Nickel(Ni)-based materials act as one of the most promising candidates as platinum-group-metal-free(PGM-free)electrocatalysts for hydrogen oxidation reaction(HOR)in alkaline solution.Nevertheless,the electrocatalytic ...Nickel(Ni)-based materials act as one of the most promising candidates as platinum-group-metal-free(PGM-free)electrocatalysts for hydrogen oxidation reaction(HOR)in alkaline solution.Nevertheless,the electrocatalytic activity of pure Ni is significantly limited due to the sluggish kinetics under alkaline condition.To accelerate the kinetics,constructing heterostructures and nitride structures have been developed as two representative strategies.Here,we combined the two methods and presented a facile synthesis of the sheet-like Ni_(3)N/MoO_(2)in-plane heterostructures for enhanced HOR in alkaline electrolytes.Relative to Ni or Ni_(3)N,the Ni_(3)N/MoO_(2)in-plane heterostructures exhibited a significantly increased mass activity by 8.6-fold or 4.4-fold,respectively.Mechanistic studies revealed that the enhanced activity of Ni_(3)N/MoO_(2)could be attributed to the weakened hydrogen adsorption and strengthened hydroxyl adsorption.This work provides a facile approach to design high-efficiency catalysts for hydrogen-oxidation catalysis and beyond.展开更多
The key technologies involved in the evolution of the Cloud-based Radio Access Network(C-RAN) are discussed in this paper. Taking the Frameless Network Architecture(FNA) as a starting point, a cell-lessbased network t...The key technologies involved in the evolution of the Cloud-based Radio Access Network(C-RAN) are discussed in this paper. Taking the Frameless Network Architecture(FNA) as a starting point, a cell-lessbased network topology for a multi-tier Heterogeneous Network(Het Net) and ultra-dense network is proposed. The FNA network topology modeling is researched with centralized processing and distributed antenna deployments. The Antenna Element(AE) is released as a new dimensional radio resource that is included in the centralized Radio Resource Management(RRM) processes. This contributes to the on-demand user-centric serving-set associations with cell-edge effect elimination. The Control Plane(CP) and User Plane(UP) separation and adaptation are introduced for energy efficiency improvements. The centralized RRM and different optimization goals are discussed for fully exploring the merits from the centralized computing of C-RAN. Considering the complexity, near-optimal approaches for specific users' Quality-of-Service(Qo S) requirements are addressed. Finally, based on the research highlighted above, the way forward of C-RAN evolution is discussed.展开更多
The reliable information about interface energetics of organic materials, especially the energy level alignment at organic heterostructures is of pronounced importance for unraveling the photon harvesting and charge s...The reliable information about interface energetics of organic materials, especially the energy level alignment at organic heterostructures is of pronounced importance for unraveling the photon harvesting and charge separation process in organic photovoltaic(OPV) cells. This article provides an overview of interface energetics at typical planar and mixed donor-acceptor heterostructures, perovskite/organic hybrid interfaces, and their contact interfaces with charge collection layers. The substrate effect on energy level offsets at organic heterostructures and the processes that control and limit the OPV operation are presented. Recent efforts on interface engineering with electrical doping are also discussed.展开更多
文摘Nickel(Ni)-based materials act as one of the most promising candidates as platinum-group-metal-free(PGM-free)electrocatalysts for hydrogen oxidation reaction(HOR)in alkaline solution.Nevertheless,the electrocatalytic activity of pure Ni is significantly limited due to the sluggish kinetics under alkaline condition.To accelerate the kinetics,constructing heterostructures and nitride structures have been developed as two representative strategies.Here,we combined the two methods and presented a facile synthesis of the sheet-like Ni_(3)N/MoO_(2)in-plane heterostructures for enhanced HOR in alkaline electrolytes.Relative to Ni or Ni_(3)N,the Ni_(3)N/MoO_(2)in-plane heterostructures exhibited a significantly increased mass activity by 8.6-fold or 4.4-fold,respectively.Mechanistic studies revealed that the enhanced activity of Ni_(3)N/MoO_(2)could be attributed to the weakened hydrogen adsorption and strengthened hydroxyl adsorption.This work provides a facile approach to design high-efficiency catalysts for hydrogen-oxidation catalysis and beyond.
基金supported by the National High Technology Research and Development Program of China No.2014AA01A701Nature and Science Foundation of China under Grants No.61471068,61421061+2 种基金Beijing Nova Programme No.Z131101000413030International Collaboration Project No.2015DFT10160National Major Project No.2016ZX03001009-003
文摘The key technologies involved in the evolution of the Cloud-based Radio Access Network(C-RAN) are discussed in this paper. Taking the Frameless Network Architecture(FNA) as a starting point, a cell-lessbased network topology for a multi-tier Heterogeneous Network(Het Net) and ultra-dense network is proposed. The FNA network topology modeling is researched with centralized processing and distributed antenna deployments. The Antenna Element(AE) is released as a new dimensional radio resource that is included in the centralized Radio Resource Management(RRM) processes. This contributes to the on-demand user-centric serving-set associations with cell-edge effect elimination. The Control Plane(CP) and User Plane(UP) separation and adaptation are introduced for energy efficiency improvements. The centralized RRM and different optimization goals are discussed for fully exploring the merits from the centralized computing of C-RAN. Considering the complexity, near-optimal approaches for specific users' Quality-of-Service(Qo S) requirements are addressed. Finally, based on the research highlighted above, the way forward of C-RAN evolution is discussed.
基金supported by the National Basic Research Program of China (2014CB932600)the National Natural Science Foundation of China (91433116, 11474214)+2 种基金Jiangsu Science and Technology Department (BK20140053)Bureau of Science and Technology of Suzhou Municipality (SYG201525, ZXG201422)the project of the Priority Academic Program Development (PAPD) of Jiangsu Higher Education Institutions
文摘The reliable information about interface energetics of organic materials, especially the energy level alignment at organic heterostructures is of pronounced importance for unraveling the photon harvesting and charge separation process in organic photovoltaic(OPV) cells. This article provides an overview of interface energetics at typical planar and mixed donor-acceptor heterostructures, perovskite/organic hybrid interfaces, and their contact interfaces with charge collection layers. The substrate effect on energy level offsets at organic heterostructures and the processes that control and limit the OPV operation are presented. Recent efforts on interface engineering with electrical doping are also discussed.
