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噻二唑类弯曲型液晶分子的合成和性能研究 被引量:2
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作者 李双全 沈冬 《液晶与显示》 CAS CSCD 北大核心 2011年第4期421-426,共6页
合成了两个系列以1,3,4-噻二唑为中心基团的弯曲型分子,结合偏光显微熔点仪(POM)观察和差示量热扫描法(DSC)研究了它们的液晶性能。研究发现,这两类弯曲型分子都会出现N相。其中,对称型五环酯类噻二唑弯曲型分子的熔点都较高,清亮点均超... 合成了两个系列以1,3,4-噻二唑为中心基团的弯曲型分子,结合偏光显微熔点仪(POM)观察和差示量热扫描法(DSC)研究了它们的液晶性能。研究发现,这两类弯曲型分子都会出现N相。其中,对称型五环酯类噻二唑弯曲型分子的熔点都较高,清亮点均超过360℃;含烯丙基非对称噻二唑类弯曲型分子熔点和清亮点温度大幅度降低,N相的温区较宽,以庚基为端基链的弯曲型分子出现N相的温度区间超过120℃。 展开更多
关键词 1 3 4-噻二唑 弯曲型分子 向列相
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Prediction of nonlocal scale parameter for carbon nanotubes 被引量:2
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作者 LIANG YingJing HAN Qiang 《Science China(Physics,Mechanics & Astronomy)》 SCIE EI CAS 2012年第9期1670-1678,共9页
Based on the theory of nonlocal elasticity,a nonlocal shell model accounting for the small scale effect is developed for the bending characteristics of CNTs subjected to the concentrated load.With this nonlocal shell ... Based on the theory of nonlocal elasticity,a nonlocal shell model accounting for the small scale effect is developed for the bending characteristics of CNTs subjected to the concentrated load.With this nonlocal shell model,explicit expressions are derived for the bending solutions.To extract the proper values of nonlocal scale parameter,we have made molecular dynamics(MD) simulations for various radii and lengths of armchair and zigzag CNTs,the results of which are matched with those of nonlocal continuum model.It is found that the present nonlocal elastic shell model with its appropriate values of nonlocal scale parameter has the capability to predict the bending behavior of CNTs,which is comparable with the results of MD simulations.Moreover,exact closed form solutions for the nonlocal scale parameter for zigzag and armchair CNTs are obtained.The results show that nonlocal scale parameter is independent of the length of CNTs,and dependent on the radius of CNTs. 展开更多
关键词 nonlocal elasticity nonlocal scale parameter carbon nanotubes nonlocal shell model molecular dynamics simulation
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