外置式硫化物应力腐蚀裂开/氢脆敏感性智能监测仪

本文对外置式硫化物应力腐蚀裂开／氢脆敏感性智能监测仪的测量原理和结构设计作了详细的阐述。

Effect of interrupted aging on mechanical properties and corrosion resistance of 7A75 aluminum alloy

The effects of interrupted aging on mechanical properties and corrosion resistance of 7A75 aluminum alloy extruded bar were investigated through various analyses,including electrical conductivity,mechanical properties,local corrosion properties,and slow strain rate tensile stress corrosion tests.Microstructure characterization techniques such as metallographic microscopy,scanning electron microscopy(SEM),and transmission electron microscopy(TEM)were also employed.The results indicate that the tensile strength of the alloy produced by T6I6 aging is similar to that produced by T6I4 aging,and it even exceeds 700 MPa.Furthermore,the yield strength increases by 52.7 MPa,reaching 654.8 MPa after T6I6 aging treatment.The maximum depths of intergranular corrosion(IGC)and exfoliation corrosion(EXCO)decrease from 116.3 and 468.5μm to 89.5 and 324.3μm,respectively.The stress corrosion factor also decreases from 2.1%to 1.6%.These findings suggest that the alloy treated with T6I6 aging exhibits both high strength and excellent stress corrosion cracking resistance.Similarly,when the alloy is treated with T6I4,T6I6 and T6I7 aging,the sizes of grain boundary precipitates(GBPs)are found to be 5.2,18.4,and 32.8 nm,respectively.The sizes of matrix precipitates are 4.8,5.7 and 15.7 nm,respectively.The atomic fractions of Zn in GBPs are 9.92 at.%,8.23 at.%and 6.87 at.%,respectively,while the atomic fractions of Mg are 12.66 at.%,8.43 at.%and 7.00 at.%,respectively.Additionally,the atomic fractions of Cu are 1.83 at.%,2.47 at.%and 3.41 at.%,respectively.

Effect of heat treatment on stress corrosion cracking, fracture toughness and strength of 7085 aluminum alloy

The influences of heat treatment on stress corrosion cracking （SCC）, fracture toughness and strength of 7085 aluminum alloy were investigated by slow strain rate testing, Kahn tear testing combined with scanning electron microscopy （SEM） and transmission electron microscopy （TEM）. The results show that the fracture toughness of T74 overaging is increased by 22.9% at the expense of 13.6% strength, and retrogression and reaging （RRA） enhances fracture toughness 14.2% without reducing the strength compared with T6 temper. The fracture toughness of dual-retrogression and reaging （DRRA） is equivalent to that of T74 with an increased strength of 14.6%. The SCC resistance increases in the order： T6〈RRA〈DRRA≈T74. The differences of fracture toughness and SCC were explained on the basis of the role of matrix precipitates and grain boundary orecioitates.

Effects of silicon content on microstructure and stress corrosion cracking resistance of 7050 aluminum alloy

Evolution of microstructure and stress corrosion cracking （SCC） susceptibility of 7050 aluminum alloy with 0.094%, 0.134% and 0.261% Si （mass fraction） in T7651 condition have been investigated. The results show that the area fraction of Mg2Si increases from 0.16% to 1,48% and the size becomes coarser, while the area fraction of the other coarse phases including Al2CuMg, Mg（Al,Cu,Zn）2 and A17Cu2Fe decreases from 2.42% to 0.78% with Si content increasing from 0.094% to 0.261%. The tensile strength and elongation of 7050-T7651 alloys is decreased with the increase of Si content by slow strain rate test （SSRT） in ambient air. However, electrical conductivity is improved and SCC susceptibility is reduced with the increase of Si content by SSRT in corrosion environment with 3.5% NaCl solution.

Grain boundary pre-precipitation and its contribution to enhancement of corrosion resistance of Al-Zn-Mg alloy

High temperature pre-precipitation （HTPP）took place in7005 alloy at various temperatures after solution treatment and itsinfluence on mechanical properties, corrosion behaviors and microstructure of the alloy was investigated using tensile test, intergranular corrosion （IGC） test, slow strain rate testing （SSRT）, together with microstructural examinations. It is found that Vickers hardness of the aged alloy decreases gradually with decreasing the HTPP temperature, and almost a reverse trend of electrical conductivity is found compared to the hardness changes. Depending on the changes, two HTPP temperaturesof 440 and 420℃ were chosen for comparative study. Results reveal that HTPP alloy tempers exhibit higher resistance to stress corrosion cracking （SCC） and IGC than none pre-precipitate one with an acceptable strength loss due to the substantial enhancement of distribution discontinuity of the coarse grain boundary precipitates （GBPs）, and the coarsening and interspacing effect on GBPs becomes more obvious with decreasing the pre-precipitation temperature.

Microstructural evolution and delayed hydride cracking of FSW-AZ31 magnesium alloy during SSRT

Evolution of microstructure including texture and fractography in a friction-stir welded（FSW） AZ31 magnesium alloy was investigated. The texture was measured using a neutron diffractometer. The microstructure and fractography of stress corrosion cracking（SCC） samples were observed by optical and scanning electron microscopy, respectively. An X-ray diffraction study was carried out on the fractured surfaces of the SCC specimens. The results indicated that a strong basal fiber was formed on the base material, whereas the grains in the stir zone were reoriented with their most basal planes tilted 25 o to the welding direction. Feather-like twins and hydride formed under slow strain rate tensile（SSRT） stress in air and aggressive solutions, respectively. Transgranular cracks propagated and finally failed on the retreating side in the solution. The hydride phase confirmed to sit on the fracture surface demonstrated the delayed hydride cracking（DHC） mechanism of the alloy.

Diversity of intergranular corrosion and stress corrosion cracking for 5083 Al alloy with different grain sizes

5083 Al alloy sheets with different grain sizes(8.7-79.2 μm) were obtained by cold rolling and annealing. Their microstructures, intergranular corrosion(IGC), stress corrosion cracking(SCC), and crack propagation behaviors were investigated. The results showed that samples with coarse grains exhibit better IGC resistance with a corrosion depth of 15 μm. The slow strain rate test results revealed that fine-grained samples exhibit better SCC resistance with a susceptibility index(ISSRT) of 11.2%. Furthermore, based on the crack propagation mechanism, grain refinement can improve the SCC resistance by increasing the number of grain boundaries to induce the corrosion crack propagation along a tortuous path. The grains with {011} orientation could hinder crack propagation by orientating it toward the low-angle grain boundary region. The crack in the fine-grained material slowly propagates due to the tortuous path, and low H;and Cl;concentrations.

Effect of quenching rate on microstructure and stress corrosion cracking of 7085 aluminum alloy

The influence of quenching rate on microstructure and stress corrosion cracking （SCC） of 7085 aluminum alloy was investigated by tensile test, slow strain rate test （SSRT）, combined with scanning electron microscopy （SEM）, transmission electron microscopy （TEM） and electrochemical test. The results show that with decreasing the quenching rate, the size and inter-particle distance of the grain boundary precipitates as well as precipitation free zone width increase, but the copper content of grain boundary precipitates decreases. The SCC resistance of the samples increases first and then decreases, which is attributed to the copper content, size and distribution of grain boundary precipitates.

Effect of three-step homogenization on microstructure and properties of 7N01 aluminum alloys

The effect of different homogenization treatments on the microstructure and properties of the 7N01 aluminum alloy was investigated using hardness measurements, electrical conductivity measurements, tensile and slow strain rate tests, electron probe microanalysis, optical microscopy, scanning electron microscopy, and transmission electron microscopy. The results revealed that three-step homogenization improved the uniformity of Zr distribution by eliminating segregation of the main alloying elements. During the second homogenization step at 350 °C for 10 h, coarse and strip-like equilibrium η phases formed which assisted the nucleation of Al3Zr dispersoids and reduced the width of the precipitate-free zone of A13Zr dispersoids. As a result, coarse recrystallization was greatly reduced after homogenization at 200 °C, 2 h ＋ 350 °C, 10 h ＋ 470 °C, 12 h, which contributed to improving the overall properties of the 7N01 aluminum alloys.

Mechanical and electrochemical characteristics in sea water of 5052-O aluminum alloy for ship

The optimum corrosion protection potentials were examined for 5052-O Al alloy,which is mainly used in ships.Various electrochemical experiments were carried out and the surface morphologies of specimens were observed by scanning electron microscopy（SEM） in order to determine the optimum corrosion protection potential to overcome pitting,corrosion,stress corrosion cracking（SCC）,and hydrogen embrittlement in sea water.An optimum protection potential range of-1.3 V to-0.7 V was determined under the application of an impressed current cathodic protection（ICCP） system.The low current densities were shown in the range of-1.3 V to-0.7 V in the electrochemical experiments and good specimen surface morphologies were observed after potentiostatic experiment.

Correlations among stress corrosion cracking,grain-boundary microchemistry,and Zn content in high Zn-containing Al-Zn-Mg-Cu alloys

The correlations among the corrosion behaviour,grain-boundary microchemistry,and Zn content in Al-Zn-Mg-Cu alloys were studied using stress corrosion cracking(SCC)and intergranular corrosion(IGC)tests,combined with scanning electron microscopy(SEM)and high-angle angular dark field scanning transmission electron microscopy(HAADF-STEM)microstructural examinations.The results showed that the tensile strength enhancement of high Zn-containing Al-Zn-Mg-Cu alloys was mainly attributed to the high density nano-scale matrix precipitates.The SCC plateau velocity for the alloy with 11.0 wt.%Zn was about an order of magnitude greater than that of the alloy with 7.9 wt.%Zn,which was mainly associated with Zn enrichment in grain boundary precipitates and wide precipitates-free zones.The SCC mechanisms of different Zn-containing alloys were discussed based on fracture features,grain-boundary microchemistry,and electrochemical properties.

Influence of aging on microstructure,mechanical properties and stress corrosion cracking of 7136 aluminum alloy

The microstructure,mechanical properties and stress corrosion cracking(SCC)of 7136 aluminum alloy under T 6,T 79 and T 74 aging treatments were studied and the effects of microstructure on the mechanical properties and SCC were discussed.The results show that the ultimate tensile strength and yield strength of the aging 7136 alloys follow this sequence from high to low:T 6>T 79>pre-aging>T 74.For 7136 Al alloy after T 6 aging,the average diameter of the precipitates was(5.7±1.7)nm,and the diameter of 60.7%(number fraction)precipitates was 2−6 nm,leading to a good precipitation strengthening.The K_(IC)of T 74-aging alloy is 38.2 MPa·m^(1/2),which is 26.1%more than that of T 6-aging alloy and 17.5%more than that of T 79-aging alloy.The improved fracture toughness in T 74-aging alloy is mainly due to the reduction of the strength difference between intragranular and grain boundary.The SCC resistance of the aging 7136 alloys follows this sequence from high to low:T 79>T 74>T 6.After T 79 aging,the discontinuous grain boundary precipitates and narrow precipitate free zones were obtained in 7136 alloy,which was beneficial to SCC resistance.

Mechanical properties of 7475 aluminum alloy sheets with fine subgrain structure by warm rolling

The effect of transition elements on grain refinement of 7475 aluminum alloy sheets produced by warm rolling was investigated. The alloy which contains zirconium instead of chromium showed ultra fine structures with stable subgrains after warm rolling at 350 ℃, followed by solution heat treatment at 480 ℃. The average subgrain diameter was approximately 3 pan. It became clear that zirconium in solution has the effect of stabilizing subgrains due to precipitation of fine Al3Zr compounds during warm rolling. On the other hand, chromium-bearing compounds precipitate before warm rolling and they grow up to relatively large size during warm rolling. The warm rolled sheets with fine subgrains have unique properties compared with conventional 7475 aluminum alloy sheets produced by cold rolling. The warm roiled sheets solution heat treated had subgrain structures through the thickness with a high proportion of low-angle boundary less than 15°. The strength of the warm rolled sheets in T6 condition was about 10% higher than that of conventional 7475 aluminum alloy sheets. As the most remarkable point in the warm rolled sheets, the high Lankford （r） value of 3.5 was measured in the orientation of 45° to rolling direction, with the average r-value of 2.2. The high r-value would be derived from well developed r-fiber textures, especially with the strong {011 }（211） brass component. The warm rolled sheets also had high resistance to SCC. From Kikuchi lines analysis and TEM images, it was found that PFZs were hardly formed along the low- angle boundaries of the warm rolled sheets in T6 condition. This would be a factor to lead to the improvement of resistance to SCC because of reducing the difference in electrochemical property between the grain boundary area and the grain interior.

Effect of pre-deformation of rolling combined with stretching on stress corrosion of aluminum alloy 2519A plate

The effect of the pre-deformation of rolling combined with stretching on the stress corrosion cracking resistance of aluminum alloy 2519A was studied by means of the slow strain rate technique at 10-6 s-1. The tensile strength and stress corrosion index of the alloy plate with 7% rolling plus 3% perpendicular stretching were 481 MPa and 0.0429, respectively, showing better mechanical property and stress corrosion cracking resistance than those with 4% rolling plus 3% parallel stretching or 7% rolling plus 3% parallel stretching, which is due to its finer and denser precipitates within the grains, discontinuous grain boundary precipitates, as well as more narrow precipitate-free zone width. Such microstructure is attributing to the denser and more homogeneously distributed dislocations which are produced by the pre-deformation.

SCC evaluation of ultra-high strength steel in acidic chloride solution

The stress corrosion crack （SCC） susceptibility of ultra-high strength steel AerMet 100 was investigated by slow strain rate technique （SSRT）, tensile with polarization and surface analysis technique. The curves of tf^Cl/tf^W -strain rate are divided into three regions： stress-dominated region, SCC-dominated region, and corrosion-dominated region, so as the curves of εf^Cl/εf^W - strain rate and tm/tf-strain rate. The results of tensile tests with polarization show that the main SCC mechanism of AerMet 100 is anodic dissolution, which controls the corrosion process. The three regions have been discussed according to the relationship between the rate of slip-step formation and the rate of dissolution. Fracture appearances in different environments were analyzed by scanning electron microscopy （SEM）. SCC fracture appears as a mixture of intergranular and dimples, while it is totally dimples in the inert environment. The εf becomes the parameter to predict tf because the relationship between εf^Cl/εf^W and tf^Cl/tf^w is a straight line for AerMet 100.

Effect of a novel three-step aging on strength, stress corrosion cracking and microstructure of AA7085

The influence of a novel three-step aging on strength, stress corrosion cracking(SCC) and microstructure of AA7085 was investigated by tensile testing and slow strain rate testing combined with transmission electron microscopy(TEM). The results indicate that with the increase of second-step aging time of two-step aging, the mechanical properties increase first and then decrease, while the SCC resistance increases. Compared with two-step aging, three-step aging treatment improves SCC resistance and the strength increases by about 5%. The effects of novel three-step aging on strength and SCC resistance are explained by the role of matrix precipitates and grain boundary precipitates, respectively.

Influence factors on stress corrosion cracking of P 110 tubing steel under CO2 injection well annulus environment

Stress corrosion cracking （SCC） behavior of P 110 tubing steel in simulated C02 injection well annulus environments was investigated through three-point bent tests, potentiodynamic polarization and EIS measurements. The results demonstrate that SCC of P110 tubing steel could occur in acidulous simulated environment, and the sensitivity of SCC increases with the decrease ofpH, as well as increase of sulfide concentration and total environmental pressure. Both anodic dissolution and hydrogen embrittlement make contributions to the SCC. Adequate concentration of corrosion inhibitor can inhibit the occurrence of SCC on account of the inhibition of localized anodic dissolution and cathodic hydrogen evolution.

Hydrogeochemical modelling of corrosive environment contributing to premature failure of anchor bolts in underground coal mines

Anchor bolts are commonly used throughout underground mining and tunnelling operations to improve roof stability.However,premature failures of anchor bolts are significant safety risks in underground excavations around the world due to susceptible bolt materials,a moist and corrosive environment and tensile stress.In this paper,laboratory experiments and hydrogeochemical models were combined to investigate anchor bolt corrosion and failure associated with aqueous environments in underground coal mines.Experimental data and collated mine water chemistry data were used to simulate bolt corrosion reactions with groundwater and rock materials with the PHREEQC code.A series of models quantified reactions involving iron and carbon under aerobic and anaerobic conditions in comparison with ion,pH and pE trends in experimental data.The models showed that corrosion processes are inhibited by some natural environmental factors,because dissolved oxygen would cause more iron from the bolts to oxidize into solution.These interdisciplinary insights into corrosion failure of underground anchor bolts confirm that environmental factors are important contributors to stress corrosion cracking.

Investigations into the corrosive environments contributing to premature failure of Australian coal mine rock bolts

University of New South Wales(UNSW Australia) had been involved in the study of premature failure of rock bolts in Australia coal mines from the initial identification of the problem in 1999. Rock bolt steel changes over the last decade appear to have not reduced the incidence of failures. A broadened UNSW research project funded by the Australian Research Council(ARC) and Industry has targeted finding the environmental causes through extensive field and laboratory experiments. This paper describes the field studies conducted in underground coal mines,in particular attempts to measure the contribution to corrosion from groundwater,mineralogy and microbial activity. Various underground survey techniques were used to determine the extent of broken bolts,with the presence of both stress corrosion cracking(SCC) and localized deep pitting making no single technique suitable on their own.Groundwater found dripping from bolts across various coalfields in Australia were found to be not aggressive and known groundwater corrosivity classification systems did not correlate to where broken bolts were found. In-hole coupon bolts placed in roof strata containing claystone bands confirmed the clay as being a major contributor to corrosion. Microbes capable of contributing to steel corrosion were found to be present in groundwater,and culturing of the microbes taken from in-situ coupon bolts proved that the bacteria was present on the bolt surface. An ‘in-hole bolt corrosion coupon' development by the project may have multiple benefits of (1) helping quantify newly developed corrosivity classification systems,(2) providing an in-situ ground support corrosion monitoring tool,and (3) for testing possible corrosion protection solutions.

Environmentally assisted cracking resistance of Al-Cu-Li alloy AA2195 using slow strain rate test in 3.5% NaCl solution

The general corrosion and environmental cracking resistances of Al-Cu-Li alloy AA2195 were investigated in 3.5% NaCl environment and compared with those of another high strength alloy AA2219. The general corrosion resistance of these alloys was examined using immersion corrosion and potentiodynamic polarization tests, while the stress corrosion cracking （SCC） resistance was evaluated by slow strain rate test （SSRT） method. The tested samples were further characterized by SEM-EDS and optical profilometry to study the change in corrosion morphology, elemental content and depth of corrosion attack. The reduction in ductility was used as a parameter to evaluate the SCC susceptibility of the alloys. The results indicated that the corrosion resistance of AA2195 alloy was better than that of AA2219 alloy as it exhibited lower corrosion rate, along with lower pit depth and density. However, the SCC index （εNaCl/εair） measured was greater than 0.90, indicating good environmental cracking resistance of both the alloys. Detailed fractography of the failed samples under SEM？EDS, in general, revealed a typical ductile cracking morphology for both the alloys.