An engine cyclic variation model has been built by using the residual gas temperature for the n th cycle as the input of the model, through constant pressure intake process, adiabatic compression process, constan...An engine cyclic variation model has been built by using the residual gas temperature for the n th cycle as the input of the model, through constant pressure intake process, adiabatic compression process, constant volume combustion process, adiabatic expansion process, adiabatic blow down process and constant pressure exhaust process to approximate the thermodynamic processes in the cylinder, finally the residual gas temperature for the ( n+1) th cycle can be estimated. Because of the adding of engine operating parameters such as engine speed, spark advance, equivalence ratio, intake air pressure, intake air temperature to the model, effects of these parameters on cyclic variation can be estimated quantitatively. Since residual gas temperature fluctuation between cycles reflects the circumstances of engine cyclic variation, parameters to which residual gas temperature is sensitive are most likely used as the means to control cyclic variation. Model simulation shows that for the nearly stiochiometric mixture, cyclic variation is not obvious or even quite stable, but for the lean mixture, under the circumstances of partial load and larger spark advances, engine cyclic variations occur chaotically or with bifurcation.展开更多
Biodiesel is an excellent option for reducing dependence on fossil fuels with environmental advantages by reducing hazardous emissions. The enzymatic transesterification has attracted the attention of researchers in t...Biodiesel is an excellent option for reducing dependence on fossil fuels with environmental advantages by reducing hazardous emissions. The enzymatic transesterification has attracted the attention of researchers in the last decade and the advantages of enzymatic catalysis show that the production of biodiesel by this route has good potential, mainly because it is friendly environment. For biodiesel, production process by enzyme catalysis is chosen the response surface methodology. It is an experimental strategy to find the best operating conditions oftransesterification reaction to improve the biodiesel quality. The Process has three variables: temperature, molar ratio oil-alcohol and catalyst quantity. The process was monitored by GC-FID (gas chromatography with flame ionization detector). The yield of the transesterification reaction by enzymatic catalysis decreases with increasing temperature, and may be due to inactivation of the enzyme by denaturation at temperatures above 50 ℃. The second-order design used was the "CDC (central design composition)" which produced a maximum yield of 95.5% in the transesterification reaction by enzymatic catalysis obtained at a temperature of 45 ℃, molar ratio methanol:oil of 8:1 and a catalyst loading of 8% wt.展开更多
文摘An engine cyclic variation model has been built by using the residual gas temperature for the n th cycle as the input of the model, through constant pressure intake process, adiabatic compression process, constant volume combustion process, adiabatic expansion process, adiabatic blow down process and constant pressure exhaust process to approximate the thermodynamic processes in the cylinder, finally the residual gas temperature for the ( n+1) th cycle can be estimated. Because of the adding of engine operating parameters such as engine speed, spark advance, equivalence ratio, intake air pressure, intake air temperature to the model, effects of these parameters on cyclic variation can be estimated quantitatively. Since residual gas temperature fluctuation between cycles reflects the circumstances of engine cyclic variation, parameters to which residual gas temperature is sensitive are most likely used as the means to control cyclic variation. Model simulation shows that for the nearly stiochiometric mixture, cyclic variation is not obvious or even quite stable, but for the lean mixture, under the circumstances of partial load and larger spark advances, engine cyclic variations occur chaotically or with bifurcation.
文摘Biodiesel is an excellent option for reducing dependence on fossil fuels with environmental advantages by reducing hazardous emissions. The enzymatic transesterification has attracted the attention of researchers in the last decade and the advantages of enzymatic catalysis show that the production of biodiesel by this route has good potential, mainly because it is friendly environment. For biodiesel, production process by enzyme catalysis is chosen the response surface methodology. It is an experimental strategy to find the best operating conditions oftransesterification reaction to improve the biodiesel quality. The Process has three variables: temperature, molar ratio oil-alcohol and catalyst quantity. The process was monitored by GC-FID (gas chromatography with flame ionization detector). The yield of the transesterification reaction by enzymatic catalysis decreases with increasing temperature, and may be due to inactivation of the enzyme by denaturation at temperatures above 50 ℃. The second-order design used was the "CDC (central design composition)" which produced a maximum yield of 95.5% in the transesterification reaction by enzymatic catalysis obtained at a temperature of 45 ℃, molar ratio methanol:oil of 8:1 and a catalyst loading of 8% wt.