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钴(Ⅱ)(C_(2v))配合物电子光谱的强场处理及AOM参量计算
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作者 张棣 豆育升 文振翼 《化学研究与应用》 CAS CSCD 1990年第2期66-71,共6页
应用强场近似拟合了10个假四面体Co(Ⅱ)(C_(2γ))配合物的配体独场光谱,由拟合得到的单电子矩阵元得到了各个配体的AOM参量。结果说明各配体的AOM参量同该配体与金属离子之间的配键强度相关。
关键词 强场处理 原子参量 配键
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Evading strength−ductility trade-off of GH605 alloy using magnetic field-assisted undercooling treatment
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作者 Yi-xuan HE Fan BU +6 位作者 Zhang-chi BIAN Ming-xiu XIANG Meng-meng ZHOU Xu-dong LIU Lei ZHU Jun WANG Jin-shan LI 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2024年第8期2575-2588,共14页
Undercooling solidification under a magnetic field(UMF)is an effective way to tailor the microstructure and properties of Co-based alloys.In this study,by attributing to the UMF treatment,the strength−ductility trade-... Undercooling solidification under a magnetic field(UMF)is an effective way to tailor the microstructure and properties of Co-based alloys.In this study,by attributing to the UMF treatment,the strength−ductility trade-off dilemma in GH605 superalloy is successfully overcome.The UMF treatment can effectively refine the grains and increase the solid solubility,leading to the high yield strength.The main deformation mechanism in the as-forged alloy is dislocation slipping.By contrast,multiple deformation mechanisms,including stacking faults,twining,dislocation slipping,and their strong interactions are activated in the UMF-treated sample during compression deformation,which enhances the strength and ductility simultaneously.In addition,the precipitation of hard Laves phases along the grain boundaries can be obtained after UMF treatment,hindering crack propagation during compression deformation. 展开更多
关键词 undercooling treatment magnetic field GH605 alloy strengthening mechanisms
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Effects of intense magnetic field on digestion and settling performances of bauxite 被引量:1
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作者 吕国志 张廷安 +4 位作者 王小晓 张旭华 刘燕 赵秋月 豆志河 《Journal of Central South University》 SCIE EI CAS 2014年第6期2168-2175,共8页
The effects of magnetic field intensity, roasting temperature and roasting time on digestion rate and settling performance of bauxite with different iron contents were investigated systematically. The results indicate... The effects of magnetic field intensity, roasting temperature and roasting time on digestion rate and settling performance of bauxite with different iron contents were investigated systematically. The results indicate that such magnetic treatment can profoundly change the microstructure and digestion performance of bauxite. For the two samples carrying different iron contents, phase transformation of the aluminum oxide phase proceeds faster in the high iron bauxite than the low one. The optimal pretreatment conditions of low iron bauxite are roasting temperature 550 ℃ and magnetic field intensity 6 T, while for high iron bauxite are 500 ℃ and 9 T. The digestion rate of alumina can reach 95% and 92% at digestion temperature of 190 ℃ and 250 ℃. The settling performances of roasted ore by intense magnetic field after digestion are enhanced through pretreatment. 展开更多
关键词 BAUXITE intense magnetic field phase transformation digestion performance settling performance
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