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α-氨基苯乙酮衍生物的合成及光引发性能测试 被引量:5
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作者 谢川 王绅典 李绚 《精细化工》 EI CAS CSCD 北大核心 2000年第4期237-240,共4页
以氟苯为原料 ,经Friedel-Crafts酰化、α 卤代、环氧化、季铵化及Stevens重排和亲核取代反应 ,合成了 3种未见报道的α 氨基苯乙酮衍生物光引发剂 :1 对吗啉苯基 2 哌啶基 2 烯丙基 1 丁酮、1 对吗啉苯基 2 哌啶基 2 苄基 1 ... 以氟苯为原料 ,经Friedel-Crafts酰化、α 卤代、环氧化、季铵化及Stevens重排和亲核取代反应 ,合成了 3种未见报道的α 氨基苯乙酮衍生物光引发剂 :1 对吗啉苯基 2 哌啶基 2 烯丙基 1 丁酮、1 对吗啉苯基 2 哌啶基 2 苄基 1 丁酮和 1 对哌啶苯基 2 哌啶基 2 烯丙基 1 丁酮。对产物的结构进行了表征 ,并将其用于清漆和色漆中 ,测试了光引发性能 ,实验结果表明 ,3种产物均能使涂层在 8~ 2 5s内固化 ,光引发性能优良。 展开更多
关键词 氨基苯乙酮 引发 结构 引发性能 衍生物
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{4-[4-(对硝基苯甲酰基)苯硫基]苯}苯基碘鎓六氟磷酸盐的合成与光引发性能测试 被引量:2
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作者 黄斌 李焱飞 +1 位作者 陈晓峰 程德军 《化学研究与应用》 CAS CSCD 北大核心 2008年第7期890-892,共3页
{4-[4-p-nitrobenzoyl(thiophenyl) phenyl]} phenyl iodonium hexafluorophosphate(Ⅳ) is synthesized from iodobenzene,p-nitro-benzoic acid and diphenyl sulfide through Friedel-Crafts acylation、substitution reaction and m... {4-[4-p-nitrobenzoyl(thiophenyl) phenyl]} phenyl iodonium hexafluorophosphate(Ⅳ) is synthesized from iodobenzene,p-nitro-benzoic acid and diphenyl sulfide through Friedel-Crafts acylation、substitution reaction and metathesis.It’s structure is identified by UV,1HNMR,MS and IR.The photoinitiability of product is tested. 展开更多
关键词 碘鎓盐 引发 合成 引发性能
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新型水溶性硫杂蒽酮类光引发剂的光引发性能研究 被引量:3
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作者 钱蓁 王金娣 《功能高分子学报》 CAS CSCD 2000年第2期154-156,共3页
利用红外光谱技术对六种新型水溶性硫杂蒽酮类光引发剂在紫外光聚合反应中的引发性能进行了测试 ,用相对峰面积法计算了聚合反应的转化率 ,并据此对引发剂结构与光化学性能之间的关系做了一定的探讨。结果表明该类光引发剂具有很高的光... 利用红外光谱技术对六种新型水溶性硫杂蒽酮类光引发剂在紫外光聚合反应中的引发性能进行了测试 ,用相对峰面积法计算了聚合反应的转化率 ,并据此对引发剂结构与光化学性能之间的关系做了一定的探讨。结果表明该类光引发剂具有很高的光化学活性 ,而引发剂的结构直接影响引发性能。研究发现硫杂蒽酮母体上甲基的引入使引发剂的引发效率增大 ,而引发剂侧链上羟基的引入 ,则由于降低了质子转移的有效性并有可能使引发剂分子缔合 ,致使引发效率下降。 展开更多
关键词 硫杂蒽酮 引发 紫外光聚合反应 引发性能
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水溶性光引发剂α-氨基-1-苯基-1-丙酮衍生物的合成和光引发性能测试 被引量:4
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作者 谢川 谭智勇 +1 位作者 李万舜 郑志明 《精细化工》 EI CAS CSCD 北大核心 2003年第7期387-389,418,共4页
合成了2种未见报道的水溶性α 氨基 1 苯基 1 丙酮衍生物。以甲苯为原料,经酰化、α 卤化、氨基化、季铵化反应,合成了溴化1 对甲苯基 2 二乙基苄基铵 1 丙酮(Ⅰ),用UV、IR、1H NMR和元素分析进行了结构表征。上述季铵化反应的条件是:0 ... 合成了2种未见报道的水溶性α 氨基 1 苯基 1 丙酮衍生物。以甲苯为原料,经酰化、α 卤化、氨基化、季铵化反应,合成了溴化1 对甲苯基 2 二乙基苄基铵 1 丙酮(Ⅰ),用UV、IR、1H NMR和元素分析进行了结构表征。上述季铵化反应的条件是:0 08mol1 对甲苯基 2 二乙氨基 1 丙酮与0 1mol苄基溴在50~60℃下反应20h,得到产物Ⅰ,产率为55 2%。参照上述季铵化反应的条件,用光引发剂Irgacure907进行了季铵化,得到溴化4 苄基 4 (1,1 二甲基 2 对甲硫苯基 2 氧代乙基) 吗啉(Ⅱ),并证实了结构。测试产物的光引发性能表明,产物Ⅰ和Ⅱ既具有水溶性又具有光引发性。 展开更多
关键词 水溶性光引发 α-氨基-1-苯基-1-丙酮 溴化l-对甲苯基-2-二乙基苄基铵-l-丙酮 溴化4-苄基-4-(1 l-二甲基-2-对甲硫苯基-2-氧代乙基)-吗啉鎓 引发性能
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光引发剂 1-对吗啉苯基-2-二甲氨基-2-苄基-1-丁酮的合成及光引发性能测试
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作者 彭梦侠 周容 +1 位作者 谢川 王绅典 《四川联合大学学报(工程科学版)》 CSCD 1999年第1期36-41,58,共7页
本文合成了1对吗啉苯基-2-二甲氨基-2-苄基-1-丁酮,将合成产品与国外同样产品的物理性质及结构表征进行了对比,并对产品的光引发性能进行了初步测试。
关键词 引发 丁酮 合成 Lrgacure369 引发性能
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1-对甲苯基-2-二乙氨基-1-丙酮的合成及光引发性能
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作者 谢川 谭智勇 潘固平 《精细石油化工》 CAS CSCD 北大核心 2004年第2期29-31,共3页
以甲苯为起始物,通过Friedel Crafts酰化、α 溴代和胺化反应合成了一种新的α 氨基苯乙酮衍生物1 对 甲苯基 2 二乙氨基 1 丙酮。对胺化反应的研究结果为:用10g1 对甲苯基 2 溴 1 丙酮与12mL二乙胺在 (50±1)℃反应16h,产率为9... 以甲苯为起始物,通过Friedel Crafts酰化、α 溴代和胺化反应合成了一种新的α 氨基苯乙酮衍生物1 对 甲苯基 2 二乙氨基 1 丙酮。对胺化反应的研究结果为:用10g1 对甲苯基 2 溴 1 丙酮与12mL二乙胺在 (50±1)℃反应16h,产率为90.8%。并对目标产物进行了元素分析和谱学表征。初步测试结果表明,其光 引发效率与Irgacure907相似。 展开更多
关键词 对甲苯基 二乙氨基 引发性能 FRIEDEL-CRAFTS 丙酮 苯乙酮衍生物 Α-氨基 反应合成 研究结果 胺化反应 谱学表征 元素分析 引发效率 二乙胺 溴代 产物
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季戊四醇四苯甲酰甲酸酯的合成及光引发性能
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作者 周彦芳 曾泽 +3 位作者 谢刚 焦晨婕 周玉炳 钟荣 《应用化学》 CAS CSCD 北大核心 2018年第6期652-658,共7页
大分子光引发剂可以解决小分子光引发剂残留碎片带来的毒性对其在食品和医用材料领域应用的限制,为此,本文以苯甲酰甲酸(BF)和季戊四醇(PET)为原料,通过酰氯法在季戊四醇主链上引入了4个苯甲酰甲酸酯基团,制备了多官能度的季戊四醇四苯... 大分子光引发剂可以解决小分子光引发剂残留碎片带来的毒性对其在食品和医用材料领域应用的限制,为此,本文以苯甲酰甲酸(BF)和季戊四醇(PET)为原料,通过酰氯法在季戊四醇主链上引入了4个苯甲酰甲酸酯基团,制备了多官能度的季戊四醇四苯甲酰甲酸酯(PTF)大分子光引发剂。PTF在225℃时失重15%,热稳定性优于2-羟基-2-甲基-1-苯基-1-丙酮(1173)光引发剂,与1173光引发剂相比,用PTF作光引发剂所制备的光固化涂料,在起始分解温度以及失去相同比例质量所需温度均提高了100℃以上。PTF引发三羟甲基丙烷三丙烯酸酯(TMPTA)聚合时最大反应速率为0.037 s-1,最终双键转化率为39.5%,PTF光引发活性大于1173光引发剂。在同等实验条件下,PTF的相对小分子残留量仅为1173光引发剂的5%。 展开更多
关键词 季戊四醇四苯甲酰甲酸酯 紫外光固化 引发性能
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(2,4,6-三甲基苯甲酰基)二苯基膦氧化物的合成及光引发性能测试 被引量:2
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作者 刘兰 《化工生产与技术》 CAS 2005年第5期14-15,共2页
合成了光引发剂(2,4,6-三甲基苯甲酰基)二苯基膦氧化物(TPO),测试了其在 丙烯酸改性环氧树脂体系清漆和色漆中的光引发性能。结果表明,与其它光引发剂相比, TPO可缩短清漆和色漆的固化时间;TPO的最佳用量为丙烯酸树脂的4%(质量分数)。
关键词 (2 4 6-三甲基苯甲酰基)二苯基膦氧化物 合成方法 引发性能 色漆 清漆 固化时间 TPO
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含胺硫杂蒽酮光引发剂的制备及其性能研究 被引量:4
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作者 王宝总 韦军 《辐射研究与辐射工艺学报》 CAS CSCD 2013年第1期31-35,共5页
为提高传统硫杂蒽酮光引发剂的引发活性,通过环氧基团的开环反应合成了含胺硫杂蒽酮光引发剂2-[2-羟基-3-(2-羟乙基-2-甲基)氨基]丙氧基硫杂蒽酮(APTX)。傅立叶变换红外光谱和核磁共振氢谱证实了APTX的结构。紫外光谱表明取代基的存在... 为提高传统硫杂蒽酮光引发剂的引发活性,通过环氧基团的开环反应合成了含胺硫杂蒽酮光引发剂2-[2-羟基-3-(2-羟乙基-2-甲基)氨基]丙氧基硫杂蒽酮(APTX)。傅立叶变换红外光谱和核磁共振氢谱证实了APTX的结构。紫外光谱表明取代基的存在使硫杂蒽酮单元的最大紫外吸收波长发生红移。以硫杂蒽酮(TX)为参照,用光致差示扫描量热计(Photo-DSC)研究了三羟甲基丙烷三丙烯酸酯(TMPTA)的光聚合反应,结果表明,APTX可更有效地引发TMPTA的光聚合。 展开更多
关键词 硫杂蒽酮 引发 光聚合 引发性能
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咔唑肟酯衍生物的合成和光引发性
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作者 谢川 李万舜 +1 位作者 冯岩 陈秋容 《四川大学学报(工程科学版)》 EI CAS CSCD 北大核心 2009年第4期109-113,219,共6页
以N-烃基咔唑为原料,经Friedel-Crafts酰化、成肟和酯化反应,合成了6种咔唑肟酯衍生物。通过正交设计实验,探讨了产物1-[3’-(6’-苯甲酰基-N-乙基咔唑)]-1-丁酮肟-O-乙酸酯的Friedel-Crafts酰化的最佳反应条件:N-乙基咔唑为0.02 mol时... 以N-烃基咔唑为原料,经Friedel-Crafts酰化、成肟和酯化反应,合成了6种咔唑肟酯衍生物。通过正交设计实验,探讨了产物1-[3’-(6’-苯甲酰基-N-乙基咔唑)]-1-丁酮肟-O-乙酸酯的Friedel-Crafts酰化的最佳反应条件:N-乙基咔唑为0.02 mol时,反应物苯甲酰氯与N-乙基咔唑摩尔配比为1∶1.2,催化剂A lC l3与N-乙基咔唑摩尔配比为1∶1.2,25℃下反应3.5 h,产率可达94.6%。利用1HNMR,IR,UV和元素分析对目标产物进行了结构表征。并进行了光引发性能测试。 展开更多
关键词 咔唑肟酯 合成 正交实验 引发性能
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高分子型米嗤酮光引发剂的制备方法
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《工程塑料应用》 CAS CSCD 北大核心 2008年第12期83-83,共1页
本发明公开了一种高分子型米嗤酮光引发剂的制备方法。先以4,4'-二氟二苯甲酮和哌嗪为原料合成含有两个甲基叔胺的米嗤酮,再将米嗤酮和双环氧单体溶于有机溶剂中升温聚合,得到高分子型米嗤酮光引发剂。该光引发剂主链上同时含有米... 本发明公开了一种高分子型米嗤酮光引发剂的制备方法。先以4,4'-二氟二苯甲酮和哌嗪为原料合成含有两个甲基叔胺的米嗤酮,再将米嗤酮和双环氧单体溶于有机溶剂中升温聚合,得到高分子型米嗤酮光引发剂。该光引发剂主链上同时含有米嗤酮和助引发剂胺,具有较高的光引发性能。 展开更多
关键词 二氟二苯甲酮 引发 高分子型 制备方法 引发性能 原料合成 有机溶剂 引发
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[4-(对苯甲酰基苯硫基)苯]苯基碘鎓六氟磷酸盐的合成
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作者 李焱飞 谢川 《应用化学》 CAS CSCD 北大核心 2008年第2期251-253,共3页
以碘苯、二苯硫醚为主要原料,经Fridel-Crafts酰基化、取代、置换反应得到[4-(对苯甲酰基苯硫基)苯]苯基碘鎓六氟磷酸盐(Ⅲ)。其结构经UV、1HNMR、IR及MS测试技术分析确证,并通过正交试验确定了合成反应的最佳实验条件:4-苯硫基二苯甲酮... 以碘苯、二苯硫醚为主要原料,经Fridel-Crafts酰基化、取代、置换反应得到[4-(对苯甲酰基苯硫基)苯]苯基碘鎓六氟磷酸盐(Ⅲ)。其结构经UV、1HNMR、IR及MS测试技术分析确证,并通过正交试验确定了合成反应的最佳实验条件:4-苯硫基二苯甲酮2.033g,羟基对甲苯磺酰氧碘苯3.294g,催化剂乙酐与浓硫酸摩尔比为1:5,在60℃下反应24h,产率可达47.9%。并对该产物进行了光引发性能测试。 展开更多
关键词 碘鎓盐 引发 合成 正交试验 引发性能
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固液相转移催化合成2-羟基-3-(4-苯甲酰基苯氧基)丙磺酸钠 被引量:2
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作者 刘蕤 徐伟箭 《化学世界》 CAS CSCD 北大核心 2005年第4期228-231,242,共5页
以苯酚和苯甲酰氯为原料,合成了中间产物4 羟基二苯甲酮,在固液相转移催化条件下,使该中间产物与3 氯 2 羟基丙基磺酸钠反应,合成了题述产品。考察了不同催化剂,催化剂用量,反应温度,反应时间对收率的影响,并对其光引发性能进行研究。
关键词 2-羟基-3-(4-苯甲酰基苯氧基)丙磺酸钠 相转移催化剂 引发性能
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Modelling of modern automotive petrol engine performance using Support Vector Machines 被引量:2
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作者 黄志文 王百键 +1 位作者 李怡平 何春明 《Journal of Zhejiang University-Science A(Applied Physics & Engineering)》 SCIE EI CAS CSCD 2005年第1期1-8,共8页
Modern automotive petrol engine performance is significantly affected by effective tune-up. Current practice of engine tune-up relies on the experience of the automotive engineer, and tune-up is usually done by trial-... Modern automotive petrol engine performance is significantly affected by effective tune-up. Current practice of engine tune-up relies on the experience of the automotive engineer, and tune-up is usually done by trial-and-error method and then the vehicle engine is run on the dynamometer to show the actual engine performance. Obviously the current practice involves a large amount of time and money, and then may even fail to tune up the engine optimally because a formal performance model of the engine has not been determined yet. With an emerging technique, Support Vector Machines (SVM), the approximate per- formance model of a petrol vehicle engine can be determined by training the sample engine performance data acquired from the dynamometer. The number of dynamometer tests for an engine tune-up can therefore be reduced because the estimated engine performance model can replace the dynamometer tests to a certain extent. In this paper, the construction, validation and accuracy of the model are discussed. The study showed that the predicted results agree well with the actual test results. To illustrate the significance of the SVM methodology, the results were also compared with that regressed using multilayer feedforward neural networks. 展开更多
关键词 Automotive petrol engines ECU tune-up Support Vector Machines (SVM)
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DESIGN AND EVALUATION OF A PIPELINED FORWARDING ENGINE 被引量:1
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作者 Li Yufeng Chen Yue Lan Julong 《Journal of Electronics(China)》 2007年第2期157-162,共6页
Recent advances in broadband technology have caused forwarding engines to handle pack- ets with over 10 gigabit per second. In this paper, we present a high-speed forwarding pipeline which can finish all of the routin... Recent advances in broadband technology have caused forwarding engines to handle pack- ets with over 10 gigabit per second. In this paper, we present a high-speed forwarding pipeline which can finish all of the routing and forwarding tasks in the way of pipelining. We also establish the analysis model of the pipeline with which one can evaluate some key performance parameters of the forwarding engine such as forwarding rate and forwarding delay. We find that the pipeline is of good scalability and can forward unicast packets up to the speed of 40Gbit/s. 展开更多
关键词 DESIGN Forwarding engine PIPELINE Evaluate
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Is there an acute exercise-induced physiological/biochemical threshold which triggers increased speed of cognitive functioning? A meta-analytic investigation 被引量:3
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作者 Terry Mc Morris Beverley J.Hale 《Journal of Sport and Health Science》 SCIE 2015年第1期4-13,共10页
Purpose: The purpose of this study was to examine, using meta-analytic measures, the evidence regarding the optimal exercise intensity at which improvements in speed of cognitive function are triggered. Specifically,... Purpose: The purpose of this study was to examine, using meta-analytic measures, the evidence regarding the optimal exercise intensity at which improvements in speed of cognitive function are triggered. Specifically, it was hypothesized that the catecholamine, lactate, and ventilatory thresholds is the point at which significant improvements in speed of cognitive function are observed. Methods: We compared mean effect sizes for threshold studies and for those studies where exercise intensity was classed as moderate (40%-- 79% VO2 or equivalent) but in which the thresholds were not measured. Results: Random effects meta-analysis showed significant, moderate, mean effect sizes for studies at the threshold (g = 0.58, Z = 2.98, p 〈 0.003) and for those during moderate intensity exercise but in which the threshold was not measured ( g = 0.54, Z = 5.0l, p 〈 0.001). There was no significant difference between mean effect sizes, which suggests that the thresholds are unlikely to represent a trigger point. Conclusion: Moderate intensity exercise, even below the thresholds, can induce improved speed of cognition, possibly due to a combination of increased peripheral catecholamine concentrations inducing vagal/nucleus tractus solitarii pathway activation and central increases due to perceptions of stress. 展开更多
关键词 Catecholamine threshold Lactate threshold Stress Vagus nerve Ventilatory threshold
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The Effect of Priming on Seed Performance of Chickpea (Cicer arietinum L.) under Drought Stress
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作者 A.R. Ajirloo G. R. Mohammadi M. Ghobadi 《Journal of Agricultural Science and Technology(A)》 2011年第8期1349-1351,共3页
In order to investigate the effect of priming on Chickpea seed performance under drought stress, a study was carried out at the Seed Research Laboratory of Razi University, Kermanshah, Iran. The experiment was a facto... In order to investigate the effect of priming on Chickpea seed performance under drought stress, a study was carried out at the Seed Research Laboratory of Razi University, Kermanshah, Iran. The experiment was a factorial with three factors arranged in a completely randomized design with four replications. The first factor was seed priming (control (untreated), HB-101 (Completely organic herbal extracts, derived from the bark of dark cones), KNO3 and distilled water), the second was drought stress levels (0.0, -0.3, -0.6, -0.9, -1.2 MPa) and the third was chickpea cultivars (Arman and Azar). Results indicated that for both cultivars germination percentage (GP), mean germination rate (MGR), radicle length (RL), plumule length (PL) and seedling dry weight (SDW) were reduced when drought stress level were increased from 0 to -!.2 Mpa, although, the cultivars showed different responses to the increased drought stress level. For all of the traits under study, the best results due to the priming treatments were obtained at the drought stress levels higher than -0.6 or -0.9 MPa. So that, at the -1.2 MPa of drought stress level, GP, MGR, and SDW were increased 53.75, 0.49, and 13.85, respectively by HB -101 when compared with control. However, seeds primed with HB-101 showed better performance than those primed with distilled water and KNO3. In general, this study revealed that seed priming especially with HB-101 improved chickpea seed performance under drought stress condition. However, the improvements were more obvious at the higher levels of drought stress. 展开更多
关键词 CHICKPEA drought stress seed priming
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Synthesis and Properties of Novel Surface Active Maleic Monomer Containing Phosphate Group
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作者 Mykola Borzenkov Yuri Galadjun +1 位作者 Natalia Mitina Orest Hevus 《Journal of Chemistry and Chemical Engineering》 2014年第5期493-500,共8页
A novel surface active monomer (surfmer) containing poly(ethylene glycol) chain and terminated phosphate group was synthesized. The copolymerization of synthesized surfmer with NVP (N-vinylpyrrolidone) and with ... A novel surface active monomer (surfmer) containing poly(ethylene glycol) chain and terminated phosphate group was synthesized. The copolymerization of synthesized surfmer with NVP (N-vinylpyrrolidone) and with NVP and VEP (5-tert-butylperoxy-5-methyl-2-hexene-3-yne monomer) led to formation of corresponding surface-active copolymers. The capability of application of resulted copolymers as surface active macroinitiators of emulsion polymerization of styrene and as components of polymeric scaffolds was investigated. 展开更多
关键词 Surface active monomers surface tension surface active polymers emulsion polymerization polymeric scaffolds.
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High yield fabrication of semiconducting thin-film field-effect transistors based on chemically functionalized single-walled carbon nanotubes
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作者 ZHAO JianWen QIAN Jun +3 位作者 SHEN YongQiang WANG XiaoHua SHI AiHua LEE ChunWei 《Science China Chemistry》 SCIE EI CAS 2011年第9期1484-1490,共7页
Here we report a simple and scalable method to fabricate high performance thin-film field-effect transistors(FETs) with high yield based on chemically functionalized single-walled carbon nanotubes(SWNTs) by organic ra... Here we report a simple and scalable method to fabricate high performance thin-film field-effect transistors(FETs) with high yield based on chemically functionalized single-walled carbon nanotubes(SWNTs) by organic radical initiators.The UV-Vis-NIR spectra,Raman spectra and electrical characterization demonstrated that metallic species in CoMoCat 65 and HiPco SWNTs could be effectively eliminated after reaction with some organic radical initiators.The effects of the substrate properties on the electrical properties of FET devices were investigated,and the results showed that the electrical properties of FET devices fabricated on high hydrophobic substrates were better than those on low hydrophobic substrates.Furthermore,it was found that FET devices based on 1,1'-azobis(cyanocyclohexane)(ACN)-modified CoMoCat 65 SWNTs exhibited more excellent electrical performance with effective mobility of ~11.8 cm2/Vs and on/off ratio of ~2×105 as compared with benzoyl peroxide(BPO)-modified CoMoCat 65 SWNTs and lauoryl peroxideand(LPO)-modified HiPco SWNTs,likely due to the introduction of the electron-withdrawing groups(CN group) on the SWNT surface.This method does not require nontrivial reaction conditions or complicated purification after reaction,therefore promising low-cost production of high-performance devices for macroelectronics. 展开更多
关键词 single-walled carbon nanotubes field-effect transistors RADICALS effectively eliminated
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