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强挥发性助燃剂在难燃地面材料燃烧痕迹特征研究 被引量:1
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作者 王俊 金静 《武警学院学报》 2017年第10期88-92,共5页
基于强挥发性助燃剂放火案件痕迹特征不显著、现场勘验困难的现状,选用酒精作为强挥发性助燃剂的代表,研究了其在阻燃橡胶和PVC地板革两种难燃地面材料的燃烧痕迹特征,探讨了酒精用量和灭火方式对燃烧痕迹的影响。制备的燃烧痕迹分为自... 基于强挥发性助燃剂放火案件痕迹特征不显著、现场勘验困难的现状,选用酒精作为强挥发性助燃剂的代表,研究了其在阻燃橡胶和PVC地板革两种难燃地面材料的燃烧痕迹特征,探讨了酒精用量和灭火方式对燃烧痕迹的影响。制备的燃烧痕迹分为自然熄灭与射水熄灭两类,对照组为报纸引燃地面材料。结果表明:酒精在阻燃橡胶与PVC地板革表面的燃烧痕迹以线状痕迹为主;酒精用量对燃烧痕迹的影响主要取决于材料自身性质;线状燃烧痕迹的稳定性强于炭化痕迹。 展开更多
关键词 强挥发性 助燃剂 燃烧痕迹 火灾调查
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甲醇等5种强极性有机物污染事故中的监测分析方法 被引量:3
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作者 魏子勇 段修宇 +1 位作者 曹方方 王述伟 《中国环境监测》 CAS CSCD 北大核心 2018年第4期118-123,共6页
建立了在突发性水污染事故中定量分析水样中甲醇、丙酮、乙腈、N,N-二甲基甲酰胺和N,N-二甲基乙酰胺等5种极性有机物的实验室和现场应急监测分析方法。采用顶空-车载气相色谱质谱法用于现场快速定性定量分析;顶空-气相色谱法用于实验室... 建立了在突发性水污染事故中定量分析水样中甲醇、丙酮、乙腈、N,N-二甲基甲酰胺和N,N-二甲基乙酰胺等5种极性有机物的实验室和现场应急监测分析方法。采用顶空-车载气相色谱质谱法用于现场快速定性定量分析;顶空-气相色谱法用于实验室准确定量分析。通过优化顶空及气相参数,在最佳实验条件下测得顶空-气相色谱质谱法中甲醇、丙酮、乙腈、N,N-二甲基甲酰胺、N,N-二甲基乙酰胺等5种化合物的检出限分别为1.0、0.06、0.5、10.0、15.0 mg/L,平行测定7次结果的相对标准偏差分别为2.1%~3.8%,加标回收率为69.4%~104%;顶空-气相色谱法灵敏度高于气相色谱质谱法,检出限分别为0.08、0.01、0.03、1.7、1.7 mg/L,平行测定7次结果的相对标准偏差分别为2.5%~4.1%,加标回收率为78.1%~116%。 展开更多
关键词 顶空 气相色谱质谱法 气相色谱法 发性水污染事故 极性挥发性有机物
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四氢呋喃废水的降解特性 被引量:6
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作者 王怡 彭党聪 《环境科学与技术》 CAS CSCD 2003年第B12期12-14,共3页
对医药及化工生产中含四氢呋喃废水近年来的大量出现,研究了四氢呋喃废水的生物降解特性。结果表明:厌氧单基质条件下,四氢呋喃对厌氧消化产生轻微的抑制作用,浓度达到200mg/L时,厌氧微生物受到明显抑制,产气量急剧减少。厌氧共基质条件... 对医药及化工生产中含四氢呋喃废水近年来的大量出现,研究了四氢呋喃废水的生物降解特性。结果表明:厌氧单基质条件下,四氢呋喃对厌氧消化产生轻微的抑制作用,浓度达到200mg/L时,厌氧微生物受到明显抑制,产气量急剧减少。厌氧共基质条件下,四氢呋喃浓度的增加反而有利于四氢呋喃的降解。四氢呋喃废水BOD5/COD为0.096,属好氧难降解污染物质,但其对好氧微生物无抑制,其原因在于四氢呋喃具有强的挥发性,曝气吹脱12h时COD去除率高达84%。 展开更多
关键词 四氢呋喃 厌氧降解特性 无好氧抑制 挥发性 曝气吹脱
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Process Intensification of VOC Removal from High Viscous Media by Rotating Packed Bed 被引量:9
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作者 李沃源 毋伟 +3 位作者 邹海魁 初广文 邵磊 陈建峰 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2009年第3期389-393,共5页
The removal of a volatile organic compound (VOC) from high viscous liquid was carried out in a rotat-ing packed bed (RPB) in this study. The mixed liquid of syrup and acetone was used as simulated high viscous polymer... The removal of a volatile organic compound (VOC) from high viscous liquid was carried out in a rotat-ing packed bed (RPB) in this study. The mixed liquid of syrup and acetone was used as simulated high viscous polymer solution with acetone as the volatile compound. The influence of the rotating speed of RPB, liquid viscos-ity, liquid flow rate, vacuum degree, and initial acetone content in the liquid on acetone removal efficiency was in-vestigated. The experimental results indicated that the removal efficiency increased with increasing rotating speed and initial acetone content in the viscous liquid and decreased with increasing liquid viscosity and flow rate. It was also observed that acetone removal efficiency increased with an increasing vacuum degree and reached 58% at a vacuum degree of 0.1 MPa. By the comparison with a flash tank devolatilizer, it was found that acetone removal ef-ficiency in RPB increased by about 67%. 展开更多
关键词 polymer devolatilization rotating packed bed high viscosity mass transfer volatile organic compound
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Enhanced Anaerobic Treatment of Textile Wastewater by Chemical Additive
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作者 Ton That Lang 《Journal of Environmental Science and Engineering(B)》 2016年第7期328-334,共7页
The textile processing plants utilize a wide variety of dyes and other chemicals such as acids, bases, salts, detergents, sizes, oxidants, mercerizing and finishing chemicals. Many of these are not retained in the fin... The textile processing plants utilize a wide variety of dyes and other chemicals such as acids, bases, salts, detergents, sizes, oxidants, mercerizing and finishing chemicals. Many of these are not retained in the final product and are discharged in the effluent. Therefore, the objective of this study was to assess the performance of Expanded Granular Sludge Bed (EGSB) reactor to treat synthetic textile wastewater. Several experiments using Direct Red 81 and volatile fatty acids as model substrates were conducted. The problems of decolorization was evaluated at a variety of relevant operational conditions, such as substrate concentration, organic and hydraulic loading rates. The results showed that retention time of EGSB equals 1.6 h and 80 mg/L at the hydraulic and dye concentration respectively, and that the color removal efficiency can reach 90%. Additionally, some chemical additions were proposed to improve the decolorization rate and increase the treatment efficiency of the system. For instance, sulfide was added at 200 mg/L in the influent, which can increase the dye removal efficiency to 95%. 展开更多
关键词 Dye removal textile wastewater EGSB.
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氯化氢合成工艺环保优化改进
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作者 李得占 徐得禄 《中文科技期刊数据库(文摘版)工程技术》 2021年第5期269-269,271,共2页
2016年习近平总书记视察青海盐湖时,强调在保护生态环境的前提下搞好开发利用。同时,青海盐湖元品化工有限责任公司(以下简称“元品化工公司”)紧盯“生态镁锂钾园”战略,打造绿色矿山。在此背景下,元品化工公司氯碱工艺中废气的回收与... 2016年习近平总书记视察青海盐湖时,强调在保护生态环境的前提下搞好开发利用。同时,青海盐湖元品化工有限责任公司(以下简称“元品化工公司”)紧盯“生态镁锂钾园”战略,打造绿色矿山。在此背景下,元品化工公司氯碱工艺中废气的回收与治理技术也要朝着这个方向发展。元品化工公司氯碱厂二期10万t/a离子膜电解装置,其中氯化氢合成工艺原设计盐酸储槽放空管道均直排至大气,该设计存在安全和环保缺陷,放空管道均直排至大气,对环境造成污染,不符合当下安全环保和生态环保要求,并且极易造成各盐酸槽氢气富集造成爆炸事故。通过改造将放空管线引入吸收系统再次吸收后排空,对储槽进行连续氮气置换防止氢气富集。 展开更多
关键词 环保 缺陷 氢气富集 挥发性腐蚀性 氯化氢排空 改造
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Technological Feasibility of Biodiesel Production from Bioaugmented Hydrolysate of Waste Sludge in a Municipal Wastewater Treatment Plant
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作者 王怡 赵景婵 +3 位作者 曲鹏程 张百鑫 彭党聪 夏四清 《Transactions of Tianjin University》 EI CAS 2013年第5期332-337,共6页
The hydrolysate of waste sludge was used as the feedstock of biodiesel production,and its technological feasibility was investigated.Waste sludge,collected from No.3 Municipal Wastewater Treatment Plant of Xi’an,was ... The hydrolysate of waste sludge was used as the feedstock of biodiesel production,and its technological feasibility was investigated.Waste sludge,collected from No.3 Municipal Wastewater Treatment Plant of Xi’an,was hydrolyzed in two parallel reactors firstly.Yeast was added into one reactor for bioaugmentation,and the other reactor without yeast was used as a control.Then an acid-catalyzed in situ esterification process was carried out to convert the hydrolysate to biodiesel.The results of hydrolysis showed that the reactor bioaugmented with yeast could promote hydrolysis compared with the control one because of an obvious variance in total suspended solid(TSS),volatile suspended solid(VSS)and soluble chemical oxygen demand(SCOD).Furthermore,gas chromatography(GC)analysis exhibited that the total volatile fatty acid(VFA)was low in the hydrolysate of bioaugmentation reactor;however,its yield of the fatty acid methyl esters(FAMEs)by in situ esterification was obviously higher when compared with the control one.Therefore,it may be inferred that the hydrolysate of bioaugmentation was mainly inclined to longer-chain fatty acid rather than to VFA.Anyway,an FAMEs yield of 9.24%(wt%)from dried sludge was attained after the 12-d bioaugmentation hydrolysis and succedent esterification.This value was not only higher than that of the control one but also higher than that reported in previous literature.The above results illuminated that it was feasible to produce biodiesel from the bioaugmented hydrolysate of waste sludge. 展开更多
关键词 waste sludge HYDROLYSIS BIOAUGMENTATION biodiesel production FEASIBILITY
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