The electrochemical oxidation of galena in collectorless and collector flotation systems, particularly in strong alkaline media, was studied. The results show that, with pH value higher than 12.5 and potentials below ...The electrochemical oxidation of galena in collectorless and collector flotation systems, particularly in strong alkaline media, was studied. The results show that, with pH value higher than 12.5 and potentials below 0.17 V, the oxidation products of galena are elemental sulfur and HPbO - 2. Elemental sulfur was present on the mineral surface in excess of oxidized lead species due to dissolution of HPbO - 2, which is beneficial to the flotation of galena. Under the same conditions, sphalerite and pyrite were depressed as a result of significant surface oxidation. Diethyldithiocarbamate (DDTC) was found to be the most suitable collector for galena flotation in strongly alkaline media. The very potential produced hydrophobic PbD 2-the surface reaction product of DDTC with galena, is 0 to 0.2 V. Meantime DDTC can depress the surface over oxidation of galena. Investigations also indicate that, in the range of -0.9 V to 0.6 V, hydrophobic PbD 2 can be firmly adsorbed on galena.展开更多
Sixteen controlled low-strength material( CLSM)mixtures with various cement-to-sand( C/Sa) ratios and water-to-solid( W/So) ratios were prepared using recycled fine aggregate from urban red brick based construction wa...Sixteen controlled low-strength material( CLSM)mixtures with various cement-to-sand( C/Sa) ratios and water-to-solid( W/So) ratios were prepared using recycled fine aggregate from urban red brick based construction waste.The fluidity and bleeding of the fresh CLSM mixtures were measured via the modified test methods, and the hardened CLSM mixtures were then molded to evaluate their compressive strength and durability. The results showthat the fluidity of the fresh CLSM mixtures is 105 to 227 mm with the corresponding bleeding rate of 3. 7% to 15. 5%, which increases with the increase in fluidity. After aging for 28 d,the compressive strength of the hardened CLSM mixtures reaches 1. 15 to 13. 96 M Pa, and their strength can be further enhanced with longer curing ages. Additionally, the strength increases with the increase of the C/Sa ratio, and decreases with the increase of the W/So ratio under the same curing age. Based on the obtained compressive strength, a fitting model for accurately predicting the compressive strength of the CLSM mixtures was established, which takes into account the above two independent variables( C/Sa and W/So ratios).M oreover, the durability of the hardened CLSM mixtures is enhanced for samples with higher C/Sa ratios.展开更多
In order to investigate the effectiveness of an orifice system in producing pressure drops and the effect of compressibility on the pressure drop, computations using the mass-averaged implicit Navier-Stokes equations ...In order to investigate the effectiveness of an orifice system in producing pressure drops and the effect of compressibility on the pressure drop, computations using the mass-averaged implicit Navier-Stokes equations were applied to the axisymmetric pipe flows with the operating pressure ratio from 1.5 to 20.0. The standard k- ε turbulence model was employed to close the governing equations. Numerical calculations were carried out for some combinations of the multiple orifice configurations. The present CFD data showed that the orifice systems, which have been applied to incompressible flow regime to date, could not be used for the high operating pressure ratio flows. The orifice interval did not strongly affect the total pressure drop, but the orifice area ratio more than 2.5 led to relatively high pressure drops. The total pressure drop rapidly increased in the range of the operating pressure ratio from 1.5 to 4.0, but it nearly did not increase when the operating pressure ratio was over 4.0. In the compressible pipe flows through double and triple orifice systems, the total pressure drop was largely due to shock losses.展开更多
文摘The electrochemical oxidation of galena in collectorless and collector flotation systems, particularly in strong alkaline media, was studied. The results show that, with pH value higher than 12.5 and potentials below 0.17 V, the oxidation products of galena are elemental sulfur and HPbO - 2. Elemental sulfur was present on the mineral surface in excess of oxidized lead species due to dissolution of HPbO - 2, which is beneficial to the flotation of galena. Under the same conditions, sphalerite and pyrite were depressed as a result of significant surface oxidation. Diethyldithiocarbamate (DDTC) was found to be the most suitable collector for galena flotation in strongly alkaline media. The very potential produced hydrophobic PbD 2-the surface reaction product of DDTC with galena, is 0 to 0.2 V. Meantime DDTC can depress the surface over oxidation of galena. Investigations also indicate that, in the range of -0.9 V to 0.6 V, hydrophobic PbD 2 can be firmly adsorbed on galena.
基金The National Science and Technology Support Program of China(No.2014BAC07B03)the Science and Technology Project of Transportation Committee of Beijing Government(No.2016-LZJKJ-01-006)the National Natural Science Foundation of China(No.51278016)
文摘Sixteen controlled low-strength material( CLSM)mixtures with various cement-to-sand( C/Sa) ratios and water-to-solid( W/So) ratios were prepared using recycled fine aggregate from urban red brick based construction waste.The fluidity and bleeding of the fresh CLSM mixtures were measured via the modified test methods, and the hardened CLSM mixtures were then molded to evaluate their compressive strength and durability. The results showthat the fluidity of the fresh CLSM mixtures is 105 to 227 mm with the corresponding bleeding rate of 3. 7% to 15. 5%, which increases with the increase in fluidity. After aging for 28 d,the compressive strength of the hardened CLSM mixtures reaches 1. 15 to 13. 96 M Pa, and their strength can be further enhanced with longer curing ages. Additionally, the strength increases with the increase of the C/Sa ratio, and decreases with the increase of the W/So ratio under the same curing age. Based on the obtained compressive strength, a fitting model for accurately predicting the compressive strength of the CLSM mixtures was established, which takes into account the above two independent variables( C/Sa and W/So ratios).M oreover, the durability of the hardened CLSM mixtures is enhanced for samples with higher C/Sa ratios.
文摘In order to investigate the effectiveness of an orifice system in producing pressure drops and the effect of compressibility on the pressure drop, computations using the mass-averaged implicit Navier-Stokes equations were applied to the axisymmetric pipe flows with the operating pressure ratio from 1.5 to 20.0. The standard k- ε turbulence model was employed to close the governing equations. Numerical calculations were carried out for some combinations of the multiple orifice configurations. The present CFD data showed that the orifice systems, which have been applied to incompressible flow regime to date, could not be used for the high operating pressure ratio flows. The orifice interval did not strongly affect the total pressure drop, but the orifice area ratio more than 2.5 led to relatively high pressure drops. The total pressure drop rapidly increased in the range of the operating pressure ratio from 1.5 to 4.0, but it nearly did not increase when the operating pressure ratio was over 4.0. In the compressible pipe flows through double and triple orifice systems, the total pressure drop was largely due to shock losses.
