The conversion of acetone derived from biomass to isobutene has attracted extensive attentions.In comparison with Brønsted acidic catalyst,Lewis acidic catalyst could exhibit a better catalytic performance with a...The conversion of acetone derived from biomass to isobutene has attracted extensive attentions.In comparison with Brønsted acidic catalyst,Lewis acidic catalyst could exhibit a better catalytic performance with a higher isobutene selectivity.However,the catalyst stability remains a key problem for the long-running acetone conversion and the reasons for catalyst deactivation are poorly understood up to now.Herein,the deactivation mechanism of Lewis acidic Y/Beta catalyst during the acetone to isobutene conversion was investigated by various characterization techniques,including acetone-temperature-programmed surface reaction,gas chromatography-mass spectrometry,in situ ultraviolet-visible,and 13C cross polarization magic angle spinning nuclear magnetic resonance spectroscopy.A successive aldol condensation and cyclization were observed as the main side-reactions during the acetone conversion at Lewis acidic Y sites.In comparison with the low reaction temperature,a rapid formation and accumulation of the larger cyclic unsaturated aldehydes/ketones and aromatics could be observed,and which could strongly adsorb on the Lewis acidic sites,and thus cause the catalyst deactivation eventually.After a simple calcination,the coke deposits could be easily removed and the catalytic activity could be well restored.展开更多
The detection of foreign object intrusion is crucial for ensuring the safety of railway operations.To address challenges such as low efficiency,suboptimal detection accuracy,and slow detection speed inherent in conven...The detection of foreign object intrusion is crucial for ensuring the safety of railway operations.To address challenges such as low efficiency,suboptimal detection accuracy,and slow detection speed inherent in conventional comprehensive video monitoring systems for railways,a railway foreign object intrusion recognition and detection system is conceived and implemented using edge computing and deep learning technologies.In a bid to raise detection accuracy,the convolutional block attention module(CBAM),including spatial and channel attention modules,is seamlessly integrated into the YOLOv5 model,giving rise to the CBAM-YOLOv5 model.Furthermore,the distance intersection-over-union_non-maximum suppression(DIo U_NMS)algorithm is employed in lieu of the weighted nonmaximum suppression algorithm,resulting in improved detection performance for intrusive targets.To accelerate detection speed,the model undergoes pruning based on the batch normalization(BN)layer,and Tensor RT inference acceleration techniques are employed,culminating in the successful deployment of the algorithm on edge devices.The CBAM-YOLOv5 model exhibits a notable 2.1%enhancement in detection accuracy when evaluated on a selfconstructed railway dataset,achieving 95.0%for mean average precision(m AP).Furthermore,the inference speed on edge devices attains a commendable 15 frame/s.展开更多
Two types of handshaking circuits are proposed to implement the asynchronous communication between two processing elements in the wavefront array processors. After correcting the flaws in the original design, these ci...Two types of handshaking circuits are proposed to implement the asynchronous communication between two processing elements in the wavefront array processors. After correcting the flaws in the original design, these circuits make the system more robust and flexible. These circuits have compact architectures and are of higher performance. Besides, compared with other handshaking circuits, these designs are more suitable for FPGA.展开更多
A novel asynchronous ACS(add-compare-select) processor for Viterbi decoder is described.It is controlled by local handshake signals instead of the globe clock.The circuits of asynchronous adder unit,asynchronous compa...A novel asynchronous ACS(add-compare-select) processor for Viterbi decoder is described.It is controlled by local handshake signals instead of the globe clock.The circuits of asynchronous adder unit,asynchronous comparator unit,and asynchronous selector unit are proposed.A full-custom design of asynchronous 4-bit ACS processor is fabricated in CSMC-HJ 0.6μm CMOS 2P2M mixed-mode process.At a supply voltage of 5V,when it operates at 20MHz,the power consumption is 75.5mW.The processor has no dynamic power consumption when it awaits an opportunity in sleep mode.The results of performance test of asynchronous 4-bit ACS processor show that the average case response time 19.18ns is only 82% of the worst-case response time 23.37ns.Compared with the synchronous 4-bit ACS processor in power consumption and performance by simulation,it reveals that the asynchronous ACS processor has some advantages than the synchronous one.展开更多
A monolithic voltage controlled oscillator （VCO） based on negative resistance principle is presented uti-lizing commercially available InGaP/GaAs hetero-junction bipolar transistor （HBT） technology. This VCO is de...A monolithic voltage controlled oscillator （VCO） based on negative resistance principle is presented uti-lizing commercially available InGaP/GaAs hetero-junction bipolar transistor （HBT） technology. This VCO is de-signed for 5GHz-band wireless applications. Except for bypass and decoupled capacitors,no external component is needed for real application. Its measured output frequency range is from 4.17 to 4.56GHz,which is very close to the simulation one. And the phase noise at an offset frequency of 1MHz is -112dBc/Hz. The VCO core dissipates 15.5mW from a 3.3V supply,and the output power ranges from 0 to 2dBm. To compare with other oscillators,the figure of merit is calculated,which is about -173.2dBc/Hz. Meanwhile, the principle and design method of nega-tive resistance oscillator are also discussed.展开更多
The pyrolysis mechanisms of quinoline and isoquinoline were investigated using the density functional theory of quantum chemistry,including eight reaction paths and a common tautomeric intermediate 1-indene imine.It i...The pyrolysis mechanisms of quinoline and isoquinoline were investigated using the density functional theory of quantum chemistry,including eight reaction paths and a common tautomeric intermediate 1-indene imine.It is concluded that the conformational tautomerism of the intermediate decides the pyrolysis products(C6H6,HC≡C—C≡N,C6H5C≡N and HC≡CH)to be the same,and also decides the total disappearance rates of the reactants to be the same,for both original reactants quinoline and isoquinoline during the pyrolysis reaction.The results indicate that the intramolecular hydrogen migration is an important reaction step,which often appears in the paths of the pyrolysis mechanism.The activation energies of the rate determining steps are obtained.The calculated results are in good agreement with the experimental results.展开更多
Adamantiades-Behcet's disease (ABD) is a chronic,relapsing,systemic vasculitis of unknown etiology.It is more prevalent in populations along the ancient Silk Road from Eastern Asia to the Mediterranean Basin,and m...Adamantiades-Behcet's disease (ABD) is a chronic,relapsing,systemic vasculitis of unknown etiology.It is more prevalent in populations along the ancient Silk Road from Eastern Asia to the Mediterranean Basin,and most frequently affects young adults between the second and fourth decades of life.ABD-complicated gastroenteropathy is a significant cause of morbidity and mortality,with abdominal pain as the most common symptom.The ileocecal region is affected predominantly,with ulcerations that may lead to penetration and/or perforation,whereas other parts of the gastrointestinal system including the esophagus and stomach can also be affected.Endoscopy is useful to locate the site and extent of the lesions,and tissue biopsy is often warranted to examine the histopathology that is often suggestive of underlying vasculitis of small veins/venules or,alternatively in some cases,nonspecific inflammation.Bowel wall thickening is the most common finding on computed tomography scan.Treatment is largely empirical since well-controlled studies are difficult to conduct due to the heterogeneity of the disease,and the unpredictable course with exacerbation and remission.Corticosteroids with or without other immunosuppressive drugs,such as cyclophosphamide,azathioprine,sulfasalazine,tumor necrosis factor α antagonist or thalidomide should be applied before surgery,except in emergency.展开更多
Many energy efficiency asynchronous duty-cycle MAC(media access control) protocols have been proposed in recent years.However,in these protocols,wireless sensor nodes almost choose their wakeup time randomly during th...Many energy efficiency asynchronous duty-cycle MAC(media access control) protocols have been proposed in recent years.However,in these protocols,wireless sensor nodes almost choose their wakeup time randomly during the operational cycle,which results in the packet delivery latency increased significantly on the multiple hops path.To reduce the packet delivery latency on multi-hop path and energy waste of the sender's idle listening,a new low latency routing-enhanced asynchronous duty-cycle MAC protocol was presented,called REA-MAC.In REA-MAC,each sensor node decided when it waked up to send the beacon based on cross-layer routing information.Furthermore,the sender adaptively waked up based on the relationship between the transmission request time and the wakeup time of its next hop node.The simulation results show that REA-MAC reduces delivery latency by 60% compared to RI-MAC and reduces 8.77% power consumption on average.Under heavy traffic,REA-MAC's throughput is 1.48 times of RI-MAC's.展开更多
文摘The conversion of acetone derived from biomass to isobutene has attracted extensive attentions.In comparison with Brønsted acidic catalyst,Lewis acidic catalyst could exhibit a better catalytic performance with a higher isobutene selectivity.However,the catalyst stability remains a key problem for the long-running acetone conversion and the reasons for catalyst deactivation are poorly understood up to now.Herein,the deactivation mechanism of Lewis acidic Y/Beta catalyst during the acetone to isobutene conversion was investigated by various characterization techniques,including acetone-temperature-programmed surface reaction,gas chromatography-mass spectrometry,in situ ultraviolet-visible,and 13C cross polarization magic angle spinning nuclear magnetic resonance spectroscopy.A successive aldol condensation and cyclization were observed as the main side-reactions during the acetone conversion at Lewis acidic Y sites.In comparison with the low reaction temperature,a rapid formation and accumulation of the larger cyclic unsaturated aldehydes/ketones and aromatics could be observed,and which could strongly adsorb on the Lewis acidic sites,and thus cause the catalyst deactivation eventually.After a simple calcination,the coke deposits could be easily removed and the catalytic activity could be well restored.
基金supported in part by the Science and Technology Innovation Project of CHN Energy Shuo Huang Railway Development Company Ltd(No.SHTL-22-28)the Beijing Natural Science Foundation Fengtai Urban Rail Transit Frontier Research Joint Fund(No.L231002)the Major Project of China State Railway Group Co.,Ltd.(No.K2023T003)。
文摘The detection of foreign object intrusion is crucial for ensuring the safety of railway operations.To address challenges such as low efficiency,suboptimal detection accuracy,and slow detection speed inherent in conventional comprehensive video monitoring systems for railways,a railway foreign object intrusion recognition and detection system is conceived and implemented using edge computing and deep learning technologies.In a bid to raise detection accuracy,the convolutional block attention module(CBAM),including spatial and channel attention modules,is seamlessly integrated into the YOLOv5 model,giving rise to the CBAM-YOLOv5 model.Furthermore,the distance intersection-over-union_non-maximum suppression(DIo U_NMS)algorithm is employed in lieu of the weighted nonmaximum suppression algorithm,resulting in improved detection performance for intrusive targets.To accelerate detection speed,the model undergoes pruning based on the batch normalization(BN)layer,and Tensor RT inference acceleration techniques are employed,culminating in the successful deployment of the algorithm on edge devices.The CBAM-YOLOv5 model exhibits a notable 2.1%enhancement in detection accuracy when evaluated on a selfconstructed railway dataset,achieving 95.0%for mean average precision(m AP).Furthermore,the inference speed on edge devices attains a commendable 15 frame/s.
文摘Two types of handshaking circuits are proposed to implement the asynchronous communication between two processing elements in the wavefront array processors. After correcting the flaws in the original design, these circuits make the system more robust and flexible. These circuits have compact architectures and are of higher performance. Besides, compared with other handshaking circuits, these designs are more suitable for FPGA.
文摘A novel asynchronous ACS(add-compare-select) processor for Viterbi decoder is described.It is controlled by local handshake signals instead of the globe clock.The circuits of asynchronous adder unit,asynchronous comparator unit,and asynchronous selector unit are proposed.A full-custom design of asynchronous 4-bit ACS processor is fabricated in CSMC-HJ 0.6μm CMOS 2P2M mixed-mode process.At a supply voltage of 5V,when it operates at 20MHz,the power consumption is 75.5mW.The processor has no dynamic power consumption when it awaits an opportunity in sleep mode.The results of performance test of asynchronous 4-bit ACS processor show that the average case response time 19.18ns is only 82% of the worst-case response time 23.37ns.Compared with the synchronous 4-bit ACS processor in power consumption and performance by simulation,it reveals that the asynchronous ACS processor has some advantages than the synchronous one.
文摘A monolithic voltage controlled oscillator （VCO） based on negative resistance principle is presented uti-lizing commercially available InGaP/GaAs hetero-junction bipolar transistor （HBT） technology. This VCO is de-signed for 5GHz-band wireless applications. Except for bypass and decoupled capacitors,no external component is needed for real application. Its measured output frequency range is from 4.17 to 4.56GHz,which is very close to the simulation one. And the phase noise at an offset frequency of 1MHz is -112dBc/Hz. The VCO core dissipates 15.5mW from a 3.3V supply,and the output power ranges from 0 to 2dBm. To compare with other oscillators,the figure of merit is calculated,which is about -173.2dBc/Hz. Meanwhile, the principle and design method of nega-tive resistance oscillator are also discussed.
基金Supported by the National Basic Research Program of China （2005CB221203）, the National Natural Science Foundation of China （20576087, 20776093） and the Foundation of Shanxi Province （2006011022, 2009021015）.
文摘The pyrolysis mechanisms of quinoline and isoquinoline were investigated using the density functional theory of quantum chemistry,including eight reaction paths and a common tautomeric intermediate 1-indene imine.It is concluded that the conformational tautomerism of the intermediate decides the pyrolysis products(C6H6,HC≡C—C≡N,C6H5C≡N and HC≡CH)to be the same,and also decides the total disappearance rates of the reactants to be the same,for both original reactants quinoline and isoquinoline during the pyrolysis reaction.The results indicate that the intramolecular hydrogen migration is an important reaction step,which often appears in the paths of the pyrolysis mechanism.The activation energies of the rate determining steps are obtained.The calculated results are in good agreement with the experimental results.
文摘Adamantiades-Behcet's disease (ABD) is a chronic,relapsing,systemic vasculitis of unknown etiology.It is more prevalent in populations along the ancient Silk Road from Eastern Asia to the Mediterranean Basin,and most frequently affects young adults between the second and fourth decades of life.ABD-complicated gastroenteropathy is a significant cause of morbidity and mortality,with abdominal pain as the most common symptom.The ileocecal region is affected predominantly,with ulcerations that may lead to penetration and/or perforation,whereas other parts of the gastrointestinal system including the esophagus and stomach can also be affected.Endoscopy is useful to locate the site and extent of the lesions,and tissue biopsy is often warranted to examine the histopathology that is often suggestive of underlying vasculitis of small veins/venules or,alternatively in some cases,nonspecific inflammation.Bowel wall thickening is the most common finding on computed tomography scan.Treatment is largely empirical since well-controlled studies are difficult to conduct due to the heterogeneity of the disease,and the unpredictable course with exacerbation and remission.Corticosteroids with or without other immunosuppressive drugs,such as cyclophosphamide,azathioprine,sulfasalazine,tumor necrosis factor α antagonist or thalidomide should be applied before surgery,except in emergency.
基金Projects(61103011,61170261) supported by the National Natural Science Foundation of China
文摘Many energy efficiency asynchronous duty-cycle MAC(media access control) protocols have been proposed in recent years.However,in these protocols,wireless sensor nodes almost choose their wakeup time randomly during the operational cycle,which results in the packet delivery latency increased significantly on the multiple hops path.To reduce the packet delivery latency on multi-hop path and energy waste of the sender's idle listening,a new low latency routing-enhanced asynchronous duty-cycle MAC protocol was presented,called REA-MAC.In REA-MAC,each sensor node decided when it waked up to send the beacon based on cross-layer routing information.Furthermore,the sender adaptively waked up based on the relationship between the transmission request time and the wakeup time of its next hop node.The simulation results show that REA-MAC reduces delivery latency by 60% compared to RI-MAC and reduces 8.77% power consumption on average.Under heavy traffic,REA-MAC's throughput is 1.48 times of RI-MAC's.
