Carbon encapsulated Fe nanoparticles were successfully prepared via confined arc plasma method. The composition, morphology, microstructure, specific surface area and particle size of the product were characterized vi...Carbon encapsulated Fe nanoparticles were successfully prepared via confined arc plasma method. The composition, morphology, microstructure, specific surface area and particle size of the product were characterized via X-ray diffraction, transmission electron microscopy, high resolution transmission electron microscopy, energy dispersive X-ray spectrometry and Brunauer-Emmett-Teller N2 adsorption. The experiment results show that the carbon encapsulated Fe nanoparticles have clear core-shell structure. The core of the particles is body centered cubic Fe, and the shell is disorder carbons. The particles are in spherical or ellipsoidal shapes. The particle size of the nanocapsules ranges from 15 to 40 nm, with the average value of about 30 nm. The particle diameter of the core is 18 nm, the thickness of the shells is 6-8 nm, and the specific surface area is 24 m2/g.展开更多
Carbon encapsulated iron nanoparticles （CEINPs） with very thin shells and good core-shell structures were prepared by DC arc discharge at argon intake temperature （AIT） of 800 ℃. The results of high resolution tr...Carbon encapsulated iron nanoparticles （CEINPs） with very thin shells and good core-shell structures were prepared by DC arc discharge at argon intake temperature （AIT） of 800 ℃. The results of high resolution transmission electron microscope （HRTEM）, energy dispersive X-ray （EDX） spectroscope, X-ray diffraction （XRD）, and X-ray photoelectron spectroscope （XPS） characterizations on the product B show that the thickness of the carbon shells of CEINPs in the product B is in the range of ca. 0.5-5.3 nm, i. e., which can be as thin as only two layers of graphite. The average diameter of the CEINPs is about 24. 7 nm. The total content of Fe element in the product B is 77.0 wt%. The saturation magnetization （Ms） and coercivity （Hc） of the product B are 107.4 emu/g and 143 Oe. resnectivelv. The formation of the CEINPs in the oroduct B is discussed briefly.展开更多
In this paper, we combine the pseudo arc-length numerical method with the mathematical model of multiphase compressible flow for simulating the shock wave interaction with a deformable particle. Firstly, an arc-length...In this paper, we combine the pseudo arc-length numerical method with the mathematical model of multiphase compressible flow for simulating the shock wave interaction with a deformable particle. Firstly, an arc-length parameter is introduced to weaken the discontinuous singularity of governing equations, and an efficient pseudo arc-length numerical method of multiphase compressible flow is proposed. Then the accuracy and adaptive moving mesh property of this algorithm are tested. Finally, the multiphase pseudo arc-length numerical method is applied to the problem of interaction between shock wave and the deformable particle. Through the flow flied change and data analysis of key points, it can be found the complex wave structures are presented after the interactions between the planar incident shock wave and the metal particle, and all these wave interactions lead to the movement and deformation of metal particle, and then the deformed particle will affect the transmitted shock wave back. According to the discussion, the deformation of particle and shock wave propagation in the particle are determined by the shock wave impedance of each medium and shock speed, so the interaction between shock wave and the deformable particle can be studied on the basis of physical properties of explosive mediums.展开更多
基金Project(208151)supported by the Key Project of Ministry of Education,ChinaProject(1014RJZA035)supported by the Natural Science Foundation of Gansu Province,China
文摘Carbon encapsulated Fe nanoparticles were successfully prepared via confined arc plasma method. The composition, morphology, microstructure, specific surface area and particle size of the product were characterized via X-ray diffraction, transmission electron microscopy, high resolution transmission electron microscopy, energy dispersive X-ray spectrometry and Brunauer-Emmett-Teller N2 adsorption. The experiment results show that the carbon encapsulated Fe nanoparticles have clear core-shell structure. The core of the particles is body centered cubic Fe, and the shell is disorder carbons. The particles are in spherical or ellipsoidal shapes. The particle size of the nanocapsules ranges from 15 to 40 nm, with the average value of about 30 nm. The particle diameter of the core is 18 nm, the thickness of the shells is 6-8 nm, and the specific surface area is 24 m2/g.
文摘Carbon encapsulated iron nanoparticles （CEINPs） with very thin shells and good core-shell structures were prepared by DC arc discharge at argon intake temperature （AIT） of 800 ℃. The results of high resolution transmission electron microscope （HRTEM）, energy dispersive X-ray （EDX） spectroscope, X-ray diffraction （XRD）, and X-ray photoelectron spectroscope （XPS） characterizations on the product B show that the thickness of the carbon shells of CEINPs in the product B is in the range of ca. 0.5-5.3 nm, i. e., which can be as thin as only two layers of graphite. The average diameter of the CEINPs is about 24. 7 nm. The total content of Fe element in the product B is 77.0 wt%. The saturation magnetization （Ms） and coercivity （Hc） of the product B are 107.4 emu/g and 143 Oe. resnectivelv. The formation of the CEINPs in the oroduct B is discussed briefly.
基金supported by the National Natural Science Foundation of China(Grant Nos.11390363,11325209 and 11221202)
文摘In this paper, we combine the pseudo arc-length numerical method with the mathematical model of multiphase compressible flow for simulating the shock wave interaction with a deformable particle. Firstly, an arc-length parameter is introduced to weaken the discontinuous singularity of governing equations, and an efficient pseudo arc-length numerical method of multiphase compressible flow is proposed. Then the accuracy and adaptive moving mesh property of this algorithm are tested. Finally, the multiphase pseudo arc-length numerical method is applied to the problem of interaction between shock wave and the deformable particle. Through the flow flied change and data analysis of key points, it can be found the complex wave structures are presented after the interactions between the planar incident shock wave and the metal particle, and all these wave interactions lead to the movement and deformation of metal particle, and then the deformed particle will affect the transmitted shock wave back. According to the discussion, the deformation of particle and shock wave propagation in the particle are determined by the shock wave impedance of each medium and shock speed, so the interaction between shock wave and the deformable particle can be studied on the basis of physical properties of explosive mediums.
