The copper based catalysts, CuO/T-Al2O3, CuO/y-Al2O3-cordierite (Cord) and CuO/Cord, were prepared by impregnation method. The catalytic activity of the catalysts was tested in absence and presence of water vapor,an...The copper based catalysts, CuO/T-Al2O3, CuO/y-Al2O3-cordierite (Cord) and CuO/Cord, were prepared by impregnation method. The catalytic activity of the catalysts was tested in absence and presence of water vapor,and the catalysts were characterized. Temperature program desorption (TPD) experiments or toluene and water on the catalysts were carried out. The influence of water vapor on the activity of the catalysts was discussed. Results showed that addition of the water vapor has a significant negative effect on the catalytic activity of the catalysts.The higher the concentration of the Water vapor in feed steam was, the lower the catalytic activity of the copper based catalysts became, which could be mainly ascribed to the competition of water molecules with toluene molecules for adsorption on the catalyst surfaces. TPD experiments showed that the strength of the interaction between water molecules and three catalysts followed the order: CuO/γ-Al2O3〉CuO/γ-Al2O3-Cord〉CuO/Cord. As a consequence of that, the degree of degradation in the catalytic activity of these three catalysts by the water vapor followed the order: CuO/γ-Al2O3〉CuO/y-Al2O3-Cord〉CuO/Cord. However, the negative effect of the water vapor was reversible.展开更多
Overlay networks have emerged as a useful approach to providing a general framework for new applications and services that are to be implemented without significantly changing the IP-layer network infrastructure.Overl...Overlay networks have emerged as a useful approach to providing a general framework for new applications and services that are to be implemented without significantly changing the IP-layer network infrastructure.Overlay routing has been used as an alternative to the default best effort Internet routing for the absence of end-to-end Quality of Service(QoS). While the former has recently been investigated, the conflict of QoS restraints and resource optimization remains unsolved. Recent studies have shown that overlay paths can give better latency, loss rate and TCP throughput. In this paper, a multi-dimensional QoS objective model based on the analysis of multiple QoS constraints has been presented, and a routing algorithm to optimise the overlay resource of its nodes and links is then proposed.In fact, the algorithm obtained multiple QoS values using probability theory to achieve the routing according to the multi-dimensional QoS objective vector of the QoS objective model. Simulation results reveals that the algorithm works better than other existing algorithms in balancing the network resources, and applications with stringent QoS requirements could be run.展开更多
It has been more than half a century since the release of the first Shimadzu UV-VIS (UV-visible) spectrophotometer QB-50 in 1952, and during this time more than 160,000 UV-VIS spectrometers have been produced and in...It has been more than half a century since the release of the first Shimadzu UV-VIS (UV-visible) spectrophotometer QB-50 in 1952, and during this time more than 160,000 UV-VIS spectrometers have been produced and installed in a wide variety of different applications. A lot of technical innovations have been implemented to improve the performance and significantly reduce the stray light levels. The latest innovation during development of sophisticated spectrophotometers is based on a new holographic exposure method and optimized etching process which has made it possible to produce both high-efficient and exceptionally low stray light gratings. These LO-RAY-LIGH~ gratings have guaranteed values of stray light at the intermediate position between zero-order and first-order lights. The values are measured by Shimadzu's laser stray-light-measuring system. The latest development in the series of UV-VIS spectrophotometers is the UV-2700 which is a true double beam double monochromator system in a compact design for high-precision spectral analysis of a wide range of samples including organic and inorganic compounds, biological samples, optical materials and photovoltaics. The high performance optical system is designed with "LO-RAY-LIGH" diffraction gratings, featuring highest efficiency and exceptionally low stray light. The spectrophotometer operates in the wavelength range from 185 nm to 900 nm and allows highly sophisticated applications such as direct measurement of high density samples up to 8 absorbance units without dilution.展开更多
The corrective machining to compensate the resulting errors is usually tried at plural times based on the trial-and-error process when the machining is realized in die and mold manufacturing. This corrective machining...The corrective machining to compensate the resulting errors is usually tried at plural times based on the trial-and-error process when the machining is realized in die and mold manufacturing. This corrective machining has an influence on accuracy and efficiency and is an important factor. The measurement system for measuring the forms of die and mold at all times is essential in order to machine the die and mold with high accuracy and efficiency. However, the problems of management and operation errors are found in compensating process of die and mold machining. In this paper, an online machining and measurement system in die and mold manufacturing is developed in order to overcome these problems. In this online system, 2-axis control system is added to a surface roughness measuring instrument, and both NC machining program and measured data are linked and controlled using a same computer. Therefore, the machining and measurement can be recognized for consistent process, and can be realized on the machine. This system has the advantages such as the high accuracy, low-price, and online convenience and so on. The possibility of practical use of this online system was investigated by fundamental experiments.展开更多
Automatic signature generation approaches have been widely applied in recent traffic classification.However,they are not suitable for LightWeight Deep Packet Inspection(LW_DPI) since their generated signatures are mat...Automatic signature generation approaches have been widely applied in recent traffic classification.However,they are not suitable for LightWeight Deep Packet Inspection(LW_DPI) since their generated signatures are matched through a search of the entire application data.On the basis of LW_DPI schemes,we present two Hierarchical Clustering(HC) algorithms:HC_TCP and HC_UDP,which can generate byte signatures from TCP and UDP packet payloads respectively.In particular,HC_TCP and HC_ UDP can extract the positions of byte signatures in packet payloads.Further,in order to deal with the case in which byte signatures cannot be derived,we develop an algorithm for generating bit signatures.Compared with the LASER algorithm and Suffix Tree(ST)-based algorithm,the proposed algorithms are better in terms of both classification accuracy and speed.Moreover,the experimental results indicate that,as long as the application-protocol header exists,it is possible to automatically derive reliable and accurate signatures combined with their positions in packet payloads.展开更多
Quantifying the functional relationships relating river discharge and weathering products places key constraints on the negative feedback between the silicate weathering and climate. In this study we analyze the conce...Quantifying the functional relationships relating river discharge and weathering products places key constraints on the negative feedback between the silicate weathering and climate. In this study we analyze the concentration–discharge relationships of weathering products from global rivers using previously compiled time-series datasets for concentrations and discharge from global rivers. To analyze the nature of the covariation between specific discharge and concentrations, we use both a power law equation and a recently developed solute production equation. The solute production equation allows us to quantify weathering efficiency, or the resistance to dilution at high runoff, via the Damkohler coefficient. These results are also compared to those derived using average concentration–discharge pairs.Both the power law exponent and the Damkohler coefficient increase and asymptote as catchments exhibit increasingly chemostatic behavior, resulting in an inverse relationship between the two parameters. We also show that using thedistribution of average concentration–discharge pairs from global rivers, rather than fitting concentration–discharge relationships for each individual river, underestimates global median weathering efficiency by up to a factor of ~10. This study demonstrates the utility of long time-series sampling of global rivers to elucidate controlling processes needed to quantify patterns in global silicate weathering rates.展开更多
There are two fundamental goals in statistical learning: identifying relevant predictors and ensuring high prediction accuracy. The first goal, by means of variable selection, is of particular importance when the tru...There are two fundamental goals in statistical learning: identifying relevant predictors and ensuring high prediction accuracy. The first goal, by means of variable selection, is of particular importance when the true underlying model has a sparse representation. Discovering relevant predictors can enhance the performance of the prediction for the fitted model. Usually an estimate is considered desirable if it is consistent in terms of both coefficient estimate and variable selection. Hence, before we try to estimate the regression coefficients β , it is preferable that we have a set of useful predictors m hand. The emphasis of our task in this paper is to propose a method, in the aim of identifying relevant predictors to ensure screening consistency in variable selection. The primary interest is on Orthogonal Matching Pursuit(OMP).展开更多
In order to prevent soil erosion in southern China,a study was performed to determine the drivers of sediment concentration variation using simulated rainfall and four soil management systems under field condition.Fou...In order to prevent soil erosion in southern China,a study was performed to determine the drivers of sediment concentration variation using simulated rainfall and four soil management systems under field condition.Four soil management systems,i.e.,forest and grass coverage(FG),forest coverage with disturbed soil surface(FD),contour tillage(CT) and downslope tillage(DT),were exposed to two rainfall intensities(40 and 54 mm h-1) using a portable rainfall simulator.The drivers of sediment concentration variation were determined by the variations of runoff rate and sediment concentration as well as their relationships.The effects of the four soil management systems in preventing water and soil losses were compared using runoff rates and sediment concentrations at steady state.At runoff initial stage,sediment concentration variation was mainly driven by rainfall and management.The degree of sediment concentration variation driven by flow varied with different soil management systems.Three best relationships between runoff rate and sediment concentration were identified,i.e.,reciprocal(CT),quadratic(FG and FD) and exponential(DT).At steady state,runoff rates of the four soil management systems varied slightly,whereas their sediment concentrations varied greatly.FG and CT were recommended as the best soil management systems for preventing water and soil losses.展开更多
The issue of navigation using binary pulsars is investigated in this paper.We show how the effect of the binary motion is incorporated in the navigation measurement equation.Necessary reference systems and time scales...The issue of navigation using binary pulsars is investigated in this paper.We show how the effect of the binary motion is incorporated in the navigation measurement equation.Necessary reference systems and time scales are introduced and the transformation between different time scales is derived.Based mainly on Damour and Deruelle's binary model and the TEMPO2 software,the timing model resolving the time delay from emission to arrival is established with the solar system,interstellar and binary system delays included,which retains all the terms exceeding 1 ns.The navigation measurement equation is thus built and the parameters needed are listed.A comparison is made between Sheikh's measurement equation and that in this paper.It is found that it is not necessary to introduce a fictitious SSB arrival time as Sheikh does.Near-Earth navigation for the Keplerian orbit in the case of observing one pulsar is investigated.The uncertainties of the orbit parameters are derived using the least square fitting method,which reveals that observing one pulsar enables one to navigate near-Earth spacecraft.展开更多
The geometric flow theory and its applications turned into one of the most intensively developing branches of modern geometry. Here, a brief introduction to Finslerian Ricci flow and their self-similar solutions known...The geometric flow theory and its applications turned into one of the most intensively developing branches of modern geometry. Here, a brief introduction to Finslerian Ricci flow and their self-similar solutions known as Ricci solitons are given and some recent results are presented. They are a generalization of Einstein metrics and are previously developed by the present authors for Finsler manifolds. In the present work, it is shown that a complete shrinking Ricci soliton Finsler manifold has a finite fundamental group.展开更多
Energy harvesting is an appealing technology that makes use of the ambient energy which is otherwise wasted. Piezoelectric materials directly convert the elastic energy to the electric energy, and thus have a great ad...Energy harvesting is an appealing technology that makes use of the ambient energy which is otherwise wasted. Piezoelectric materials directly convert the elastic energy to the electric energy, and thus have a great advantage in scavenging vibrational energy for simplicity in device structure with relatively high power density. This paper provides an overview on the research of piezoelectric materials in energy harvesting in recent decades, from basics of piezoelectricity and working principle of energy harvesting with piezoelectric materials, to the progress of development of high-performance piezoelectrics including ceramics, single crystals and polymers, then to experimental attempts on the device fabrication and optimization, finally to perspective applications of piezoelectric energy harvesting(PEH). The criteria for selection of materials for PEH applications are introduced. Not only the figure of merit but also maximum allowable stress of materials are taken into account in the evaluation of their potential in achieving high energy density and output power density. The influence of the device configuration on the performance is also acknowledged and discussed. The magnitude and distribution of induced stress in the piezoelectric unit upon excitation by the vibration source play an important role in determining the output power density and can be tuned via proper design of device configuration without changing its resonant frequency. Approaches to address the issue of frequency match accompanying with the resonant mode are illustrated with literature examples. Usage of PEH devices can be extended to a variety of vibration sources in everyday life as well as in nature. Some appealing applications of PEH, such as in implantable and wearable devices, are reviewed.展开更多
基金Supported by the National-Natural Science Foundation of China (20936001), the Natural Science Foundation of Guangdong Province, and the State Key Lab of Subtropical Building Science, South China University of Technology (x2yj C709028Z).
文摘The copper based catalysts, CuO/T-Al2O3, CuO/y-Al2O3-cordierite (Cord) and CuO/Cord, were prepared by impregnation method. The catalytic activity of the catalysts was tested in absence and presence of water vapor,and the catalysts were characterized. Temperature program desorption (TPD) experiments or toluene and water on the catalysts were carried out. The influence of water vapor on the activity of the catalysts was discussed. Results showed that addition of the water vapor has a significant negative effect on the catalytic activity of the catalysts.The higher the concentration of the Water vapor in feed steam was, the lower the catalytic activity of the copper based catalysts became, which could be mainly ascribed to the competition of water molecules with toluene molecules for adsorption on the catalyst surfaces. TPD experiments showed that the strength of the interaction between water molecules and three catalysts followed the order: CuO/γ-Al2O3〉CuO/γ-Al2O3-Cord〉CuO/Cord. As a consequence of that, the degree of degradation in the catalytic activity of these three catalysts by the water vapor followed the order: CuO/γ-Al2O3〉CuO/y-Al2O3-Cord〉CuO/Cord. However, the negative effect of the water vapor was reversible.
基金supported by the National Natural Science Foundation of China under Grant No.61071126the National Science and Technology Major Projects of New Generation Broadband Wireless Mobile Communication Network under Grants No.2010ZX0300400201,No.2010ZX03003-001,No.2010ZX03004-001-01,No.2011ZX03002-001-02
文摘Overlay networks have emerged as a useful approach to providing a general framework for new applications and services that are to be implemented without significantly changing the IP-layer network infrastructure.Overlay routing has been used as an alternative to the default best effort Internet routing for the absence of end-to-end Quality of Service(QoS). While the former has recently been investigated, the conflict of QoS restraints and resource optimization remains unsolved. Recent studies have shown that overlay paths can give better latency, loss rate and TCP throughput. In this paper, a multi-dimensional QoS objective model based on the analysis of multiple QoS constraints has been presented, and a routing algorithm to optimise the overlay resource of its nodes and links is then proposed.In fact, the algorithm obtained multiple QoS values using probability theory to achieve the routing according to the multi-dimensional QoS objective vector of the QoS objective model. Simulation results reveals that the algorithm works better than other existing algorithms in balancing the network resources, and applications with stringent QoS requirements could be run.
文摘It has been more than half a century since the release of the first Shimadzu UV-VIS (UV-visible) spectrophotometer QB-50 in 1952, and during this time more than 160,000 UV-VIS spectrometers have been produced and installed in a wide variety of different applications. A lot of technical innovations have been implemented to improve the performance and significantly reduce the stray light levels. The latest innovation during development of sophisticated spectrophotometers is based on a new holographic exposure method and optimized etching process which has made it possible to produce both high-efficient and exceptionally low stray light gratings. These LO-RAY-LIGH~ gratings have guaranteed values of stray light at the intermediate position between zero-order and first-order lights. The values are measured by Shimadzu's laser stray-light-measuring system. The latest development in the series of UV-VIS spectrophotometers is the UV-2700 which is a true double beam double monochromator system in a compact design for high-precision spectral analysis of a wide range of samples including organic and inorganic compounds, biological samples, optical materials and photovoltaics. The high performance optical system is designed with "LO-RAY-LIGH" diffraction gratings, featuring highest efficiency and exceptionally low stray light. The spectrophotometer operates in the wavelength range from 185 nm to 900 nm and allows highly sophisticated applications such as direct measurement of high density samples up to 8 absorbance units without dilution.
文摘The corrective machining to compensate the resulting errors is usually tried at plural times based on the trial-and-error process when the machining is realized in die and mold manufacturing. This corrective machining has an influence on accuracy and efficiency and is an important factor. The measurement system for measuring the forms of die and mold at all times is essential in order to machine the die and mold with high accuracy and efficiency. However, the problems of management and operation errors are found in compensating process of die and mold machining. In this paper, an online machining and measurement system in die and mold manufacturing is developed in order to overcome these problems. In this online system, 2-axis control system is added to a surface roughness measuring instrument, and both NC machining program and measured data are linked and controlled using a same computer. Therefore, the machining and measurement can be recognized for consistent process, and can be realized on the machine. This system has the advantages such as the high accuracy, low-price, and online convenience and so on. The possibility of practical use of this online system was investigated by fundamental experiments.
基金supported by the National Key Basic Research Program of China (973 Program) under Grant No. 2011CB302605the National High Technical Research and Development Program of China (863 Program) underGrants No. 2010AA012504,No. 2011AA010705+1 种基金the National Natural Science Foundation of China under Grant No. 60903166the National Science and Technology Support Program under Grants No. 2012BAH37B00,No. 2012-BAH37B01
文摘Automatic signature generation approaches have been widely applied in recent traffic classification.However,they are not suitable for LightWeight Deep Packet Inspection(LW_DPI) since their generated signatures are matched through a search of the entire application data.On the basis of LW_DPI schemes,we present two Hierarchical Clustering(HC) algorithms:HC_TCP and HC_UDP,which can generate byte signatures from TCP and UDP packet payloads respectively.In particular,HC_TCP and HC_ UDP can extract the positions of byte signatures in packet payloads.Further,in order to deal with the case in which byte signatures cannot be derived,we develop an algorithm for generating bit signatures.Compared with the LASER algorithm and Suffix Tree(ST)-based algorithm,the proposed algorithms are better in terms of both classification accuracy and speed.Moreover,the experimental results indicate that,as long as the application-protocol header exists,it is possible to automatically derive reliable and accurate signatures combined with their positions in packet payloads.
基金supported by a Stanford EDGE-STEM Fellowshipinitiated under NSF EAR-1254156 to Kate Maher and was also supported by the California Alliance Research Exchange NSF HRD-1306595 to C.Page Chamberlain
文摘Quantifying the functional relationships relating river discharge and weathering products places key constraints on the negative feedback between the silicate weathering and climate. In this study we analyze the concentration–discharge relationships of weathering products from global rivers using previously compiled time-series datasets for concentrations and discharge from global rivers. To analyze the nature of the covariation between specific discharge and concentrations, we use both a power law equation and a recently developed solute production equation. The solute production equation allows us to quantify weathering efficiency, or the resistance to dilution at high runoff, via the Damkohler coefficient. These results are also compared to those derived using average concentration–discharge pairs.Both the power law exponent and the Damkohler coefficient increase and asymptote as catchments exhibit increasingly chemostatic behavior, resulting in an inverse relationship between the two parameters. We also show that using thedistribution of average concentration–discharge pairs from global rivers, rather than fitting concentration–discharge relationships for each individual river, underestimates global median weathering efficiency by up to a factor of ~10. This study demonstrates the utility of long time-series sampling of global rivers to elucidate controlling processes needed to quantify patterns in global silicate weathering rates.
文摘There are two fundamental goals in statistical learning: identifying relevant predictors and ensuring high prediction accuracy. The first goal, by means of variable selection, is of particular importance when the true underlying model has a sparse representation. Discovering relevant predictors can enhance the performance of the prediction for the fitted model. Usually an estimate is considered desirable if it is consistent in terms of both coefficient estimate and variable selection. Hence, before we try to estimate the regression coefficients β , it is preferable that we have a set of useful predictors m hand. The emphasis of our task in this paper is to propose a method, in the aim of identifying relevant predictors to ensure screening consistency in variable selection. The primary interest is on Orthogonal Matching Pursuit(OMP).
基金Supported by the National Basic Research Program of China(No.2007CB407206)the National Natural Science Foundation of China(No.40621001)the Frontier Project of the Chinese Academy of Sciences(No.ISSASIP0715)
文摘In order to prevent soil erosion in southern China,a study was performed to determine the drivers of sediment concentration variation using simulated rainfall and four soil management systems under field condition.Four soil management systems,i.e.,forest and grass coverage(FG),forest coverage with disturbed soil surface(FD),contour tillage(CT) and downslope tillage(DT),were exposed to two rainfall intensities(40 and 54 mm h-1) using a portable rainfall simulator.The drivers of sediment concentration variation were determined by the variations of runoff rate and sediment concentration as well as their relationships.The effects of the four soil management systems in preventing water and soil losses were compared using runoff rates and sediment concentrations at steady state.At runoff initial stage,sediment concentration variation was mainly driven by rainfall and management.The degree of sediment concentration variation driven by flow varied with different soil management systems.Three best relationships between runoff rate and sediment concentration were identified,i.e.,reciprocal(CT),quadratic(FG and FD) and exponential(DT).At steady state,runoff rates of the four soil management systems varied slightly,whereas their sediment concentrations varied greatly.FG and CT were recommended as the best soil management systems for preventing water and soil losses.
基金supported by the National Natural Science Foundation of China (Grant No. 41074023)
文摘The issue of navigation using binary pulsars is investigated in this paper.We show how the effect of the binary motion is incorporated in the navigation measurement equation.Necessary reference systems and time scales are introduced and the transformation between different time scales is derived.Based mainly on Damour and Deruelle's binary model and the TEMPO2 software,the timing model resolving the time delay from emission to arrival is established with the solar system,interstellar and binary system delays included,which retains all the terms exceeding 1 ns.The navigation measurement equation is thus built and the parameters needed are listed.A comparison is made between Sheikh's measurement equation and that in this paper.It is found that it is not necessary to introduce a fictitious SSB arrival time as Sheikh does.Near-Earth navigation for the Keplerian orbit in the case of observing one pulsar is investigated.The uncertainties of the orbit parameters are derived using the least square fitting method,which reveals that observing one pulsar enables one to navigate near-Earth spacecraft.
文摘The geometric flow theory and its applications turned into one of the most intensively developing branches of modern geometry. Here, a brief introduction to Finslerian Ricci flow and their self-similar solutions known as Ricci solitons are given and some recent results are presented. They are a generalization of Einstein metrics and are previously developed by the present authors for Finsler manifolds. In the present work, it is shown that a complete shrinking Ricci soliton Finsler manifold has a finite fundamental group.
基金supported by the National Natural Science Foundation of China(Grant No.51302143)Shenzhen Special Fund for the Development of Emerging Industries(Grant No.JCYJ20140417115840233)Shenzhen Peacock Plan(Grant No.KQCX20140521161756228)
文摘Energy harvesting is an appealing technology that makes use of the ambient energy which is otherwise wasted. Piezoelectric materials directly convert the elastic energy to the electric energy, and thus have a great advantage in scavenging vibrational energy for simplicity in device structure with relatively high power density. This paper provides an overview on the research of piezoelectric materials in energy harvesting in recent decades, from basics of piezoelectricity and working principle of energy harvesting with piezoelectric materials, to the progress of development of high-performance piezoelectrics including ceramics, single crystals and polymers, then to experimental attempts on the device fabrication and optimization, finally to perspective applications of piezoelectric energy harvesting(PEH). The criteria for selection of materials for PEH applications are introduced. Not only the figure of merit but also maximum allowable stress of materials are taken into account in the evaluation of their potential in achieving high energy density and output power density. The influence of the device configuration on the performance is also acknowledged and discussed. The magnitude and distribution of induced stress in the piezoelectric unit upon excitation by the vibration source play an important role in determining the output power density and can be tuned via proper design of device configuration without changing its resonant frequency. Approaches to address the issue of frequency match accompanying with the resonant mode are illustrated with literature examples. Usage of PEH devices can be extended to a variety of vibration sources in everyday life as well as in nature. Some appealing applications of PEH, such as in implantable and wearable devices, are reviewed.