Polyvinyl alcohol (PVA)-containing desizing wastewater was treated by various wet oxidation methods.Parameters such as reaction temperature, initial solution pH, and the dosage of H2O2 were investigated in terms of ch...Polyvinyl alcohol (PVA)-containing desizing wastewater was treated by various wet oxidation methods.Parameters such as reaction temperature, initial solution pH, and the dosage of H2O2 were investigated in terms of chemical oxygen demand (CODcr) and total organic carbon (TOC) removal rate. Up to 90% of the initial CODcr was removed by wet air oxidation(WAO) at 270℃ with stoichiometric oxygen supply, while at temperature of 200℃, the CODcr removal rate was found to be 80%. Similar results were obtained by Promoted WAO (PWAO) and wet peroxide oxidation(WPO) at a lower temperature of 150℃. Reaction temperature was found to have a significant effect on the oxidation performance for all the methods. Initial solution pH was observed to play a significant role in PWAO and WPO where H2O2 was employed. Comparison of WAO, CWAO(catalytic wet air oxidation), PWAO and WPO shows that the rate of CODcr removal increases in the order: WAO, CWAO, PWAO and WPO.展开更多
The process of treatment and utilization of organic chlorinecompounds: 1,2-dichloropropane and propylene chlorohydrin, wereinvestigated with application of contact catalysts to obtain thelowest possible temperature of...The process of treatment and utilization of organic chlorinecompounds: 1,2-dichloropropane and propylene chlorohydrin, wereinvestigated with application of contact catalysts to obtain thelowest possible temperature of the process by selection of propercatalysts and determination of optimum reaction parameters.Experiments were carried out with application of oxide, copper-zinc(TMC-2, TCM 3/1) and platinum (PA-2) Catalysts. Results ofinvestigations proved the possibility of total oxidation ofabove-mentioned compounds And components of industrial wastewater inthe temperature range form 350 to 450 deg. C.展开更多
Based on ecological niche theory, Microcystis Aeruginosa(MA) immobilized in the complex of polyvinyl alcohol(PVA)and sodium alginate(SA) crosslinked by CaCl2, was treated as a new kind of special species, and its prop...Based on ecological niche theory, Microcystis Aeruginosa(MA) immobilized in the complex of polyvinyl alcohol(PVA)and sodium alginate(SA) crosslinked by CaCl2, was treated as a new kind of special species, and its properties were investigated.Chlorophyll a was used to characterize the bioactivity of the immobilized MA. Results reveal that the gel beads have mechanical strength and chemical stability even under non-sterile harsh conditions, which may be attributed to the rarely seen structure(including three different layers: dense surface, tubular-shaped divergent structure and honeycomb crystal lattice layer) of the immobilized MA determined by scanning electron microscope(SEM). SEM also displays that more quantity of MA is attached to the inwall after cultivation, which demonstrates that the MA within beads maintains high bioactivity. Removal capacities on phosphorous(P) removal in wastewater in the presence and absence of the BG-11 medium were examined, and the removal ratios are 80.3% and76.7%, respectively, which indicates that the beads without providing ample nutrients still have high capacity of P removal. In addition, control experiment, utilizing polyvinyl alcohol and sodium alginate(PVA-SA) beads without immobilized MA,demonstrates that MA within beads plays the key role in absorbing P.展开更多
文摘Polyvinyl alcohol (PVA)-containing desizing wastewater was treated by various wet oxidation methods.Parameters such as reaction temperature, initial solution pH, and the dosage of H2O2 were investigated in terms of chemical oxygen demand (CODcr) and total organic carbon (TOC) removal rate. Up to 90% of the initial CODcr was removed by wet air oxidation(WAO) at 270℃ with stoichiometric oxygen supply, while at temperature of 200℃, the CODcr removal rate was found to be 80%. Similar results were obtained by Promoted WAO (PWAO) and wet peroxide oxidation(WPO) at a lower temperature of 150℃. Reaction temperature was found to have a significant effect on the oxidation performance for all the methods. Initial solution pH was observed to play a significant role in PWAO and WPO where H2O2 was employed. Comparison of WAO, CWAO(catalytic wet air oxidation), PWAO and WPO shows that the rate of CODcr removal increases in the order: WAO, CWAO, PWAO and WPO.
基金Project (No. 3T09B 01112) partly supported by the Polish State Committee for Scientific Research.
文摘The process of treatment and utilization of organic chlorinecompounds: 1,2-dichloropropane and propylene chlorohydrin, wereinvestigated with application of contact catalysts to obtain thelowest possible temperature of the process by selection of propercatalysts and determination of optimum reaction parameters.Experiments were carried out with application of oxide, copper-zinc(TMC-2, TCM 3/1) and platinum (PA-2) Catalysts. Results ofinvestigations proved the possibility of total oxidation ofabove-mentioned compounds And components of industrial wastewater inthe temperature range form 350 to 450 deg. C.
基金Projects(51178172,51308076)supported by the National Natural Science Foundation of ChinaProject(13JJ4107)supported by Hunan Provincial Natural Science Foundation,ChinaProject(K1207026-31)supported by Changsha Planning Project of Science and Technology,China
文摘Based on ecological niche theory, Microcystis Aeruginosa(MA) immobilized in the complex of polyvinyl alcohol(PVA)and sodium alginate(SA) crosslinked by CaCl2, was treated as a new kind of special species, and its properties were investigated.Chlorophyll a was used to characterize the bioactivity of the immobilized MA. Results reveal that the gel beads have mechanical strength and chemical stability even under non-sterile harsh conditions, which may be attributed to the rarely seen structure(including three different layers: dense surface, tubular-shaped divergent structure and honeycomb crystal lattice layer) of the immobilized MA determined by scanning electron microscope(SEM). SEM also displays that more quantity of MA is attached to the inwall after cultivation, which demonstrates that the MA within beads maintains high bioactivity. Removal capacities on phosphorous(P) removal in wastewater in the presence and absence of the BG-11 medium were examined, and the removal ratios are 80.3% and76.7%, respectively, which indicates that the beads without providing ample nutrients still have high capacity of P removal. In addition, control experiment, utilizing polyvinyl alcohol and sodium alginate(PVA-SA) beads without immobilized MA,demonstrates that MA within beads plays the key role in absorbing P.
