidized by water steam to produce Mn O at 450°C.(3)The Mn O compound is oxidized by air to yield Mn2O3.The X-ray diffraction(XRD)crystallite characterization results indicate the high conversion in each step under the optimum experimental conditions.Long term experiments for continuous conversion of HCl to Cl2by using Mn2O3as intermediate in a fixed bed reactor indicate that over 90%of HCl could be converted to Cl2on stream of 30 h.The production of Cl2from HCl with Mn compound as an intermediate and atmospheric steam is a feasible and recyclable process.展开更多
To explore the feasibility of the full automatic animal experimental cabin to establish the animal models in normobaric/hypobaric hypoxic and high carbon dioxide environment. Methods： Sixty SPF-class male DS rats wer...To explore the feasibility of the full automatic animal experimental cabin to establish the animal models in normobaric/hypobaric hypoxic and high carbon dioxide environment. Methods： Sixty SPF-class male DS rats were divided into 2 groups, 20 for normobaric, hypoxic conditions and the other 40 for hypobaric, hypoxic conditions. For each group, the pulmonary arterial pressure and carotid arterial pressure indicators of rats were examined by using the physiological multi-detector, and the pulmonary vascular changes in the structure were observed. Results： The normobaric/hypobaric hypoxic with high carbon dioxide environment can promote the formation of pulmonary hypertension and accelerate changes in pulmonary vascular remodeling, and promote the right ventricular hypertrophy. Conclusion： Clinical applications showed that the animal experimental cabin has observed and controlled accurately. The result was safe, reliable and reproducible. The cabin can successfully establish the pulmonary hypertension model in normobaric/hypobaric hypoxic with high carbon dioxide environment, and in order to study the physiological mechanism of a variety of circulation and respiratory diseases caused by lack of oxygen, which provided an experimental technology platform for clinical research.展开更多
基金Supported by the National Natural Science Foundation of China(21406008)
文摘Using catalytic oxidative absorption for H_2S removal is of great interest due to its distinct advantages. However,traditional scrubbing process faces a great limitation in the confined space. Therefore, there is an urgent demand to develop high-efficiency process intensification technology for such a system. In this article, H_2S absorption experimental research was conducted in a rotating packed bed(RPB) reactor with ferric chelate absorbent and a mixture of N_2 and H_2S, which was used to simulate natural gas. The effects of absorbent p H value, gas–liquid ratio, gravity level of RPB, absorption temperature and character of the packing on the desulfurization efficiency were investigated. The results showed that H_2S removal efficiency could reach above 99.6% under the most of the experimental condition and above 99.9% under the optimal condition. A long-time continuous experiment was conducted to investigate the stability of the whole process combining absorption and regeneration. The result showed that the process could well realize simultaneous desulfurization and absorbent regeneration, and the H_2S removal efficiency kept relatively stable in the whole duration of 72 h. It can be clearly seen that high gravity technology desulfurization process, which is simple, high-efficiency, and space intensive, has a good prospect for industrial application of H_2S removal in confined space.
基金the National Natural Science Foundation of China (No. 29870619).
文摘The gas-liquid mass transfer of H2 and CO in a high temperature and high-pressure three-phase slurry bubble column reactor is studied. The gas-liquid volumetric mass transfer coefficients kLa are obtained by measuring the dissolution rate of H2 and CO. The influences of the main operation conditions, such as temperature, pressure, superficial gas velocity and solid concentration, are studied systematically. Two empirical correlations are proposed to predict kLa values for H2 and CO in liquid paraffin/solid particles slurry bubble column reactors.
文摘9th NPY Meeting was held for the f irst time in Japan in March 2008, which was organized by Akio Inui, Profes-sor and Chairman, Department of Psychosomatic In-ternal Medicine, Kagoshima University Graduate School of Medical and Dental Sciences, Kagoshima, Japan. We have invited him to write TOPIC HIGHLIGHT for WJG focused on ghrelin along the gut-brain axis.This TOPIC HIGHLIGHT is the 'ghrelin version' of the proceedings of 9th NPY Meeting and presents ex-amples of the critical interplay in ghrelin-NPY pathway in response to environmental,
文摘This study aimed to obtain, by selection two lines of New Zealand white rabbits differing in total motor activity and to compare them for fertility, prolificacy, mortality and weight gains of young rabbits from birth until weaning. The emotional states of animals such as fear were analysed with the behavioural tests （open field, tonic immobility） and stress-induced hyperthermia （SIH）. These tests were the criterion for assigning animals to two experimental groups： group I, 10 males and 20 females with the highest total motor activity （A）; group II, 10 males and 20 females showing little or no motor activity （N）. Important differences were found in male and female fertility. During the first week, 80% of males mated in group I compared to only 20% in group II. Despite their normal breeding condition, passive males were timid and ponderous during mating, unlike active males which mated willingly and rapidly. Fertility was high in both groups （87.5% and 94.7% in group I and II）. Unlike females from group II, females from group I showed no tendency towards nest building. 40% of females from group I gave birth in different cage areas, while 90% of females from group II gave birth in nest boxes with down and straw bedding. No differences were found between the active and passive lines for body weight at birth or at 35 days of age.
文摘The incipient condition of hang-up for three Geldart-D powders has been experimentally studied in a 21 m long standpipe hopper system. Experimental results show that the pressure gradient for hang-up to occur is independent of the materials height in the hopper and the diameter of orifice and equals to (dpw/dl)s, which can be predicted by Eq. (7). While the corresponding gas velocity in the standpipe equals to the incipient fluidized velocity of particles at the high pressure and can be predicted by Kwauk's equation.
文摘Risk quantification in grade is critical for mine design and planning.Grade uncertainty is assessed using multiple grade realizations,from geostatistical conditional simulations,which are effective to evaluate local or global uncertainty by honouring spatial correlation structures.The sequential Gaussian conditional simulation was used to assess uncertainty of grade estimates and illustrate simulated models in Sivas gold deposit,Turkey.In situ variability and risk quantification of the gold grade were assessed by probabilistic approach based on the sequential Gaussian simulations to yield a series of conditional maps characterized by equally probable spatial distribution of the gold grade for the study area.The simulation results were validated by a number of tests such as descriptive statistics,histogram,variogram and contour map reproductions.The case study demonstrates the efficiency of the method in assessing risk associated with geological and engineering variable such as the gold grade variability and distribution.The simulated models can be incorporated into exploration,exploitation and scheduling of the gold deposit.
基金Supported by the National High Technology Research and Development Program of China(2011AA060703)the Innovation Funds of institute of processes engineering of Chinese Academy of Sciences(062702)
文摘A new process is developed by using compound Mn as intermediate to produce Cl2from HCl,with the following steps.(1)HCl steam is decomposed by intermediate Mn2O3to produce Cl2and Mn Cl2at 500°C.(2)Produced Mn Cl2is oxidized by water steam to produce Mn O at 450°C.(3)The Mn O compound is oxidized by air to yield Mn2O3.The X-ray diffraction(XRD)crystallite characterization results indicate the high conversion in each step under the optimum experimental conditions.Long term experiments for continuous conversion of HCl to Cl2by using Mn2O3as intermediate in a fixed bed reactor indicate that over 90%of HCl could be converted to Cl2on stream of 30 h.The production of Cl2from HCl with Mn compound as an intermediate and atmospheric steam is a feasible and recyclable process.
文摘To explore the feasibility of the full automatic animal experimental cabin to establish the animal models in normobaric/hypobaric hypoxic and high carbon dioxide environment. Methods： Sixty SPF-class male DS rats were divided into 2 groups, 20 for normobaric, hypoxic conditions and the other 40 for hypobaric, hypoxic conditions. For each group, the pulmonary arterial pressure and carotid arterial pressure indicators of rats were examined by using the physiological multi-detector, and the pulmonary vascular changes in the structure were observed. Results： The normobaric/hypobaric hypoxic with high carbon dioxide environment can promote the formation of pulmonary hypertension and accelerate changes in pulmonary vascular remodeling, and promote the right ventricular hypertrophy. Conclusion： Clinical applications showed that the animal experimental cabin has observed and controlled accurately. The result was safe, reliable and reproducible. The cabin can successfully establish the pulmonary hypertension model in normobaric/hypobaric hypoxic with high carbon dioxide environment, and in order to study the physiological mechanism of a variety of circulation and respiratory diseases caused by lack of oxygen, which provided an experimental technology platform for clinical research.
