The precipitation behavior of carbide in K416 B superalloy was investigated by means of creep measurement and microstructure observation. The results show that nanometer M6 C particles discontinuously precipitate in t...The precipitation behavior of carbide in K416 B superalloy was investigated by means of creep measurement and microstructure observation. The results show that nanometer M6 C particles discontinuously precipitate in the γ matrix or along the γ/γ′ interface of the alloy during high temperature tensile creep. Thereinto, the amount of fine M6 C carbide increases as creep goes on, and the coherent interfaces of M6 C phase precipitating from the γ matrix are {100} and {111} planes. The thermodynamics analysis indicates that the solubility of element carbon in the matrix decreases when the alloy is deformed by the axial tensile stress during creep, so as to cause the carbon segregating in the regions of stress concentration and combining with carbide-forming elements M(W, Co), which promotes the fine M6 C carbide to precipitate from the γ matrix.展开更多
Catalysis effect of triphenyl bismuth (TPB) on kinetics of hydroxyl terminated polybutadiene-toluene diisocyanate (HTPB-TDI) curing reaction was studied by non-isothermal differential scanning calorimetry (DSC)....Catalysis effect of triphenyl bismuth (TPB) on kinetics of hydroxyl terminated polybutadiene-toluene diisocyanate (HTPB-TDI) curing reaction was studied by non-isothermal differential scanning calorimetry (DSC). The characteristic temperature of curing system was measured for calculating kinetic parameters and establishing curing reaction kinetic equations. The results show that activation energy (Ea) of uncatalyzed HTPB-TDI curing system is 51.29 kJmol-1, and TPB decreases Ea to 46.43 kJ'mol-1. Catalyst lowers reaction temperature and shortens curing time through decreasing ac- tivation energy of curing reaction and accelerating reaction rate. TPB can increase the reaction rate at 27 ℃ to the value of uncatalyzed system at 80 ℃. The catalytic activity reaches the maximum when concentration is 0.5 %.展开更多
Based on the characteristic that the potential sliding surfaces of rock slope are commonly in the shape of either line or fold line,analysis thought of conventional pile foundation in the flat ground under complex loa...Based on the characteristic that the potential sliding surfaces of rock slope are commonly in the shape of either line or fold line,analysis thought of conventional pile foundation in the flat ground under complex load condition was applied and the upper-bound theorem of limit analysis was used to compute thrust of rock layers with all possible distribution shapes. The interaction of slope and pile was considered design load in terms of slope thrust,and the finite difference method was derived to calculate inner-force and displacement of bridge pile foundation in rock slope under complex load condition. The result of example shows that the distribution model of slope thrust has certain impact on displacement and inner-force of bridge pile foundation. The maximum displacement growth rate reaches 54% and the maximum moment and shear growth rates reach only 15% and 20%,respectively,but the trends of inner-force and displacement of bridge pile foundation are basically the same as those of the conventional pile foundation in the flat ground. When the piles bear the same level lateral thrust,the distribution shapes of slope thrust have different influence on inner-force of pile foundation,especially the rectangle distribution,and the triangle thrust has the smallest displacement and inner-force of pile foundation.展开更多
Based on the fact that the shear stress along anchorage segment is neither linearly nor uniformly distributed, the load transfer mechanism of the tension type anchor was studied and the mechanical characteristic of an...Based on the fact that the shear stress along anchorage segment is neither linearly nor uniformly distributed, the load transfer mechanism of the tension type anchor was studied and the mechanical characteristic of anchorage segment was analyzed. Shear stress?strain relationship of soil surrounding anchorage body was simplified into three-folding-lines model consisting of elastic phase, elasto-plastic phase and residual phase considering its softening characteristic. Meanwhile, shear displacement method that has been extensively used in the analysis of pile foundation was introduced. Based on elasto-plastic theory, the distributions of displacement, shear stress and axial force along the anchorage segment of tension type anchor were obtained, and the formula for calculating the elastic limit load was also developed accordingly. Finally, an example was given to discuss the variation of stress and displacement in the anchorage segment with the loads exerted on the anchor, and a program was worked out to calculate the anchor maximum bearing capacity. The influence of some parameters on the anchor bearing capacity was discussed, and effective anchorage length was obtained simultaneously. The results show that the shear stress first increases and then decreases and finally trends to the residual strength with increase of distance from bottom of the anchorage body, the displacement increases all the time with the increase of distance from bottom of the anchorage body, and the increase of velocity gradually becomes greater.展开更多
A new kinetic model for commercial unit of toluene disproportionation and C9-armatiocs transalkylation is developed based on the reported reaction scheme.A time based catalyst deactivation function taking weight hourl...A new kinetic model for commercial unit of toluene disproportionation and C9-armatiocs transalkylation is developed based on the reported reaction scheme.A time based catalyst deactivation function taking weight hourly space velocity(WHSV)into account is incorporated into the model,which reasonably accounts for the loss in activity because of coke deposition on the surface of catalyst during long-term operation.The kinetic parameters are benchmarked with several sets of balanced plant data and estimated by the differential variable metric optimiza- tion method.Sets of plant data at different operating conditions are applied to make sure validation of the model and the results show a good agreement between the model predictions and plant observations.The simulation analysis of key variables such as temperature and WHSV affecting process performance is discussed in detail,giv- ing the guidance to select suitable operating conditions.展开更多
The models of stress corrosion, pressure solution and flee-face dissolution/precipitation were introduced. Taking a hypothetical nuclear waste repository in an unsaturated dual-porosity rock mass as the calculation ob...The models of stress corrosion, pressure solution and flee-face dissolution/precipitation were introduced. Taking a hypothetical nuclear waste repository in an unsaturated dual-porosity rock mass as the calculation objective, four cases were designed 1) the fracture aperture is a function of stress corrosion, pressure solution and free-face dissolution/precipitation; 2) the fracture aperture changes with stress corrosion and pressure solution; 3) the fracture aperture changes with pressure solution and free-face dissolution/precipitation; 4) the fracture aperture is only a function of pressure solution, and the matrix porosity is also a function of stress in these four cases. Then, the corresponding two-dimensional FEM analyses for the coupled thermo-hydro-mechanical processes were carried out. The results show that the effects of stress corrosion are more prominent than those of pressure solution and free-face dissolution/precipitation, and the fracture aperture and relevant permeability caused by the stress corrosion arc only about 1/5 and 1/1000 of the corresponding values created by the pressure solution and free-face dissolution/precipitation, respectively Under the action of temperature field from released heat, the negative pore and fracture pressures in the computation domain rise continuously, and are inversely proportional to the sealing of fracture aperture. The vector fields of flow velocity of fracture water in the cases with and without considering stress corrosion are obviously different. The differences between the magnitudes and distributions of stresses within the rock mass are very small in all cases.展开更多
Anchor bolts are commonly used throughout underground mining and tunnelling operations to improve roof stability.However,premature failures of anchor bolts are significant safety risks in underground excavations aroun...Anchor bolts are commonly used throughout underground mining and tunnelling operations to improve roof stability.However,premature failures of anchor bolts are significant safety risks in underground excavations around the world due to susceptible bolt materials,a moist and corrosive environment and tensile stress.In this paper,laboratory experiments and hydrogeochemical models were combined to investigate anchor bolt corrosion and failure associated with aqueous environments in underground coal mines.Experimental data and collated mine water chemistry data were used to simulate bolt corrosion reactions with groundwater and rock materials with the PHREEQC code.A series of models quantified reactions involving iron and carbon under aerobic and anaerobic conditions in comparison with ion,pH and pE trends in experimental data.The models showed that corrosion processes are inhibited by some natural environmental factors,because dissolved oxygen would cause more iron from the bolts to oxidize into solution.These interdisciplinary insights into corrosion failure of underground anchor bolts confirm that environmental factors are important contributors to stress corrosion cracking.展开更多
The experimental installation and measurement system of ultrasonic wave property in rocks during complete stress-strain process were established and perfected. The interrelations between ultrasonic wave property of mu...The experimental installation and measurement system of ultrasonic wave property in rocks during complete stress-strain process were established and perfected. The interrelations between ultrasonic wave property of muds tone, sands tone and limestone specimens during complete stress-strain process and their mechanic property were investigated. A new type of device for the observation of surrounding rock stability-borehole ultrasonic device with completely dry coupling was developed to get better coupling and more accurate measurement data comparing with those of water coupling situation. Preliminary study on the application of ultrasonic measurement technique at belt conveyor roadway of north wing in Baodian Coal Mine (Shandong province) was conducted. Based on the interrelations between the complete stress-strain properties of specimens and their wave properties, the structural properties of surrounding rocks, the range of yield zones, and the change of stresses within surrounding rocks when a longwall face was across over the roadway were analyzed.Therefore,a new and feasible way was found for the research on the deformation law of surrounding rock of roadway and rational selection of support parameters.展开更多
This paper numerically simulates the stress development and generates a three-dimensional model of the medium-length hole blasting in infinite rock mass for continuous charge and divided charge in blasting by using th...This paper numerically simulates the stress development and generates a three-dimensional model of the medium-length hole blasting in infinite rock mass for continuous charge and divided charge in blasting by using the large-scale nonlinear dynamic analysis software LS-DYNA and the elastic-plastic model ~*MAT_PLASTIC_KINEMATIC and JWO-EOS.The differences of the decreasing rate in Von Mises effective stress of blasting,element effective stress peak of free surface,bore wall stress and acceleration are investigated.It is shown that divided charge could greatly improve the blasting effect by engineering blasting practice.展开更多
Based on the phenomenon that acoustic emissions (AE) generated by rock mass increase suddenly because of underground excavation, time sequence of AE rate in rock failure has been discussed by using statistical damage ...Based on the phenomenon that acoustic emissions (AE) generated by rock mass increase suddenly because of underground excavation, time sequence of AE rate in rock failure has been discussed by using statistical damage theory. It has been demonstrated that how the influence of confining pressure on the deformation behavior and AE characteristics in rocks can be inferred from a simple mechanics model. The results show that loading confining pressure sharply brings out increasing of AE. On the other hand, few AE emits when confining pressure is loaded sharply, and AE occurs again when axial pressure keeps on increasing. These results have been well simulated with computer and show close correspondence with directly measured curves in experiments.展开更多
Reactive distillation could be utilized to produce cyclohexanol through the cyclohexene hydration. By means of highly active zeolite catalyst HZSM-5, the kinetic-thermodynamic analysis of this reactive distillation ha...Reactive distillation could be utilized to produce cyclohexanol through the cyclohexene hydration. By means of highly active zeolite catalyst HZSM-5, the kinetic-thermodynamic analysis of this reactive distillation has been carried out to get the characteristics of the reactive distillation. Results from kinetic and thermodynamic analysis indicate that the optimal pressure of this reactive distillation process should be set to higher pressure such as 0.3 or 0.4 MPa. To avoid the recovery of cyclohexanol at the top of the column, an unreactive section should be allocated at the upper column. In addition, the inert component benzene is more unfavorable to the reactive distillation process in comparison with the inert cyclohexane.展开更多
Objective: The aim of this study was to investigate the biomechanical property of lumbosacral reconstruction after subtotal sacrectomy. Methods: Three three-dimensional finite element models of lumbosacral region we...Objective: The aim of this study was to investigate the biomechanical property of lumbosacral reconstruction after subtotal sacrectomy. Methods: Three three-dimensional finite element models of lumbosacral region were established: (1) An intact model (INT); (2) A defective model (DEF) on which subtotal sacrectomy was performed cephalad to the $1 foramina; (3) A reconstructed model (REC). These models were validated by compared with literature. Upright posture was stimulated under a compression load of 925N. A finite element analysis was performed to account for the displacement and stress on the models. The REC model was calculated twice, with the material property of reconstruction instrument set as titanium and stainless steel, respectively. Results: The displacements of anchor point on the L3 vertebrae in INT, DEF and REC model were 6.63 mm, 10.62 mm, 4.29 mm (titanium) and 3.86 mm (stainless steel), respectively. The stress distribution of the instrument in REC model showed excessively concentration on caudal spinal rod, which may cause rod failure between spine and ilia. The maximum von Mise stress of stainless steel instrument was higher than that of titanium instruments (992 MPa vs 655 MPa), and the value of stress of anchor point around sacroiliac joint in REC model were 26.4 MPa with titanium instruments and 23.9 MPa with stainless steel instruments. Conclusion: Lumbosacral reconstruction can significantly increase the stiffness of spino-pelvis of the patient who underwent subtotal sacrectomy. However, the rod between L5 and ilia is the weakest region of all the instruments. It is suggested that the bending of rod should be conducted carefully and smoothly to avoid significant stress concentration so as to reduce the risk of rod failure. And stainless steel instrument has higher maximum stress and significantly greater stress shielding effect than titanium instrument, which means stainless steel instruments are of higher risk of rod failure and less favorable for lumboiliac arthrodesis than titanium instruments.展开更多
The effects of geometry on mechanical properties in woven fabric composites were explored. Two types of composites, including one-layered and two-layered composites, were designed and studied. For one-layered composit...The effects of geometry on mechanical properties in woven fabric composites were explored. Two types of composites, including one-layered and two-layered composites, were designed and studied. For one-layered composites, inter-strand gap effects on the mechanical properties were studied, while three cases of geometries with inter-strand gaps in two-layered composites were evaluated. A woven fiber micromechanics analytical model called MESOTEX was employed for theoretical simulation. The predicted results show that the inter-strand gap and simple variation of the strand positions in a repeating unit cell significantly affect the mechanical properties of woven fabric composites.展开更多
In this article, we considers the thermodynamics analysis of creeping viscous nanofluid flow in a horizontal ciliated tube under the effects of a uniform magnetic field and porous medium. Moreover, energy analysis is ...In this article, we considers the thermodynamics analysis of creeping viscous nanofluid flow in a horizontal ciliated tube under the effects of a uniform magnetic field and porous medium. Moreover, energy analysis is performed in the presence of an internal heat source and thermal radiation phenomena. The thermal conductivity of base fluid water is strengthened by considering the carbon nanotubes (CNTs). Mathematical formulation operated, results in a set of non-linear coupled partial differential equations. The governed differential system is transformed into an ordinary differential system by considering suitable similarity variables. Exact solutions in the closed form are computed for the temperature, momentum and pressure gradient profiles. In this study, special attention is devoted to the electrical conductivity of the CNTs. Streamlines patterns are also discussed to witness the flow lines for different parameters. Thermodynamics analysis shows that entropy of the current flow system is an increasing function of Brinkmann number, magnetic parameter, nanoparticle concentration parameter and Darcy number.展开更多
The chemism of the chlorination of copper (I) sulphide by calcium chloride in the presence of oxygen has been determined based on the thermodynamic analysis in the Cu2S-CaCl2-O2 system as well as characterization of...The chemism of the chlorination of copper (I) sulphide by calcium chloride in the presence of oxygen has been determined based on the thermodynamic analysis in the Cu2S-CaCl2-O2 system as well as characterization of used raw materials and obtained products. The influence of temperature (from 473 to 773 K), time (from 2 to 120 min), oxygen flow (from 20 to 100 L/h) and calcium chloride quantity (from 5 to 40%) on the chlorination degree has been investigated. Kinetic analysis and the activation energy values of 20.89 kJ/mol showed that the chlorination of copper (I) sulphide by calcium chloride in the presence of oxygen is diffusion controlled.展开更多
Finite element analysis has been carried out to understand the effect of various processing routes and condition on the microscale deformation behavior of Al–4.5 Cu–2 Mg alloy. The alloy has been developed through f...Finite element analysis has been carried out to understand the effect of various processing routes and condition on the microscale deformation behavior of Al–4.5 Cu–2 Mg alloy. The alloy has been developed through four different routes and condition, i.e. conventional gravity casting with and without refiner, rheocasting and SIMA process. The optical microstructures of the alloy have been used to develop representative volume elements(RVEs). Two different boundary conditions have been employed to simulate the deformation behavior of the alloy under uniaxial loading. Finally, the simulated stress-strain behavior of the alloy is compared with the experimental result. It is found that the microstructural morphology has a significant impact on stress and strain distribution and load carrying capacity. The eutectic phase always carries a higher load than the α(Al) phase. The globular α(Al) grains with thinner and uniformly distributed eutectic network provide a better stress and strain distribution. Owing to this, SIMA processed alloy has better stress and strain distribution than other processes. Finally, the simulated yield strength of the alloy is verified by experiment and they have great agreement.展开更多
Non-consistency of stress results is of ten observed during field measurements. In some cases, even the rneasurernents are made at the same location in a massive rockrnass, the results can vary widely. In order to sol...Non-consistency of stress results is of ten observed during field measurements. In some cases, even the rneasurernents are made at the same location in a massive rockrnass, the results can vary widely. In order to solve the problem, extensive research has been carried out to study the major factors wh1ch rnay affect stress deterrnlnation. They include the rock behaviour and the stress state. For rocks showing non-isotropic behaviour, the values of Young’s modulus and Poisson ratio vary with the orientation of loading and measurement. Stress condition in the rock affects the rock behaviour. Furtherrnore, the loading condition on rock samples durlng laboratory tests is different from in the field and therefore the determined e1astic constants may not represent the field condi tion. In general , the Young’s modulus may depend on the orientation, the loading path, the stress magnitude and the stress ratio. This paper examines in detail the effects of those factors, especially for rocks showing transversely isotropic behaviour. It is found that the discrepancy of stress results from field measurernents in this type of rock is mainly due to over simplification of the rock behavior and inadequate use of elastic constants of the rock during stress calculation. A case study is given,which indicates the significance of these factors and demonstrates the proper procedure for stress calculation from measurements.展开更多
The mechanism of the leaching process of chalcopyrite concentrate with sodium nitrate in sulphuric acid solution were studied and discussed. Chemical reactions of leaching and their thermodynamic probabilities are pre...The mechanism of the leaching process of chalcopyrite concentrate with sodium nitrate in sulphuric acid solution were studied and discussed. Chemical reactions of leaching and their thermodynamic probabilities are predicted based on the calculated Gibbs energies and analysis of E-pH diagrams. Experimental data, thermodynamic analysis, chemical, XRD, and SEM/EDX analyses of concentrate and the leach residues, were performed to develop a better understanding of the chemical reactions that took place in the system. Elemental sulphur was formed as the main leaching product, precipitated at the particle surfaces and tended to inhibit the leaching rate.展开更多
基金Projects(2010CB631200,2010CB631206)supported by the National Basic Research Program of ChinaProject(50931004)supported by the National Natural Science Foundation of China
文摘The precipitation behavior of carbide in K416 B superalloy was investigated by means of creep measurement and microstructure observation. The results show that nanometer M6 C particles discontinuously precipitate in the γ matrix or along the γ/γ′ interface of the alloy during high temperature tensile creep. Thereinto, the amount of fine M6 C carbide increases as creep goes on, and the coherent interfaces of M6 C phase precipitating from the γ matrix are {100} and {111} planes. The thermodynamics analysis indicates that the solubility of element carbon in the matrix decreases when the alloy is deformed by the axial tensile stress during creep, so as to cause the carbon segregating in the regions of stress concentration and combining with carbide-forming elements M(W, Co), which promotes the fine M6 C carbide to precipitate from the γ matrix.
文摘Catalysis effect of triphenyl bismuth (TPB) on kinetics of hydroxyl terminated polybutadiene-toluene diisocyanate (HTPB-TDI) curing reaction was studied by non-isothermal differential scanning calorimetry (DSC). The characteristic temperature of curing system was measured for calculating kinetic parameters and establishing curing reaction kinetic equations. The results show that activation energy (Ea) of uncatalyzed HTPB-TDI curing system is 51.29 kJmol-1, and TPB decreases Ea to 46.43 kJ'mol-1. Catalyst lowers reaction temperature and shortens curing time through decreasing ac- tivation energy of curing reaction and accelerating reaction rate. TPB can increase the reaction rate at 27 ℃ to the value of uncatalyzed system at 80 ℃. The catalytic activity reaches the maximum when concentration is 0.5 %.
基金Project(50578060) supported by the National Natural Science Foundation of China
文摘Based on the characteristic that the potential sliding surfaces of rock slope are commonly in the shape of either line or fold line,analysis thought of conventional pile foundation in the flat ground under complex load condition was applied and the upper-bound theorem of limit analysis was used to compute thrust of rock layers with all possible distribution shapes. The interaction of slope and pile was considered design load in terms of slope thrust,and the finite difference method was derived to calculate inner-force and displacement of bridge pile foundation in rock slope under complex load condition. The result of example shows that the distribution model of slope thrust has certain impact on displacement and inner-force of bridge pile foundation. The maximum displacement growth rate reaches 54% and the maximum moment and shear growth rates reach only 15% and 20%,respectively,but the trends of inner-force and displacement of bridge pile foundation are basically the same as those of the conventional pile foundation in the flat ground. When the piles bear the same level lateral thrust,the distribution shapes of slope thrust have different influence on inner-force of pile foundation,especially the rectangle distribution,and the triangle thrust has the smallest displacement and inner-force of pile foundation.
基金Project(20050532021) supported by the Research Fund for the Doctoral Program of Higher Education
文摘Based on the fact that the shear stress along anchorage segment is neither linearly nor uniformly distributed, the load transfer mechanism of the tension type anchor was studied and the mechanical characteristic of anchorage segment was analyzed. Shear stress?strain relationship of soil surrounding anchorage body was simplified into three-folding-lines model consisting of elastic phase, elasto-plastic phase and residual phase considering its softening characteristic. Meanwhile, shear displacement method that has been extensively used in the analysis of pile foundation was introduced. Based on elasto-plastic theory, the distributions of displacement, shear stress and axial force along the anchorage segment of tension type anchor were obtained, and the formula for calculating the elastic limit load was also developed accordingly. Finally, an example was given to discuss the variation of stress and displacement in the anchorage segment with the loads exerted on the anchor, and a program was worked out to calculate the anchor maximum bearing capacity. The influence of some parameters on the anchor bearing capacity was discussed, and effective anchorage length was obtained simultaneously. The results show that the shear stress first increases and then decreases and finally trends to the residual strength with increase of distance from bottom of the anchorage body, the displacement increases all the time with the increase of distance from bottom of the anchorage body, and the increase of velocity gradually becomes greater.
基金Supported by the National'Creative Research Groups Science Foundation of China (No.60421002) and priority supported financially by "the New Century 151 Talent Project" of Zhejiang Province.
文摘A new kinetic model for commercial unit of toluene disproportionation and C9-armatiocs transalkylation is developed based on the reported reaction scheme.A time based catalyst deactivation function taking weight hourly space velocity(WHSV)into account is incorporated into the model,which reasonably accounts for the loss in activity because of coke deposition on the surface of catalyst during long-term operation.The kinetic parameters are benchmarked with several sets of balanced plant data and estimated by the differential variable metric optimiza- tion method.Sets of plant data at different operating conditions are applied to make sure validation of the model and the results show a good agreement between the model predictions and plant observations.The simulation analysis of key variables such as temperature and WHSV affecting process performance is discussed in detail,giv- ing the guidance to select suitable operating conditions.
基金Project(2010CB732101) supported by the National Basic Research Program of ChinaProject(51079145) supported by the National Natural Science Foundation of ChinaProject(2009BAK53B03) supported by the National Key Technology R&D Program of China
文摘The models of stress corrosion, pressure solution and flee-face dissolution/precipitation were introduced. Taking a hypothetical nuclear waste repository in an unsaturated dual-porosity rock mass as the calculation objective, four cases were designed 1) the fracture aperture is a function of stress corrosion, pressure solution and free-face dissolution/precipitation; 2) the fracture aperture changes with stress corrosion and pressure solution; 3) the fracture aperture changes with pressure solution and free-face dissolution/precipitation; 4) the fracture aperture is only a function of pressure solution, and the matrix porosity is also a function of stress in these four cases. Then, the corresponding two-dimensional FEM analyses for the coupled thermo-hydro-mechanical processes were carried out. The results show that the effects of stress corrosion are more prominent than those of pressure solution and free-face dissolution/precipitation, and the fracture aperture and relevant permeability caused by the stress corrosion arc only about 1/5 and 1/1000 of the corresponding values created by the pressure solution and free-face dissolution/precipitation, respectively Under the action of temperature field from released heat, the negative pore and fracture pressures in the computation domain rise continuously, and are inversely proportional to the sealing of fracture aperture. The vector fields of flow velocity of fracture water in the cases with and without considering stress corrosion are obviously different. The differences between the magnitudes and distributions of stresses within the rock mass are very small in all cases.
基金Project(140100153)supported by Australian Research Council Linkage Grant。
文摘Anchor bolts are commonly used throughout underground mining and tunnelling operations to improve roof stability.However,premature failures of anchor bolts are significant safety risks in underground excavations around the world due to susceptible bolt materials,a moist and corrosive environment and tensile stress.In this paper,laboratory experiments and hydrogeochemical models were combined to investigate anchor bolt corrosion and failure associated with aqueous environments in underground coal mines.Experimental data and collated mine water chemistry data were used to simulate bolt corrosion reactions with groundwater and rock materials with the PHREEQC code.A series of models quantified reactions involving iron and carbon under aerobic and anaerobic conditions in comparison with ion,pH and pE trends in experimental data.The models showed that corrosion processes are inhibited by some natural environmental factors,because dissolved oxygen would cause more iron from the bolts to oxidize into solution.These interdisciplinary insights into corrosion failure of underground anchor bolts confirm that environmental factors are important contributors to stress corrosion cracking.
基金This project is supported by returned specialists fund of China National Coal Corporation
文摘The experimental installation and measurement system of ultrasonic wave property in rocks during complete stress-strain process were established and perfected. The interrelations between ultrasonic wave property of muds tone, sands tone and limestone specimens during complete stress-strain process and their mechanic property were investigated. A new type of device for the observation of surrounding rock stability-borehole ultrasonic device with completely dry coupling was developed to get better coupling and more accurate measurement data comparing with those of water coupling situation. Preliminary study on the application of ultrasonic measurement technique at belt conveyor roadway of north wing in Baodian Coal Mine (Shandong province) was conducted. Based on the interrelations between the complete stress-strain properties of specimens and their wave properties, the structural properties of surrounding rocks, the range of yield zones, and the change of stresses within surrounding rocks when a longwall face was across over the roadway were analyzed.Therefore,a new and feasible way was found for the research on the deformation law of surrounding rock of roadway and rational selection of support parameters.
基金National Natural Science Foundation of China (No. 51304087) Foundation Projects of Yun- nan Province (No. KKSY201404056, No. KKSA201121083)
文摘This paper numerically simulates the stress development and generates a three-dimensional model of the medium-length hole blasting in infinite rock mass for continuous charge and divided charge in blasting by using the large-scale nonlinear dynamic analysis software LS-DYNA and the elastic-plastic model ~*MAT_PLASTIC_KINEMATIC and JWO-EOS.The differences of the decreasing rate in Von Mises effective stress of blasting,element effective stress peak of free surface,bore wall stress and acceleration are investigated.It is shown that divided charge could greatly improve the blasting effect by engineering blasting practice.
文摘Based on the phenomenon that acoustic emissions (AE) generated by rock mass increase suddenly because of underground excavation, time sequence of AE rate in rock failure has been discussed by using statistical damage theory. It has been demonstrated that how the influence of confining pressure on the deformation behavior and AE characteristics in rocks can be inferred from a simple mechanics model. The results show that loading confining pressure sharply brings out increasing of AE. On the other hand, few AE emits when confining pressure is loaded sharply, and AE occurs again when axial pressure keeps on increasing. These results have been well simulated with computer and show close correspondence with directly measured curves in experiments.
文摘Reactive distillation could be utilized to produce cyclohexanol through the cyclohexene hydration. By means of highly active zeolite catalyst HZSM-5, the kinetic-thermodynamic analysis of this reactive distillation has been carried out to get the characteristics of the reactive distillation. Results from kinetic and thermodynamic analysis indicate that the optimal pressure of this reactive distillation process should be set to higher pressure such as 0.3 or 0.4 MPa. To avoid the recovery of cyclohexanol at the top of the column, an unreactive section should be allocated at the upper column. In addition, the inert component benzene is more unfavorable to the reactive distillation process in comparison with the inert cyclohexane.
文摘Objective: The aim of this study was to investigate the biomechanical property of lumbosacral reconstruction after subtotal sacrectomy. Methods: Three three-dimensional finite element models of lumbosacral region were established: (1) An intact model (INT); (2) A defective model (DEF) on which subtotal sacrectomy was performed cephalad to the $1 foramina; (3) A reconstructed model (REC). These models were validated by compared with literature. Upright posture was stimulated under a compression load of 925N. A finite element analysis was performed to account for the displacement and stress on the models. The REC model was calculated twice, with the material property of reconstruction instrument set as titanium and stainless steel, respectively. Results: The displacements of anchor point on the L3 vertebrae in INT, DEF and REC model were 6.63 mm, 10.62 mm, 4.29 mm (titanium) and 3.86 mm (stainless steel), respectively. The stress distribution of the instrument in REC model showed excessively concentration on caudal spinal rod, which may cause rod failure between spine and ilia. The maximum von Mise stress of stainless steel instrument was higher than that of titanium instruments (992 MPa vs 655 MPa), and the value of stress of anchor point around sacroiliac joint in REC model were 26.4 MPa with titanium instruments and 23.9 MPa with stainless steel instruments. Conclusion: Lumbosacral reconstruction can significantly increase the stiffness of spino-pelvis of the patient who underwent subtotal sacrectomy. However, the rod between L5 and ilia is the weakest region of all the instruments. It is suggested that the bending of rod should be conducted carefully and smoothly to avoid significant stress concentration so as to reduce the risk of rod failure. And stainless steel instrument has higher maximum stress and significantly greater stress shielding effect than titanium instrument, which means stainless steel instruments are of higher risk of rod failure and less favorable for lumboiliac arthrodesis than titanium instruments.
基金Work supported by the Second Stage of the Brain Korea 21 Projects
文摘The effects of geometry on mechanical properties in woven fabric composites were explored. Two types of composites, including one-layered and two-layered composites, were designed and studied. For one-layered composites, inter-strand gap effects on the mechanical properties were studied, while three cases of geometries with inter-strand gaps in two-layered composites were evaluated. A woven fiber micromechanics analytical model called MESOTEX was employed for theoretical simulation. The predicted results show that the inter-strand gap and simple variation of the strand positions in a repeating unit cell significantly affect the mechanical properties of woven fabric composites.
文摘In this article, we considers the thermodynamics analysis of creeping viscous nanofluid flow in a horizontal ciliated tube under the effects of a uniform magnetic field and porous medium. Moreover, energy analysis is performed in the presence of an internal heat source and thermal radiation phenomena. The thermal conductivity of base fluid water is strengthened by considering the carbon nanotubes (CNTs). Mathematical formulation operated, results in a set of non-linear coupled partial differential equations. The governed differential system is transformed into an ordinary differential system by considering suitable similarity variables. Exact solutions in the closed form are computed for the temperature, momentum and pressure gradient profiles. In this study, special attention is devoted to the electrical conductivity of the CNTs. Streamlines patterns are also discussed to witness the flow lines for different parameters. Thermodynamics analysis shows that entropy of the current flow system is an increasing function of Brinkmann number, magnetic parameter, nanoparticle concentration parameter and Darcy number.
文摘The chemism of the chlorination of copper (I) sulphide by calcium chloride in the presence of oxygen has been determined based on the thermodynamic analysis in the Cu2S-CaCl2-O2 system as well as characterization of used raw materials and obtained products. The influence of temperature (from 473 to 773 K), time (from 2 to 120 min), oxygen flow (from 20 to 100 L/h) and calcium chloride quantity (from 5 to 40%) on the chlorination degree has been investigated. Kinetic analysis and the activation energy values of 20.89 kJ/mol showed that the chlorination of copper (I) sulphide by calcium chloride in the presence of oxygen is diffusion controlled.
文摘Finite element analysis has been carried out to understand the effect of various processing routes and condition on the microscale deformation behavior of Al–4.5 Cu–2 Mg alloy. The alloy has been developed through four different routes and condition, i.e. conventional gravity casting with and without refiner, rheocasting and SIMA process. The optical microstructures of the alloy have been used to develop representative volume elements(RVEs). Two different boundary conditions have been employed to simulate the deformation behavior of the alloy under uniaxial loading. Finally, the simulated stress-strain behavior of the alloy is compared with the experimental result. It is found that the microstructural morphology has a significant impact on stress and strain distribution and load carrying capacity. The eutectic phase always carries a higher load than the α(Al) phase. The globular α(Al) grains with thinner and uniformly distributed eutectic network provide a better stress and strain distribution. Owing to this, SIMA processed alloy has better stress and strain distribution than other processes. Finally, the simulated yield strength of the alloy is verified by experiment and they have great agreement.
文摘Non-consistency of stress results is of ten observed during field measurements. In some cases, even the rneasurernents are made at the same location in a massive rockrnass, the results can vary widely. In order to solve the problem, extensive research has been carried out to study the major factors wh1ch rnay affect stress deterrnlnation. They include the rock behaviour and the stress state. For rocks showing non-isotropic behaviour, the values of Young’s modulus and Poisson ratio vary with the orientation of loading and measurement. Stress condition in the rock affects the rock behaviour. Furtherrnore, the loading condition on rock samples durlng laboratory tests is different from in the field and therefore the determined e1astic constants may not represent the field condi tion. In general , the Young’s modulus may depend on the orientation, the loading path, the stress magnitude and the stress ratio. This paper examines in detail the effects of those factors, especially for rocks showing transversely isotropic behaviour. It is found that the discrepancy of stress results from field measurernents in this type of rock is mainly due to over simplification of the rock behavior and inadequate use of elastic constants of the rock during stress calculation. A case study is given,which indicates the significance of these factors and demonstrates the proper procedure for stress calculation from measurements.
文摘The mechanism of the leaching process of chalcopyrite concentrate with sodium nitrate in sulphuric acid solution were studied and discussed. Chemical reactions of leaching and their thermodynamic probabilities are predicted based on the calculated Gibbs energies and analysis of E-pH diagrams. Experimental data, thermodynamic analysis, chemical, XRD, and SEM/EDX analyses of concentrate and the leach residues, were performed to develop a better understanding of the chemical reactions that took place in the system. Elemental sulphur was formed as the main leaching product, precipitated at the particle surfaces and tended to inhibit the leaching rate.