An efficient analytical method combining pyrolysis and capillary GC/MS has been developed for determination and quantitation of targeted polycyclic aromatic hydrocarbons.The limit of detection ranged from 0.29 μg/g t...An efficient analytical method combining pyrolysis and capillary GC/MS has been developed for determination and quantitation of targeted polycyclic aromatic hydrocarbons.The limit of detection ranged from 0.29 μg/g to 43.46 μg/g,and repeatability values were between 0.1% and 8.2% for blank spiked samples and between 0.1 % and 9.8% for real samples of heavy oils.Through application of the proposed method in hydrotreating processes,it has been found out that heavy oils before and after the specified hydroprocessing treatment exhibited a diverse PAHs distribution which might be determined by the discrepancy in their intrinsic contents and hydrogenation reactivity.Furthermore,the hydrogenation reactivity of different polycyclic aromatic hydrocarbons was further investigated and discovered to be more interrelated to molecular structure and rings alignment or conjugation mode.展开更多
Deforestation to reclaim land often triggers severe soil erosion in the Guizhou Karst Plateau. 137Cs dating of the deposited sediments in the karst depression bottom was used to estimate soil losses by surface erosion...Deforestation to reclaim land often triggers severe soil erosion in the Guizhou Karst Plateau. 137Cs dating of the deposited sediments in the karst depression bottom was used to estimate soil losses by surface erosion since deforestation started in 1979 on hillslopes in the Shirenzhai catchment, Puding County, Guizhou Province. The catchment has a drainage area of 0.054 km2. The average 137Cs contents of the top and peak layers in five cores of the depression bottom (with an area of 2652 m2), collected in 2009, were 2.35 and 7.25 Bq kg-1, respectively. The medium depths in the depression (which ranged between 84 cm and 113.5 cm with a mean value of 92.1 cm) showed the presence of sediments deposited in 1979. The total volume and weight of the deposited sediments since 1979 were estimated to be 1965 m3 and 2496 t, respectively. The depression bottom can be treated as a temporary impoundment and its sediment trapping efficiency was estimated to be 0.7. The relevant average soil erosion rate on the hillslopes was 2315 t km-2 yr-1 since 1979. The mean 137Cs inventory of the five cores was 7693 Bq m-2, which was ~10 times the local reference inventory of 782 Bq m-2. The total 137Cs activity of the sediments in the bottom was 20.4×106 Bq, and the relevant 137Cs inventory loss from the hillslopes was 358 Bq m-2 (since 1954), which accounted for 45.8% of the reference inventory. As soil erosion was not severe before and after the period of deforestation and following cultivation in 1979-1990, the erosion rates on the hillslopes could potentially reach 7000 t km-2 yr-1.展开更多
The thermodynamic systems and dynamic model suitable for determining the nonlinear chemical fingerprints of samples were analyzed.The results indicated that the damp nonlinear chemical reactions in close systems away ...The thermodynamic systems and dynamic model suitable for determining the nonlinear chemical fingerprints of samples were analyzed.The results indicated that the damp nonlinear chemical reactions in close systems away from the equilibrium and open systems without the complementarity of the dissipation substances have important significance for the throng characterization and whole content analysis of chemical components in samples.Various factors influencing on nonlinear chemical fingerprint,such as reactant species and their concentrations,electrode types,temperature,stir rate,the sort,dosage and granularity of the sample,etc.were amply researched by a nonlinear chemistry reaction,namely,damp B-Z oscillation which used acetone and glucose as the main dissipative substances.In addition,the quantitative information on the whole of chemical components in samples and the traits and applications of the fingerprint were investigated.The method and its important conditions for determining nonlinear chemistry fingerprint used in distinguishing and evaluating complex samples were successfully put forward.展开更多
基金support from the National Key Basic Research Science Foundation (Grant No. 2006CB202500. 4-1)
文摘An efficient analytical method combining pyrolysis and capillary GC/MS has been developed for determination and quantitation of targeted polycyclic aromatic hydrocarbons.The limit of detection ranged from 0.29 μg/g to 43.46 μg/g,and repeatability values were between 0.1% and 8.2% for blank spiked samples and between 0.1 % and 9.8% for real samples of heavy oils.Through application of the proposed method in hydrotreating processes,it has been found out that heavy oils before and after the specified hydroprocessing treatment exhibited a diverse PAHs distribution which might be determined by the discrepancy in their intrinsic contents and hydrogenation reactivity.Furthermore,the hydrogenation reactivity of different polycyclic aromatic hydrocarbons was further investigated and discovered to be more interrelated to molecular structure and rings alignment or conjugation mode.
基金supported by National Basic Research Program of China (Grant No. 2006CB403200)National Natural Science Foundation of China (Grant No. 41001162)+3 种基金Knowledge Innovation Project of the Chinese Academy of Sciences (Grant No. KZCX2-YW-306)National Key Technology R&D Program (Grant Nos. 2006BAC01A09 and 2008BAD98B07)Provincial Governor Foundation of Guizhou (Grant No. 2010-95)Opening Fund of State Key Laboratory of Environmental Geochemistry (Grant No. SKLEG9008)
文摘Deforestation to reclaim land often triggers severe soil erosion in the Guizhou Karst Plateau. 137Cs dating of the deposited sediments in the karst depression bottom was used to estimate soil losses by surface erosion since deforestation started in 1979 on hillslopes in the Shirenzhai catchment, Puding County, Guizhou Province. The catchment has a drainage area of 0.054 km2. The average 137Cs contents of the top and peak layers in five cores of the depression bottom (with an area of 2652 m2), collected in 2009, were 2.35 and 7.25 Bq kg-1, respectively. The medium depths in the depression (which ranged between 84 cm and 113.5 cm with a mean value of 92.1 cm) showed the presence of sediments deposited in 1979. The total volume and weight of the deposited sediments since 1979 were estimated to be 1965 m3 and 2496 t, respectively. The depression bottom can be treated as a temporary impoundment and its sediment trapping efficiency was estimated to be 0.7. The relevant average soil erosion rate on the hillslopes was 2315 t km-2 yr-1 since 1979. The mean 137Cs inventory of the five cores was 7693 Bq m-2, which was ~10 times the local reference inventory of 782 Bq m-2. The total 137Cs activity of the sediments in the bottom was 20.4×106 Bq, and the relevant 137Cs inventory loss from the hillslopes was 358 Bq m-2 (since 1954), which accounted for 45.8% of the reference inventory. As soil erosion was not severe before and after the period of deforestation and following cultivation in 1979-1990, the erosion rates on the hillslopes could potentially reach 7000 t km-2 yr-1.
基金supported by the National Key Technologies R & DProgram (2009GJD20033)the International Scientific and Technological Cooperation Project (2007DFA40680) from the Ministry of Scienceand Technology of China
文摘The thermodynamic systems and dynamic model suitable for determining the nonlinear chemical fingerprints of samples were analyzed.The results indicated that the damp nonlinear chemical reactions in close systems away from the equilibrium and open systems without the complementarity of the dissipation substances have important significance for the throng characterization and whole content analysis of chemical components in samples.Various factors influencing on nonlinear chemical fingerprint,such as reactant species and their concentrations,electrode types,temperature,stir rate,the sort,dosage and granularity of the sample,etc.were amply researched by a nonlinear chemistry reaction,namely,damp B-Z oscillation which used acetone and glucose as the main dissipative substances.In addition,the quantitative information on the whole of chemical components in samples and the traits and applications of the fingerprint were investigated.The method and its important conditions for determining nonlinear chemistry fingerprint used in distinguishing and evaluating complex samples were successfully put forward.
