The 7xxx series alloys are heat treatable wrought aluminium alloys based on the Al-Zn-Mg(-Cu) system. They are widely used in high-performance structural aerospace and transportation applications. Apart from composi...The 7xxx series alloys are heat treatable wrought aluminium alloys based on the Al-Zn-Mg(-Cu) system. They are widely used in high-performance structural aerospace and transportation applications. Apart from compositional, casting and thermo-mechanical processing effects, the balance of properties is also significantly influenced by the way in which the materials are heat-treated. This paper describes the effects of homogenisation, solution treatment, quenching and ageing treatments on the evolution of the microstructure and properties of some important medium to high-strength 7xxx alloys. With a focus on recent work at Monash University, where the whole processing route from homogenisation to final ageing has been studied for thick plate products, it is reported how microstructural features such as dispersoids, coarse constituent particles, fine-scale precipitates, grain structure and grain boundary characteristics can be controlled by heat treatment to achieve improved microstructure-property combinations. In particular, the paper presents methods for dissolving unwanted coarse constituent particles by controlled high- temperature treatments, quench sensitivity evaluations based on a systematic study of continuous cooling precipitation behaviour, and ageing investigations of one-, two- and three-step ageing treatments using experimental and modelling approaches, in each case, the effects on both the microstructure and the resulting properties are discussed.展开更多
Metallic glasses(MGs)constitute an emerging class of advanced structural materials due to their excellent mechanical properties.However,brittle failure at room temperature and the resultant complicated fracture behavi...Metallic glasses(MGs)constitute an emerging class of advanced structural materials due to their excellent mechanical properties.However,brittle failure at room temperature and the resultant complicated fracture behavior greatly limit their wide engineering applications.Over the past decades,the deformation and fracture in ductile or brittle mode referring to material compositions,load conditions,sample size,etc.,have been widely studied,and significant progress has been made in understanding the failure behavior of MGs.Micromechanisms of fracture have been revealed involving shear banding,cavitation and the nature of the crack tip field.The ductile-to-brittle transition and inherent governing parameters have been found.To well describe and predict the failure behavior of MGs,failure criteria for ductile and brittle MGs have been established empirically or based on atomic interactions.In this paper,we provide a detailed review of the above advances and identify outstanding issues in the failure of MGs that need to be further clarified.展开更多
Research on structure of tectonically deformed coals(TDC) is a key issue in coal and gas outburst prevention and coalbed methane(CBM) exploitation.This paper presents a summary on the research progress in TDC's st...Research on structure of tectonically deformed coals(TDC) is a key issue in coal and gas outburst prevention and coalbed methane(CBM) exploitation.This paper presents a summary on the research progress in TDC's structural-genetic classification,tectonic strain influence on coal microstructure,coal porosity system,coal chemical structure and constituents,and their relationship with the excess coalbed methane.Previous studies suggested that tectonic deformation had significant influence on coal microstructure,coal super microstructure,and even chemical macromolecular structure.The main mechanisms of coal deformation are the tectonic stress degradation and polycondensation metamorphism(dynamical metamorphism).Besides,under different deformation mechanisms,the ultra-and micro-structure and chemical constituents of TDC presented distinct characteristics.Based on these achievements,we propose one possible evolutionary trend of TDC with different deformation mechanisms,and suggest that the coal and gas outburst in the TDC,especially in the mylonitic coals,may be not only controlled by geological structure,but also influenced by the tectonic stress degradation of ductile deformation.Therefore,further study on TDC should be focused on the controlling mechanism of deformation on structure and composition of coal,generation conditions and occurrence state of excess coalbed methane from deformation mechanism of coal.展开更多
The influence of pre-deformation on phase transformations,microstructures and hardening response in nearβTi alloy Ti5Al-3Mo-3V-2Cr-2Zr-1Nb-1Fe(wt%)during aging treatment was studied.The results show that obviousαpha...The influence of pre-deformation on phase transformations,microstructures and hardening response in nearβTi alloy Ti5Al-3Mo-3V-2Cr-2Zr-1Nb-1Fe(wt%)during aging treatment was studied.The results show that obviousαphase refinement and stronger age hardening effect can be achieved when the alloy is slightly deformed before aging treatment.Because the formation of intermediate phases(O′,ωand O′′)suppresses long-range stress induced martensitic transformation and mechanical twinning,the alloy is mainly deformed via dislocation slipping during loading.Large numbers of crystal defects are generated during predeformation.With increasing the predeformation,the number density of dislocations increases gradually.These crystal defects generated by pre-deformation may partly annihilate upon early aging,but the precipitation ofαcan also be promoted,resulting in refinedαprecipitates.In the sample with 5%pre-strain,the average thickness ofαprecipitates decreases by 57%after aging at 600℃ compared with the sample without pre-strain,and the number density increases from 7.0±1 laths/μm^(2)to 22.0±3 laths/μm^(2).Some platelet-shapedαphases form when the samples experience comparably large pre-strains such as 12%and 20%.It proves that the refinedαprecipitates and better hardening effect can be achieved by pre-deformation plus aging treatment for titanium alloy.展开更多
基金The Aluminium Corporation of China Ltd.(Chalco)for supporting aspects of this work financiallyproviding AA7150 materials as part of the Australia-China International Centre for Light Alloy Research(ICLAR)+1 种基金Monash University for developing the retrogression and reageing Matlab model (as part of the PhD project of Dr Adrian GROSVENOR)The ARC Centre of Excellence for Design in Light Metals and its Directors (first Prof Barry MUDDLE and then Prof Xin-hua WU) for supporting
文摘The 7xxx series alloys are heat treatable wrought aluminium alloys based on the Al-Zn-Mg(-Cu) system. They are widely used in high-performance structural aerospace and transportation applications. Apart from compositional, casting and thermo-mechanical processing effects, the balance of properties is also significantly influenced by the way in which the materials are heat-treated. This paper describes the effects of homogenisation, solution treatment, quenching and ageing treatments on the evolution of the microstructure and properties of some important medium to high-strength 7xxx alloys. With a focus on recent work at Monash University, where the whole processing route from homogenisation to final ageing has been studied for thick plate products, it is reported how microstructural features such as dispersoids, coarse constituent particles, fine-scale precipitates, grain structure and grain boundary characteristics can be controlled by heat treatment to achieve improved microstructure-property combinations. In particular, the paper presents methods for dissolving unwanted coarse constituent particles by controlled high- temperature treatments, quench sensitivity evaluations based on a systematic study of continuous cooling precipitation behaviour, and ageing investigations of one-, two- and three-step ageing treatments using experimental and modelling approaches, in each case, the effects on both the microstructure and the resulting properties are discussed.
基金supported by the National Natural Science Foundation Basic Science Center Program for"Multiscale Problems in Nonlinear Mechanics"(Grant No.11988102)the National Natural Science Foundation of China(Grant Nos.11972346 and 11790292)+3 种基金the National Key Research and Development Program of China(Grant No.2017YFB0702003)the Strategic Priority Research Program(Grant Nos.XDB22040302 and XDB22040303)the Key Research Program of Frontier Sciences(Grant No.QYZDJSSW-JSC011)the Science Challenge Project(Grant No.TZ2018001).
文摘Metallic glasses(MGs)constitute an emerging class of advanced structural materials due to their excellent mechanical properties.However,brittle failure at room temperature and the resultant complicated fracture behavior greatly limit their wide engineering applications.Over the past decades,the deformation and fracture in ductile or brittle mode referring to material compositions,load conditions,sample size,etc.,have been widely studied,and significant progress has been made in understanding the failure behavior of MGs.Micromechanisms of fracture have been revealed involving shear banding,cavitation and the nature of the crack tip field.The ductile-to-brittle transition and inherent governing parameters have been found.To well describe and predict the failure behavior of MGs,failure criteria for ductile and brittle MGs have been established empirically or based on atomic interactions.In this paper,we provide a detailed review of the above advances and identify outstanding issues in the failure of MGs that need to be further clarified.
基金supported by National Natural Science Foundation of China (Grant Nos. 41030422,40972131,40940014)National Basic Research Program of China (Grant No. 2009CB219601)
文摘Research on structure of tectonically deformed coals(TDC) is a key issue in coal and gas outburst prevention and coalbed methane(CBM) exploitation.This paper presents a summary on the research progress in TDC's structural-genetic classification,tectonic strain influence on coal microstructure,coal porosity system,coal chemical structure and constituents,and their relationship with the excess coalbed methane.Previous studies suggested that tectonic deformation had significant influence on coal microstructure,coal super microstructure,and even chemical macromolecular structure.The main mechanisms of coal deformation are the tectonic stress degradation and polycondensation metamorphism(dynamical metamorphism).Besides,under different deformation mechanisms,the ultra-and micro-structure and chemical constituents of TDC presented distinct characteristics.Based on these achievements,we propose one possible evolutionary trend of TDC with different deformation mechanisms,and suggest that the coal and gas outburst in the TDC,especially in the mylonitic coals,may be not only controlled by geological structure,but also influenced by the tectonic stress degradation of ductile deformation.Therefore,further study on TDC should be focused on the controlling mechanism of deformation on structure and composition of coal,generation conditions and occurrence state of excess coalbed methane from deformation mechanism of coal.
基金Natural Science Foundation of Shandong Province(ZR2022QE115)Liaocheng City Key Research Plan(2022YDSF85)+4 种基金Liaocheng University Doctoral Initiation Fund(318052132)Liaocheng University Students Innovation Plan(CXCY2023029)National Natrual Science Foundation of China(51671012,51671007,52174346)International Science and Technology Cooperation Program of China(2015DFA51430)Aeronautical Science Foundation of China(2015ZF51069)。
文摘The influence of pre-deformation on phase transformations,microstructures and hardening response in nearβTi alloy Ti5Al-3Mo-3V-2Cr-2Zr-1Nb-1Fe(wt%)during aging treatment was studied.The results show that obviousαphase refinement and stronger age hardening effect can be achieved when the alloy is slightly deformed before aging treatment.Because the formation of intermediate phases(O′,ωand O′′)suppresses long-range stress induced martensitic transformation and mechanical twinning,the alloy is mainly deformed via dislocation slipping during loading.Large numbers of crystal defects are generated during predeformation.With increasing the predeformation,the number density of dislocations increases gradually.These crystal defects generated by pre-deformation may partly annihilate upon early aging,but the precipitation ofαcan also be promoted,resulting in refinedαprecipitates.In the sample with 5%pre-strain,the average thickness ofαprecipitates decreases by 57%after aging at 600℃ compared with the sample without pre-strain,and the number density increases from 7.0±1 laths/μm^(2)to 22.0±3 laths/μm^(2).Some platelet-shapedαphases form when the samples experience comparably large pre-strains such as 12%and 20%.It proves that the refinedαprecipitates and better hardening effect can be achieved by pre-deformation plus aging treatment for titanium alloy.