The influences of heat treatment on stress corrosion cracking （SCC）, fracture toughness and strength of 7085 aluminum alloy were investigated by slow strain rate testing, Kahn tear testing combined with scanning ele...The influences of heat treatment on stress corrosion cracking （SCC）, fracture toughness and strength of 7085 aluminum alloy were investigated by slow strain rate testing, Kahn tear testing combined with scanning electron microscopy （SEM） and transmission electron microscopy （TEM）. The results show that the fracture toughness of T74 overaging is increased by 22.9% at the expense of 13.6% strength, and retrogression and reaging （RRA） enhances fracture toughness 14.2% without reducing the strength compared with T6 temper. The fracture toughness of dual-retrogression and reaging （DRRA） is equivalent to that of T74 with an increased strength of 14.6%. The SCC resistance increases in the order： T6〈RRA〈DRRA≈T74. The differences of fracture toughness and SCC were explained on the basis of the role of matrix precipitates and grain boundary orecioitates.展开更多
One group of SiC films are grown on silicon-on-insulator （SOI） substrates with a series of silicon-overlayer thickness. Raman scattering spectroscopy measurement clearly indicates that a systematic trend of residual...One group of SiC films are grown on silicon-on-insulator （SOI） substrates with a series of silicon-overlayer thickness. Raman scattering spectroscopy measurement clearly indicates that a systematic trend of residual stress reduction as the silicon over-layer thickness decreases for the SOI substrates. Strain relaxation in the SiC epilayer is explained by force balance approach and near coincidence lattice model.展开更多
In order to ensure the safety and stability of the soft rock roadway under high stress, based on the char- acteristics of the surrounding rock deformation and failure, this paper presented the support technology“coup...In order to ensure the safety and stability of the soft rock roadway under high stress, based on the char- acteristics of the surrounding rock deformation and failure, this paper presented the support technology“coupling support of double yielding shell”, then gave the design method of inner and outer shells and analyzed the principle and requirements of the support technology by taking the -850 meast belt mad-way of Qujiang coal mine as the background. The field application results show that the support technol- ogy can control the soft rock roadway deformation better under high stress. The displacement between roadway sides was 851 mm, the displacement of the roof was 430 mm, and the displacement of the floor was 510 mm.展开更多
Stress corrosion cracking （SCC） is degradation of mechanical properties under the combined action of stress and corrosive environment of the susceptible material. Out of eight series of aluminium alloys, 2xxx, 5xxx...Stress corrosion cracking （SCC） is degradation of mechanical properties under the combined action of stress and corrosive environment of the susceptible material. Out of eight series of aluminium alloys, 2xxx, 5xxx and 7xxx aluminium alloys are susceptible to SCC. Among them, 7xxx series aluminium alloys have specific application in aerospace, military and structural industries due to superior mechanical properties. In these high strength 7xxx aluminium alloys, SCC plays a vital factor of consideration, as these failures are catastrophic during the service. The understanding of SCC behaviour possesses critical challenge for this alloy. The main aim of this review paper is to understand the effect of constituent alloying elements on the response of microstructural variation in various heat-treated conditions on SCC behavior. Further, review was made for improving the SCC resistance using thermomechanical treatments and by surface modifications of 7xxx alloys. Apart from a brief review on SCC of 7xxx alloys, this paper presents the effect of stress and pre-strain, effect of constituent alloying elements in the alloy, and the effect of environments on SCC behaviour. In addition, the SCC behaviours of weldments, 7xxx metal matrix composites and also laser surface modifications were also reviewed.展开更多
The underbalanced drilling has been widely used due to its advantages of high drilling efficiency and low cost etc., especially for hard formation drilling. These advantages, however, are closely related to the stress...The underbalanced drilling has been widely used due to its advantages of high drilling efficiency and low cost etc., especially for hard formation drilling. These advantages, however, are closely related to the stress state of the bottom-hole rock; therefore, it is significant to research the stress distribution of bottom-hole rock for the correct understanding of the mechanism of rock fragmentation and high penetration rate. The stress condition of bottom-hole rock is very complicated while under the co-action of overburden pressure, horizontal in-situ stresses, drilling mud pressure, pore pressure and temperature etc. In this paper, the fully coupled simulation model is established and the effects of overburden pressure, horizontal in-situ stresses, drilling mud pressure, pore pressure and temperature on stress distribution of bottom-hole rock are studied. The research shows that： in air drilling, as the well depth increases, the more easily the bottom-hole rock is broken; the mud pressure has a great effect on the bottom hole rock. The bigger the mud pressure is, the more difficult to break the bottom-hole rock; the max principle stress of the bottom-hole increased with the increasing of mud pressure, well depth and temperature difference. The bottom-hole rock can be divided into 3 regions respectively according to the stress state, 3 direction stretch zone, 2 direction compression area and 3 direction compression zone; the corresponding fragmentation degree of difficulty is easily, normally and hardly.展开更多
MnO2/MnO cathode material with superior Zn^2+storage performance is prepared through a simple physical mixing method.The MnO2/MnO nanocomposite with a mixed mass ratio of 12:1 exhibits the highest specific capacity(36...MnO2/MnO cathode material with superior Zn^2+storage performance is prepared through a simple physical mixing method.The MnO2/MnO nanocomposite with a mixed mass ratio of 12:1 exhibits the highest specific capacity(364.2 mA·h/g at 0.2C),good cycle performance(170.4 mA·h/g after 100 cycles)and excellent rate performance(205.7 mA·h/g at 2C).Analysis of cyclic voltammetry(CV)data at various scan rates shows that both diffusioncontrolled insertion behavior and surface capacitive behavior contribute to the Zn2+storage performance of MnO2/MnO cathodes.And the capacitive behavior contributes more at high discharge rates,due to the short paths of ion diffusion and the rapid transfer of electrons.展开更多
In order to analyze the influence of replacement depth of black cotton soil(BCS)foundation on the initial cracking depth of a highway embankment,the laboratory tests were performed to construct the constitutive relati...In order to analyze the influence of replacement depth of black cotton soil(BCS)foundation on the initial cracking depth of a highway embankment,the laboratory tests were performed to construct the constitutive relationship between state variables and stress variables of BCS,and the coupled consolidation theory for unsaturated soils was employed to simulate the change in the major principal stress of the subgrade soils caused by water loss shrinkage of BCS with the help of Abaqus 6.11 codes.The simulation results indicate that the water losing shrinkage of BCS causes tensile stress within the subgrade,which leads to embankment cracking.The crack depth decreases with the increase in the BCS replacement depth and the embankment height,and increases with the increase in the burial depth of BCS.In the distribution area of deep BCS,the key values of foundation replacement depth for controlling the crack depth of the embankment with the height of 1 to 4 m are 1.2 and 1.5 m.In the low filling section,when the buried depth of BCS is 2,3 and 4 m,the key values of the foundation replacement depth to control the crack depth of the embankment are 0.8 and 1.2 m.In order to control the embankment cracking induced by the water losing shrinkage of BCS,a reasonable replacement depth of the foundation should be selected while slope protection is carried out well.展开更多
With no annealing treatment, cathodic polarization trends in 5083F A1 alloy revealed concentration polarization and activation polarization. However, the annealed specimens have lower current densities at corrosion pr...With no annealing treatment, cathodic polarization trends in 5083F A1 alloy revealed concentration polarization and activation polarization. However, the annealed specimens have lower current densities at corrosion protection potential compared to the non-annealed specimen. The results of SSRTs conducted in seawater at the applied potential range of-l.8 V to -0.5 V indicated that the maximum tensile strength, elongation, and time-to-fracture had high values at applied potentials of -0.7 to -1.4 V. The maximum tensile strength, elongation, and time-to-f？acture decreased when the potential values were beyond this range in either anodic or cathodic direction. In general, the increased shear lip caused by annealing treatment indicates elongation. Time-to-fracture would likely increase with elongation. Potentials between -0.5 V to -0.6 V were found to be in the region of stress corrosion cracking. The corrosion protection zone was determined to be -0.7 V to -J,4 V because these potential ranges produced good mechanical properties. Potential less than -1.4 V produced a fractured surface with a mixture of dimples （ductile fractures） and a quasi-cleavage pattern resulting from the effects of hydrogen gas.展开更多
Methylphenyldichlorosilane(MPDS, CH3C6H5 SiC l2) is an important silicone monomer for the synthesis of highperformance polymethylphenylsiloxane polymers. In this work, the mechanism of the synthesis of MPDS from methy...Methylphenyldichlorosilane(MPDS, CH3C6H5 SiC l2) is an important silicone monomer for the synthesis of highperformance polymethylphenylsiloxane polymers. In this work, the mechanism of the synthesis of MPDS from methyldichlorosilane and chlorobenzene by gas phase condensation was studied, and a kinetic model with 35 species and 58 elementary reactions was established. Experiments were carried out in a tubular reactor under a wide range of reaction conditions. The calculated mole fractions of the reactants and products were in a good agreement with the experimental results. A mechanism of the insertion of chloromethylsilylene into the C\Cl bond of chlorobenzene was proposed, which was proved to be the main pathway of MPDS production. The established kinetic model can be used in design and optimization of the industrial reactor for MPDS synthesis.展开更多
基金Projects(2010CB731701,2012CB619502)supported by the National Basic Research Program of ChinaProjects(51201186,51327902)supported by the National Natural Science Foundation of China
文摘The influences of heat treatment on stress corrosion cracking （SCC）, fracture toughness and strength of 7085 aluminum alloy were investigated by slow strain rate testing, Kahn tear testing combined with scanning electron microscopy （SEM） and transmission electron microscopy （TEM）. The results show that the fracture toughness of T74 overaging is increased by 22.9% at the expense of 13.6% strength, and retrogression and reaging （RRA） enhances fracture toughness 14.2% without reducing the strength compared with T6 temper. The fracture toughness of dual-retrogression and reaging （DRRA） is equivalent to that of T74 with an increased strength of 14.6%. The SCC resistance increases in the order： T6〈RRA〈DRRA≈T74. The differences of fracture toughness and SCC were explained on the basis of the role of matrix precipitates and grain boundary orecioitates.
文摘One group of SiC films are grown on silicon-on-insulator （SOI） substrates with a series of silicon-overlayer thickness. Raman scattering spectroscopy measurement clearly indicates that a systematic trend of residual stress reduction as the silicon over-layer thickness decreases for the SOI substrates. Strain relaxation in the SiC epilayer is explained by force balance approach and near coincidence lattice model.
基金supported by the National Natural Science Foundation for Youth (No. 51304200)the China Postdoctoral Science Foundation Project (No. 2013M540477)
文摘In order to ensure the safety and stability of the soft rock roadway under high stress, based on the char- acteristics of the surrounding rock deformation and failure, this paper presented the support technology“coupling support of double yielding shell”, then gave the design method of inner and outer shells and analyzed the principle and requirements of the support technology by taking the -850 meast belt mad-way of Qujiang coal mine as the background. The field application results show that the support technol- ogy can control the soft rock roadway deformation better under high stress. The displacement between roadway sides was 851 mm, the displacement of the roof was 430 mm, and the displacement of the floor was 510 mm.
文摘Stress corrosion cracking （SCC） is degradation of mechanical properties under the combined action of stress and corrosive environment of the susceptible material. Out of eight series of aluminium alloys, 2xxx, 5xxx and 7xxx aluminium alloys are susceptible to SCC. Among them, 7xxx series aluminium alloys have specific application in aerospace, military and structural industries due to superior mechanical properties. In these high strength 7xxx aluminium alloys, SCC plays a vital factor of consideration, as these failures are catastrophic during the service. The understanding of SCC behaviour possesses critical challenge for this alloy. The main aim of this review paper is to understand the effect of constituent alloying elements on the response of microstructural variation in various heat-treated conditions on SCC behavior. Further, review was made for improving the SCC resistance using thermomechanical treatments and by surface modifications of 7xxx alloys. Apart from a brief review on SCC of 7xxx alloys, this paper presents the effect of stress and pre-strain, effect of constituent alloying elements in the alloy, and the effect of environments on SCC behaviour. In addition, the SCC behaviours of weldments, 7xxx metal matrix composites and also laser surface modifications were also reviewed.
基金Projects(U1562212,51525404)supported by the National Natural Science Foundation of ChinaProject(JYBFX-YQ-1)supported by the Research Project of Key Laboratory Machinery and Power Machinery(Xihua University),Ministry of Education,China
文摘The underbalanced drilling has been widely used due to its advantages of high drilling efficiency and low cost etc., especially for hard formation drilling. These advantages, however, are closely related to the stress state of the bottom-hole rock; therefore, it is significant to research the stress distribution of bottom-hole rock for the correct understanding of the mechanism of rock fragmentation and high penetration rate. The stress condition of bottom-hole rock is very complicated while under the co-action of overburden pressure, horizontal in-situ stresses, drilling mud pressure, pore pressure and temperature etc. In this paper, the fully coupled simulation model is established and the effects of overburden pressure, horizontal in-situ stresses, drilling mud pressure, pore pressure and temperature on stress distribution of bottom-hole rock are studied. The research shows that： in air drilling, as the well depth increases, the more easily the bottom-hole rock is broken; the mud pressure has a great effect on the bottom hole rock. The bigger the mud pressure is, the more difficult to break the bottom-hole rock; the max principle stress of the bottom-hole increased with the increasing of mud pressure, well depth and temperature difference. The bottom-hole rock can be divided into 3 regions respectively according to the stress state, 3 direction stretch zone, 2 direction compression area and 3 direction compression zone; the corresponding fragmentation degree of difficulty is easily, normally and hardly.
基金Project(21905304)supported by the National Natural Science Foundation of ChinaProject(ZR2019BEM031)supported by the Natural Science Foundation of Shandong Province,ChinaProjects(18CX02158A,19CX05001A)supported by the Fundamental Research Funds for the Central Universities,China。
文摘MnO2/MnO cathode material with superior Zn^2+storage performance is prepared through a simple physical mixing method.The MnO2/MnO nanocomposite with a mixed mass ratio of 12:1 exhibits the highest specific capacity(364.2 mA·h/g at 0.2C),good cycle performance(170.4 mA·h/g after 100 cycles)and excellent rate performance(205.7 mA·h/g at 2C).Analysis of cyclic voltammetry(CV)data at various scan rates shows that both diffusioncontrolled insertion behavior and surface capacitive behavior contribute to the Zn2+storage performance of MnO2/MnO cathodes.And the capacitive behavior contributes more at high discharge rates,due to the short paths of ion diffusion and the rapid transfer of electrons.
基金The National Natural Science Foundation of China(No.51778139)the Construction System Science and Technology Project of Jiangsu Province(No.2019ZD058).
文摘In order to analyze the influence of replacement depth of black cotton soil(BCS)foundation on the initial cracking depth of a highway embankment,the laboratory tests were performed to construct the constitutive relationship between state variables and stress variables of BCS,and the coupled consolidation theory for unsaturated soils was employed to simulate the change in the major principal stress of the subgrade soils caused by water loss shrinkage of BCS with the help of Abaqus 6.11 codes.The simulation results indicate that the water losing shrinkage of BCS causes tensile stress within the subgrade,which leads to embankment cracking.The crack depth decreases with the increase in the BCS replacement depth and the embankment height,and increases with the increase in the burial depth of BCS.In the distribution area of deep BCS,the key values of foundation replacement depth for controlling the crack depth of the embankment with the height of 1 to 4 m are 1.2 and 1.5 m.In the low filling section,when the buried depth of BCS is 2,3 and 4 m,the key values of the foundation replacement depth to control the crack depth of the embankment are 0.8 and 1.2 m.In order to control the embankment cracking induced by the water losing shrinkage of BCS,a reasonable replacement depth of the foundation should be selected while slope protection is carried out well.
文摘With no annealing treatment, cathodic polarization trends in 5083F A1 alloy revealed concentration polarization and activation polarization. However, the annealed specimens have lower current densities at corrosion protection potential compared to the non-annealed specimen. The results of SSRTs conducted in seawater at the applied potential range of-l.8 V to -0.5 V indicated that the maximum tensile strength, elongation, and time-to-fracture had high values at applied potentials of -0.7 to -1.4 V. The maximum tensile strength, elongation, and time-to-f？acture decreased when the potential values were beyond this range in either anodic or cathodic direction. In general, the increased shear lip caused by annealing treatment indicates elongation. Time-to-fracture would likely increase with elongation. Potentials between -0.5 V to -0.6 V were found to be in the region of stress corrosion cracking. The corrosion protection zone was determined to be -0.7 V to -J,4 V because these potential ranges produced good mechanical properties. Potential less than -1.4 V produced a fractured surface with a mixture of dimples （ductile fractures） and a quasi-cleavage pattern resulting from the effects of hydrogen gas.
文摘Methylphenyldichlorosilane(MPDS, CH3C6H5 SiC l2) is an important silicone monomer for the synthesis of highperformance polymethylphenylsiloxane polymers. In this work, the mechanism of the synthesis of MPDS from methyldichlorosilane and chlorobenzene by gas phase condensation was studied, and a kinetic model with 35 species and 58 elementary reactions was established. Experiments were carried out in a tubular reactor under a wide range of reaction conditions. The calculated mole fractions of the reactants and products were in a good agreement with the experimental results. A mechanism of the insertion of chloromethylsilylene into the C\Cl bond of chlorobenzene was proposed, which was proved to be the main pathway of MPDS production. The established kinetic model can be used in design and optimization of the industrial reactor for MPDS synthesis.
