There are many automatic organization phenomena and automatic organization unities in the universe. The automatic organization whole refers to a life body with the thinking. The thinking is the core of automatic organ...There are many automatic organization phenomena and automatic organization unities in the universe. The automatic organization whole refers to a life body with the thinking. The thinking is the core of automatic organization. The thinking is at eternal restless motion and binds to substances. The universe, organism and society are the automatic organization unities or life systems with the thinking. The thinking can perceive, attract, drive, organize and control all individuals and it is a force of life structure or universal gravitation and universal repulsion. The thinking has a life structure, a template and dynamic of entity-life＇s automatic organization. Life body has five dynamic systems： the thinking motion and information flow, breathing motion, closed-loop current （particle flow） and energy flow, interaction among state-varying, state-stabilizing and control organizations and active ＆ automatic chemical-physical reactions, cardiac pulsation and active motion and transportation. Human, galaxies and society can change from low to high energy state initiatively. This is realized by controlling the desires of life entity via the thinking and breathing motions and by altering the body＇s binding forces dominating the life entity （in turn, by bond force, strong interaction and quark confinement）. All forces in the universe present in the universe of life： force of the thinking-universal gravitation and universal repulsion, electromagnetic interaction, bond force, strong interaction, quark confinement and weak interaction. Under the automatic organization of the thinking, these forces bind into a 4-season＇ whole. The united state of these forces is controlled by the thinking and breathing motion, which is capable of changing from 3-, 2- and 1-dimensional states to a 0-dimensional state.展开更多
Boosting the alkaline hydrogen evolution and oxidation reaction(HER/HOR)kinetics is vital to practicing the renewable hydrogen cycle in alkaline media.Recently,intensive research has demonstrated that interface engine...Boosting the alkaline hydrogen evolution and oxidation reaction(HER/HOR)kinetics is vital to practicing the renewable hydrogen cycle in alkaline media.Recently,intensive research has demonstrated that interface engineering is of critical significance for improving the performance of heterostructured electrocatalysts particularly toward the electrochemical reactions involving multiple reaction intermediates like alkaline hydrogen electrocatalysis,and the research advances also bring substantial non-trivial fundamental insights accordingly.Herein,we review the current status of interface engineering with respect to developing efficient heterostructured electrocatalysts for alkaline HER and HOR.Two major subjects—how interface engineering promotes the reaction kinetics and what fundamental insights interface engineering has brought into alkaline HER and HOR—are discussed.Specifically,heterostructured electrocatalysts with abundant interfaces have shown substantially accelerated alkaline hydrogen electrocatalysis kinetics owing to the synergistic effect from different components,which could balance the adsorption/desorption behaviors of the intermediates at the interfaces.Meanwhile,interface engineering can effectively tune the electronic structures of the active sites via electronic interaction,interfacial bonding,and lattice strain,which would appropriately optimize the binding energy of targeted intermediates like hydrogen.Furthermore,the confinement effect is critical for delivering high durability by sustaining high density of active sites.At last,our own perspectives on the challenges and opportunities toward developing efficient heterostructured electrocatalysts for alkaline hydrogen electrocatalysis are provided.展开更多
We present a facile and controllable method for the large-scale fabrication of highly-ordered octahedral Fe3O4 colloidal ＂single crystals＂ without the assistance of a substrate. Oleic acid is used to reduce the solu...We present a facile and controllable method for the large-scale fabrication of highly-ordered octahedral Fe3O4 colloidal ＂single crystals＂ without the assistance of a substrate. Oleic acid is used to reduce the solubility of the nano-building blocks in colloidal solution and to induce a ＂crystallization＂ process. Our colloidal crystals are of multimicron size and show typical crystallographic characteristics. They have a very robust structure and can serve as a novel ordered magnetic mesoporous material with a relatively narrow pore size distribution. The sample possesses an extremely high Verwey transition temperature （Tv） of 100 K and a high saturation magnetization （Ms） of 86 emu/g at 5 K based on its good crystallinity, as well as the interparticle dipolar interaction behavior arising from its unique structure. Electrochemical measurements have demonstrated the excellent capacity of the mesoporous colloidal crystals when used in lithium-ion batteries.展开更多
文摘There are many automatic organization phenomena and automatic organization unities in the universe. The automatic organization whole refers to a life body with the thinking. The thinking is the core of automatic organization. The thinking is at eternal restless motion and binds to substances. The universe, organism and society are the automatic organization unities or life systems with the thinking. The thinking can perceive, attract, drive, organize and control all individuals and it is a force of life structure or universal gravitation and universal repulsion. The thinking has a life structure, a template and dynamic of entity-life＇s automatic organization. Life body has five dynamic systems： the thinking motion and information flow, breathing motion, closed-loop current （particle flow） and energy flow, interaction among state-varying, state-stabilizing and control organizations and active ＆ automatic chemical-physical reactions, cardiac pulsation and active motion and transportation. Human, galaxies and society can change from low to high energy state initiatively. This is realized by controlling the desires of life entity via the thinking and breathing motions and by altering the body＇s binding forces dominating the life entity （in turn, by bond force, strong interaction and quark confinement）. All forces in the universe present in the universe of life： force of the thinking-universal gravitation and universal repulsion, electromagnetic interaction, bond force, strong interaction, quark confinement and weak interaction. Under the automatic organization of the thinking, these forces bind into a 4-season＇ whole. The united state of these forces is controlled by the thinking and breathing motion, which is capable of changing from 3-, 2- and 1-dimensional states to a 0-dimensional state.
基金funding support from “Hundred Talents Program” of Zhejiang University, Chinapartially supported by the Australian Research Council (ARC) Discovery Project (DP200100365)
文摘Boosting the alkaline hydrogen evolution and oxidation reaction(HER/HOR)kinetics is vital to practicing the renewable hydrogen cycle in alkaline media.Recently,intensive research has demonstrated that interface engineering is of critical significance for improving the performance of heterostructured electrocatalysts particularly toward the electrochemical reactions involving multiple reaction intermediates like alkaline hydrogen electrocatalysis,and the research advances also bring substantial non-trivial fundamental insights accordingly.Herein,we review the current status of interface engineering with respect to developing efficient heterostructured electrocatalysts for alkaline HER and HOR.Two major subjects—how interface engineering promotes the reaction kinetics and what fundamental insights interface engineering has brought into alkaline HER and HOR—are discussed.Specifically,heterostructured electrocatalysts with abundant interfaces have shown substantially accelerated alkaline hydrogen electrocatalysis kinetics owing to the synergistic effect from different components,which could balance the adsorption/desorption behaviors of the intermediates at the interfaces.Meanwhile,interface engineering can effectively tune the electronic structures of the active sites via electronic interaction,interfacial bonding,and lattice strain,which would appropriately optimize the binding energy of targeted intermediates like hydrogen.Furthermore,the confinement effect is critical for delivering high durability by sustaining high density of active sites.At last,our own perspectives on the challenges and opportunities toward developing efficient heterostructured electrocatalysts for alkaline hydrogen electrocatalysis are provided.
文摘We present a facile and controllable method for the large-scale fabrication of highly-ordered octahedral Fe3O4 colloidal ＂single crystals＂ without the assistance of a substrate. Oleic acid is used to reduce the solubility of the nano-building blocks in colloidal solution and to induce a ＂crystallization＂ process. Our colloidal crystals are of multimicron size and show typical crystallographic characteristics. They have a very robust structure and can serve as a novel ordered magnetic mesoporous material with a relatively narrow pore size distribution. The sample possesses an extremely high Verwey transition temperature （Tv） of 100 K and a high saturation magnetization （Ms） of 86 emu/g at 5 K based on its good crystallinity, as well as the interparticle dipolar interaction behavior arising from its unique structure. Electrochemical measurements have demonstrated the excellent capacity of the mesoporous colloidal crystals when used in lithium-ion batteries.
