舆论危机的异化极化效应研究

随着Web2.0时代的到来,网络媒体逐渐成为舆论生成、传播和交锋的主阵地,舆论危机的形成及其异化也成为日益突出的社会风险问题.本文以舆论的异化演化机理为研究对象,通过梳理典型事件舆论话题的异化过程,对其基本内涵、表现形式和演化模式等进行系统总结.随后,研究以舆论超网络模型为基础,借鉴社会影响理论的基本原则,提出舆论异化机理的极化算法,并对其具体流程进行解析和实现.最后,本文以"7·23甬温动车事故"为例,对舆论危机的异化极化过程和影响因素进行系统仿真和实证分析.

对腐败问题中权力因素的政治学思考

腐败现象的本质特征是公共权力的腐败,因此,从政治学的角度出发,搞清国家公务人员手中权力的性质和权力的异化机理,建立切实可行的权力制约机制,是卓有成效地开展反腐败斗争所首先要明确的问题。

Carbcations Chemistry： β-Methyl Shift--A New Rearrangement of the Carbcations Bridged Alicyclic Hydrocarbons

Results of researches on study of the kinetics and isomerization mechanism of the alkyladamantanes in the presence of the heterogeneous catalysts of the acid type are considered as detection and experimental proof of a new intramolecular rearrangement of the carbcations bridged alicyclic hydrocarbons--2,4-moving of the methyl groups （β-methyl shift）. The proof of realization of such rearrangement is direct and primary formation 1,4-dimethyladamantane from 1,2-dimethyladamatane, passing a formation stage of the thermodynamic much stable 1,3-dimethyladamantane; direct formation 1,3,6-trimethyladamantane from 1,3,4-trimethyladamantane, excepting a formation stage 1,3.5-trimethyladamantane, and also other isomers which formation is impossible to explain by means of known 1,2-methyl shift （a-methyl shift）.

Sulfur-doped g-C3N4/TiO2 S-scheme heterojunction photocatalyst for Congo Red photodegradation

Constructing step-scheme(S-scheme)heterojunctions has been confirmed as a promising strategy for enhancing the photocatalytic activity of composite materials.In this work,a series of sulfur-doped g-C3N4(SCN)/TiO2 S-scheme photocatalysts were synthesized using electrospinning and calcination methods.The as-prepared SCN/TiO2 composites showed superior photocatalytic performance than pure TiO2 and SCN in the photocatalytic degradation of Congo Red(CR)aqueous solution.The significant enhancement in photocatalytic activity benefited not only from the 1D well-distributed nanostructure,but also from the S-scheme heterojunction.Furthermore,the XPS analyses and DFT calculations demonstrated that electrons were transferred from SCN to TiO2 across the interface of the SCN/TiO2 composites.The built-in electric field,band edge bending,and Coulomb interaction synergistically facilitated the recombination of relatively useless electrons and holes in hybrid when the interface was irradiated by simulated solar light.Therefore,the remaining electrons and holes with higher reducibility and oxidizability endowed the composite with supreme redox ability.These results were adequately verified by radical trapping experiments,ESR tests,and in situ XPS analyses,suggesting that the electron immigration in the photocatalyst followed the S-scheme heterojunction mechanism.This work can enrich our knowledge of the design and fabrication of novel S-scheme heterojunction photocatalysts and provide a promising strategy for solving environmental pollution in the future.

食品安全治理中的声誉异化及其法律规制

基于繁重的执法负荷与稀缺的执法资源,我国当前食品安全治理未能取得预期目标绩效,亟待改进治理模式。声誉机制作为社会共治的重要载体之一,有助于促使消费者"用脚投票",借助抵制交易惩罚违法违规企业,具有较好的威慑效应。然而,如不对声誉机制加以法律规制,其经由消费者的认知—心理基础、扩散—连带机制、社会建构—强化过程,容易导致惩罚过度和惩罚错误之弊。因此,应当借助公法规制与私法救济并举、行政法律责任和民事法律责任共存的复合模式,确保声誉惩罚指向准确、宽严有度,既优化其威慑功能又维护企业合法权益,促进食品安全治理中的社会共治有序发展。

Three-dimensional ordered macroporous g-C_(3)N_(4)-Cu_(2)O-TiO_(2) heterojunction for enhanced hydrogen production

In this study,a g-C_(3)N_(4)-Cu_(2)O-TiO_(2) photocatalyst with a novel three-dimensional ordered macroporous(3DOM)structure was successfully prepared using a sacrificial template strategy and a photodeposition method.The influence of the special porous structure with cross pore channels on the photocatalytic properties of the as-prepared sample was studied in detail.Compared with the original photocatalyst(TiO_(2) with 3 wt%Pt),g-C_(3)N_(4)-Cu_(2)O-TiO_(2) exhibited a higher specific surface area and more active sites,thus accelerating the separation efficiency of the photogenerated electron-hole pair.Consequently,the as-prepared photocatalyst showed good photocatalytic performance,reaching a maximum hydrogen production rate of 12,108μmol g^(-1) h^(-1) and approximately five times higher than that of the pristine comparison sample.The enhanced photoactivity of the g-C_(3)N_(4)-Cu_(2)O-TiO_(2) heterojunction can be ascribed to its double p-n heterojunction and robust porous structure,where the photodeposited Cu_(2)O plays a synergistic catalytic role in the photocatalytic process and the outer clad g-C_(3)N_(4) layer prevents Cu_(2)O oxidation.Additionally,the possible photocatalytic mechanism was briefly discussed based on the experimental results.This work identifies viable pathways for developing low-cost heterojunction photocatalysts with highly efficient photocatalytic activity toward improved solar energy conversion.

In Situ Dissimilatory Nitrate Reduction to Ammonium in a Paddy Soil Fertilized with Liquid Cattle Waste

Most studies on dissimilatory nitrate reduction to ammonium （DNRA） in paddy soils were conducted in the laboratory and in situ studies are in need for better understanding of the DNRA process. In this study, in situ incubations of soil DNRA using ^15N tracer were carried out in paddy fields under conventional water （CW） and low water （LW） managements to explore the potential of soil DNRA after liquid cattle waste （LCW） application and to investigate the impacts of soil redox potential （Eh） and labile carbon on DNRA. DNRA rates ranged from 3.06 to 10.40 mg N kg 1 dry soil d-1, which accounted for 8.55%-12.36% and 3.88% 25.44% of consumption of added NO3-^15N when Eh at 5 cm soil depth ranged from 230 to 414 mV and -225 to -65 mV, respectively. DNRA rates showed no significant difference in paddy soils under two water managements although soil Eh and/or dissolved organic carbon （DOC） were more favorable for DNRA in the paddy soil under CW management 1 d before, or 5 and 7 d after LCW application. Soil DNRA rates were negatively correlated with soil Eh （P 〈 0.05, n = 5） but positively correlated with soil DOC （P 〈 0.05, n - 5） in the paddy soil under LW management, while no significant correlations were shown in the paddy soil under CW management. The potential of DNRA measured in situ was consistent with previous laboratory studies; and the controlling factors of DNRA in paddy soils might be different under different water managements, probably due to the presence of different microfioras of DNRA.