The gas-liquid phase equilibrium is used in controlling the nitrosation reaction process. Decomposition of nitrous acid and oxidation side reaction.are suppressed in a closed reaction system. The system pressure is us...The gas-liquid phase equilibrium is used in controlling the nitrosation reaction process. Decomposition of nitrous acid and oxidation side reaction.are suppressed in a closed reaction system. The system pressure is used as the criterion of the end of reaction, avoiding excessive feeding and reducing＇the decomposition＇of nitrous acid. The head space of the reactor is used as the gas buffer, stabilizing the feeding fluctuations and inhibiting the side reaction, decomposition of nitrous acid. Nitrogen oxide concentration is controlled at the minimum level.Thus the zero release ofnitrogen ox!de waste gas can be achieved without using any absorption process.展开更多
Targeting the problem of large amounts of gas emission from the goaf of the No.14201 working face in the Shaqu coal mine of Huajin Coking Coal Co. Ltd., we used a negative exponential function to describe the attenuat...Targeting the problem of large amounts of gas emission from the goaf of the No.14201 working face in the Shaqu coal mine of Huajin Coking Coal Co. Ltd., we used a negative exponential function to describe the attenuation process of gas emission in goaf (the stable source) based on the principle of field flow. Equations of two-component flow (gas and air) and seep- age-diffusion in a heterogeneous goaf flow field are solved by means of numerical simulation and fluid mechanics principles of air movement and gas distribution during gas emission from goaf. The results indicate that the air diversion volume has a negative, exponential relation with the volume of gas emitted from goaf to the working face and is clearly inversely related to gas concentra- tion. We calculated the minimum amount of air diversion and distributed air volume in the tailing roadway required for safe pro- duction.展开更多
The problem of climate change is a global challenge.It is closely associated with social development and human survival,and it has a significant impact to all countries on energy development,economic competitiveness,t...The problem of climate change is a global challenge.It is closely associated with social development and human survival,and it has a significant impact to all countries on energy development,economic competitiveness,technological innovation,and way of life.In recent years,with the rapid economic development in China,there is a rumor that the rapid growth of China's carbon dioxide emission offset the efforts of the international community in reducing emissions,and China should bear the international responsibility corresponding to its significant role in greenhouse gas emission,which obviously are unfair and not objective.As this paper reveals,"China environment responsibility" that is the socalled "China environment threat" or theories,China has made a positive contribution to addressing the climate change in the past and China will still be the backbone on the protection of global climate in the future.展开更多
The contribution of anthropogenic mineral aerosol dust has been of interest to understand the impact of dust aerosols on climate, and the health of workers occupational exposure. Several studies have been investigated...The contribution of anthropogenic mineral aerosol dust has been of interest to understand the impact of dust aerosols on climate, and the health of workers occupational exposure. Several studies have been investigated the physical and chemical properties mainly in particulate matter. However, the characterizations have not extended diameters below to 1.0 μm. In this study, it described chemical composition and shape measurements of individual aerosol particles with 50% cut-off diameters less than 1.1 μm emitted at ceramic-tile manufacturing. Four emission sites of process were selected, and their samples were collected using a cascade-impactor, investigated using X-ray diffraction, energy dispersive X-ray spectroscopy, and digital image processing, where the data were analysed applying a combination of principal component and cluster analysis. Particles of tectosilicate （quartz, zeolite）, phyllosilicate （illite, montmorillonite）, and inosilicate （calcium silicate） were founded in all sampling sites; also, silicates mixed with transition metals oxides used as pigments （e.g., Fe, Ti, Co, Ni, Zn and Mo）. Silicates were granulated and flat crystals with a transparent, translucent appearance; otherwise, the mixture had flake shapes and opaque appearance. Analyses of multivariate data showed that the process stages emissions were related with specific composition and shape suggesting the use three measurements related （1） the internal axis, （2） roundness and （3） roughness to isolate particles shapes, and the presence of transition metals oxides as emissions tracer of the ceramic industry.展开更多
In the Greater Casablanca, road transport is the second largest emissions source of gaseous pollutants and particles after the industry [ 1 ]. The emitters are mobile and include different categories of vehicles in ci...In the Greater Casablanca, road transport is the second largest emissions source of gaseous pollutants and particles after the industry [ 1 ]. The emitters are mobile and include different categories of vehicles in circulation, in the road network of the region [2]. Air emissions from road transport considered in this study are the exhaust emissions from combustion of fuel during vehicle movement. This is mainly SO2 （sulfur dioxide）, NOx （nitrogen oxides）, CO （carbon monoxide）, CO2 （carbon dioxide）, SP （suspended particulate） [3], VOC （volatile organic compounds）, benzene, lead Pb and cadmium. These emissions depend mainly on the technology of the vehicle （type, fuel, engine size, and age）, the vehicle speed, the engine temperature and ambient temperature [4].展开更多
To reduce carbon intensity, an improved management method balancing the reduction in costs and greenhouse gas(GHG)emissions is required for Tianjin's waste management system. Firstly, six objective functions, name...To reduce carbon intensity, an improved management method balancing the reduction in costs and greenhouse gas(GHG)emissions is required for Tianjin's waste management system. Firstly, six objective functions, namely, cost minimization, GHG minimization, eco-efficiency minimization, cost maximization, GHG maximization and eco-efficiency maximization, are built and subjected to the same constraints with each objective function corresponding to one scenario. Secondly, GHG emissions and costs are derived from the waste flow of each scenario. Thirdly, the range of GHG emissions and costs of other potential scenarios are obtained and plotted through adjusting waste flow with infinitely possible step sizes according to the correlation among the above six scenarios. And the optimal scenario is determined based on this range. The results suggest the following conclusions. 1) The scenarios located on the border between scenario cost minimization and GHG minimization create an optimum curve, and scenario GHG minimization has the smallest eco-efficiency on the curve; 2) Simple pursuit of eco-efficiency minimization using fractional programming may be unreasonable; 3) Balancing GHG emissions from incineration and landfills benefits Tianjin's waste management system as it reduces GHG emissions and costs.展开更多
The atmospheric mercury pollution in Beijing is a serious problem.Atmospheric mercury has three sources:natural emission,anthropogenic emission and previously deposited mercury reemission or recycling,composing elemen...The atmospheric mercury pollution in Beijing is a serious problem.Atmospheric mercury has three sources:natural emission,anthropogenic emission and previously deposited mercury reemission or recycling,composing elemental mercury,divalent mercury and particulate-phase mercury.Many studies showed that mercury in Beijing's air was higher than the general level of mercury concentration in the atmosphere.Mercury emission sources were discussed.Industrial emissions,coal burning,vehicle exhaust emissions and waste incineration were thought to be the main sources of atmospheric mercury pollution in Beijing.And also meteorology has an effect on atmospheric mercury concentration in Beijing.Measures have been taken to control the emission of mercury into the air in recent years.展开更多
This study defines and compares four scenarios for MSW （municipal solid waste） management： Scenario 1, unsorted waste taken to a landfill （baseline scenario）; Scenario 2, sorted waste used for home or communal co...This study defines and compares four scenarios for MSW （municipal solid waste） management： Scenario 1, unsorted waste taken to a landfill （baseline scenario）; Scenario 2, sorted waste used for home or communal composting; Scenario 3, sorted waste used for anaerobic digestion; and Scenario 4, sorted waste taken to a composting centre. The results of this study suggest that Scenario 1 would emit the highest levels of GHG （greenhouse gas） emissions, 692 x 103 tonnes CO2eq per year. Scenario 3 would have the lowest levels of GHG emissions, 195 x 103 tonnes CO2eq per year. Compared with the baseline scenario, it yields a 72% reduction of GHG emissions with a total savings of 498 ~ 103 tonnes CO2eq per year. The second-best option is Scenario 2, followed closely by Scenario 4, both yield 66.6% reductions with deviation by 0.03%. The deviation is due to transportation, which emission is negligibly small. The amounts of GHG savings for Scenario 2 and 4 are 461.3 ×10^3 tonnes CO2eq per year and 461×10^3 tonnes CO2eq per year, respectively It is evident from these results that anaerobic digestion has the highest potential for reducing GHG emissions.展开更多
文摘The gas-liquid phase equilibrium is used in controlling the nitrosation reaction process. Decomposition of nitrous acid and oxidation side reaction.are suppressed in a closed reaction system. The system pressure is used as the criterion of the end of reaction, avoiding excessive feeding and reducing＇the decomposition＇of nitrous acid. The head space of the reactor is used as the gas buffer, stabilizing the feeding fluctuations and inhibiting the side reaction, decomposition of nitrous acid. Nitrogen oxide concentration is controlled at the minimum level.Thus the zero release ofnitrogen ox!de waste gas can be achieved without using any absorption process.
基金Project 50574038 supported by the National Natural Science Foundation of China
文摘Targeting the problem of large amounts of gas emission from the goaf of the No.14201 working face in the Shaqu coal mine of Huajin Coking Coal Co. Ltd., we used a negative exponential function to describe the attenuation process of gas emission in goaf (the stable source) based on the principle of field flow. Equations of two-component flow (gas and air) and seep- age-diffusion in a heterogeneous goaf flow field are solved by means of numerical simulation and fluid mechanics principles of air movement and gas distribution during gas emission from goaf. The results indicate that the air diversion volume has a negative, exponential relation with the volume of gas emitted from goaf to the working face and is clearly inversely related to gas concentra- tion. We calculated the minimum amount of air diversion and distributed air volume in the tailing roadway required for safe pro- duction.
文摘The problem of climate change is a global challenge.It is closely associated with social development and human survival,and it has a significant impact to all countries on energy development,economic competitiveness,technological innovation,and way of life.In recent years,with the rapid economic development in China,there is a rumor that the rapid growth of China's carbon dioxide emission offset the efforts of the international community in reducing emissions,and China should bear the international responsibility corresponding to its significant role in greenhouse gas emission,which obviously are unfair and not objective.As this paper reveals,"China environment responsibility" that is the socalled "China environment threat" or theories,China has made a positive contribution to addressing the climate change in the past and China will still be the backbone on the protection of global climate in the future.
文摘The contribution of anthropogenic mineral aerosol dust has been of interest to understand the impact of dust aerosols on climate, and the health of workers occupational exposure. Several studies have been investigated the physical and chemical properties mainly in particulate matter. However, the characterizations have not extended diameters below to 1.0 μm. In this study, it described chemical composition and shape measurements of individual aerosol particles with 50% cut-off diameters less than 1.1 μm emitted at ceramic-tile manufacturing. Four emission sites of process were selected, and their samples were collected using a cascade-impactor, investigated using X-ray diffraction, energy dispersive X-ray spectroscopy, and digital image processing, where the data were analysed applying a combination of principal component and cluster analysis. Particles of tectosilicate （quartz, zeolite）, phyllosilicate （illite, montmorillonite）, and inosilicate （calcium silicate） were founded in all sampling sites; also, silicates mixed with transition metals oxides used as pigments （e.g., Fe, Ti, Co, Ni, Zn and Mo）. Silicates were granulated and flat crystals with a transparent, translucent appearance; otherwise, the mixture had flake shapes and opaque appearance. Analyses of multivariate data showed that the process stages emissions were related with specific composition and shape suggesting the use three measurements related （1） the internal axis, （2） roundness and （3） roughness to isolate particles shapes, and the presence of transition metals oxides as emissions tracer of the ceramic industry.
文摘In the Greater Casablanca, road transport is the second largest emissions source of gaseous pollutants and particles after the industry [ 1 ]. The emitters are mobile and include different categories of vehicles in circulation, in the road network of the region [2]. Air emissions from road transport considered in this study are the exhaust emissions from combustion of fuel during vehicle movement. This is mainly SO2 （sulfur dioxide）, NOx （nitrogen oxides）, CO （carbon monoxide）, CO2 （carbon dioxide）, SP （suspended particulate） [3], VOC （volatile organic compounds）, benzene, lead Pb and cadmium. These emissions depend mainly on the technology of the vehicle （type, fuel, engine size, and age）, the vehicle speed, the engine temperature and ambient temperature [4].
基金Project(51406133) supported by the National Natural Science Foundation of ChinaProject supported by the Scientific Research Foundation for the Returned Overseas,ChinaProject supported by Independent Innovation Fund of Tianjin University,China
文摘To reduce carbon intensity, an improved management method balancing the reduction in costs and greenhouse gas(GHG)emissions is required for Tianjin's waste management system. Firstly, six objective functions, namely, cost minimization, GHG minimization, eco-efficiency minimization, cost maximization, GHG maximization and eco-efficiency maximization, are built and subjected to the same constraints with each objective function corresponding to one scenario. Secondly, GHG emissions and costs are derived from the waste flow of each scenario. Thirdly, the range of GHG emissions and costs of other potential scenarios are obtained and plotted through adjusting waste flow with infinitely possible step sizes according to the correlation among the above six scenarios. And the optimal scenario is determined based on this range. The results suggest the following conclusions. 1) The scenarios located on the border between scenario cost minimization and GHG minimization create an optimum curve, and scenario GHG minimization has the smallest eco-efficiency on the curve; 2) Simple pursuit of eco-efficiency minimization using fractional programming may be unreasonable; 3) Balancing GHG emissions from incineration and landfills benefits Tianjin's waste management system as it reduces GHG emissions and costs.
文摘The atmospheric mercury pollution in Beijing is a serious problem.Atmospheric mercury has three sources:natural emission,anthropogenic emission and previously deposited mercury reemission or recycling,composing elemental mercury,divalent mercury and particulate-phase mercury.Many studies showed that mercury in Beijing's air was higher than the general level of mercury concentration in the atmosphere.Mercury emission sources were discussed.Industrial emissions,coal burning,vehicle exhaust emissions and waste incineration were thought to be the main sources of atmospheric mercury pollution in Beijing.And also meteorology has an effect on atmospheric mercury concentration in Beijing.Measures have been taken to control the emission of mercury into the air in recent years.
文摘This study defines and compares four scenarios for MSW （municipal solid waste） management： Scenario 1, unsorted waste taken to a landfill （baseline scenario）; Scenario 2, sorted waste used for home or communal composting; Scenario 3, sorted waste used for anaerobic digestion; and Scenario 4, sorted waste taken to a composting centre. The results of this study suggest that Scenario 1 would emit the highest levels of GHG （greenhouse gas） emissions, 692 x 103 tonnes CO2eq per year. Scenario 3 would have the lowest levels of GHG emissions, 195 x 103 tonnes CO2eq per year. Compared with the baseline scenario, it yields a 72% reduction of GHG emissions with a total savings of 498 ~ 103 tonnes CO2eq per year. The second-best option is Scenario 2, followed closely by Scenario 4, both yield 66.6% reductions with deviation by 0.03%. The deviation is due to transportation, which emission is negligibly small. The amounts of GHG savings for Scenario 2 and 4 are 461.3 ×10^3 tonnes CO2eq per year and 461×10^3 tonnes CO2eq per year, respectively It is evident from these results that anaerobic digestion has the highest potential for reducing GHG emissions.
