Roof disaster has always been an important factor restricting coal mine safety production.Acidic effect can reform the rock mass structure to weaken the macroscopic strength characteristics,which is an effective way t...Roof disaster has always been an important factor restricting coal mine safety production.Acidic effect can reform the rock mass structure to weaken the macroscopic strength characteristics,which is an effective way to control the hard limestone roof.In this study,the effects of various factors on the reaction characteristics and mechanical properties of limestone were analyzed.The results show that the acid with stronger hydrogen production capacity after ionization(pK_(a)<0)has more prominent damage to the mineral grains of limestone.When pKa increases from−8.00 to 15.70,uniaxial compressive strength and elastic modulus of limestone increase by 117.22%and 75.98%.The influence of acid concentration is manifested in the dissolution behavior of mineral crystals,the crystal defects caused by large-scale acid action will lead to the deterioration of limestone strength,and the strength after 15%concentration reformation can be reduced by 59.42%.The effect of acidification time on limestone has stages and is the most obvious in the initial metathesis reaction stage(within 60 min).The key to the strength damage of acidified limestone is the participation of hydrogen ions in the reaction system.Based on the analytic hierarchy process method,the influence weights of acid type,acid concentration and acidification time on strength are 24.30%,59.54% and 16.16%,respectively.The research results provide theoretical support for the acidification control of hard limestone roofs in coal mines.展开更多
Due to inadequate bearing capacity of the chemically-planted steel bar in low-strength concrete, a new mixed post-installed connection is proposed using small diameter anchoring steel bars and grouting materials toget...Due to inadequate bearing capacity of the chemically-planted steel bar in low-strength concrete, a new mixed post-installed connection is proposed using small diameter anchoring steel bars and grouting materials together to anchor the main steel bar. To investigate the feasibility of the proposed post-installed connections, a series of pull-out tests with different anchors were conducted for comparison,including fully adhesive anchors, partially adhesive anchors,grouting material anchoring connection and the new mixed post-installed connection. The experimental results of the single steel bar pull-out test show that the mixed post-installed connection can effectively enhance the bearing capacity of post-installed steel bars in low-strength concrete. The bearing capacity is increased by nearly two times with no cone-type concrete failure compared with the fully adhesive anchor. The results show that adopting the new mixed post-installed connection can ensure that joint performance meets the requirements if the space dimension is available.展开更多
Through the research on stress metamorphism character of the II1 coal seam in Ludian gliding structure, the stress effecting factors of metamorphism and hydrocarbon generation process of tectonic coal were studied. It...Through the research on stress metamorphism character of the II1 coal seam in Ludian gliding structure, the stress effecting factors of metamorphism and hydrocarbon generation process of tectonic coal were studied. It is shown that different tectonic stress has different coal evolution effects. Compared with tensional stress, compressive stress, which has apparent anisotropic characteristics, has greater stimulative effect against the increase of coal metamorphic degree, the abscission of functional group and side chains of basic structural unit, and the formation of gas primarily composed of methane.展开更多
Zircon LA-ICP-MS U-Pb dating of the Jingju syenogranites in the southwestern part of Zhejiang Province shows that these rocks were crystallized in the Late Triassic at 215±2 Ma, rather than in the Cretaceous as p...Zircon LA-ICP-MS U-Pb dating of the Jingju syenogranites in the southwestern part of Zhejiang Province shows that these rocks were crystallized in the Late Triassic at 215±2 Ma, rather than in the Cretaceous as previously proposed. The Jingju sy- enogranites are characterized by relatively high K2O and FeO*, and low MgO. They have high concentrations of large ion lithophile elements (LIL) and LREE, such as K, Th, La, and Ce, but are depleted in high field strength elements (HFSE) such as Nb, Ta, and Ti. Their 104Ga/A1 ratios and (Zr+Nb+Ce+Y) contents are also high. These characteristics are similar to those of A-type granites. The syenogranites have high Isr (0.7179-0.7203), low eNa(t) (from --14.2 to --13.2), and relatively old T2DM ages, similar to those of the ancient metamorphic basement in the Cathaysia Block. It is suggested that the Jingju syenogranites were formed by partial melting of the Cathaysia basement rocks during tectonic extension. This identification of Indosinian A-type granite in Jingju has significant implications for understanding the early Mesozoic tectonic evolution of South China.展开更多
基金Project(2021YFC2902102)supported by the National Key Research and Development Program of ChinaProject(52374142)supported by the National Natural Science Foundation of ChinaProject(JSTU-2022-066)supported by the Young Talent Support Project of Jiangsu Association for Science and Technology,China。
文摘Roof disaster has always been an important factor restricting coal mine safety production.Acidic effect can reform the rock mass structure to weaken the macroscopic strength characteristics,which is an effective way to control the hard limestone roof.In this study,the effects of various factors on the reaction characteristics and mechanical properties of limestone were analyzed.The results show that the acid with stronger hydrogen production capacity after ionization(pK_(a)<0)has more prominent damage to the mineral grains of limestone.When pKa increases from−8.00 to 15.70,uniaxial compressive strength and elastic modulus of limestone increase by 117.22%and 75.98%.The influence of acid concentration is manifested in the dissolution behavior of mineral crystals,the crystal defects caused by large-scale acid action will lead to the deterioration of limestone strength,and the strength after 15%concentration reformation can be reduced by 59.42%.The effect of acidification time on limestone has stages and is the most obvious in the initial metathesis reaction stage(within 60 min).The key to the strength damage of acidified limestone is the participation of hydrogen ions in the reaction system.Based on the analytic hierarchy process method,the influence weights of acid type,acid concentration and acidification time on strength are 24.30%,59.54% and 16.16%,respectively.The research results provide theoretical support for the acidification control of hard limestone roofs in coal mines.
基金The National Natural Science Foundation of China(No.51409084)the Natural Science Foundation of Jiangsu Province(No.BK20130836)
文摘Due to inadequate bearing capacity of the chemically-planted steel bar in low-strength concrete, a new mixed post-installed connection is proposed using small diameter anchoring steel bars and grouting materials together to anchor the main steel bar. To investigate the feasibility of the proposed post-installed connections, a series of pull-out tests with different anchors were conducted for comparison,including fully adhesive anchors, partially adhesive anchors,grouting material anchoring connection and the new mixed post-installed connection. The experimental results of the single steel bar pull-out test show that the mixed post-installed connection can effectively enhance the bearing capacity of post-installed steel bars in low-strength concrete. The bearing capacity is increased by nearly two times with no cone-type concrete failure compared with the fully adhesive anchor. The results show that adopting the new mixed post-installed connection can ensure that joint performance meets the requirements if the space dimension is available.
文摘Through the research on stress metamorphism character of the II1 coal seam in Ludian gliding structure, the stress effecting factors of metamorphism and hydrocarbon generation process of tectonic coal were studied. It is shown that different tectonic stress has different coal evolution effects. Compared with tensional stress, compressive stress, which has apparent anisotropic characteristics, has greater stimulative effect against the increase of coal metamorphic degree, the abscission of functional group and side chains of basic structural unit, and the formation of gas primarily composed of methane.
基金supported by Ministry of Science and Technology of China (Grant No. 2007DFA21230)Natural Science Foundation of Hubei Province (Grant No. 2009CDA004)+2 种基金National Natural Science Foundation of China (Grant Nos. 40821061, 40334037)Ministry Education of China, State Administration of Foreign Expert Affairs of China (Grant No. B07039)Survey and Assessment of Geology and Mineral Resources (Grant No. B[2010]AMR01-17-05)
文摘Zircon LA-ICP-MS U-Pb dating of the Jingju syenogranites in the southwestern part of Zhejiang Province shows that these rocks were crystallized in the Late Triassic at 215±2 Ma, rather than in the Cretaceous as previously proposed. The Jingju sy- enogranites are characterized by relatively high K2O and FeO*, and low MgO. They have high concentrations of large ion lithophile elements (LIL) and LREE, such as K, Th, La, and Ce, but are depleted in high field strength elements (HFSE) such as Nb, Ta, and Ti. Their 104Ga/A1 ratios and (Zr+Nb+Ce+Y) contents are also high. These characteristics are similar to those of A-type granites. The syenogranites have high Isr (0.7179-0.7203), low eNa(t) (from --14.2 to --13.2), and relatively old T2DM ages, similar to those of the ancient metamorphic basement in the Cathaysia Block. It is suggested that the Jingju syenogranites were formed by partial melting of the Cathaysia basement rocks during tectonic extension. This identification of Indosinian A-type granite in Jingju has significant implications for understanding the early Mesozoic tectonic evolution of South China.