This paper puts forward a rigorous approach for a sensitivity analysis of stochastic user equilibrium with the elastic demand (SUEED) model. First, proof is given for the existence of derivatives of output variables...This paper puts forward a rigorous approach for a sensitivity analysis of stochastic user equilibrium with the elastic demand (SUEED) model. First, proof is given for the existence of derivatives of output variables with respect to the perturbation parameters for the SUEED model. Then by taking advantage of the gradient-based method for sensitivity analysis of a general nonlinear program, detailed formulae are developed for calculating the derivatives of designed variables with respect to perturbation parameters at the equilibrium state of the SUEED model. This method is not only applicable for a sensitivity analysis of the logit-type SUEED problem, but also for the probit-type SUEED problem. The application of the proposed method in a numerical example shows that the proposed method can be used to approximate the equilibrium link flow solutions for both logit-type SUEED and probit-type SUEED problems when small perturbations are introduced in the input parameters.展开更多
The possibility of underground imbalance between heat emission and absorption has a negative impact on the performance of ground-source heat pump systems (GSHPs). Numerical and experimental researches were made in a...The possibility of underground imbalance between heat emission and absorption has a negative impact on the performance of ground-source heat pump systems (GSHPs). Numerical and experimental researches were made in a residential building, which is supplied with a GSHP system and a ceiling radiation system combined with a replacement fresh air system. EnergyPlus simulations were used to estimate heating and cooling loads, and to assess the heat generated from the water pump, the fan and the heat pump unit. Then, Fluent simulations were used to compare three different control strategies of handling the underground heat exchange. These simulations were strongly based on an experimentally verified model. It is obtained that a ratio between cooling and heating loads is 5.08 : 1 in a case study in Nanjing. Moreover, the control strategy based on the starting time is more efficient and reliable than the temperature and temperature difference strategies to control the underground heat exchange.展开更多
Because the normal operation of the engine is located near the equilibrium manifold, the method of equilibrium mani fold nonlinear dynamic modeling is adopted for turbofan engine more than the local train modeling. Th...Because the normal operation of the engine is located near the equilibrium manifold, the method of equilibrium mani fold nonlinear dynamic modeling is adopted for turbofan engine more than the local train modeling. The method studies the sys tem characteristics near the equilibrium manifold. The modeling method can be realized through dynamic and static twostep, and for the specific parameter modeling steps and algorithm are given. The output of the test data is compared with the model output through numerical simulation, to check the model with an additional set of test data. The simulation results show that the model has reached the requirements of engineering accuracy.展开更多
Thickeners are important units for water recovery in various industries. In this study, a semi-industrial pilot plant thickener similar to the tailing thickener of the Sarcheshmeh Copper Mine was simulated by CFD mode...Thickeners are important units for water recovery in various industries. In this study, a semi-industrial pilot plant thickener similar to the tailing thickener of the Sarcheshmeh Copper Mine was simulated by CFD modeling. The population balance was used to describe the particle aggregation and breakup. In this population balance, 15 particle sizes categories were considered. The Eulerian-Eulerian approach with standard k-e turbulence model was applied to describe two phases of slurry flow in the thickener under steady-state condition. The simulation results have been compared with the experimental measurements to validate the accuracy of the CFD modeling. After checking the numerical results, the effect of important parameters such as, feed flow rate, solid percentage in the feed, and solid particle size on the thickener performance was studied. The thickener residence time distribution were obtained by the modeling and also compared with the experimental data. Finally, the effects of feedwell feeding on the average diameter of aggregate and turbulent intensity were evaluated.展开更多
A reservoir landslide not only reduces the water storage capacity, but also causes extensive damages to the dam body, power/water transmission lines, roads, and other infrastructures. The Latian Dam, located 35 km nor...A reservoir landslide not only reduces the water storage capacity, but also causes extensive damages to the dam body, power/water transmission lines, roads, and other infrastructures. The Latian Dam, located 35 km north east of Tehran (Iran), is one of the cases which has encountered serious problems with instability of its rock abutments. This paper addresses the stability analysis of the right abutment of the Latian Dam using limit equilibrium and numerical methods. Geomechanical characteristics of the rock abutment were first estimated based on engineering classification of the rock mass. Different search methods were examined for locating the critical circular/non-circular slip surface in conjunction with the general limit equilibrium method. The effect of variabi]ity of rock mass properties, water table, and earthquake load on the factor of safety (FS) and probability of failure (PF) was studied. In the event of rapid drawdown in the reservoir, the limit equilibrium analysis calculated FS=1.067 and PF=21.1%, and the numerical analysis returned FS=1.01. The results of the analyses suggest that the right abutment of the Latian Dam is prone to slide and needs treatment. Investigations demonstrated that a slope reduction by 15° at the upper part of the abutment would meet stability conditions even in the worst-case scenario (FS=1.297 and PF=2.07%).展开更多
Vapor-liquid equilibrium(VLE) data were measured for ternary system water + ethanol + 1-butyl-3methylimidazolium acetate([bmim][OAc]),in a relatively wide range of ionic liquid(IL) mass fractions up to 0.8.Six sets of...Vapor-liquid equilibrium(VLE) data were measured for ternary system water + ethanol + 1-butyl-3methylimidazolium acetate([bmim][OAc]),in a relatively wide range of ionic liquid(IL) mass fractions up to 0.8.Six sets of complete T-x-y data were obtained,in which the mole fraction of ethanol on IL-free basis was fixed separately at 0.1,0.2,0.4,0.6,0.8,and approximate 0.98.The non-random-two-liquid(NRTL) and electrolyte non-random-two-liquid(eNRTL) equations were used for correlation,showing similar deviations.The ternary VLE was also modeled with the correlation from two data sets,with the mole fractions of ethanol on IL-free basis being 0.1 and approximate 0.98.The VLE data were also reproduced satisfactorily.With the eNRTL model,the root-mean-square deviation for temperature is 0.79 K and that for vapor-phase mole fraction is 0.0094.The calculations are in good agreement with experimental data.The effect of the IL on the VLE behavior of the volatile components is also illustrated.展开更多
The paper addresses the identity construction in social organizations whose primary role is to define their singularity against other organizations and have them take on this singular role in the minds of its related ...The paper addresses the identity construction in social organizations whose primary role is to define their singularity against other organizations and have them take on this singular role in the minds of its related audiences. This construction is carried out in the course of the organizational existence and it is reflected in the image that it depicts. Those two elements are essential values to be handled by promotional communication through its several channels, means, and products. The aim of the study is to discuss the importance of corporate identity and image in the promotional communication of an organization. Bibliographical research and a case study were both used as methodologies. We have found the need to cultivate a positive image for the consolidation of the future of the organization including the contribution to the economic development of the country.展开更多
In order to deal with modeling problem of a pressure balance system with time-delay, nonlinear, time-varying and uncertain characteristics, an intelligent modeling procedure is proposed, which is based on artificial n...In order to deal with modeling problem of a pressure balance system with time-delay, nonlinear, time-varying and uncertain characteristics, an intelligent modeling procedure is proposed, which is based on artificial neural network(ANN) and input-output data of the system during shield tunneling and can overcome the precision problem in mechanistic modeling(MM) approach. The computational results show that the training algorithm with Gauss-Newton optimization has fast convergent speed. The experimental investigation indicates that, compared with mechanistic modeling approach, intelligent modeling procedure can obviously increase the precision in both soil pressure fitting and forecasting period. The effectiveness and accuracy of proposed intelligent modeling procedure are verified in laboratory tests.展开更多
The macro modeling and the solution of traffic flow with road width were investigated.Firstly,a new macro model with the consideration of road width was proposed.Secondly,the effects of road width on uniform flow and ...The macro modeling and the solution of traffic flow with road width were investigated.Firstly,a new macro model with the consideration of road width was proposed.Secondly,the effects of road width on uniform flow and small perturbation were studied.The analytical and numerical results show that widening (shrinking) road can enhance (reduce) the equilibrium speed and flow,and the increments (decrements) will increase with the absolute value of road width gradient.In addition,the numerical results illustrate that the new model can describe the effects of road width on the evolutions of uniform flow and small perturbation.展开更多
Wave transmission and overtopping around nearshore breakwaters can have significant influence on the transmitted wave parameters,which affects wave conditions and sediment transportation and becomes the focus of desig...Wave transmission and overtopping around nearshore breakwaters can have significant influence on the transmitted wave parameters,which affects wave conditions and sediment transportation and becomes the focus of design in engineering.The objective of this paper is to present a simplified model to estimate these important wave parameters.This paper describes the incorporation of wave transmission and overtopping module into a wave model for multi-directional random wave transformation based on energy balance equation with the consideration of wave shoaling,refraction,diffraction,reflection and breaking.Wen's frequency spectrum and non-linear dispersion relation are also included in this model.The influence of wave parameters of transmitted waves through a smooth submerged breakwater has been considered in this model with an improved description of the transmitted wave spectrum of van der Meer et al.(2000) by Carevic et al.(2013).This improved wave model has been validated through available laboratory experiments.Then the verified model is applied to investigate the effect of wave transmission and overtopping on wave heights behind low-crested breakwaters in a project for nearshore area.Numerical calculations are carried out with and without consideration of the wave transmission and overtopping,and comparison of them indicates that there is a considerable difference in wave height and thus it is important to include wave transmission and overtopping in modelling nearshore wave field with the presence of low-crested breakwaters.Therefore,this model can provide a general estimate of the desired wave field parameters,which is adequate for engineers at the preliminary design stage of low-crested breakwaters.展开更多
Up to now, reuse and recycling of existing buildings have not been examined widely. This paper discusses the theories, methods and practicalities of buildings' end of life with a main focus on planning and managing r...Up to now, reuse and recycling of existing buildings have not been examined widely. This paper discusses the theories, methods and practicalities of buildings' end of life with a main focus on planning and managing reuse and recycling of existing buildings. Our aim is the realistic modelling of theoretical scenarios for end of life based on a case study. The methods of building survey, material classification and documentation for reuse, recycling and disposal of existing constructions are presented. Investigations and calculations were done on an existing cottage in the Alps. The ecologically most beneficial disposal phase of the old wooden hut is our main objective. Critical questions arise from the quality of the material and how it can be extracted, separated and balanced in an appropriate way. A systematic survey of the building by inspection of constructions and materials in iterative steps allows a detailed material balance with condition and property information. This information is crucial for scenarios and material flow analysis of demolished and rebuilt building in environmental system analysis. For future planning, the reuse and recycling of existing buildings should be integrated quite early in the planning process so that we can use the materials in the best way.展开更多
Demographic transitions occur at different times and speed across different economies, and age structures consequently differ across regions. Using a solvable four-phase model, we show that economies with a higher pro...Demographic transitions occur at different times and speed across different economies, and age structures consequently differ across regions. Using a solvable four-phase model, we show that economies with a higher proportion of working-age force and a lower dependency ratio tend to have higher savings rates. Because the demographic " center of gravity"for investment demand falls at a younger point in the age distribution than that of savings supply, countries with a younger age-distribution like those described above generate national savings in excess of domestic investment, resulting in a current account surplus. Numerical simulation supports this hypothesis. But the relative youth or age of a country's population reflects temporary demographic trends which change continuously. Therefore, while trade imbalances caused by demographic factors are structural and long-term, they are not permanent, and may be reversed by changes in age structure.展开更多
Kinetics of adsorption of furfural from aqueous solution on zeolite: ZSM-5 (Zeolite Socony Mobil-5), surface have been studied at room temperature. For evaluation of adsorption properties and mechanism, the adsorpt...Kinetics of adsorption of furfural from aqueous solution on zeolite: ZSM-5 (Zeolite Socony Mobil-5), surface have been studied at room temperature. For evaluation of adsorption properties and mechanism, the adsorption isotherms have been described. Adsorption data have been fitted by the models Langmuir, Freundlich, BET (Brunauer-Emmett-Teller), Redlich-Peterson, T6th and Dubinin-Radushkevitch. Adsorption capacity of zeolite for furfural in the studied range of concentrations (0-100 mmol/L) is found to reach 60 mg/g. The Langmuir and BET models are found to be the best for experimental data description with Re= 0.9959 and 0.9994, respectively. The Dubinin-Radushkevitch model has been used for determination of the equation constants. The latter has been applied further for calculation of energy of adsorption of furfural on zeolite ZSM-5, which is equal to 11 kJ/mol, indicating the chemical nature of adsorption interaction. The kinetics data have been modeled using pseudo-first-order and pseudo-second-order models. The kinetic sorption offered rather good fit with pseudo-second-order model with the Re value of 0.9821. The rate-limiting step is found to be intraparticle diffusion. Zeolite ZSM-5 is convenient sorbent for furfural uptake within the tested concentration range.展开更多
In order to realize an optimal balance between the efficiency and reliability requirements ofroad models,a road modeling method for digital maps based on cardinal spline is studied.First,the cardinal spline is chosen ...In order to realize an optimal balance between the efficiency and reliability requirements ofroad models,a road modeling method for digital maps based on cardinal spline is studied.First,the cardinal spline is chosen to establish an initial road model,which is specified by a series of control points and tension parameters.Then,in view of the initial road model,a gradual optimization algorithm,which can determine the reasonable control points and optimal tension parameters according to the degree of the change of road curvature,is proposed to determine the final road model.Finally,the proposed road modeling method is verified a d evaluated through experiments,and it is compared with the conventional method for digital maps based on the B-spline.The results show that the proposed method can resize a neaoptimal balance between the efficiency and reliability requirements.Compared with the conventional method based on the B-spline,this method occupies less data storage and achieves higher accuracy.展开更多
The vapor-liquid equilibrium of binary mixtures of propyl acetate, butyl acetate and isobutyl acetate with meth- anol has been determined at a constant pressure of 0.6 MPa. Results have been modeled with the Peng-Robi...The vapor-liquid equilibrium of binary mixtures of propyl acetate, butyl acetate and isobutyl acetate with meth- anol has been determined at a constant pressure of 0.6 MPa. Results have been modeled with the Peng-Robinson equation, a traditional cubic equation of state widely employed in chemical industries, as well as with the perturbed-chain statistical associating fluid PC-SAFT theory of Gross-Sadowski. By correlation of the binary inter- action parameters of these equations, the measured vapor-liquid equilibrium data can be accurately predicted. Thus, this work shows that these models are able to represent the experimental data for systems with associating comoounds via hydrogen bonding.展开更多
基金The Scientific Innovation Research of College Graduates in Jiangsu Province(No.CXLX13_110)the Young Scientists Fund of National Natural Science Foundation of China(No.51408253)the Young Scientists Fund of Huaiyin Institute of Technology(No.491713328)
文摘This paper puts forward a rigorous approach for a sensitivity analysis of stochastic user equilibrium with the elastic demand (SUEED) model. First, proof is given for the existence of derivatives of output variables with respect to the perturbation parameters for the SUEED model. Then by taking advantage of the gradient-based method for sensitivity analysis of a general nonlinear program, detailed formulae are developed for calculating the derivatives of designed variables with respect to perturbation parameters at the equilibrium state of the SUEED model. This method is not only applicable for a sensitivity analysis of the logit-type SUEED problem, but also for the probit-type SUEED problem. The application of the proposed method in a numerical example shows that the proposed method can be used to approximate the equilibrium link flow solutions for both logit-type SUEED and probit-type SUEED problems when small perturbations are introduced in the input parameters.
文摘The possibility of underground imbalance between heat emission and absorption has a negative impact on the performance of ground-source heat pump systems (GSHPs). Numerical and experimental researches were made in a residential building, which is supplied with a GSHP system and a ceiling radiation system combined with a replacement fresh air system. EnergyPlus simulations were used to estimate heating and cooling loads, and to assess the heat generated from the water pump, the fan and the heat pump unit. Then, Fluent simulations were used to compare three different control strategies of handling the underground heat exchange. These simulations were strongly based on an experimentally verified model. It is obtained that a ratio between cooling and heating loads is 5.08 : 1 in a case study in Nanjing. Moreover, the control strategy based on the starting time is more efficient and reliable than the temperature and temperature difference strategies to control the underground heat exchange.
文摘Because the normal operation of the engine is located near the equilibrium manifold, the method of equilibrium mani fold nonlinear dynamic modeling is adopted for turbofan engine more than the local train modeling. The method studies the sys tem characteristics near the equilibrium manifold. The modeling method can be realized through dynamic and static twostep, and for the specific parameter modeling steps and algorithm are given. The output of the test data is compared with the model output through numerical simulation, to check the model with an additional set of test data. The simulation results show that the model has reached the requirements of engineering accuracy.
文摘Thickeners are important units for water recovery in various industries. In this study, a semi-industrial pilot plant thickener similar to the tailing thickener of the Sarcheshmeh Copper Mine was simulated by CFD modeling. The population balance was used to describe the particle aggregation and breakup. In this population balance, 15 particle sizes categories were considered. The Eulerian-Eulerian approach with standard k-e turbulence model was applied to describe two phases of slurry flow in the thickener under steady-state condition. The simulation results have been compared with the experimental measurements to validate the accuracy of the CFD modeling. After checking the numerical results, the effect of important parameters such as, feed flow rate, solid percentage in the feed, and solid particle size on the thickener performance was studied. The thickener residence time distribution were obtained by the modeling and also compared with the experimental data. Finally, the effects of feedwell feeding on the average diameter of aggregate and turbulent intensity were evaluated.
文摘A reservoir landslide not only reduces the water storage capacity, but also causes extensive damages to the dam body, power/water transmission lines, roads, and other infrastructures. The Latian Dam, located 35 km north east of Tehran (Iran), is one of the cases which has encountered serious problems with instability of its rock abutments. This paper addresses the stability analysis of the right abutment of the Latian Dam using limit equilibrium and numerical methods. Geomechanical characteristics of the rock abutment were first estimated based on engineering classification of the rock mass. Different search methods were examined for locating the critical circular/non-circular slip surface in conjunction with the general limit equilibrium method. The effect of variabi]ity of rock mass properties, water table, and earthquake load on the factor of safety (FS) and probability of failure (PF) was studied. In the event of rapid drawdown in the reservoir, the limit equilibrium analysis calculated FS=1.067 and PF=21.1%, and the numerical analysis returned FS=1.01. The results of the analyses suggest that the right abutment of the Latian Dam is prone to slide and needs treatment. Investigations demonstrated that a slope reduction by 15° at the upper part of the abutment would meet stability conditions even in the worst-case scenario (FS=1.297 and PF=2.07%).
基金Supported by the National Natural Science Foundation of China (20776132)
文摘Vapor-liquid equilibrium(VLE) data were measured for ternary system water + ethanol + 1-butyl-3methylimidazolium acetate([bmim][OAc]),in a relatively wide range of ionic liquid(IL) mass fractions up to 0.8.Six sets of complete T-x-y data were obtained,in which the mole fraction of ethanol on IL-free basis was fixed separately at 0.1,0.2,0.4,0.6,0.8,and approximate 0.98.The non-random-two-liquid(NRTL) and electrolyte non-random-two-liquid(eNRTL) equations were used for correlation,showing similar deviations.The ternary VLE was also modeled with the correlation from two data sets,with the mole fractions of ethanol on IL-free basis being 0.1 and approximate 0.98.The VLE data were also reproduced satisfactorily.With the eNRTL model,the root-mean-square deviation for temperature is 0.79 K and that for vapor-phase mole fraction is 0.0094.The calculations are in good agreement with experimental data.The effect of the IL on the VLE behavior of the volatile components is also illustrated.
文摘The paper addresses the identity construction in social organizations whose primary role is to define their singularity against other organizations and have them take on this singular role in the minds of its related audiences. This construction is carried out in the course of the organizational existence and it is reflected in the image that it depicts. Those two elements are essential values to be handled by promotional communication through its several channels, means, and products. The aim of the study is to discuss the importance of corporate identity and image in the promotional communication of an organization. Bibliographical research and a case study were both used as methodologies. We have found the need to cultivate a positive image for the consolidation of the future of the organization including the contribution to the economic development of the country.
基金Project(2013CB035402) supported by the National Basic Research Program of ChinaProjects(51105048,51209028) supported by the National Natural Science Foundation of China
文摘In order to deal with modeling problem of a pressure balance system with time-delay, nonlinear, time-varying and uncertain characteristics, an intelligent modeling procedure is proposed, which is based on artificial neural network(ANN) and input-output data of the system during shield tunneling and can overcome the precision problem in mechanistic modeling(MM) approach. The computational results show that the training algorithm with Gauss-Newton optimization has fast convergent speed. The experimental investigation indicates that, compared with mechanistic modeling approach, intelligent modeling procedure can obviously increase the precision in both soil pressure fitting and forecasting period. The effectiveness and accuracy of proposed intelligent modeling procedure are verified in laboratory tests.
基金Project(NCET-08-0038) supported by the Program for New Century Excellent Talents in Chinese UniversityProjects(70701002,70971007 and 70521001) supported by the National Natural Science Foundation of ChinaProject(2006CB705503) supported by the National Basic Research Program of China
文摘The macro modeling and the solution of traffic flow with road width were investigated.Firstly,a new macro model with the consideration of road width was proposed.Secondly,the effects of road width on uniform flow and small perturbation were studied.The analytical and numerical results show that widening (shrinking) road can enhance (reduce) the equilibrium speed and flow,and the increments (decrements) will increase with the absolute value of road width gradient.In addition,the numerical results illustrate that the new model can describe the effects of road width on the evolutions of uniform flow and small perturbation.
基金supported by the NSFC-Shandong Joint Fund Project(No.U1706226)Research Award Fund for Outstanding Young and Middle-aged Scientists of Shandong Province(No.ZR2016EEB06)the Scientific Research Foundation of Shandong University of Science and Technology for Recruited Talents
文摘Wave transmission and overtopping around nearshore breakwaters can have significant influence on the transmitted wave parameters,which affects wave conditions and sediment transportation and becomes the focus of design in engineering.The objective of this paper is to present a simplified model to estimate these important wave parameters.This paper describes the incorporation of wave transmission and overtopping module into a wave model for multi-directional random wave transformation based on energy balance equation with the consideration of wave shoaling,refraction,diffraction,reflection and breaking.Wen's frequency spectrum and non-linear dispersion relation are also included in this model.The influence of wave parameters of transmitted waves through a smooth submerged breakwater has been considered in this model with an improved description of the transmitted wave spectrum of van der Meer et al.(2000) by Carevic et al.(2013).This improved wave model has been validated through available laboratory experiments.Then the verified model is applied to investigate the effect of wave transmission and overtopping on wave heights behind low-crested breakwaters in a project for nearshore area.Numerical calculations are carried out with and without consideration of the wave transmission and overtopping,and comparison of them indicates that there is a considerable difference in wave height and thus it is important to include wave transmission and overtopping in modelling nearshore wave field with the presence of low-crested breakwaters.Therefore,this model can provide a general estimate of the desired wave field parameters,which is adequate for engineers at the preliminary design stage of low-crested breakwaters.
文摘Up to now, reuse and recycling of existing buildings have not been examined widely. This paper discusses the theories, methods and practicalities of buildings' end of life with a main focus on planning and managing reuse and recycling of existing buildings. Our aim is the realistic modelling of theoretical scenarios for end of life based on a case study. The methods of building survey, material classification and documentation for reuse, recycling and disposal of existing constructions are presented. Investigations and calculations were done on an existing cottage in the Alps. The ecologically most beneficial disposal phase of the old wooden hut is our main objective. Critical questions arise from the quality of the material and how it can be extracted, separated and balanced in an appropriate way. A systematic survey of the building by inspection of constructions and materials in iterative steps allows a detailed material balance with condition and property information. This information is crucial for scenarios and material flow analysis of demolished and rebuilt building in environmental system analysis. For future planning, the reuse and recycling of existing buildings should be integrated quite early in the planning process so that we can use the materials in the best way.
基金This research is supported by: National Social Science Foundation " Study on China's imbalanced foreign trade from the perspective of intra-product specialization" (10BJY079).
文摘Demographic transitions occur at different times and speed across different economies, and age structures consequently differ across regions. Using a solvable four-phase model, we show that economies with a higher proportion of working-age force and a lower dependency ratio tend to have higher savings rates. Because the demographic " center of gravity"for investment demand falls at a younger point in the age distribution than that of savings supply, countries with a younger age-distribution like those described above generate national savings in excess of domestic investment, resulting in a current account surplus. Numerical simulation supports this hypothesis. But the relative youth or age of a country's population reflects temporary demographic trends which change continuously. Therefore, while trade imbalances caused by demographic factors are structural and long-term, they are not permanent, and may be reversed by changes in age structure.
文摘Kinetics of adsorption of furfural from aqueous solution on zeolite: ZSM-5 (Zeolite Socony Mobil-5), surface have been studied at room temperature. For evaluation of adsorption properties and mechanism, the adsorption isotherms have been described. Adsorption data have been fitted by the models Langmuir, Freundlich, BET (Brunauer-Emmett-Teller), Redlich-Peterson, T6th and Dubinin-Radushkevitch. Adsorption capacity of zeolite for furfural in the studied range of concentrations (0-100 mmol/L) is found to reach 60 mg/g. The Langmuir and BET models are found to be the best for experimental data description with Re= 0.9959 and 0.9994, respectively. The Dubinin-Radushkevitch model has been used for determination of the equation constants. The latter has been applied further for calculation of energy of adsorption of furfural on zeolite ZSM-5, which is equal to 11 kJ/mol, indicating the chemical nature of adsorption interaction. The kinetics data have been modeled using pseudo-first-order and pseudo-second-order models. The kinetic sorption offered rather good fit with pseudo-second-order model with the Re value of 0.9821. The rate-limiting step is found to be intraparticle diffusion. Zeolite ZSM-5 is convenient sorbent for furfural uptake within the tested concentration range.
基金The National Natural Science Foundation of China(No.61273236)the National Key Research and Development Plan of China(No.2016YFC0802706,2017YFC0804804)+1 种基金the Program for Special Talents in Six Major Fields of Jiangsu Province(No.2017JXQC-003)the Project of Beijing Municipal Science and Technology Commission(No.Z161100001416001)
文摘In order to realize an optimal balance between the efficiency and reliability requirements ofroad models,a road modeling method for digital maps based on cardinal spline is studied.First,the cardinal spline is chosen to establish an initial road model,which is specified by a series of control points and tension parameters.Then,in view of the initial road model,a gradual optimization algorithm,which can determine the reasonable control points and optimal tension parameters according to the degree of the change of road curvature,is proposed to determine the final road model.Finally,the proposed road modeling method is verified a d evaluated through experiments,and it is compared with the conventional method for digital maps based on the B-spline.The results show that the proposed method can resize a neaoptimal balance between the efficiency and reliability requirements.Compared with the conventional method based on the B-spline,this method occupies less data storage and achieves higher accuracy.
文摘The vapor-liquid equilibrium of binary mixtures of propyl acetate, butyl acetate and isobutyl acetate with meth- anol has been determined at a constant pressure of 0.6 MPa. Results have been modeled with the Peng-Robinson equation, a traditional cubic equation of state widely employed in chemical industries, as well as with the perturbed-chain statistical associating fluid PC-SAFT theory of Gross-Sadowski. By correlation of the binary inter- action parameters of these equations, the measured vapor-liquid equilibrium data can be accurately predicted. Thus, this work shows that these models are able to represent the experimental data for systems with associating comoounds via hydrogen bonding.