The unsaturated undisturbed quaternary system middle pleistocene loess,a typical unsaturated soil,often occurs in the implementation of western development strategy.To obtain the shearing strength characteristics of t...The unsaturated undisturbed quaternary system middle pleistocene loess,a typical unsaturated soil,often occurs in the implementation of western development strategy.To obtain the shearing strength characteristics of this unsaturated undisturbed loess,based on the analysis of mineral composition,the triaxial shear test of undisturbed quaternary system middle pleistocene loess under different moisture contents is conducted with the specialized triaxial instrument for unsaturated soil.The test results show that the mainly mineral composition of undisturbed quaternary system middle pleistocene loess is quartz and albite.Under the same confining pressure,the matric suction increases with the decrease of moisture content.The smaller the moisture content,the larger the matric suction;the higher the moisture content,the lower the matric suction.Under the same moisture content,the matric suction increases with the confining pressure and reaches a maximum when the confining pressure is 100 kPa,and then decreases with the increase of confining pressure.This phenomenon is closely related to the grain contact tightness of soil mass under high confining pressure.According to the triaxial test of loess,the sample of loess experiences 4 stages from loading to failure:1) compaction stage;2) compression stage;3) microcrack developing stage;4) shear failure stage.The test sample is of brittle failure(weak softening)under low moisture content and confining pressure.With the decrease of matric suction and the increase of consolidated confining pressure,the stress-strain curve changes from softening type to ideal plastic type.In the shearing strength parameters of unsaturated undisturbed loess,the influence of moisture content on internal friction angle is small,but that on cohesive force is obvious.Therefore,the shearing strength of unsaturated undisturbed loess is higher than that of saturated undisturbed loess and varies with the moisture content.展开更多
Based on the Danckwerts surface renewal model, a simple explicit expression of the enhancement factor in ozone absorption with a first order ozone self-decomposition and parallel second order ozonation reactions has b...Based on the Danckwerts surface renewal model, a simple explicit expression of the enhancement factor in ozone absorption with a first order ozone self-decomposition and parallel second order ozonation reactions has been derived. The results are compared with our previous work based on the film theory. The 2,4-dichlorophenol destruction rate by ozonation is predicted using the enhancement factor model in this paper.展开更多
基金Project(51108485)supported by the National Natural Science Foundation of ChinaProject(20110191120033)supported by the Specialized Research Fund for the Doctoral Program of Higher Education of China+1 种基金Projects(106112013CDJZR200001,CDJZR12200012)supported by the Fundamental Research Funds for the Central Universities,ChinaProject(cstc2013jcyjA30005)supported by the Natural Science Foundation of Chongqing,China
文摘The unsaturated undisturbed quaternary system middle pleistocene loess,a typical unsaturated soil,often occurs in the implementation of western development strategy.To obtain the shearing strength characteristics of this unsaturated undisturbed loess,based on the analysis of mineral composition,the triaxial shear test of undisturbed quaternary system middle pleistocene loess under different moisture contents is conducted with the specialized triaxial instrument for unsaturated soil.The test results show that the mainly mineral composition of undisturbed quaternary system middle pleistocene loess is quartz and albite.Under the same confining pressure,the matric suction increases with the decrease of moisture content.The smaller the moisture content,the larger the matric suction;the higher the moisture content,the lower the matric suction.Under the same moisture content,the matric suction increases with the confining pressure and reaches a maximum when the confining pressure is 100 kPa,and then decreases with the increase of confining pressure.This phenomenon is closely related to the grain contact tightness of soil mass under high confining pressure.According to the triaxial test of loess,the sample of loess experiences 4 stages from loading to failure:1) compaction stage;2) compression stage;3) microcrack developing stage;4) shear failure stage.The test sample is of brittle failure(weak softening)under low moisture content and confining pressure.With the decrease of matric suction and the increase of consolidated confining pressure,the stress-strain curve changes from softening type to ideal plastic type.In the shearing strength parameters of unsaturated undisturbed loess,the influence of moisture content on internal friction angle is small,but that on cohesive force is obvious.Therefore,the shearing strength of unsaturated undisturbed loess is higher than that of saturated undisturbed loess and varies with the moisture content.
基金Supported by the China Scholarship Council and Guangdong Provincial Natural Science Foundation of China(No.950215).
文摘Based on the Danckwerts surface renewal model, a simple explicit expression of the enhancement factor in ozone absorption with a first order ozone self-decomposition and parallel second order ozonation reactions has been derived. The results are compared with our previous work based on the film theory. The 2,4-dichlorophenol destruction rate by ozonation is predicted using the enhancement factor model in this paper.
