In-situ reactive compatibilization of high-density polyethylene （HDPE）/ground tire rubber （GTR） blends by dicumyl peroxide （DCP） and HY-2045 - a kind of thermoplastic phenolic resin without catalyst was inves...In-situ reactive compatibilization of high-density polyethylene （HDPE）/ground tire rubber （GTR） blends by dicumyl peroxide （DCP） and HY-2045 - a kind of thermoplastic phenolic resin without catalyst was investigated by studying the mor-phology, stress and strain behavior, dynamic mechanical properties and crystallization performance of the blends. Scanning e-lectron microscopy （SEM） results show that there are a lot of fibrous materials distributing in the interface, which connects the dispersed phase with the matrix and obtains better interfacial strength for prominent mechanical properties. The addition of compatibilizers results in the decrease of crystallinity of the blends and the disappearance of an obvious yield phenomenon, which was proved by the differential scanning calorimeter （DSC） test and X-ray diffraction （XRD） characterization Although the crystallinity of the blends decreases,the tensile strength and tensile strain of the blends significantly increases, especially for the HDPE/GTR/DCP/HY-2045 blends, which is possibly attributed to the good compatibility of the blends owing to the in-situ interface crosslinking. In addition, it is found that the compatibilizing HDPE/GTR blends shows a higher tan^ peak temperature and a broaden transition peak for GTR phase.展开更多
Aromatic oil has been used to promote the properties of crumb rubber modified asphalt which is an ideal method to deal with the resource utilization of waste rubber tires and by-product of refinery. Furfural extract o...Aromatic oil has been used to promote the properties of crumb rubber modified asphalt which is an ideal method to deal with the resource utilization of waste rubber tires and by-product of refinery. Furfural extract oil(FEO) was separated into the light fraction and the heavy fraction. Swelling and dissolution process of natural rubber sheet in these three oil samples was investigated to shed light on the interaction mechanism. Crumb rubber also interacted on FEO and asphalt respectively. Energy dispersive spectrometer(EDS), thermo-gravimetric analysis(TGA) and scanning electron microscope(SEM) were used to characterize the chemical and structural properties of processed rubber. The chemical composition of processed oils and asphalt was investigated by using the hydrocarbon group analysis(SARA) and gel permeation chromatography. The results revealed that the swelling rate and mass loss of rubber in oils were much higher than those in asphalt and rose with an increasing processing temperature. The heavy fraction of FEO had more diffusion and dissolving capability than the light fraction, whilst compatibility was observed between the heavy fraction and the light fraction. Selective absorption was not observed in the study and detachment of dissolved rubber was disseminated from the outside to the inside. The cross-linking degree of the residue rubber was unchanged with the processing time, and sulfur predominantly remained in the undissolved rubber. Dissolution of crumbed rubber in oils was attributed to devulcanization, while that in the asphalt was mainly attributed to depolymerization.展开更多
Within a context of sustainable development, innovative processes for various applications to recycle rubber are put in place to make aggregates or crumb rubber. These uses include sports floor coverings, to manufactu...Within a context of sustainable development, innovative processes for various applications to recycle rubber are put in place to make aggregates or crumb rubber. These uses include sports floor coverings, to manufacture of sealants, sound absorbing walls, to make roads, as an alternative fuel in cement kilns, etc. In this study, the addition of crumb rubber to mortar was investigated through optical and mechanical tests. The results showed that the incorporation of crumb rubber from used tires into mortar produced a better resistance to shrinkage cracking, but a compressive strength/tensile is reduced. This feature could lend itself to making playgrounds and sports grounds more absorbing and flexible, which would allow a more significant fall to be withstood without injury and consequently enhance the safety of playgrounds.展开更多
Investigation of seismic performance of buildings with STRP （scrap tire rubber pad） seismic isolators by means of pseudo-dynamic tests and numerical simulation is presented. The isolated building is numerically mode...Investigation of seismic performance of buildings with STRP （scrap tire rubber pad） seismic isolators by means of pseudo-dynamic tests and numerical simulation is presented. The isolated building is numerically modeled, while the base isolation layer is considered as the experimental substructure in the pseudo-dynamic tests. The test result verifies that the STRP isolator shows acceptable shear deformation performance predicted by the design methods, and demonstrated that seismic isolation using STRP works as a protective measure to provide enhanced seismic performance of the building indicated by the reduction of top floor absolute acceleration, drift and base shear as designated.展开更多
The research considered urgent ecological reasons linked to environment such as worn tires, the waste tire rubber＇s powder was collected from the tire cars repair shops （passed from the sieve No 18 μm）, and used t...The research considered urgent ecological reasons linked to environment such as worn tires, the waste tire rubber＇s powder was collected from the tire cars repair shops （passed from the sieve No 18 μm）, and used to improve the asphalt concrete properties. Raw materials used were prepared and tested. Varies of asphalt concrete mixtures were prepared with different ratios of bitumen （5, 5.5, 6, 6.5, 7% % of concrete weight）. The Marshall mix design method was used to determine optimum conditions for bitumen in asphalt concrete with specific weight, stability and flow Test, the optimum amount of bitumen was 6.1% of whole asphalt concrete. The different percentages of waste tire rubber powder （0.0, 0.05, 0.10, 0.15% of bitumen weight） were added in optimum bitumen of asphalt concretes, then specific weight and Marshall test were evaluated. These asphalt-rubber mixtures were found to act quite differently from traditional, unmodified asphalt mixtures. However, these results indicate that improved pavement performance can be achieved with asphalt-rubber binder.展开更多
文摘In-situ reactive compatibilization of high-density polyethylene （HDPE）/ground tire rubber （GTR） blends by dicumyl peroxide （DCP） and HY-2045 - a kind of thermoplastic phenolic resin without catalyst was investigated by studying the mor-phology, stress and strain behavior, dynamic mechanical properties and crystallization performance of the blends. Scanning e-lectron microscopy （SEM） results show that there are a lot of fibrous materials distributing in the interface, which connects the dispersed phase with the matrix and obtains better interfacial strength for prominent mechanical properties. The addition of compatibilizers results in the decrease of crystallinity of the blends and the disappearance of an obvious yield phenomenon, which was proved by the differential scanning calorimeter （DSC） test and X-ray diffraction （XRD） characterization Although the crystallinity of the blends decreases,the tensile strength and tensile strain of the blends significantly increases, especially for the HDPE/GTR/DCP/HY-2045 blends, which is possibly attributed to the good compatibility of the blends owing to the in-situ interface crosslinking. In addition, it is found that the compatibilizing HDPE/GTR blends shows a higher tan^ peak temperature and a broaden transition peak for GTR phase.
文摘Aromatic oil has been used to promote the properties of crumb rubber modified asphalt which is an ideal method to deal with the resource utilization of waste rubber tires and by-product of refinery. Furfural extract oil(FEO) was separated into the light fraction and the heavy fraction. Swelling and dissolution process of natural rubber sheet in these three oil samples was investigated to shed light on the interaction mechanism. Crumb rubber also interacted on FEO and asphalt respectively. Energy dispersive spectrometer(EDS), thermo-gravimetric analysis(TGA) and scanning electron microscope(SEM) were used to characterize the chemical and structural properties of processed rubber. The chemical composition of processed oils and asphalt was investigated by using the hydrocarbon group analysis(SARA) and gel permeation chromatography. The results revealed that the swelling rate and mass loss of rubber in oils were much higher than those in asphalt and rose with an increasing processing temperature. The heavy fraction of FEO had more diffusion and dissolving capability than the light fraction, whilst compatibility was observed between the heavy fraction and the light fraction. Selective absorption was not observed in the study and detachment of dissolved rubber was disseminated from the outside to the inside. The cross-linking degree of the residue rubber was unchanged with the processing time, and sulfur predominantly remained in the undissolved rubber. Dissolution of crumbed rubber in oils was attributed to devulcanization, while that in the asphalt was mainly attributed to depolymerization.
文摘Within a context of sustainable development, innovative processes for various applications to recycle rubber are put in place to make aggregates or crumb rubber. These uses include sports floor coverings, to manufacture of sealants, sound absorbing walls, to make roads, as an alternative fuel in cement kilns, etc. In this study, the addition of crumb rubber to mortar was investigated through optical and mechanical tests. The results showed that the incorporation of crumb rubber from used tires into mortar produced a better resistance to shrinkage cracking, but a compressive strength/tensile is reduced. This feature could lend itself to making playgrounds and sports grounds more absorbing and flexible, which would allow a more significant fall to be withstood without injury and consequently enhance the safety of playgrounds.
文摘Investigation of seismic performance of buildings with STRP （scrap tire rubber pad） seismic isolators by means of pseudo-dynamic tests and numerical simulation is presented. The isolated building is numerically modeled, while the base isolation layer is considered as the experimental substructure in the pseudo-dynamic tests. The test result verifies that the STRP isolator shows acceptable shear deformation performance predicted by the design methods, and demonstrated that seismic isolation using STRP works as a protective measure to provide enhanced seismic performance of the building indicated by the reduction of top floor absolute acceleration, drift and base shear as designated.
文摘The research considered urgent ecological reasons linked to environment such as worn tires, the waste tire rubber＇s powder was collected from the tire cars repair shops （passed from the sieve No 18 μm）, and used to improve the asphalt concrete properties. Raw materials used were prepared and tested. Varies of asphalt concrete mixtures were prepared with different ratios of bitumen （5, 5.5, 6, 6.5, 7% % of concrete weight）. The Marshall mix design method was used to determine optimum conditions for bitumen in asphalt concrete with specific weight, stability and flow Test, the optimum amount of bitumen was 6.1% of whole asphalt concrete. The different percentages of waste tire rubber powder （0.0, 0.05, 0.10, 0.15% of bitumen weight） were added in optimum bitumen of asphalt concretes, then specific weight and Marshall test were evaluated. These asphalt-rubber mixtures were found to act quite differently from traditional, unmodified asphalt mixtures. However, these results indicate that improved pavement performance can be achieved with asphalt-rubber binder.
