为研究X80管线钢的金属磁记忆效应,通过不同载荷水平的板材拉伸加-卸载以及离线磁场测量,结合多项式拟合与矢量分析,得到试件表面磁场长度方向分量极值、法向分量梯度值以及合成矢量的变化规律,并根据应力等效磁化模型对其进行解释。研...为研究X80管线钢的金属磁记忆效应,通过不同载荷水平的板材拉伸加-卸载以及离线磁场测量,结合多项式拟合与矢量分析,得到试件表面磁场长度方向分量极值、法向分量梯度值以及合成矢量的变化规律,并根据应力等效磁化模型对其进行解释。研究结果表明:在加载环境磁场和拉伸载荷的耦合作用下,磁场长度方向分量极值和法向分量梯度值均呈现出单调递增的变化规律,而磁场矢量会发生反转。当载荷在20 k N以内时,长度方向分量极值和法向分量梯度值均随载荷幅值增加而缓慢增加,磁场矢量大小及其与长度方向的夹角随载荷增加而缓慢减小;而当载荷大于20 k N时,长度方向分量极值、法向分量梯度值以及磁场矢量大小均呈线性增加趋势,磁场矢量方向发生反向并逐渐趋于恒定。展开更多
Siderite,as an abundant iron ore,has not been effectively utilized,with a low utilization rate.In this study,the in-situ kinetics and mechanism of siderite during suspension magnetization roasting(SMR)were investigate...Siderite,as an abundant iron ore,has not been effectively utilized,with a low utilization rate.In this study,the in-situ kinetics and mechanism of siderite during suspension magnetization roasting(SMR)were investigated to improve the selective conversion of siderite to magnetite and CO,enriching the theoretical system of green SMR using siderite as a reductant.According to the gas products analyses,the peak value of the reaction rate increased with increasing temperature,and its curves presented the feature of an early peak and long tail.The mechanism function of the siderite pyrolysis was the contraction sphere model(R_(3)):f(α)=3(1−α)2/3;E_(α)was 46.4653 kJ/mol;A was 0.5938 s^(−1);the kinetics equation was k=0.5938exp[−46.4653/(RT)].The in-situ HT-XRD results indicated that siderite was converted into magnetite and wüstite that exhibited a good crystallinity in SMR under a N_(2) atmosphere.At 620℃,the saturation magnetization(M_(s)),remanence magnetization(Mr),and coercivity(Hc)of the product peaked at 53.63×10^(-3)A·m^(2)/g,10.23×10^(-3)A·m^(2)/g,and 12.40×10^(3)A/m,respectively.Meanwhile,the initial particles with a smooth surface were transformed into particles with a porous and loose structure in the roasting process,which would contribute to reducing the grinding cost.展开更多
The authors have shown that the process of information and thinking can be modeled on the basis of chemical thermodynamics. The authors offer general equations to calculate the thinking of the work of judgment the L a...The authors have shown that the process of information and thinking can be modeled on the basis of chemical thermodynamics. The authors offer general equations to calculate the thinking of the work of judgment the L and of entropy solutions G in the presence of a magnetic field. As a result, studies have shown that the magnetic effects strongly influence the thermodynamics of the process of thinking.展开更多
This paper reports Precambrian rock magnetic fabrics in the Nyalam area of southern Tibet. The analytical results of magnetic fabrics show that the values of H are high （〉 10% in general）, so the ductile deformatio...This paper reports Precambrian rock magnetic fabrics in the Nyalam area of southern Tibet. The analytical results of magnetic fabrics show that the values of H are high （〉 10% in general）, so the ductile deformations of the Precambrian rock are strong. The orientation of the maximum principal stress inferred from the minimum magnetic susceptibility is nearly S-N, NE-SW and NW-SE. The Flinn diagram of the magnetic fabrics show that the strain pattern is oblate and constrictional type. Magnetic foliation of great majority of rock samples is well developed and the magnetic lineation is poor and the magnetic susceptibility ellipsoid is flattened. The magnetic lineation of the minority rock samples is well developed and the magnetic foliation is poor and the magnetic susceptibility ellipsoid is prolate. According to the geological field and the magnetic fabrics, there are 3 times tectonic stress field in SN directed extruding, NW-SE directed extruding, NW-SE directed extension. It shows that the Nyalam area has undergone process the orientation of SN, NW-SE nappe structure and NW-SE directed extension structure. The change of tectonic stress is reflected by the field characteristics of the Precambrian rock magnetic fabrics that is the direct responding result of the arc-continental, continent-continental collision between the India and Asian continents in the late part of the Late Cretaceous to Late Eocene and subsequently shifted to intra-continental convergent, the plateau uplifting and extension structure stage since the Late Eocene.展开更多
The authors have shown that the process data can be modeled on the basis of chemical thermodynamics. The authors offer general information of the equation in the presence of a magnetic field. As a result, studies have...The authors have shown that the process data can be modeled on the basis of chemical thermodynamics. The authors offer general information of the equation in the presence of a magnetic field. As a result, studies have shown that the magnetic effects strongly influence the thermodynamics of information.展开更多
A large and reversible magnetocaloric effect is found in the compound DyB2, which is associated with two successive mag- netic transitions： a spin-reorientation-like transition followed by a ferromagnetic-paramagneti...A large and reversible magnetocaloric effect is found in the compound DyB2, which is associated with two successive mag- netic transitions： a spin-reorientation-like transition followed by a ferromagnetic-paramagnetic transition. These two transitions appreciably enlarge the magnetic-refrigeration temperature window and yield a huge refrigeration capacity of 610 J kg^-1, with a maximum magnetic entropy change -ASmax of 17 J kg^-1K^-1, at a magnetic-field change of 5 T. The corresponding values for low magnetic-field change of 2 T are 193 J kg^-1 and 7.4 J kg-lK^-1, respectively.展开更多
Magnetic properties and magnetocaloric effects （MCEs） of the HoPdA1 compounds with the hexagonal ZrNiAl-type and the orthorhombic TiNiSi-type structures are investigated. Both the compounds are found to be antiferro...Magnetic properties and magnetocaloric effects （MCEs） of the HoPdA1 compounds with the hexagonal ZrNiAl-type and the orthorhombic TiNiSi-type structures are investigated. Both the compounds are found to be antiferromagnet with the Nrel tem- perature TN=12 and 10 K, respectively. A field-induced metamagnetic transition from antiferromagnetic （AFM） state to ferro- magnetic （FM） state is observed below TN. For the hexagonal HoPdA1, a small magnetic field can induce an FM-like state due to a weak AFM coupling, which leads to a high saturation magnetization and gives rise to a large MCE around TN. The maxi- mal value of magnetic entropy change （ASM） is -20.6 J/kg K with a refrigerant capacity （RC） value of 386 J/kg for a field change of 0-5 T. For the orthorhombic HoPdA1, the critical field required for metamagnetic transition is estimated to be about 1.5 T, showing a strong AFM coupling. However, the maximal ASM value is still -13.7 J/kg K around TN for a field change of 0-5 T. The large reversible ASM and considerable RC suggest that HoPdA1 may be an appropriate candidate for magnetic re- frigerant in a low temperature range.展开更多
文摘为研究X80管线钢的金属磁记忆效应,通过不同载荷水平的板材拉伸加-卸载以及离线磁场测量,结合多项式拟合与矢量分析,得到试件表面磁场长度方向分量极值、法向分量梯度值以及合成矢量的变化规律,并根据应力等效磁化模型对其进行解释。研究结果表明:在加载环境磁场和拉伸载荷的耦合作用下,磁场长度方向分量极值和法向分量梯度值均呈现出单调递增的变化规律,而磁场矢量会发生反转。当载荷在20 k N以内时,长度方向分量极值和法向分量梯度值均随载荷幅值增加而缓慢增加,磁场矢量大小及其与长度方向的夹角随载荷增加而缓慢减小;而当载荷大于20 k N时,长度方向分量极值、法向分量梯度值以及磁场矢量大小均呈线性增加趋势,磁场矢量方向发生反向并逐渐趋于恒定。
基金Projects(51874071,52022019,51734005)supported by the National Natural Science Foundation of ChinaProject(161045)supported by the Fok Ying Tung Education Foundation for Yong Teachers in the Higher Education Institutions of China。
文摘Siderite,as an abundant iron ore,has not been effectively utilized,with a low utilization rate.In this study,the in-situ kinetics and mechanism of siderite during suspension magnetization roasting(SMR)were investigated to improve the selective conversion of siderite to magnetite and CO,enriching the theoretical system of green SMR using siderite as a reductant.According to the gas products analyses,the peak value of the reaction rate increased with increasing temperature,and its curves presented the feature of an early peak and long tail.The mechanism function of the siderite pyrolysis was the contraction sphere model(R_(3)):f(α)=3(1−α)2/3;E_(α)was 46.4653 kJ/mol;A was 0.5938 s^(−1);the kinetics equation was k=0.5938exp[−46.4653/(RT)].The in-situ HT-XRD results indicated that siderite was converted into magnetite and wüstite that exhibited a good crystallinity in SMR under a N_(2) atmosphere.At 620℃,the saturation magnetization(M_(s)),remanence magnetization(Mr),and coercivity(Hc)of the product peaked at 53.63×10^(-3)A·m^(2)/g,10.23×10^(-3)A·m^(2)/g,and 12.40×10^(3)A/m,respectively.Meanwhile,the initial particles with a smooth surface were transformed into particles with a porous and loose structure in the roasting process,which would contribute to reducing the grinding cost.
文摘The authors have shown that the process of information and thinking can be modeled on the basis of chemical thermodynamics. The authors offer general equations to calculate the thinking of the work of judgment the L and of entropy solutions G in the presence of a magnetic field. As a result, studies have shown that the magnetic effects strongly influence the thermodynamics of the process of thinking.
基金Acknowledgements This work was supported by China Geological Survey （Grant No. H45C004002, 1212010784007） and the Project of the National Natural Science Foundation of China （Grant No. 40272012）.
文摘This paper reports Precambrian rock magnetic fabrics in the Nyalam area of southern Tibet. The analytical results of magnetic fabrics show that the values of H are high （〉 10% in general）, so the ductile deformations of the Precambrian rock are strong. The orientation of the maximum principal stress inferred from the minimum magnetic susceptibility is nearly S-N, NE-SW and NW-SE. The Flinn diagram of the magnetic fabrics show that the strain pattern is oblate and constrictional type. Magnetic foliation of great majority of rock samples is well developed and the magnetic lineation is poor and the magnetic susceptibility ellipsoid is flattened. The magnetic lineation of the minority rock samples is well developed and the magnetic foliation is poor and the magnetic susceptibility ellipsoid is prolate. According to the geological field and the magnetic fabrics, there are 3 times tectonic stress field in SN directed extruding, NW-SE directed extruding, NW-SE directed extension. It shows that the Nyalam area has undergone process the orientation of SN, NW-SE nappe structure and NW-SE directed extension structure. The change of tectonic stress is reflected by the field characteristics of the Precambrian rock magnetic fabrics that is the direct responding result of the arc-continental, continent-continental collision between the India and Asian continents in the late part of the Late Cretaceous to Late Eocene and subsequently shifted to intra-continental convergent, the plateau uplifting and extension structure stage since the Late Eocene.
文摘The authors have shown that the process data can be modeled on the basis of chemical thermodynamics. The authors offer general information of the equation in the presence of a magnetic field. As a result, studies have shown that the magnetic effects strongly influence the thermodynamics of information.
基金supported by the National Natural Science Foundation of China (Grant No. 50831006)the National Basic Research Program of China ("973" Project) (Grant No. 2010CB934603)
文摘A large and reversible magnetocaloric effect is found in the compound DyB2, which is associated with two successive mag- netic transitions： a spin-reorientation-like transition followed by a ferromagnetic-paramagnetic transition. These two transitions appreciably enlarge the magnetic-refrigeration temperature window and yield a huge refrigeration capacity of 610 J kg^-1, with a maximum magnetic entropy change -ASmax of 17 J kg^-1K^-1, at a magnetic-field change of 5 T. The corresponding values for low magnetic-field change of 2 T are 193 J kg^-1 and 7.4 J kg-lK^-1, respectively.
基金supported by the National Natural Science Foundation of China (Grant Nos. 50731007 and 51021061)the Knowledge Innovation Project of the Chinese Academy of Sciencesthe High-Technology Research and Development Program of China
文摘Magnetic properties and magnetocaloric effects （MCEs） of the HoPdA1 compounds with the hexagonal ZrNiAl-type and the orthorhombic TiNiSi-type structures are investigated. Both the compounds are found to be antiferromagnet with the Nrel tem- perature TN=12 and 10 K, respectively. A field-induced metamagnetic transition from antiferromagnetic （AFM） state to ferro- magnetic （FM） state is observed below TN. For the hexagonal HoPdA1, a small magnetic field can induce an FM-like state due to a weak AFM coupling, which leads to a high saturation magnetization and gives rise to a large MCE around TN. The maxi- mal value of magnetic entropy change （ASM） is -20.6 J/kg K with a refrigerant capacity （RC） value of 386 J/kg for a field change of 0-5 T. For the orthorhombic HoPdA1, the critical field required for metamagnetic transition is estimated to be about 1.5 T, showing a strong AFM coupling. However, the maximal ASM value is still -13.7 J/kg K around TN for a field change of 0-5 T. The large reversible ASM and considerable RC suggest that HoPdA1 may be an appropriate candidate for magnetic re- frigerant in a low temperature range.
