The hydrothermal reaction of ZnO, H3PO4(85%), (H2NCH2CH2)2NH and H2pydc results in the formation of a discrete mononuclear zinc(II) complex Zn(Hpydc)2(H2O). It crystallizes in monoclinic space group C2/c with a = 17.9...The hydrothermal reaction of ZnO, H3PO4(85%), (H2NCH2CH2)2NH and H2pydc results in the formation of a discrete mononuclear zinc(II) complex Zn(Hpydc)2(H2O). It crystallizes in monoclinic space group C2/c with a = 17.9947(8), b = 7.1875(3), c = 12.5895(4) , b = 110.802(2), V = 1522.14(10) 3, Z = 4, Mr = 415.61, (C14H10N2O9Zn), Dc = 1.814g/cm3, = 16.71cm-1, F(000) = 840, R = 0.0505, wR = 0.1144. Each zinc(II) is coordinated to two nitrogen and three oxygen atoms of which two nitrogen and two oxygen atoms are from two pydc ligands, and one oxygen atom from the coordinated water molecule to form an irregular polyhedral geometry. The complex is linked further into a three-dimensional structure through the weak interactions of hydrogen bonds between the two oxygen atoms. IR spectrum of the complex is also discussed.展开更多
In this paper, we consider a system consisting of two capacitively coupled superconducting islands viaJosephson junctions. We show that it can be reduced to two coupling harmonic oscillators under certain conditions,a...In this paper, we consider a system consisting of two capacitively coupled superconducting islands viaJosephson junctions. We show that it can be reduced to two coupling harmonic oscillators under certain conditions,and can be solved exactly in terms of a displacing transformation, a beam-splitter-like transformation, and a squeezingtransformation. It is found that the system evolves by a rotated-squeezed-coherent state when the system is initially in acoherent state. Quantum dynamics of the Cooper pairs in the two superconducting islands are investigated. It is shownthat the number of the Cooper pairs in the two islands evolves periodically.展开更多
基金the National Natural Science Foundation of China the Natural Science Foundation of Fujian Provincea key project from the Chinese Academic of Sciences.
文摘The hydrothermal reaction of ZnO, H3PO4(85%), (H2NCH2CH2)2NH and H2pydc results in the formation of a discrete mononuclear zinc(II) complex Zn(Hpydc)2(H2O). It crystallizes in monoclinic space group C2/c with a = 17.9947(8), b = 7.1875(3), c = 12.5895(4) , b = 110.802(2), V = 1522.14(10) 3, Z = 4, Mr = 415.61, (C14H10N2O9Zn), Dc = 1.814g/cm3, = 16.71cm-1, F(000) = 840, R = 0.0505, wR = 0.1144. Each zinc(II) is coordinated to two nitrogen and three oxygen atoms of which two nitrogen and two oxygen atoms are from two pydc ligands, and one oxygen atom from the coordinated water molecule to form an irregular polyhedral geometry. The complex is linked further into a three-dimensional structure through the weak interactions of hydrogen bonds between the two oxygen atoms. IR spectrum of the complex is also discussed.
文摘In this paper, we consider a system consisting of two capacitively coupled superconducting islands viaJosephson junctions. We show that it can be reduced to two coupling harmonic oscillators under certain conditions,and can be solved exactly in terms of a displacing transformation, a beam-splitter-like transformation, and a squeezingtransformation. It is found that the system evolves by a rotated-squeezed-coherent state when the system is initially in acoherent state. Quantum dynamics of the Cooper pairs in the two superconducting islands are investigated. It is shownthat the number of the Cooper pairs in the two islands evolves periodically.
